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Department of Chemistry, National Institute of
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China University of Petroleum, Beijing,
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Department of Chemical Engineering,
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Department of Chemical Engineering,
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Saudi Arabia.
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Bapatla Engineering College (Autonomous),
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Department of Chemistry, Nanoscience and
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Research Institute of Petroleum Industry
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National University of Singapore,
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Louisiana State University, United States.
From the Editor's Desk
Dear Readers,
We would like to present, with great pleasure, the inaugural volume of a new scholarly
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ManagingDirector
1. Effect of Heat Ageing on Mechanical Properties of Polyamide 6(Nylon 6) and Polyamide 12(Nylon 12)
Hitkam Pandya, Jinkal Mistry, Lokesh Jain, Kathan Patel, Sandeep Rai 1
2. Sal Wood Flour and Its Mechanical Behavior
Mahaveer Jain 13
3. Article on Polyurethanes That Are Based on Tung Oil
Rishabh Singh Kuperkar 18
4. Natural Rubber and the Resin Exuded from Ailan malab Tree
John Jacob 24
5. Plastics Product Design and Analysis
Mujahid A. Ansari, Srushti Wadekar, Priyanka Gaikwad, Sujata Shinde 31
Contents
IJPSE (2016) 1-12 © JournalsPub 2016. All Rights Reserved Page 1
International Journal of Polymer Science and Engineering
eISSN: 2455-8745
Vol. 2: Issue 2
www.journalspub.com
Effect of Heat Ageing on Mechanical Properties of Polyamide
6(Nylon 6) and Polyamide 12(Nylon 12)
Hitkam Pandya1
, Jinkal Mistry1
, Lokesh Jain2
, Kathan Patel3
, Sandeep Rai1,3*
1
GRP Limited, Panoli Industrial Estate, GIDC, Bharuch, Gujarat, India
2
Narmada Valley Rubber Pvt Ltd, GIDC, Ankleshwar, Bharuch, Gujarat, India
3
Shorff S.R. Rotary Institute of Chemical Technology, Vataria, Ankleshwar, Bharuch, Gujarat, India
ABSTRACT
Polyamide 6 or nylon 6(PA 6) and polyamide 12 or Nylon 12 (PA 12) are well known
engineering semi-crystalline polar polymers characterized by the presence of amide linkage
(-CONH-) in the repeating units of their chains. The glass transition temperature (Tg) of PA
6 and PA 12 is ~50 and ~37°C, respectively. PA 6 is widely used for gears and bearings,
fittings in automobile industry for under hood parts and also as a material for power tools
housings. PA 12 is mainly used for special applications in automobile industry like, to
prepare fuel tank and oil-gasoline resistant pipes/tubes. When any polymer is used for a long
period of time, it becomes aged. Heat aging process affects not only the material property
but also decide the service life of polymer. Therefore study of heat aging properties of
polymers is a fundamental topic both from academic and industrial view-point. In the present
study, Injection molded specimens of PA 6 and PA 12 were heat-aged in an oven at a
temperature ranging from below the glass transition temperature (Tg) of PA and above the Tg
for a specific period ranging. The heat aging effects on PA 6 and PA 12 in terms of
mechanical properties such as tensile modulus (E), tensile yield strength (σy), elongation at
break (εb) and Izod impact strength were investigated under various conditions. Extensive
literature survey revealed that, no such systematic aging studies for Nylon 6 and Nylon 12
are reported so far.
Keywords: polyamide, heat ageing effect, mechanical properties, morphology
INTRODUCTION
Now a day’s polyamides are useful in
different types of applications like
Electric and Electronics applications,
under hood parts of automobiles, to
make safety air bags to make ropes which
are used by rock and ice climbers, brush
filaments, wire coating, coil forms, and
gears, etc.
As Polyamides have tough, possessing
high tensile strength, elasticity, luster and
also have good chemical resistance, so if
we want to apply such applications
according to its properties, then we need
to study how polyamides behave after a
long age in atmosphere. Polyamides have
high heat distortion temperature (HDT)
and good mechanical properties, such as
tensile strength and tensile modulus.
Polyamide can also be used in high
temperature environments. However,
when polyamides is exposed to a high
temperature for a prolonged period, such
as, in case with objects that serve in
automotive under-the-hood applications
and in electric and electronic applications,
the polymer generally starts to show
IJPSE (2016) 13-17 © JournalsPub 2016. All Rights Reserved Page 13
International Journal of Polymer Science and Engineering
eISSN: 2455-8745
Vol. 2: Issue 2
www.journalspub.com
Sal Wood Flour and Its Mechanical Behavior
Mahaveer Jain*
Department of Chemistry, IFTM University, Lodhipur Rajput, Delhi Road, Moradabad, U.P., India
ABSTRACT
In this paper mechanical parameters of polypropylene (PP) to a limit of 15 wt% of copolymer
are investigated. The PP/SEBS blend with 15 wt% of copolymer is then changed to 14, 16, 31
and 55 wt% of sal wood. The tensile properties like modulus, strength, and impact strength
are observed. The effect of salt spray on these properties is also the part of study. The results
were found to be very mesmerizing.
