This document describes several methods for quantitatively analyzing the components of organic compounds:
1. Carbon and hydrogen are estimated by burning the compound in oxygen and measuring the amount of water and carbon dioxide produced.
2. Nitrogen can be estimated using the Dumas or Kjeldahl methods, which involve heating the compound to produce nitrogen gas or ammonia for measurement.
3. Other elements like halogens, sulfur, phosphorus, and oxygen can be estimated through various oxidation and precipitation reactions to form compounds that can be weighed or titrated. Formulas are provided for calculating the percentage of each element from the experimental results.
An organic species which has a carbon atom bearing only six electrons in its outermost shell and has a positive charge is called carbocation.
The positively charged carbon of carbocation is sp2 hybridized.
The unhybridized p-orbital remains vacant.
They are highly reactive and act as reaction intermediate.
They are also called carbonium ion.
An organic species which has a carbon atom bearing only six electrons in its outermost shell and has a positive charge is called carbocation.
The positively charged carbon of carbocation is sp2 hybridized.
The unhybridized p-orbital remains vacant.
They are highly reactive and act as reaction intermediate.
They are also called carbonium ion.
Introductory PPT on Metal Carbonyls having its' classification,structure and applications.This is a basic level PPT specially prepared for UG/PG Chemistry students.
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups. A compound containing a carbonyl group is often referred to as a carbonyl compound.
Introductory PPT on Metal Carbonyls having its' classification,structure and applications.This is a basic level PPT specially prepared for UG/PG Chemistry students.
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups. A compound containing a carbonyl group is often referred to as a carbonyl compound.
Estimation of phosphorus loss from agricultural land in the heartland region ...LPE Learning Center
Full Proceedings is available at: http://www.extension.org/72813
Phosphorus (P) indices are a key tool to minimize P loss from agricultural fields but there is insufficient water quality data to fully test them. Our goal is to use the Agricultural Policy/Environmental eXtender Model (APEX), calibrated with existing edge-of-field runoff data, to refine P indices and demonstrate their utility as a field assessment tool capable of protecting water quality. In this phase of the project our goal is to use existing small-watershed data from the Heartland Region (IA, KS, MO and NE) to determine the level of calibration needed for APEX before using the model to generate estimates of P loads appropriate for evaluating a P Index.
Modeling phosphorus runoff in the chesapeake bay region to test the phosphoru...LPE Learning Center
Full Proceedings available at: http://www.extension.org/72795
The revision of USDA-NRCS’s standard for nutrient management coincided with significant assessment of the performance of Phosphorus (P) Indices in the six states that are tied to the Chesapeake Bay watershed. The 64,000 square mile watershed is the focus of unprecedented activity around nutrient management as a result of a 2011 Total Maximum Daily Load for P, nitrogen (N), and sediment under the Clean Water Act. In addition, the state of Maryland had required updates to it’s original P Index, resulting in broad scrutiny by various interest groups. Within this setting, USDA-NRCS funded a multi-state project to help advance the testing and harmonization of P-based management in the Chesapeake region.
Comparatives Study of Soil Organic Carbon (SOC) under Forest, Cultivated and ...Surendra Bam
The journal article is based upon the need of sustainable land use management of different land use types for improving their carbon sequestration and hence supporting to mitigate climate change impacts.
The most frequently used methods for measuring protein content in foods include the Kjeldahl method, Dumas method, direct measurement methods using UV-spectroscopy and refractive index measurement. Each method has advantages and disadvantages
1-Consider the reaction when aqueous solutions of magnesium sulfat.docxdorishigh
1-Consider the reaction when aqueous solutions of magnesium sulfate and manganese (II) nitrate are combined. The net ionic equation for this reaction is:
2-Consider the reaction when aqueous solutions of lead nitrate and aluminum sulfate are combined. The net ionic equation for this reaction is:
3-Consider the reaction when aqueous solutions of ammonium phosphate and sodium iodide are combined. The net ionic equation for this reaction is:
4-Consider the reaction when aqueous solutions of magnesium bromide and potassium phosphate are combined. The net ionic equation for this reaction is:
5-Consider the reaction when aqueous solutions of ammonium sulfide and magnesium sulfate are combined. The net ionic equation for this reaction is:
6-Consider the reaction when aqueous solutions of potassium nitrate and barium sulfide are combined. The net ionic equation for this reaction is:
7-Consider the reaction when aqueous solutions of sodium sulfide and potassium nitrate are combined. The net ionic equation for this reaction is:
8-Consider the reaction when aqueous solutions of ammonium phosphate and potassium nitrate are combined. The net ionic equation for this reaction is:
9-Consider the reaction when aqueous solutions of iron(III) nitrate and copper(II) sulfate are combined. The net ionic equation for this reaction is:
10-How many mL of 0.406 M HI are needed to dissolve 5.97 g of CaCO3?
