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Z7e Chapter 22 Organic Chemistry  pp 50 questions on online HW Stop whining! They’re not too hard (for me)
Z5e 22.1 Alkanes:  Saturated Hydrocarbons   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Tr 114 Methane - Tetrahedral sp 3  Structure
Tr 115 Bonding in Ethene & Ethyne
Isomers ,[object Object],[object Object],[object Object]
Examples of Isomers ,[object Object],[object Object],[object Object],[object Object],[object Object]
Structural  Isomers   pp ,[object Object],[object Object],[object Object]
Geometric Isomers   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Geometric  Isomers   pp ,[object Object],[object Object]
Geometric  Isomers of 1,2-dichloroethene ,[object Object],[object Object]
Geometric  Isomers of chloroethene?   pp ,[object Object],[object Object],[object Object]
Non geometric versions of 1,2-dichloroeth”ene”   pp ,[object Object],[object Object]
Z5e 22.1 Alkanes:  Saturated Hydrocarbons ,[object Object],[object Object],[object Object],[object Object]
Straight-Chain Alkanes ,[object Object],[object Object],[object Object]
Straight-Chain Alkanes ,[object Object],[object Object],[object Object]
Tr 115A Carbon-Atom Chain Prefixes
Tr 117 Some Alkanes
Straight-Chain Alkanes ,[object Object],[object Object],[object Object]
Tr 117A Straight-Chain Alkyl Groups How are alkyl groups different from their corresponding alkanes? They have one less hydrogen so they can bond to another atom. What would a nine-carbon alkyl group be called? Nonyl
Alkanes ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Complete Structural Formulas ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
More Alkanes ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Naming Straight-Chain Alkanes ,[object Object],[object Object],[object Object]
Naming Straight-Chain Alkanes ,[object Object],[object Object],[object Object]
Branched-Chain Alkanes ,[object Object],[object Object],[object Object]
Branched-Chain Alkanes ,[object Object],[object Object],[object Object]
Alkyl Groups ,[object Object],[object Object],[object Object]
Branched-Chain Alkanes   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Branched-Chain Alkanes ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
IUPAC Names ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Cyclic Hydrocarbons ,[object Object],[object Object],[object Object],[object Object]
Cycloalkanes ,[object Object],[object Object],[object Object],[object Object]
Naming Cycloalkanes with  Side Groups ,[object Object],[object Object],[object Object]
Alkane name review ,[object Object],1.  Find the root word (ending in -ane) in the hydrocarbon name; write the longest hydrocarbon chain to create the parent 2. Number the carbons of this parent chain 3. Identify substituents and attach them 4. Add hydrogens as necessary
Naming Review ,[object Object],[object Object],[object Object],propyl 2,2-dimethylbutane a
Z5e 22.2 Alkenes & Alkynes ,[object Object],[object Object],[object Object]
Tr 118 Structures of Alkenes Name ends in “-ene” Why are these called unsaturated? Less than 4 “things” on some of the carbons. Note the  cis  and  trans  isomers.
Naming Alkenes   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Alkynes ,[object Object],[object Object],[object Object],[object Object]
Z5e 22.3 Aromatic Hydrocarbons ,[object Object],[object Object]
Aromatic Compounds and Benzene ,[object Object],[object Object],[object Object]
Benzene Structure ,[object Object],[object Object],[object Object]
Tr 119 Resonance Structures of Benzene
Tr 118A Representations of Benzene
Aromatic Hydrocarbons ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Tr 119A Structural Formula for Aspirin
Naming Aromatic Compounds   pp ,[object Object],[object Object],[object Object]
Naming Aromatic Compounds   pp ,[object Object]
Some Common Names   pp ,[object Object]
Review ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
An Interlude: The Petrochemical Industry ,[object Object],[object Object],[object Object]
Natural Gas ,[object Object],[object Object],[object Object]
Petroleum ,[object Object],[object Object],[object Object],[object Object]
Petroleum ,[object Object],[object Object],[object Object]
Petroleum Refinery
Z5e 22.4 Hydrocarbon Derivatives
Functional Group ,[object Object],[object Object],[object Object],[object Object]
Z7e 1011 Table 22.4 Common Functional Groups   pp
Alcohols   pp ,[object Object],[object Object],[object Object],[object Object]
Alcohols   pp ,[object Object],[object Object],[object Object]
Organic Chemicals ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Properties of Alcohols ,[object Object],[object Object]
Properties of Alcohols ,[object Object],[object Object]
Alcohols   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Naming Alcohols   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Alcohols   pp ,[object Object],[object Object]
More Names of Alcohols   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Name the following alcohols: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],3-methyl - 2 -pentan ol cyclobutan ol
Some Typical Alcohols ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Anti-freeze