Keywords: polypropylene, sal wood, salt spray, SEBS, wood flour
INTRODUCTION
Due to a growing environmental
awareness throughout the world by the
environmentalists, it has triggered a
paradigm shift towards selecting materials
compatible with the environment. Owing
to their excellent mechanical properties,
composite materials have been widely
used throughout the last four decades. The
use of natural fibers, as reinforcing fibers
in both thermoplastics and thermosets
matrix composites provides positive
environmental benefits with respect to
ultimate disposability and raw material
utilization.[1]
Polypropylene (PP) is a polymer with a
very simple chemical structure which is
probably the most used mineral filled
thermoplastic polymer for injection
molding applications.[2,3]
Fillers into
polymer, find applications in the polymer
industry almost exclusively, e.g. to
improve mechanical, thermal, electrical
properties and dimensional-stability.[4–6]
Over the past two decades, natural fibers
have been replacing synthetic fiber
reinforcement such as glass fiber in
polymer.[7,8]
The advantages of these fibers
are low density, low cost, acceptable
specific strength, good thermal insulation
properties, reduced dermal and respiratory
irritation, reduced tool wear, renewable
resource and recycling possible without
affecting the environmental damage, and
together with biodegradable ability.[9–13]
Polymer with fillers based composites has
received considerable interest in the
materials field because of their potential
for large gains in mechanical properties.
The understanding of mechanical
properties of the fillers, mainly wood flour
and PP based composites is very important
in order to use in different applications,
such as, the automotive and building
industries in which they are used in
structural applications as fencing, decking,
outdoor furniture, window parts, roofline
products, door panels, etc.[14,15]
Although there are several reports in the
literature which discuss the of
wood/polymer composites;[16–19]
however,
very limited work has been done on effect
of addition of wood flour into
polypropylene on its mechanical behavior.
Generally these composites are also used
corrosive environment. In this paper, a
study of effect of addition of Sal wood
IJPSE (2016) 18-23 © JournalsPub 2016. All Rights Reserved Page 18
International Journal of Polymer Science and Engineering
eISSN: 2455-8745
Vol. 2: Issue 2
www.journalspub.com
Article on Polyurethanes That Are Based on Tung Oil
Rishabh Singh Kuperkar*
Department of Applied Chemistry, Sardar Vallabhbhai National Institute of Technology (SVNIT), Ichchhanath,
Surat, Gujarat, India
ABSTRACT
Polyurethane (PU) formulated from natural polyols obtained from Tung oil (TO) have
improved hydroxylation of the double bonds in the fatty acid chains of the unsaturated oil
followed by the alcoholysis of the hydroxylated oil. The comparative chemical analysis
between unmodified and modified TO suggested that the hydroxyl content increased
significantly after the hydroxylation and alcoholysis reactions. Incorporated wood flour
(WF), microcrystalline cellulose (MCC) or rice husk ash (RHA) as fillers in modified TO
imparts between formulation in physical, thermal and mechanical properties of reinforced
rigid PUs.
Keywords: composites, foams, polyurethanes, thermosetting polymers, tung oil
INTRODUCTION
Use of renewable natural products as an
alternative source for nonrenewable
material has gained enormous importance
in the research and industries since decade.
Vegetable oils are relatively low cost
materials and offer prior quality of
biodegradation. Chemically, they are
composed of triglyceride molecules
obtained from esters of glycerol and fatty
acid chains with 16–22 carbon atoms with
0–3 double bonds per chain. It is the
unsaturated fatty acid which offers many
reactive sites to obtain the desire
polymeric product according to industrial
applications [1].
Tung oil obtained from the seeds or nuts of
the tung tree belongs to the family of
Euphorbiaceae [2, 3]. This oil is
interesting because of its major constituent
α-eleostearic acid (77–82%) with three
conjugated double bonds, oleic acid (3.5–
12.7%) with one double bond and linoleic
acid (8–10%) with two non-conjugated
double bonds structural formula is
presented in Figure 1 [4, 5]. The exothermi
c reaction between isocyanates and
alcohols is the most important reaction in
PU synthesis leading to the production of
urethane [-NH-COO-] linkages.
There is no -OH (hydroxyl) group and free
acids in the unmodified TO. The carbon-
carbon double bonds can be used to
introduce new reactive groups through a
hydroxylation reaction. Additionally, the
triglyceride molecules can be cut through
transesterification reaction with molecules
such as glycerol or triethanolamine, which
also allows in increasing the concentration
of hydroxyls per molecule. The resulting
oil-based polyols can be used as a
replacement of synthetic polyol to produce
PUs which is used in paints and varnish
industries [1, 2, 6–8].
Structurally, these long pendant chains and
modified fatty acids with the hydroxyl
groups imparts effective thermosetting
nature, flexibility, high strength elasticity
and hydrolytic resistance to the network,
IJPSE (2016) 24-30 © JournalsPub 2016. All Rights Reserved Page 24
International Journal of Polymer Science and Engineering
eISSN: 2455-8745
Vol. 2: Issue 2
www.journalspub.com
Natural Rubber and the Resin Exuded from Ailan malab Tree
John Jacob*
Department of Physics, Vemana Institute of Technology, Bangalore, Karnataka, India
Abstract
Elastomeric blends of natural rubber and exuded resin of Ailanthus malabaricum tree have
been prepared from solution casting technique. Benzene was used as the common solvent for
both the constituent polymers. Compared to the elasticity of natural rubber, the resin exhibits
excellent elasticity. The combination of both the elastomers with different composition
showed a considerable enhancement in elasticity of rubber. Universal testing machine was
employed to study the tensile properties of the resulting blend system. Tensile strength,
elongation at break and modulus at various elongations were determined from this
experiment. Tensile strength of natural rubber reduced and elongation at break increased by
the addition of exuded resin. Modulus of the samples was also reduced with the addition of
exuded resin. Surface hardness of the blend was measured from Shore A durometer and it
shows a reduction in hardness with the incorporation of resin into natural rubber. From the
overall tensile and hardness studies, it can be concluded that the resin collected from
Ailanthus malabaricum tree has been used to enhance the elastic performance of natural
rubber.