2HI(aq) + CaCO3(s) CaI2(aq) + H2O(l) + CO2(g)
mL
11-A 0.5488 g sample of a pure soluble chloride compound is dissolved in water, and all of the chloride ion is precipitated asAgCl by the addition of an excess of silver nitrate. The mass of the resulting AgCl is found to be 1.1541 g.
What is the mass percentage of chlorine in the original compound?
%
12-A student determines the aluminum content of a solution by first precipitating it as aluminum hydroxide, and then decomposing the hydroxide to aluminum oxide by heating. How many grams of aluminum oxide should the student obtain if her solution contains 51.0 mL of 0.583 M aluminumnitrate?
g
13-Write a net ionic equation to show that hydrobromic acid, HBr, behaves as an acid in water.
14-Write a net ionic equation to show why solid potassium hydroxide, KOH (s), forms a basic solution when it dissolves in water.
15-The substance ethylamine is a weak nitrogenous base like ammonia.
Write a net ionic equation to show how ethylamine, C2H5NH2, behaves as a base in water.
16-Write a net ionic equation for the reaction that occurs when aqueous solutions of sodium hydroxide and hydrobromic acid are combined.
17-Write a net ionic equation for the reaction that occurs when aqueous solutions of potassium hydroxide andhypochlorous acid are combined.
18-Write a net ionic equation for the reaction that occurs when aqueous solutions of ammonia and acetic acid are combined
19-Write a net ionic equation for the reaction that occurs when aqueous solutions of hydrobromic acid and ammonia are combined
...
The combination of a carbonyl group and a hydroxyl on the same carbon atom is called a carboxyl group. Compounds containing the carboxyl group are called carboxylic acids. The carboxyl group is one of the most widely occurring functional groups in organic chemistry.
Aromatic Carboxylic acids: Carboxylic acids have an aryl group bound to the carboxyl group is known as aromatic carboxylic acids. The general formula of an aliphatic aromatic carboxylic acid is Ar-COOH.
Acidity of carboxylic acid:
A carboxylic acid may dissociate in water to give a proton and a carboxylate ion. Dissociation of a carboxylic acid involves breaking an O-H bond gives a carboxylate ion with the negative charge spread out equally over two oxygen atoms, compared with just one oxygen atom in an alkoxide ion. The delocalized charge makes the carboxylate ion more stable therefore; dissociation of a carboxylic acid to a carboxylate ion is less endothermic.
Preparation Methods:
1. Oxidation:
The oxidation of aldehyde with oxidizing agents such as CrO3 to forms carboxylic acids containing the same numbers of carbon atoms with a oxidizing agents like chromic acid, chromium trioxide. The silver oxide (Ag2O) in aqueous ammonia solution (Tollen’s reagent) is mild reagent give good yield at room temperature. E.g. Acetaldehyde reacts with CrO3 in aqueous acid to give acetic acid.
2. Grignard reagents (from CO2):
Carboxylic acid can be prepared by the reaction of Grignard reagent (alkyl magnesium halide) with carbon dioxide (CO2) in presence of dry ether. Grignard reagents react with carbon dioxide to forms a magnesium carboxylates which on hydrolysis by dilute HCl produces carboxylic acids.
3. Hydrolysis of nitrile:
The hydrolysis of nitrile or cyanide in presence of dilute acid to forms a carboxylic acid. In this reaction –CN group is converted to a –COOH group.