Halogen Substituents ,[object Object],[object Object],[object Object]
Chlorofluorocarbons (CFCs and the  Ozone Layer ,[object Object],[object Object],[object Object],[object Object],[object Object]
Chlorofluorocarbons and the  Ozone Layer ,[object Object],[object Object],[object Object],[object Object],[object Object]
Chlorofluorocarbons and the  Ozone Layer ,[object Object],[object Object],[object Object],[object Object]
Ethers   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Aldehydes and Ketones   pp ,[object Object],[object Object],[object Object],[object Object]
Aldehydes and Ketones   pp ,[object Object],[object Object],[object Object],[object Object]
Aldehydes and Ketones   pp ,[object Object],[object Object],[object Object]
Aldehydes and Ketones ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Naming Aldehydes and Ketones   pp ,[object Object],[object Object],[object Object],[object Object]
Naming Aldehydes   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Naming Ketones   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Aldehydes and Ketones   pp ,[object Object],[object Object]
Common Aldehydes and Ketones ,[object Object],[object Object],[object Object],[object Object],[object Object]
Aldehydes and Ketones ,[object Object],[object Object],[object Object]
Ketones ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
More Aldehydes as Flavorings
Review Check ,[object Object],[object Object],[object Object],[object Object],(  b  ) (  diethyl ether  ) ( an  -OH group on a benzene ring  ) O R - C -  H
Review Check ,[object Object],[object Object],[object Object],[object Object],O R  - C -  R (  b  ) (  2-butanone  )
Learning Check   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],2 2 3 1
Carboxylic Acids   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Carboxyl Group   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Carboxylic Acids - look for functional group   pp
Naming Rules   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Naming Carboxylic Acids   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Tr 123 Fig 21.5 Carboxylic Acid:  Citric Acid How many carboxyls groups does this have? Three Why is this acidic? It can lose a hydrogen ion. How does it affect the taste of citrus fruits? Acids give a sour taste.
Esters   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Esters   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Esters   pp ,[object Object],[object Object]
Naming Esters   pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Naming Esters   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Some Esters and Their Names ,[object Object],[object Object],[object Object]
Learning Check ,[object Object],[object Object],[object Object],[object Object]
Solution ,[object Object],[object Object],[object Object],[object Object],[object Object]
Esters in Plants ,[object Object],[object Object]
Common Flavors & Odors of Esters
Amines   pp ,[object Object],[object Object],[object Object],[object Object]
Naming Amines   pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Learning Check ,[object Object],[object Object],[object Object],[object Object],ethyl methyl amine , 2° ethyl dimethyl amine , 3°
DNA & RNA contain amines
Alkaloids ,[object Object],[object Object],[object Object],[object Object]
Nicotine
Caffeine
Z7e 1011 Table 22.5 Common Functional Groups
Organic Reactions ,[object Object],[object Object]
Substitution Reactions   pp ,[object Object],[object Object]
Substitution Reactions   pp ,[object Object],[object Object],Iodomethane Methanol Bromoethane Ethanol
Addition Reactions   pp ,[object Object],[object Object],[object Object],[object Object]
Fatty Acid Addition Reaction
Saturated  vs.  Unsaturated Fatty Acids
Condensation Reactions   pp ,[object Object],[object Object],[object Object]
Elimination Reactions   pp ,[object Object]
Z7e 22.5 Polymers ,[object Object],[object Object],[object Object]
Addition Polymers ,[object Object],[object Object],[object Object]
Addition Polymers ,[object Object],[object Object],[object Object]
Addition Polymers
Addition Polymers ,[object Object],[object Object],[object Object],polyethylene R => H polypropylene R => CH 3 polyvinylchloride R => Cl polystyrene R => benzene ring
Addition Polymers Vulcanization  - cross-linking of polyisoprene molecules that occurs when heated with sulfur. Charles Goodyear accidentally discovered this and used it to make synthetic rubber for tires, etc.
Condensation Polymer   pp ,[object Object],[object Object],[object Object],[object Object]
Condensation to Nylon   pp   Monomers  - hexanediamine & adipic acid Polyamide  - amide (peptide) is in the polymer Nylon 66 - each monomer has 6 carbon atoms Polyester is another type of condensation polymer
Nylon 66 being wound on a stirring rod

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Ch22 z5e organic

  • 1. Z7e Chapter 22 Organic Chemistry pp 50 questions on online HW Stop whining! They’re not too hard (for me)
  • 2.
  • 3. Tr 114 Methane - Tetrahedral sp 3 Structure
  • 4. Tr 115 Bonding in Ethene & Ethyne
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11.
  • 12.
  • 13.
  • 14.
  • 15.