Keywords: Ailanthus malabaricum tree, elastomer, natural rubber, tensile strength
INTRODUCTION
Blending of two or more polymers has
been one of the major areas of research
and development in the field of polymer
science. The technology of polymer blends
is a best solution to achieve desired
material with suitable properties for the
end use application. It reduces the research
and development expense compared to the
development of new polymers or
monomers [1–3].
The phase structure of the resulting
material can be either miscible or
immiscible when two or more polymers
are mixed. Most of the blends are
immiscible and its physical properties are
poor compared to their constituent
polymers. This problem can be solved by
the addition of compatibilizers into the
blend by enhancing the favorable
interaction between the blend phases [4,
5]. Formation of interpenetrating polymer
network is the other way to obtain the
blend with better stability. Interpenetrating
polymer networks (IPNs) are unique type
of polymer alloys consisting of two or
more cross-linked polymers with no
covalent bonds or grafts between them [6].
When one of the phases is cross-linked,
pseudo- or semi-IPNs will be formed.
When both phases are cross-linked full-
IPNs are developed [7].
These intimate mixtures of cross-linked
polymers are held together by permanent
entanglements lead to forced miscibility
compared with usual blends and the
resulting materials exhibit good
dimensional stability. IPN materials offer
great promise for the future in view of the
increasing number of applications of these
IJPSE (2016) 31–34 © JournalsPub 2016. All Rights Reserved Page 31
International Journal of Polymer Science and Engineering
eISSN: 2455-8745
Vol. 2: Issue 2
www.journalspub.com
Plastics Product Design and Analysis
Mujahid A. Ansari*, Srushti Wadekar, Priyanka Gaikwad, Sujata Shinde
Department of Plastics & Polymer Engineering, Maharashtra Institute of Technology, Aurangabad, India
ABSTRACT
Product design of commonly used articles like key-chains is to make it more attractive, user
friendly, cost effective yet durable and providing longevity. Therefore, this work deals with
the designing of optimized 3D model of key-chain if suitable shape and size and doing its
analysis in Moldflow analysis software to study the material flow behaviour, impact of
processing parameters on the product and possible defects after one complete cycle of
processing. Lastly by trial and error method we could minimize the defects and could
optimize the product design for better and smooth production.
Keywords: moldflow, optimize, product design
INTRODUCTION
Why design a product specifically made of
plastics material? Usually, the reason to
design products made of plastics is either
to create new products, never made before,
or to create something similar to existing
old products but which is better, more
appealing to the user, or more economical
to produce.
"The design is the problem of anticipating
or trying to do what will be required in
future and improving what is being
already produced”.
Plastic products† are a dominant part of
the manufacturing world. It is very likely
that you the reader could, at this moment,
reach out and touch a plastic product from
where you sit.
Successful product design requires
knowledge, intelligence, and flair. The
knowledge requirement may in turn be
subdivided into[1–3]
:
(1) Knowledge of the requirements of the
product.
(2) Knowledge of the behaviour of
plastics materials.
(3) Knowledge of plastics processes.
(4) Knowledge of all relevant economic
and psychological factors.
Intelligence is required to relate this
knowledge, and flair to bring the design to
a successful reality
FACTORS TO BE CONSIDERED
WHILE DESIGNING A PRODUCT
While designing a product, several factors
are considered, some of them are:
Materials: Materials should be cheap and
should be able to withstand design
requirements. During production wastage,
should be minimized.
Manufacturing facility: Product design
should commensurate with the facilities
available in the factory about to equipment,
labour, and layout.
Aesthetic: The product should be good in
appearance and should have attractive
colours.
Tolerance: It should have desired
tolerances, as tight tolerances will result in
increased rejection and thereby adding to
the cost of product.
