This document provides an overview of organic chemistry concepts including:
- Organic compounds contain carbon and are found in living things. Key elements are hydrogen, oxygen, nitrogen, sulfur.
- Hydrocarbons are the simplest organic compounds and are divided into aliphatic and aromatic types.
- Aliphatic hydrocarbons include alkanes (single bonds), alkenes (double bonds), and alkynes (triple bonds).
- IUPAC nomenclature rules are used to systematically name organic compounds based on functional groups, chain length, and substituents.
- Derivatives of hydrocarbons like alkenes and alkynes introduce double and triple bonds that impact properties. Geometric isomers
Structural diagrams,condensed structures and line structures of hydrocarbons.How to identify a substance as Organic and inorganic ?.How to classify hydrocarbons? What is the difference between alkanes,alkenes and alkynes?
This is a summary of the topic "Alkanes and Alkenes" in the GCE O levels subject: Chemistry. Students taking either the combined science (chemistry/physics) or pure chemistry will find this useful. These slides are prepared according to the learning outcomes required by the examinations board.
Organic reactions are chemical reactions involving organic compounds. Organic reactions are used in the construction of new organic molecules. The production of many man-made chemicals such as drugs, plastics, food additives, fabrics depend on organic reactions.
Structural diagrams,condensed structures and line structures of hydrocarbons.How to identify a substance as Organic and inorganic ?.How to classify hydrocarbons? What is the difference between alkanes,alkenes and alkynes?
This is a summary of the topic "Alkanes and Alkenes" in the GCE O levels subject: Chemistry. Students taking either the combined science (chemistry/physics) or pure chemistry will find this useful. These slides are prepared according to the learning outcomes required by the examinations board.
Organic reactions are chemical reactions involving organic compounds. Organic reactions are used in the construction of new organic molecules. The production of many man-made chemicals such as drugs, plastics, food additives, fabrics depend on organic reactions.
Chemistry power point presentation on Hydrocarbons, which covers all the basic topics and sub- topics. Including Alkane,alkene and alkyne. This power point also consists of preparation of hydrcarbons.
This a 90 page power point.
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Organic Chemistry
1. History
2. Properties of Organic Chemistry
3. comparison of Compounds
4. Sources of Organic Compounds
5. Types of Organic Compounds
6.Types of Organic Formula
7. Carbon
8. Structural Formulas of Carbon
9. Isomerism
10 Classification of Organic Compounds
11. HydroCarbons
Explain chemical properties of alcohols by various chemical reactions
Define and explain preparation of ethers from alcohols by using chemical equations
Chemistry power point presentation on Hydrocarbons, which covers all the basic topics and sub- topics. Including Alkane,alkene and alkyne. This power point also consists of preparation of hydrcarbons.
This a 90 page power point.
GooD LucK !!!
Organic Chemistry
1. History
2. Properties of Organic Chemistry
3. comparison of Compounds
4. Sources of Organic Compounds
5. Types of Organic Compounds
6.Types of Organic Formula
7. Carbon
8. Structural Formulas of Carbon
9. Isomerism
10 Classification of Organic Compounds
11. HydroCarbons
Explain chemical properties of alcohols by various chemical reactions
Define and explain preparation of ethers from alcohols by using chemical equations
Classification, Nomenclature and structural isomerism of organic compound Ganesh Mote
Classification of organic compound, Nomenclature of alkane, alkene, alkyne, alcohol, alkyl halide, aldehyde, ketone, carboxylic acid and its derivatives, amines, ethers, polyfunctional groups and structural isomerism of organic compounds
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The people of Punjab felt alienated from main stream due to denial of their just demands during a long democratic struggle since independence. As it happen all over the word, it led to militant struggle with great loss of lives of military, police and civilian personnel. Killing of Indira Gandhi and massacre of innocent Sikhs in Delhi and other India cities was also associated with this movement.
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2. Organic Chemistry - Introduction
Organic chemistry is the study of carbon
compounds.
Animals, plants, and other forms of life consist of
organic compounds.
Intro
3. Bonding in Organic Compounds
Besides carbon, the most common elements in
organic compounds are hydrogen, oxygen,
nitrogen, sulfur, and the halogens.
organic compounds have covalent bonding.
4. Hydrocarbons
Hydrocarbons are the most simple organic
compounds.
Hydrocarbons contain only carbon (C) and
hydrogen (H).
For classification purposes, all other organic
compounds are considered derivatives of
hydrocarbons.
Hydrocarbons can be divided into aromatic and
aliphatic hydrocarbons.