  • 16. Tr 115A Carbon-Atom Chain Prefixes
  • 17. Tr 117 Some Alkanes
  • 18.
  • 19. Tr 117A Straight-Chain Alkyl Groups How are alkyl groups different from their corresponding alkanes? They have one less hydrogen so they can bond to another atom. What would a nine-carbon alkyl group be called? Nonyl
  • 20.
  • 21.
  • 22.
  • 23.
  • 24.
  • 25.
  • 26.
  • 27.
  • 28.
  • 29.
  • 30.
  • 31.
  • 32.
  • 33.
  • 34.
  • 35.
  • 36.
  • 37. Tr 118 Structures of Alkenes Name ends in “-ene” Why are these called unsaturated? Less than 4 “things” on some of the carbons. Note the cis and trans isomers.
  • 38.
  • 39.
  • 40.
  • 41.
  • 42.
  • 43. Tr 119 Resonance Structures of Benzene
  • 45.
  • 46. Tr 119A Structural Formula for Aspirin
  • 47.
  • 48.
  • 49.
  • 50.
  • 51.
  • 52.
  • 53.
  • 54.
  • 56. Z5e 22.4 Hydrocarbon Derivatives
  • 57.
  • 58. Z7e 1011 Table 22.4 Common Functional Groups pp
  • 59.
  • 60.
  • 61.
  • 62.
  • 63.
  • 64.
  • 65.
  • 66.
  • 67.
  • 68.
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  • 72.
  • 73.
  • 74.
  • 75.
  • 76.
  • 77.
  • 78.
  • 79.
  • 80.
  • 81.
  • 82.
  • 83.
  • 84.
  • 85.
  • 86. More Aldehydes as Flavorings
  • 87.
  • 88.
  • 89.
  • 90.
  • 91.
  • 92. Carboxylic Acids - look for functional group pp
  • 93.
  • 94.
  • 95. Tr 123 Fig 21.5 Carboxylic Acid: Citric Acid How many carboxyls groups does this have? Three Why is this acidic? It can lose a hydrogen ion. How does it affect the taste of citrus fruits? Acids give a sour taste.
  • 96.
  • 97.
  • 98.
  • 99.
  • 100.
  • 101.
  • 102.
  • 103.
  • 104.
  • 105. Common Flavors & Odors of Esters
  • 106.
  • 107.
  • 108.
  • 109. DNA & RNA contain amines
  • 110.
  • 113. Z7e 1011 Table 22.5 Common Functional Groups
  • 114.
  • 115.
  • 116.
  • 117.
  • 118. Fatty Acid Addition Reaction
  • 119. Saturated vs. Unsaturated Fatty Acids
  • 120.
  • 121.
  • 122.
  • 123.
  • 124.
  • 126.
  • 127. Addition Polymers Vulcanization - cross-linking of polyisoprene molecules that occurs when heated with sulfur. Charles Goodyear accidentally discovered this and used it to make synthetic rubber for tires, etc.
  • 128.
  • 129. Condensation to Nylon pp Monomers - hexanediamine & adipic acid Polyamide - amide (peptide) is in the polymer Nylon 66 - each monomer has 6 carbon atoms Polyester is another type of condensation polymer
  • 130. Nylon 66 being wound on a stirring rod

Editor's Notes

  1. Hrw 625
  2. Hrw 629; z5e 1057
  3. Hrw 625 Tr 114
  4. Hwr 631; z5e 983 Structural isomers are compounds that have the same molecular formula with different arrangements of the atoms.
  5. Hwr 631 z5e 984
  6. Hrw 631; z5e 1068
  7. Hrw 632; z5e 1060
  8. Hrw 632; z5e 1059
  9. Hrw 632; z5e 1059
  10. Hrw 632; z5e 1059
  11. Hrw 632; z5e 1059
  12. Hrw 634; z5e 1058
  13. Hrw 634; z5e 1058
  14. Hrw 634; z5e 1058
  15. Hrw Table 20.2 635
  16. Hrw 643; z5e 1058
  17. Hrw 643; z5e 1059
  18. Hrw 635; z5e 1058 In methane, CH 4 the four valence electrons of carbon are shared with the single electrons of four hydrogen (H) atoms. Each pair of electrons is a single bond, which can be drawn as a line. When a structure is drawn to show each bond, it is called a complete structural formula.
  19. Hrw 635; z5e 1058 The complete structural formula for ethane shows the single bonds between two carbon atoms and six H atoms. The complete structural formula of propane shows the 3-carbon chain with single bonds to the attached H atoms. To write a condensed structural formula, the H atoms are written as a group next to their respective C atoms.