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International Journal of Polymer Science & Engineering (Vol 2 Issue 2)

  • 1. plymer Mechanical Engineering Chemical Engineering Architecture Applied Mechanics 5 more... 1 more... 2 more... 2 more... 5 more... Computer Science and Engineering Nanotechnology « International Journal of Solid State Materials « International Journal of Optical Sciences Physics Civil Engineering Electrical Engineering Material Sciences and Engineering Chemistry 5 more... 4 more... 3 more... Biotechnology 3 more... Nursing « International Journal of Immunological Nursing « International Journal of Cardiovascular Nursing « International Journal of Neurological Nursing « International Journal of Orthopedic Nursing « International Journal of Oncological Nursing 5 more... 4 more... Subm it Your A rticle2017 www.journalspub.com International Journal of JUL–DEC 2016 eISSN: 2455-8745 IJPSE
  • 2. International Journals Publisher JournalsPub is a multi-disciplinary international journal boosting innovative & eminence research work by Division of Dhruv Infosystems Pvt. Ltd. Launched in 2014 under the support and guidance by our Honorable EditorialBoard Members from renownedinstitutes. ObjectivesofJournalsPub  JournalsPub is international scholarly journal that publishes peer reviewed journal in the frontier areas of AppliedSciences,MedicalandEngineering.  JournalsPub publishes Original Research Papers, Review Papers, Popular Articles, Short Communications&CaseStudy.  Publishingspecialissues on Proceedingsof Conferences,SeminarsandSymposia.  JournalsPub Publishes issues twice a year (bi-annually) in English-language which is available online (openaccess)andinprintedversionwithagoaltopromoteanextensiveacademicawareness.  JournalsPub desires to set a good benchmark in the publishing industry by launching more than 100+ new International Journals to help the scientific community to enhance communication within the research communities and maintain a balance between the existing and emerging interdisciplinary technologies.  JournalsPub aims to provide quality research articles for Academic Researchers, Industrial Professionals, Engineers, Scientists, Professors, etc. working in the areas of Applied Sciences, Medical andEngineeringtocontributeandcommunicateinnovativework. SalientFeatures  An umbrellaof 100+ journalsthatcoversAppliedSciences,MedialandEngineeringArena.  The first and one of the rapidly emerging publication website in Country as well as overseas for its excellenceandexposure.  Universaltransmissionandreflectivity.  ARigorous, Fast andConstructivePeerReviewProcess  SpeedyPublicationof Manuscripts  EminentEditorialBoardMembersfromrenownedorganizations.  FreeRegistration,OnlineSubmission, Processing, Publication&OnlineAccessofManuscripts.  Thejournalpublishesnovelresearcharticleswithemphasison theoreticalandexperimentalwork. International Journal of Polymer Science & Engineering
  • 3. JournalsPub (Division of Dhruv Infosystems Private Ltd.) having its Marketing office located at Office No. 4, First Floor, CSC pocket E Market, Mayur Vihar Phase II, New Delhi-110091, India is the Publisher of Journals. Statements and opinionsexpressedintheJournalreflecttheviews oftheAuthor(s) andarenottheopinionofJournalsPub unless so stated. Subscription Information and Order Cost of Journal National Subscription Rs. 3000/-perJournal(includes2 printissues), SingleIssue copypurchaseRs.1800/copy International Subscription OnlineOnly- $99, PrintOnly-$149 (includes2printissues) Online+ Print-$199(includes2printissues +onlineaccessof publishedbackvolumes) To purchaseprintcompilationof backissues pleasesendyourqueryatinfo@journalspub.com Subscription must be prepaid. Rates outside the India include speed delivery charges. Prices subject to change without notice. Mode of Payment:At par cheque, Demand draft, and RTGS (payment to be made in favor of Dhruv Infosystems Pvt. ltd., payableatDelhi/NewDelhi. OnlineAccess Policy A). ForAuthors: In order to provide maximum citation and wide publicity to the authors work, JournalsPub also have OpenAccess Policy; Authors who would like to get their work open access can opt for Optional Open Access publication at nominal cost as follows: India,SARC andAfricanCountries:INR 1500 includingsinglehardcopyofAuthor's Journal. OtherCountries:USD 200includingsinglehardcopyofAuthor's Journal. B.) ForSubscribers: Online access will be activated within 72 hours of receipt of the payment (working days), subject to receipt of correct informationonuser details/StaticIPaddress of thesubscriber. The accesswillbeblocked: If the user requests for the same and furnishes valid reasons for blocking due to technical issue. Misuse of the access rights as pertheaccesspolicy. Advertising and Commercial Reprint Inquiries: JournalsPub with wide circulation and visibility offer an excellent media for showcasing/promotion of your products/services and the events-namely, Conferences, Symposia/Seminars etc.These journals have very high potential to deliver the message across the targeted audience regularly with each published issue. The advertisements on bulk subscriptions, gift subscriptions or reprint purchases for distribution etc. are also very welcome. LostIssue Claims:Pleasenotethefollowingwhen applyingfor lostor missingissues: Claims for print copies lost will be honored only after 45 days of the dispatch date and before publication of the next issue as perthefrequency. Tracking id for the speed post will be provided to all our subscribers and the claims for the missing Journals will be entertainedonlywiththeproofs whichwillbeverifiedatboththeends. Claimsfiledduetoinsufficient(or nonotice)ofchangeof address willnotbehonored. Change ofAddress of Dispatch should be intimated to JournalsPub at least 2 months prior to the dispatch schedule as per thefrequencyby mentioningsubscriberID andthesubscriptionID. Refundrequestswillnotbeentertained. LegalDisputes AllthelegaldisputesaresubjectedtoDelhiJurisdictiononly. If you haveanyquestions,pleasecontactthePublicationManagementTeam: info@journalspub.com;Tel:+910120-4347644.