4. Hydrolysis Reactions:
All the carboxylic acid derivatives can be hydrolyzed into the carboxylic acid in the acidic or basic media; the hydrolysis reaction is fast and occurs in presence of water with no acid or base catalyst.
1. From Ester (Hydrolysis of ester): Ester can be hydrolyzed in either acidic or basic medium to yield carboxylic acid. The ester is heated with an excess of water contains strong acid or base catalyst.
Properties of Carboxylic Acids:
1. Low molecular weights carboxylic acids are colourless liquid at room temperature i.e. lower member ate liquid up to C9 and have characteristic odors whereas higher members are solid.
2. Carboxylic acids are polar organic compound. Low molecular weight carboxylic acids (first four members) are soluble in water whereas solubility in water decrease as molecular weight and chain lengthing increases.
3. Aromatic acids are insoluble in water.
4. Carboxylic acids have higher melting and boiling point due to their capacity to readily form stable hydrogen-bonded dimers.
Learning objectives
Introduction
Preparation of a standard solution used for redox titration
Oxidizing and reducing agents used in volumetric analysis
N/10 potassium permanganate preparation
N/10 potassium dichromate preparation
N/10 Iodine solution preparation
Examples of redox titrations
Conclusion
References
this is a case chapter for class 12 as it was not available on the net however this ppt u won't be able download ...if you personally want it pls contact me on ritik.tatia@gmail.com .......
2. Detection of carbon and hydrogen
Both carbon and hydrogen are estimated in one experiment. A
known mass of an organic compound is burnt in the presence of
excess of oxygen and copper(II) oxide. Carbon and hydrogen in the
compound are oxidised to carbon dioxide and water respectively.
The mass of water produced is determined by passing the mixture
through a weighed U-tube containing anhydrous calcium chloride.
Carbon dioxide is absorbed in another U-tube containing
concentrated solution of potassium hydroxide. These tubes are
connected in series
The increase in masses of calcium chloride and potassium
hydroxide gives the amounts of water and carbon dioxide from
3. The reaction formula for detection of carbon and hydrogen is:-
Estimation of carbon and hydrogen. Water and carbon dioxide
formed on oxidation of substance are absorbed in anhydrous
calcium chloride and potassium hydroxide solutions
respectively contained in U tubes.
4. % C can be calculated by the following formula
% H can be calculated by the following formula
5. Estimation of nitrogen
Nitrogen is estimated by 2 methods :-
1) DUMAS METHOD:-
The nitrogen containing organic compound,
when heated with copper oxide in an atmosphere
of carbon dioxide, yields free nitrogen in addition
to carbon dioxide and water.
ALEXANDER
DUMAS
6. Traces of nitrogen oxides formed, if any, are reduced to
nitrogen by passing the gaseous mixture over a heated copper
gauze. The mixture of gases so produced is collected over an
aqueous solution of potassium hydroxide which absorbs
carbon dioxide. Nitrogen is collected in the upper part of the
graduated tube .
7. Let the mass of organic compound = m g
Volume of nitrogen collected = V1 mL
Room temperature = T1K
Volume of nitrogen at STP= p1V1 273
760 T1
(Let it be V mL) Where p1 and V1 are the pressure and volume of nitrogen, p1 is
different from the atmospheric pressure at which nitrogen gas is collected. The
value of p1 is obtained by the relation,
p1= Atmospheric pressure – Aqueous tension
% of nitrogen can be calculated as :-
8. KJELDAHL’S METHOD:-
The compound containing nitrogen is heated with
concentrated sulphuric acid. Nitrogen in the
compound gets converted to ammonium sulphate.
The resulting acid mixture is then heated with excess
of sodium hydroxide.
The liberated ammonia gas is absorbed in an excess
of standard solution of sulphuric acid. The amount of
ammonia produced is determined by estimating the
amount of sulphuric acid consumed in the reaction.
It is done by estimating unreacted sulphuric acid left
after the absorption of ammonia by titrating it with
standard alkali solution.
The difference between the initial amount of acid
taken and that left after the reaction gives the amount
of acid reacted with ammonia.