  20. Hrw 636; z5e 1061
  21. Hrw 636; z5e 1061
  22. Hrw 637; z5e 1058
  23. Hrw 637; z5e 1058
  24. Hrw 651 z5e 1077 An alkyl group is composed of one or more carbon atoms attached to a carbon chain. An alkyl group is derived from an alkane by removing one hydrogen. The ending –ane of the alkane is changed to –yl. The carbon branch from methane is the methyl group. The carbon branch from ethane is the ethyl group.
  25. Hrw 637; z5e 1058
  26. Hrw 639; z5e 1058
  27. Hrw 637; z5e 1059 The names of organic compounds are determined by the IUPAC rules (International Union of Pure and Applied Chemistry). The stem of the name states the number of carbon atoms in the carbon chain of the compounds. The suffix, in this case –ane, indicates the alkane family.
  28. Hrw 634; z5e 1066
  29. Hwr 635 z5e1065 hwr 636, z5e1066 The is a group of alkanes that have a cyclic structure. These cycloalkanes contain a carbon chain that is in a ring. Each cycloalkane has a formula that is 2C less than the corresponding alkane. For example, propane is C 3 H 8 whereas cyclopropane ic C 3 H 6 . Butane is C 4 H 10 and cyclobutane is C 4 H 10 . The names of the cyclic structures use the prefix cyclo in from of the alkane name for the carbon chain.
  30. Hwr 642 z5e 1066
  31. Hrw 636
  32. Hrw 653
  33. Hrw 647; z5e 1069
  34. Hrw 118
  35. Hrw 648; z5e 1067
  36. Hrw 651; z5e 1067-1068
  37. Hrw 652; z5e 1070
  38. Hwr 652 z5e 1070
  39. Hrw 653 z5e 1071
  40. Hrw 653
  41. Hrw 753
  42. Hrw 652; z5e 1071
  43. Hwr653-654
  44. Hwr 653-654 z5e 1071
  45. Z5e 1071
  46. Hrw 643
  47. Hrw 643
  48. Hrw 643; z5e 268
  49. Hrw 644
  50. Hrw 663; z5e 1076
  51. Hrw 663; z5e 1076
  52. Hrw 663; z5e 1077
  53. Hrw 663-664; z5e 1078
  54. Hrw 664; z5e 1079
  55. Hrw 666; z5e 1078
  56. Hrw 663; z5e 1077
  57. Hwr 663 z5e 1077
  58. Hrw 663; z5e 1078
  59. Hwr 664 z5e 1078
  60. Hrw 666; z5e 1065?
  61. Hwr 669 z5e 1065
  62. Hwr 669
  63. Hwr 668
  64. Hwr 669 z5e 1077
  65. Hrw 672; z5e (review)1080
  66. Hrw 672; z5e 1080
  67. Hrw 672; z5e 1080
  68. Hwr 672 z5e 1080
  69. Hrw 672-673; z5e 1080
  70. Hwr 672 z5e 1080
  71. Hwr 672-673 z5e 1080
  72. Hrw 673; z5e 1080
  73. Hrw 673; z5e 1080
  74. Hrw 673; z5e 1080
  75. Z5e 1081
  76. Hwr 673 z5e 1080
  77. Hrw 672
  78. Hrw 672
  79. Hrw 674; z5e 1081
  80. Hwr 674 z5e 1081
  81. Hrw Tr 121A Table 21-5 p. 675 Carboxylic Acids
  82. Hwr 674
  83. Hwr 674 z5e 1081
  84. Hwr 675 z5e 1081
  85. Hrw 675-676; z5e 1081
  86. Hrw 676; z5e 1081
  87. Hrw 675; z5e 1082
  88. Hwr 675
  89. Hwr 676 z5e 1082
  90. Hrw Tr 123A Common Flavors & Odors of Esters
  91. Hwr 677 z5e 1082
  92. Hwr 677 z5e 1082
  93. Hrw 681
  94. Hwr 678
  95. Hwr 678
  96. Hwr 678
  97. Hrw 682-683; z5e 1069
  98. Hrw 682; z5e 1077
  99. Hrw 682; z5e 1069
  100. Hrw 682-683; z5e 1069
  101. Hrw Tr127 Fig 21.8 Fatty Acid Addition Reaction
  102. Tr122A Saturated vs. Unsaturated Fatty Acids
  103. Hrw 682-683; z5e 1069
  104. Hrw Tr 127A Elimination Reactions
  105. Hrw 686; z5e 1083
  106. Hrw 686; z5e 1084
  107. Hrw 686
  108. Hrw 687 Tr 124A p. 687 Table 21.8 Addition Polymers
  109. Hrw Tr127C Condensation to Nylon
  110. Hrw Tr127D Nylon 66 being wound on a stirring rod