  • 4. International Journal of Polymer Science & Engineering The International Journal of Polymer Science & Engineering publishes an original research article that comprehensively deals with the fundamentals of Polymer Science & Engineering, it also focuses on the editorial reviews covering recent trends in polymer engineering. Both theoretical and experimental papers are welcome all, these papers are peer-reviewed by experts and only high impact papers are published. Journalalsopublishesproceedingsthatareinfluentialtothescientificcommunity. Focus andScopeoftheJournal  Biopolymer  Conjugated microporous polymer  Biopolymer  Conjugated microporous polymer  Polyanhydrides  Polymer adsorption  Polymer separators  Polymerization  Polymersome  Plastics engineering International Journal of Polymer Science & Engineering is published twice a year (bi-annual) by JournalsPub, an imprint of Dhruv Infosystems Pvt. Ltd., India. The outlooks stated in the articles do not essentially reflect of the publisher. The publisher does not endorse the quality or value of the advertised/sponsored products described therein. Please consult full prescribing information before issuing aprescriptionfor anyproductsmentionedinthispublication. No part of this publication may be reproduced, stored in retrieval or transmitted in any form without written permissiontothepublisher. To cite any of the material contained in this journal, in English or translation, please use the full English reference at the beginning of each article. To reuse any of the material, please contact JournalsPub (info@journalspub.com).
  • 5. PUBLICATION MANAGEMENT TEAM INTERNAL MEMBERS Associate Manager Chairman Mr. Puneet Mehrotra Managing Director, JournalsPub, New Delhi Hidam Renubala Ankita Singh Deepika Bhadauria Rekha Rani Commissioning Editors Dr. Chhavi Goel Manisha Dhoble
  • 6. EDITORIAL BOARD MEMBERS Alexander Russell Mechanical Process Engineering, University of Magdeburg, Germany. Dr. Animes K Golder Department of Chemical Engineering, Indian Institute of Technology, Assam, India. Dr. Asif Mahmood Department of Chemical Engineering, King Saud University, Riyadh, Saudi Arabia. Prof. Ateeq Rahman Department of Chemistry, Bindura University of Science Education, Bindura, Zimbabwe. Dr. Bharat Modhera Department of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal, India. Prof. C. M. Narayanan Department of Chemical Engineering, National Institute of Technology, Durgapur, India. Dr. Chandi Charan Malakar Department of Chemistry, National Institute of Technology, Imphal, India. Prof. Chang-Yu Sun, China University of Petroleum, Beijing, China. Dr. Dharam Pal, Department of Chemical Engineering, National Institute of Technology, Raipur, India. Dr. Didik Prasetyoko, Department of Chemistry, Faculty of Mathematics and Sciences, ITS, Surabaya, Indonesia. Dr. M. Jhansi L. Kishore Department of Chemical Engineering, Institute of Technology, Nirma University, Ahmedabad, India. Dr. Mohamed Abashar, Department of Chemical Engineering, College of Engineering, King Saud University, Saudi Arabia. Dr. Nagamalleswara Rao Kanidarapu Bapatla Engineering College (Autonomous), Bapatla, Andhra Pradesh, India. Dr. Nanda Gopal Sahoo Department of Chemistry, Nanoscience and Nanotechnology Centre D. S. B. Campus, Kumaun University, Uttarakhand, India. Dr. P. A. Pawar Department of Chemical Technology, Sant Gadge Baba Amravati University, Amravati, India. Prof. Radha Das Department of Chemical Engineering, West Bengal University of Technology, India. Dr. Rajendrasinh Jadeja Department of Chemistry, The M.S. University of Baroda, Vadodara, India. Saeed Soltanali Research Institute of Petroleum Industry (RIPI), Iran. Saeed Soltanali Research Institute of Petroleum Industry (RIPI), Iran. Mr. Sanjay L Bhagat, Pravara Rural Engineering College, Maharashtra, India.
  • 7. EDITORIAL BOARD MEMBERS Dr. Shi-Peng Sun, National University of Singapore, Singapore. Dr. Shivkumar Ranganathan R & D (Battery), Su-Kam Power Systems Limited, Apparel Park Cum Industrial Area, Himachal Pradesh, India. Dr. Soumitra Kumar Choudhuri, Department of In Vitro Carcinogenesis, Chittaranjan National Cancer Institute, Calcutta, India. Dr. Srinivasan Anandan, Center for Nano-materials, International Advanced Research Centre for Powder Metallurgy & New Materials (ARCI), Bolapur, Hyderabad, India. Dr. Stoyan Novakov Nedeltchev Helmholtz Zentrum Dresden-Rossendorf Institute of Fluid Dynamics, Germany. Dr. Suryya K Rana Dungarpur College of Engineering & Technology, India. Dr. Suyogkumar V. Taralkar Chemical Engineering Department, MIT Academy of Engineering, Pune, India. Dr. T. K. Radhakrishnan Department of Chemical Engineering, National Institute of Technology, Tiruchirappalli, India. Dr. V. Venkata Basava Rao Faculty of Technology, Principal Investigator for Centre of Excellence TEQIP Coordinator, University College of Technology (A), Osmania University Hyderabad, India. Dr. Vangalapati Meena, Department of Chemical Engineering, A. U. C. E (A), Andhra University, Andhra Pradesh, India. Prof. Velluru Sridevi Department of Chemical Engineering, A. U. College of Engineering, Andhra University, India. Dr. Vijaya Kumar Bulasara Department of Chemical Engineering, Thapar University, Patiala, India. Dr. Vipan Kumar Sohpal Department of Chemical Engineering & Biotechnology, Beant College of Engineering & Technology, Punjab, India. Dr Wenming Yang, National University of Singapore, Singapore. Dr. Zhi Shang Louisiana State University, United States.
