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Chapter 9 Orbitals and Covalent Bonds  pp
9.1 Atomic Orbitals Don’t Work ,[object Object],[object Object],[object Object],[object Object],[object Object]
Hybridization ,[object Object],[object Object],[object Object],[object Object]
Figure 9.3 p. 417
Fig. 9.3 p. 417 - Tetrahedral
Figure 9.3 p. 417 The Formation of  sp 3  Hybrid Orbitals
In terms of energy  (LD 2:6.65) Energy 2p 2s Hybridization sp 3
How we get to hybridization ,[object Object],[object Object],[object Object],[object Object],[object Object]
sp 3   geometry ,[object Object],[object Object],[object Object],109.5º
sp 2  hybridization ,[object Object],[object Object],[object Object],[object Object],[object Object]
sp 2  hybridization ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Figure 9.8, p. 419
Fig. 9.8 p. 419
Figure 9.8 The Hybridization of the  s ,  p x , and  p y  Atomic Orbitals
In terms of energy  (fig. 9.9 p. 419) Energy 2p 2s sp 2 Hybridization 2p
Where is the P orbital? ,[object Object],[object Object]
Two types of Bonds ,[object Object],[object Object],[object Object],[object Object],[object Object]
Fig. 9.13, p. 420 C C H H H H
What about two ,[object Object],[object Object],[object Object]
sp hybridization ,[object Object],[object Object],[object Object],[object Object]
Summary of sigma & pi bonds   pp ,[object Object],[object Object],[object Object],[object Object]
In terms of energy Energy 2p 2s Hybridization sp 2p
CO 2 ,[object Object],[object Object],C O O
N 2
N 2
Breaking the octet ,[object Object],[object Object],[object Object],[object Object]
dsp 3 ,[object Object],[object Object],[object Object],[object Object]
PCl 5 Can’t tell the hybridization of Cl Assume it’s sp 3  to  minimize  repulsion of electron  pairs .
d 2 sp 3 ,[object Object],[object Object]
Localized e- model:  Summary   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
p. 426 Figure 9.24 The Relationship of the Number of Effective Pairs, Their Spatial Arrangement, and the Hybrid Orbital Set Required (end 9.1) Effective pairs are also known as  RHED  (Regions of High Electron Density) - use for online HW
(Partial) 9.2 Bond Order ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
9.2 Molecular Orbital Model ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What do you get? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The Molecular Orbital Model ,[object Object],[object Object],[object Object],[object Object]
The Molecular Orbital Model ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The H 2  Molecular Orbital Model Energy MO 2 MO 1  s  s
The Molecular Orbital Model ,[object Object],[object Object],[object Object],[object Object],[object Object]
The Molecular Orbital Model ,[object Object],[object Object]
H 2 1-  ion Energy  1s  1s *  s  s
Molecular Orbital Summary   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Magnetism   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Bond Order   pp ,[object Object]
Bond Order   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Bond Order   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Molecular Orbitals  Part 2
More on M.O. Theory ,[object Object],[object Object],[object Object],[object Object],[object Object]
9.3 Bonding in Homonuclear Diatomic Molecules ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
B 2
B 2  2p *  2p  2p *  2p
Expected Energy Diagram Energy 2s 2s 2p 2p  2s  2p *  2p  2s *  2p *  2p *  2p  2p
B 2 Energy 2s 2s 2p 2p
B 2 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Magnetism ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Magnetism ,[object Object],[object Object],[object Object]
Correct energy diagram 2s 2s 2p 2p  2s  2p *  2p  2s *  2p *  2p *  2p  2p
B 2 2s 2s 2p 2p
Patterns ,[object Object],[object Object],[object Object],[object Object],[object Object]
Examples ,[object Object],[object Object],[object Object],[object Object],[object Object]
Finishing Chapter 9 Details, details, details
9.4 Heteronuclear Diatomic Species ,[object Object],[object Object],[object Object]
NO 2s 2s 2p 2p
You try ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
1s 2p  
Consequences ,[object Object],[object Object],[object Object],[object Object]
9.5 Names ,[object Object],[object Object],[object Object],[object Object],[object Object]
  delocalized bonding ,[object Object],H H H H H H H H H H H H
C 2 H 6
NO 3 -

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Ch9 z5e orbitals unhidden

Editor's Notes

  1. Section 9.1 Hybridization and the Localized e- model Z5e 415
  2. The 4 Hydrogen “s” orbital e- share with carbon’s 2s and its three 2p orbitals. The p orbitals are 90 degrees perpendicular in space along the x, y and z axis. So, would expect 90 degree bond angels. But, the bond angles are actually 109.5. So, the s and p orbitals must hybridize to something giving equal bond angles of 109.5 degrees.
  3. Fig 9.3 Z5e 417; 1st half
  4. Fig 9.3 Z5e 417; 2nd half
  5. Fig 9.3 Z5e 417
  6. Fig 9.5 Z5e 417 Hybridization is intermediate in energy
  7. Fig 9.8 1st half Z5e 419
  8. Fig 9.8 2nd half Z5e 419
  9. Fig 9.8 Z5e 419
  10. Fig 9.9 Z5e 419
  11. Figs 9.10 & 9.11 Z5e 420
  12. Fig. 9.13 Z5e 420 Note the sp 2 carbon orbitals with the 1s hydrogen orbitals
  13. Fig. 9.16 Z5e 421
  14. Z5e 420
  15. Z5e 422
  16. Z5e 423
  17. Fig 9.21 Z5e 423
  18. Although assume Cl is sp 3 , P is dsp 3
  19. Z5e 424
  20. Z5e 425
  21. Fig 9.24 Z5e 426
  22. Section 9.2 The Molecular Orbital Model; Z5e 428 Bond order is the important thing here for AP exam (a few MC questions)
  23. Z5e 429 Fig. 9.25 The combination of hydrogen 1 s atomic orbitals to form molecular orbitals.
  24. Z5e 429
  25. Z5e 430. The 1s on either side are the atomic orbitals in a free H atom.
  26. Z5e 431 Fig. 9.29. The molecular orbital energy-level diagram for the H 2 1- ion.
  27. Go to Web: http://learn.chem.vt.edu/tutorials/bonding/mo2.html (defunct?) Try http://www.wwnorton.com/chemistry/tutorials/ch6.htm
  28. Z5e 431
  29. Z5e 431
  30. Z5e 431
  31. Z5e section 9.3 Bonding in Homonuclear Diatomic Molecules
  32. Z5e 438 Section 9.4 Bonding in Heternoculear Diatomic Molecules
  33. Z5e 440. Section 9.5 Combining the Localized Electron and Molecular Orbital Models.