Section 14.2
11. Aliphatic Hydrocarbons
Aliphatic hydrocarbons are hydrocarbons having
no benzene rings.
Aliphatic hydrocarbons can be divided into four
major divisions:
Alkanes
Cycloalkanes
Alkenes
Alkynes
13. Alkanes
Alkanes are hydrocarbons that contain only single
bonds.
Alkanes are said to be saturated hydrocarbons
Because their hydrogen content is at a maximum.
Alkane general formula CnH2n + 2
The names of alkanes all end in “-ane.”
Methane butane are gases
Pentane C17H36 are liquids
C18H38 and higher are solids
14. Physical Properties
No color & odour
Lower alkane: gases
Middle alkane: liquids
Higher alkane: solid
Higher boiling point : higher molecular wt.
Branched chain: decrease surface area
Long chain : higher surface area.
Even no. of carbon : higher M.P
Odd no. of carbon : lower M.P
Higher density: higher mol. Wt
Non polar : soluble in organic solvent
Higher mol. Wt : decrease solubility
15. The First Eight Members of the Alkane Series
All satisfy the general formula CnH2n + 2
16. Visualization of an Alkane’s Structure
Structural formula – a graphical
representation of the way atoms
are connected
Condensed structural formula –
save time/space and are
convenient
Ball-and-Stick models – 3D
models that can be built by
students
17. Models of Three Alkanes
Names, Structural Formulas, Condensed Structural
Formulas, and Ball-and-Stick Models
18. Methane – Tetrahedral Geometry
Ball-and-
Stick &
Space-
Filling
Models
Carbon’s
four single
bonds form
angles of
109.5o
2
19. Alkyl Group
Alkyl group contains one less hydrogen than the
corresponding alkane.
General abbreviation “R” (for Radical, an
incomplete species or the “rest” of the molecule)
In naming this group the “-ane” is dropped and “-
yl” is added.
CH3 is “methyl” (from methane)
CH2CH3 is “ethyl” from ethane
Section 14.3
20. Alkyl Group
This group does not exist independently but occurs bonded to another
atom or molecule.
21. Types of Alkyl groups
Classified by the connection site
a carbon at the end of a chain (primary alkyl group)
a carbon in the middle of a chain (secondary alkyl
group)
a carbon with three carbons attached to it (tertiary
alkyl group)
24. Organic Compound Nomenclature
Due to the large number, variety, and complexity of
organic compounds, a consistent method of
nomenclature has been developed.
Section 14.3
25. IUPAC System of Nomenclature
For Alkanes
Identify the longest chain -- parent
number from the end closest to first branch
Name the groups attached to the chain, using the
carbon number as the locator.
Alphabetize substituents.
Use di-, tri-, etc., for multiples of same substituent
combine number and name of substituent with
parent name, separating with hyphen
26. An Example to Consider
The longest continuous chain of C atoms is five
Therefore this compound is a pentane derivative
with an attached methyl group
Start numbering from end nearest the substituent
The methyl group is in the #2 position
The compound’s name is 2-methylpentane.
27. Longest Chain
The number of carbons in the longest chain
determines the base name: ethane, hexane.
If there are two possible chains with the same
number of carbons, use the chain with the most
substituents.
C
CH3
CH2
CH3
CH CH2 CH2 CH3
CH CH2 CH3
H3C
H3C
39. Drawing a Structure from a Name
Draw the structural formula for
2,2,4trimethylpentane.
Note that the end name is pentane .
Draw a continuous chain of five carbon (C) atoms,
with four bonds around each.
40. Drawing a Structure from a Name
Number the C atoms from right to left.
Attach two methyl groups (CH3--) to carbon
number 2 and one to number 4.
41. Drawing a Structure from a Name
Add necessary H atoms.
2,2,4-trimethylpentane
Section 14.3
42. Cycloalkanes
Members of the cycloalkane group possess rings of
carbon atoms.
They have the general formula CnH2n.
Each carbon atom is bonded to a total of four
carbon or hydrogen atoms.
The smallest possible ring consists of
cyclopropane, C3H6.
Section 14.3
43. The First Four Cycloalkanes
Note that in the condensed structural formulas, there is a
carbon atom at each corner and enough hydrogens are
assumed to be attached to give a total of four single bonds.
Section 14.3
44. Drawing the Structure of a
Cycloalkane
Draw the geometric figure indicated by the
compound’s name , “pentane.”