  • 8. From the Editor's Desk Dear Readers, We would like to present, with great pleasure, the inaugural volume of a new scholarly journal, International Journal of Polymer Science & Engineering. This journal is part of the Applied Sciences, and is devoted to the scope of present Polymer Engineering issues, from theoreticalaspectstoapplication-dependentstudiesand thevalidationofemergingtechnologies. This new journal was planned and established to represent the growing needs of Polymer Science & Engineering as an emerging and increasingly vital field, now widely recognized as an integral part of scientific and technical investigations. Its mission is to become a voice of the Polymer Engineering community,addressing researchersandpractitionersinthisarea. The core vision of International Journal of Polymer Science & Engineering in JournalsPub is to propagate novel awareness and know-how for the profit of mankind ranging from the academic and professional research societies to industry practitioners in a range of topics in Polymer Science & Engineering in general. JournalsPub acts as a pathfinder for the scientific community to publish their papers at excellently, well-time&successfully. International Journal of Polymer Science & Engineering focuses on original high-quality research in the realm of Alternative energy conversion & transport mechanisms, Thermodynamics, Chemical reaction engineering, Polymer Science and Engineering, Modern instrumental analysis, Colloidal and interfacial science,Moleculardynamics&Chemicalkinetics,and manymore. Many scientists and researchers have contributed to the creation and the success of the Polymer Science & Engineering. We are very thankful to everybody within that community who supported the idea of creating an innovative platform. We are certain that this issue will be followed by many others, reporting new developmentsinthefieldofPolymerEngineering. This issue would not have been possible without the great support of the Editorial Board members, and we would like to express our sincere thanks to all of them. We also like to express our gratitude to the editorial staffofJournalsPub,who supported us ateverystageoftheproject. It is our hope that this fine collection of articles will be a valuable resource for Polymer Engineering readers and willstimulatefurtherresearchintothevibrantareaofPolymerScience&Engineering. PuneetMehrotra ManagingDirector
  • 9. 1. Effect of Heat Ageing on Mechanical Properties of Polyamide 6(Nylon 6) and Polyamide 12(Nylon 12) Hitkam Pandya, Jinkal Mistry, Lokesh Jain, Kathan Patel, Sandeep Rai 1 2. Sal Wood Flour and Its Mechanical Behavior Mahaveer Jain 13 3. Article on Polyurethanes That Are Based on Tung Oil Rishabh Singh Kuperkar 18 4. Natural Rubber and the Resin Exuded from Ailan malab Tree John Jacob 24 5. Plastics Product Design and Analysis Mujahid A. Ansari, Srushti Wadekar, Priyanka Gaikwad, Sujata Shinde 31 Contents
  • 10. IJPSE (2016) 1-12 © JournalsPub 2016. All Rights Reserved Page 1 International Journal of Polymer Science and Engineering eISSN: 2455-8745 Vol. 2: Issue 2 www.journalspub.com Effect of Heat Ageing on Mechanical Properties of Polyamide 6(Nylon 6) and Polyamide 12(Nylon 12) Hitkam Pandya1 , Jinkal Mistry1 , Lokesh Jain2 , Kathan Patel3 , Sandeep Rai1,3* 1 GRP Limited, Panoli Industrial Estate, GIDC, Bharuch, Gujarat, India 2 Narmada Valley Rubber Pvt Ltd, GIDC, Ankleshwar, Bharuch, Gujarat, India 3 Shorff S.R. Rotary Institute of Chemical Technology, Vataria, Ankleshwar, Bharuch, Gujarat, India ABSTRACT Polyamide 6 or nylon 6(PA 6) and polyamide 12 or Nylon 12 (PA 12) are well known engineering semi-crystalline polar polymers characterized by the presence of amide linkage (-CONH-) in the repeating units of their chains. The glass transition temperature (Tg) of PA 6 and PA 12 is ~50 and ~37°C, respectively. PA 6 is widely used for gears and bearings, fittings in automobile industry for under hood parts and also as a material for power tools housings. PA 12 is mainly used for special applications in automobile industry like, to prepare fuel tank and oil-gasoline resistant pipes/tubes. When any polymer is used for a long period of time, it becomes aged. Heat aging process affects not only the material property but also decide the service life of polymer. Therefore study of heat aging properties of polymers is a fundamental topic both from academic and industrial view-point. In the present study, Injection molded specimens of PA 6 and PA 12 were heat-aged in an oven at a temperature ranging from below the glass transition temperature (Tg) of PA and above the Tg for a specific period ranging. The heat aging effects on PA 6 and PA 12 in terms of mechanical properties such as tensile modulus (E), tensile yield strength (σy), elongation at break (εb) and Izod impact strength were investigated under various conditions. Extensive literature survey revealed that, no such systematic aging studies for Nylon 6 and Nylon 12 are reported so far. Keywords: polyamide, heat ageing effect, mechanical properties, morphology INTRODUCTION Now a day’s polyamides are useful in different types of applications like Electric and Electronics applications, under hood parts of automobiles, to make safety air bags to make ropes which are used by rock and ice climbers, brush filaments, wire coating, coil forms, and gears, etc. As Polyamides have tough, possessing high tensile strength, elasticity, luster and also have good chemical resistance, so if we want to apply such applications according to its properties, then we need to study how polyamides behave after a long age in atmosphere. Polyamides have high heat distortion temperature (HDT) and good mechanical properties, such as tensile strength and tensile modulus. Polyamide can also be used in high temperature environments. However, when polyamides is exposed to a high temperature for a prolonged period, such as, in case with objects that serve in automotive under-the-hood applications and in electric and electronic applications, the polymer generally starts to show