JOHN KJELDHAL
9.
10. Let the mass of organic compound taken = m g Volume of
H2SO4 of molarity,M taken = V mL
Volume of NaOH of molarity, M, used for titration of excess of
H2SO4 = V1 mL
V1mL of NaOH of molarity M = V1 /2 mL of H2SO4 of molarity M
Volume of H2SO4 of molarity M unused = (V - V1/2) mL
(V- V1/2) mL of H2SO4 of molarity M = 2(V-V1/2) mL of NH3
solution of molarity M.
Therefore ,1000 mL of 1 M NH3 solution contains 17g NH3 or14g
of N
2(V-V1/2) mL of NH3 solution of molarity M contains:
14 M 2 V V1/2
11. Therefore % of N = 14 M 2 V V1/2 x 100
1000 m
=1.4 M 2 V V1/2
1000
Kjeldahl method is not applicable to compounds containing
nitrogen in nitro and azo groups and nitrogen present in the ring
(e.g. pyridine) as nitrogen of these compounds does not change
to ammonium sulphate under these conditions.
12. Carius method
A known mass of an organic compound is
heated with fuming nitric acid in the
presence of silver nitrate contained in a
hard glass tube known as Carius tube, in a
furnace.
Carbon and hydrogen present in the
compound are oxidised to carbon dioxide
and water. The halogen present forms the
corresponding silver halide (AgX). It is
filtered, washed, dried and weighed.
OTTO CARIUS
13. Let the mass of organic compound taken = m g
Mass of AgX formed = m1g 1mol of AgX contains
1 mol of X
Mass of halogen in m1g of AgX = atomic mass of X x
m1g
molecular mass of
AgX
% of halogen = atomic mass of X m1 100
molecular mass of AgX m
14. Estimation of sulphur
A known mass of an organic compound
is heated in a Carius tube with sodium
peroxide or fuming nitric acid.
Sulphur present in the compound is
oxidised to sulphuric acid. It is
precipitated as barium sulphate by
adding excess of barium chloride
solution in water.
The precipitate is filtered, washed, dried
and weighed. The percentage of SULPHUR ESTIMATION IN
CARIUS TUBE
15. Let the mass of organic compound taken = mg and the mass
of barium sulphate formed = m1g
1mol of BaSO4 =233 g BaSO4 =32 g sulphur
Therefore m1g BaSO4 contains 32 m1 g sulphur
233
% of sulphur = 32 m1 100
233 m
16. Estimation for phosphorus
A known mass of an organic compound
is heated with fuming nitric acid
whereupon phosphorus present in the
compound is oxidised to phosphoric
acid.
It is precipitated as ammonium
phosphomolybdate, (NH4)3
PO4.12MoO3, by adding ammonia and
ammonium molybdate.
Alternatively, phosphoric acid may be
precipitated as MgNH4PO4 by adding
17. Let the mass of organic compound taken = mg and mass of ammonium
phosphomolydate = m1g
Molar mass of (NH4)3PO4.12MoO3 = 1877 g
Percentage of phosphorus =31 x m1 x100
1877 x m
If phosphorus is estimated as Mg2P2O7,
% of phosphorus = 62 m1 100 %
222 x m
where, 222 u is the molar mass of Mg2P2O7, m, the mass of
organic compound taken, m1, the mass of Mg2P2O7 formed and
62, the mass of two phosphorus atoms present in the compound
Mg2P2O7.
18. Estimation of oxygen
A definite mass of an organic compound is
decomposed by heating in a stream of
nitrogen gas.
The mixture of gaseous products containing
oxygen is passed over red-hot coke when
all the oxygen is converted to carbon
monoxide.
This mixture is passed through warm iodine
pentoxide (I2O5) when carbon monoxide is
oxidised to carbon dioxide producing iodine.
19. Let the mass of organic compound taken be m g Mass of
carbon dioxide produced be m1 g
∴ m1 g carbon dioxide is obtained from
32 x m1 g O2
88
∴ % of oxygen = 32 x m1 x 100 %
88 x m
The percentage of oxygen can be derived from the
amount of iodine produced.