Section 14.3
45. Drawing the Structure of a
Cycloalkane
Place each substituent on the ring in the numbered
position “1 chloro-2-ethyl-”
1-chloro-2-ethylcyclopentane
Section 14.3
46. Classes of Carbon and
Hydrogen atoms
1o Carbon - primary carbon is attached to only
one other C atoms
2o Carbon - secondary carbon is attached to two
other C atoms
3o Carbon - tertiary carbon is attached to three
other C atoms
49. Derivatives of Hydrocarbons
Organic molecule characteristics depend on the
number, arrangement, and type of atoms.
Functional Group – any atom, group of atoms,
or organization of bonds that determine
specific properties of a molecule
Generally the functional group is the reactive part of
the molecule.
Due to the functional group’s presence, certain
predictable properties rise.
Section 14.4
50. Alkenes
Members of the alkene group have a double bond
between two carbon atoms.
One hydrogen atom has been removed from two
adjacent carbon atoms, thereby allowing the two
adjacent carbon atoms to form a double bond.
General formula is CnH2n
Begins with ethene (ethylene)
C2H4
Section 14.3
52. Physical properties:
Carbon-carbon double bond changes the physicals properties of
alkenes.
At R.T. , alkenes exist in all three phases, solid, liquids, and gases.
1. Physical state:
Ethene, Propene, and Butene exists as colorless gases.
Members of the 5 or more carbons such as Pentene, Hexene, and
Heptene are liquid
Members of the 15 carbons or more are solids.
2. Density: Alkenes are lighter than water
53. 3.Solubility: insoluble in water.
Alkenes are only soluble in nonpolar solvent like
benzene, ether, chloroform.
4.Boiling point : depends on more molecular mass (chain
length).
more intermolecular mass is added, the higher the boiling
point.
5. Melting point : depends on the packaging of the molecules.
Alkenes have similar melting points to that of alkanes,
54. Naming Alkenes
“-ane” suffix for the corresponding alkane is
changed to “-ene” for alkenes.
A number preceding the name indicates the C
atom on which the double bond starts.
The carbons are numbered such that the double bond
has the lowest number.
For example, 1-butene and 2-butene
Section 14.3
55. Example
Write the IUPAC name for each of the following:
CH3
B. CH3─CH2─C=CH─CH3 3 –methyl 2-pentene
56. Note: Always number so that double bond gets the lowest number
CH3 CHCH CH CH
CH3
CH3
CH3
236 145
41 2 3 6
5
Correct name is : 2,5-dimethyl-3-hexene
57. Alkynes
Members of the alkyne group have a triple bond
between two carbon atoms.
Two hydrogen atoms have been removed from
each of two adjacent carbon atoms, thereby
allowing the two adjacent carbon atoms to form
a triple bond.
General formula is CnH2n-2
Begins with ethyne (acetylene)
C2H2
Section 14.3
59. Physical properties
1. Physical properties:
- First 3 members of alkyne : gaseous form
up to C8 : liquid,
more than 8 carbons: solid.
- Colorless & except ethyne all are odorless.
- Lighter than water
- Insoluble in polar and soluble in non polar organic
solvents.
- Melting point, Boiling point and increase with
molecular mass.
60. Longest chain containing triple bond
Location and number of groups?
Name: 6-chloro-5-ethyl-4-methyl-2-heptyne
5-ethyl
1 2 3 4 5 6 7
2-heptyne
(triple bond)
4-methyl 6-chloro
62. GEOMETRICAL ISOMERISM
The geometrical isomerism arises when atoms or groups are
arranged differently in space due to restricted rotation of a
bond or bonds in a molecule.
E.g.,
1) Two different spatial arrangements of methyl groups about a
double bond in 2-butene give rise to the following geometrical
isomers.
i.e., cis-2-butene and trans-2-butene
63. Above two forms are not inter convertible due to restricted rotation of
double bond.
In the cis isomer, the two methyl groups are arranged on the same side of a
double bond.
Whereas in the trans isomer, they are on the opposite side.
2) There are two geometrical isomers (cis & trans) possible in case of 1,4–
dimethylcyclohexane as shown below:
3
64. In the above geometrical isomers, the methyl groups are arranged
differently about the plane of the cyclohexane ring. These isomers
are not inter convertible since it is not possible to rotate the bonds
in the cyclohexane ring.
The geometrical isomers often show different physical and
chemical properties. The difference in their physical properties is
more significant when there is more difference in their polarity.
Usually the dipole moment of cis-isomers is greater than that of
trans isomers. Hence the cis isomers usually have more solubility
in polar solvents.
In general, the trans isomers are more stable than cis isomers.