  • 11. IJPSE (2016) 13-17 © JournalsPub 2016. All Rights Reserved Page 13 International Journal of Polymer Science and Engineering eISSN: 2455-8745 Vol. 2: Issue 2 www.journalspub.com Sal Wood Flour and Its Mechanical Behavior Mahaveer Jain* Department of Chemistry, IFTM University, Lodhipur Rajput, Delhi Road, Moradabad, U.P., India ABSTRACT In this paper mechanical parameters of polypropylene (PP) to a limit of 15 wt% of copolymer are investigated. The PP/SEBS blend with 15 wt% of copolymer is then changed to 14, 16, 31 and 55 wt% of sal wood. The tensile properties like modulus, strength, and impact strength are observed. The effect of salt spray on these properties is also the part of study. The results were found to be very mesmerizing. Keywords: polypropylene, sal wood, salt spray, SEBS, wood flour INTRODUCTION Due to a growing environmental awareness throughout the world by the environmentalists, it has triggered a paradigm shift towards selecting materials compatible with the environment. Owing to their excellent mechanical properties, composite materials have been widely used throughout the last four decades. The use of natural fibers, as reinforcing fibers in both thermoplastics and thermosets matrix composites provides positive environmental benefits with respect to ultimate disposability and raw material utilization.[1] Polypropylene (PP) is a polymer with a very simple chemical structure which is probably the most used mineral filled thermoplastic polymer for injection molding applications.[2,3] Fillers into polymer, find applications in the polymer industry almost exclusively, e.g. to improve mechanical, thermal, electrical properties and dimensional-stability.[4–6] Over the past two decades, natural fibers have been replacing synthetic fiber reinforcement such as glass fiber in polymer.[7,8] The advantages of these fibers are low density, low cost, acceptable specific strength, good thermal insulation properties, reduced dermal and respiratory irritation, reduced tool wear, renewable resource and recycling possible without affecting the environmental damage, and together with biodegradable ability.[9–13] Polymer with fillers based composites has received considerable interest in the materials field because of their potential for large gains in mechanical properties. The understanding of mechanical properties of the fillers, mainly wood flour and PP based composites is very important in order to use in different applications, such as, the automotive and building industries in which they are used in structural applications as fencing, decking, outdoor furniture, window parts, roofline products, door panels, etc.[14,15] Although there are several reports in the literature which discuss the of wood/polymer composites;[16–19] however, very limited work has been done on effect of addition of wood flour into polypropylene on its mechanical behavior. Generally these composites are also used corrosive environment. In this paper, a study of effect of addition of Sal wood
  • 12. IJPSE (2016) 18-23 © JournalsPub 2016. All Rights Reserved Page 18 International Journal of Polymer Science and Engineering eISSN: 2455-8745 Vol. 2: Issue 2 www.journalspub.com Article on Polyurethanes That Are Based on Tung Oil Rishabh Singh Kuperkar* Department of Applied Chemistry, Sardar Vallabhbhai National Institute of Technology (SVNIT), Ichchhanath, Surat, Gujarat, India ABSTRACT Polyurethane (PU) formulated from natural polyols obtained from Tung oil (TO) have improved hydroxylation of the double bonds in the fatty acid chains of the unsaturated oil followed by the alcoholysis of the hydroxylated oil. The comparative chemical analysis between unmodified and modified TO suggested that the hydroxyl content increased significantly after the hydroxylation and alcoholysis reactions. Incorporated wood flour (WF), microcrystalline cellulose (MCC) or rice husk ash (RHA) as fillers in modified TO imparts between formulation in physical, thermal and mechanical properties of reinforced rigid PUs. Keywords: composites, foams, polyurethanes, thermosetting polymers, tung oil INTRODUCTION Use of renewable natural products as an alternative source for nonrenewable material has gained enormous importance in the research and industries since decade. Vegetable oils are relatively low cost materials and offer prior quality of biodegradation. Chemically, they are composed of triglyceride molecules obtained from esters of glycerol and fatty acid chains with 16–22 carbon atoms with 0–3 double bonds per chain. It is the unsaturated fatty acid which offers many reactive sites to obtain the desire polymeric product according to industrial applications [1]. Tung oil obtained from the seeds or nuts of the tung tree belongs to the family of Euphorbiaceae [2, 3]. This oil is interesting because of its major constituent α-eleostearic acid (77–82%) with three conjugated double bonds, oleic acid (3.5– 12.7%) with one double bond and linoleic acid (8–10%) with two non-conjugated double bonds structural formula is presented in Figure 1 [4, 5]. The exothermi c reaction between isocyanates and alcohols is the most important reaction in PU synthesis leading to the production of urethane [-NH-COO-] linkages. There is no -OH (hydroxyl) group and free acids in the unmodified TO. The carbon- carbon double bonds can be used to introduce new reactive groups through a hydroxylation reaction. Additionally, the triglyceride molecules can be cut through transesterification reaction with molecules such as glycerol or triethanolamine, which also allows in increasing the concentration of hydroxyls per molecule. The resulting oil-based polyols can be used as a replacement of synthetic polyol to produce PUs which is used in paints and varnish industries [1, 2, 6–8]. Structurally, these long pendant chains and modified fatty acids with the hydroxyl groups imparts effective thermosetting nature, flexibility, high strength elasticity and hydrolytic resistance to the network,
