The lanthanide contraction is the result of poor shielding of the 4f electrons by inner orbitals. As atomic number increases from La to Lu, the nuclear charge increases and 4f electrons penetrate closer to the nucleus. This causes the atomic and ionic radii to steadily decrease, resulting in smaller sizes down the lanthanide series. Due to the decreasing size, properties like ionization energy and electronegativity increase while chemical reactivity and basicity of hydroxides decrease from La to Lu.