  • 13. IJPSE (2016) 24-30 © JournalsPub 2016. All Rights Reserved Page 24 International Journal of Polymer Science and Engineering eISSN: 2455-8745 Vol. 2: Issue 2 www.journalspub.com Natural Rubber and the Resin Exuded from Ailan malab Tree John Jacob* Department of Physics, Vemana Institute of Technology, Bangalore, Karnataka, India Abstract Elastomeric blends of natural rubber and exuded resin of Ailanthus malabaricum tree have been prepared from solution casting technique. Benzene was used as the common solvent for both the constituent polymers. Compared to the elasticity of natural rubber, the resin exhibits excellent elasticity. The combination of both the elastomers with different composition showed a considerable enhancement in elasticity of rubber. Universal testing machine was employed to study the tensile properties of the resulting blend system. Tensile strength, elongation at break and modulus at various elongations were determined from this experiment. Tensile strength of natural rubber reduced and elongation at break increased by the addition of exuded resin. Modulus of the samples was also reduced with the addition of exuded resin. Surface hardness of the blend was measured from Shore A durometer and it shows a reduction in hardness with the incorporation of resin into natural rubber. From the overall tensile and hardness studies, it can be concluded that the resin collected from Ailanthus malabaricum tree has been used to enhance the elastic performance of natural rubber. Keywords: Ailanthus malabaricum tree, elastomer, natural rubber, tensile strength INTRODUCTION Blending of two or more polymers has been one of the major areas of research and development in the field of polymer science. The technology of polymer blends is a best solution to achieve desired material with suitable properties for the end use application. It reduces the research and development expense compared to the development of new polymers or monomers [1–3]. The phase structure of the resulting material can be either miscible or immiscible when two or more polymers are mixed. Most of the blends are immiscible and its physical properties are poor compared to their constituent polymers. This problem can be solved by the addition of compatibilizers into the blend by enhancing the favorable interaction between the blend phases [4, 5]. Formation of interpenetrating polymer network is the other way to obtain the blend with better stability. Interpenetrating polymer networks (IPNs) are unique type of polymer alloys consisting of two or more cross-linked polymers with no covalent bonds or grafts between them [6]. When one of the phases is cross-linked, pseudo- or semi-IPNs will be formed. When both phases are cross-linked full- IPNs are developed [7]. These intimate mixtures of cross-linked polymers are held together by permanent entanglements lead to forced miscibility compared with usual blends and the resulting materials exhibit good dimensional stability. IPN materials offer great promise for the future in view of the increasing number of applications of these
  • 14. IJPSE (2016) 31–34 © JournalsPub 2016. All Rights Reserved Page 31 International Journal of Polymer Science and Engineering eISSN: 2455-8745 Vol. 2: Issue 2 www.journalspub.com Plastics Product Design and Analysis Mujahid A. Ansari*, Srushti Wadekar, Priyanka Gaikwad, Sujata Shinde Department of Plastics & Polymer Engineering, Maharashtra Institute of Technology, Aurangabad, India ABSTRACT Product design of commonly used articles like key-chains is to make it more attractive, user friendly, cost effective yet durable and providing longevity. Therefore, this work deals with the designing of optimized 3D model of key-chain if suitable shape and size and doing its analysis in Moldflow analysis software to study the material flow behaviour, impact of processing parameters on the product and possible defects after one complete cycle of processing. Lastly by trial and error method we could minimize the defects and could optimize the product design for better and smooth production. Keywords: moldflow, optimize, product design INTRODUCTION Why design a product specifically made of plastics material? Usually, the reason to design products made of plastics is either to create new products, never made before, or to create something similar to existing old products but which is better, more appealing to the user, or more economical to produce. "The design is the problem of anticipating or trying to do what will be required in future and improving what is being already produced”. Plastic products† are a dominant part of the manufacturing world. It is very likely that you the reader could, at this moment, reach out and touch a plastic product from where you sit. Successful product design requires knowledge, intelligence, and flair. The knowledge requirement may in turn be subdivided into[1–3] : (1) Knowledge of the requirements of the product. (2) Knowledge of the behaviour of plastics materials. (3) Knowledge of plastics processes. (4) Knowledge of all relevant economic and psychological factors. Intelligence is required to relate this knowledge, and flair to bring the design to a successful reality FACTORS TO BE CONSIDERED WHILE DESIGNING A PRODUCT While designing a product, several factors are considered, some of them are: Materials: Materials should be cheap and should be able to withstand design requirements. During production wastage, should be minimized. Manufacturing facility: Product design should commensurate with the facilities available in the factory about to equipment, labour, and layout. Aesthetic: The product should be good in appearance and should have attractive colours. Tolerance: It should have desired tolerances, as tight tolerances will result in increased rejection and thereby adding to the cost of product.
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