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Study of Chemical and Physical Properties and the Soil Sorption of  Metolachlor and Carbofuran in Three Tropical Soils  Jos é  A. Dumas, Peter Nkedi-Kizza  and  Rafael Montalvo-Zapata
[object Object],[object Object],Introduction Organic Matter Clay Two main soil components associated to pesticide sorption are clay and organic matter
[object Object],Organic matter Organic Matter – Humic and fulvic acids
Humic acid-pesticide interaction Van der Waals and electrostatic interactions. How pesticide’s sorption occurs?
Hypothesis ,[object Object]
Objectives ,[object Object],[object Object]
Hydrogeographic (HP)  map of Puerto Rico   North Coastal Limestone Aquifer South Coastal Alluvial Aquifer Chemico-pharmaceutical industries High urban development
Sampling areas and Soil Series Selected   Tiburones Catano Aguilita
Methods ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Soil properties CCE-Calcium carbonate equivalen; WHC-Water holding capacityt Soil Series pH CCE % Clay % Silt % Sand % WHC Aguilita 8.18 63.13 47.68 22.88 29.44 45 Cata ñ o 8.60 14.01 4.56 3.36 92.08 22 Tiburones 4.07 0.84 17.44 2.84 79.72 38
Organic matter properties HA-humic acid; FA-fulvic acid;  1 mg/50g soil; OC-organic carbon Soil Series HA mg 1 FA mg 1 HA/FA OC % Fat mg/kg OC Aguilita 600 590 1.0 4.08 950 Cata ñ o 25 84 0.3 0.53 161 Tiburones 990 490 2.0 7.93 2730
Fulvic and Humic acid properties E4/E6-absorbance ratio at 400 and 600 nm Soil Series E4/E6 Total Acidity (meq/g humic) HA FA HA FA Aguilita 5.5 10.0 1.4 2.8 Cata ñ o 4.9 6.5 ND 0.44 Tiburones 3.2 10.4 1.6 3.2
Potentiometric tiltration of Fulvic acid -COOH Phenolic OH
Potentiometric tiltration of Humic acid Non  clearly defined  acidic group protons
Derivative spectrum of Humic acid  (100ug/mL) Aguilita Catano Tiburones
Derivative spectrum of Fulvic acid (100ug/mL) Aguilita Catano Tiburones
Main functional groups of Fulvic acids ( β -humus) identified by ATR-IR Aguiliita Catano Tiburones Benzene rings Hydroxy groups Aromatic  C-H Si-H C=O C-O
Main functional groups of Humic acids  identified by ATR-IR Aguiliita Catano Tiburones
Structure of pesticides   Metolachlor Carbofuran Chloroacetanilide  Carbamate
Chemical and physical properties of Metolachlor and Carbofuran MET-metolachlor; CAR-carbofuran Name Family Sol. (mg/L) Koc (mL/g) Kow pK b MET cloroacetanilide 530 200 2820 NA CAR carbamate 700 14-160 17-26 NA
Sorption isotherms for Metolachlor
Soil sorption coefficient   Soil Series Metolachlor Kd Aguilita 3.6 Cata ñ o 1.2 Tiburones 9.3
Conclusion ,[object Object],[object Object]
[object Object],Conclusion
[object Object],Acknowledgement

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Study of Chemical and Physical Properties and the Soil Sorption of Metolachlor and Carbofuran in Three Tropical Soils

  • 1. Study of Chemical and Physical Properties and the Soil Sorption of Metolachlor and Carbofuran in Three Tropical Soils Jos é A. Dumas, Peter Nkedi-Kizza and Rafael Montalvo-Zapata
  • 2.
  • 3.
  • 4. Humic acid-pesticide interaction Van der Waals and electrostatic interactions. How pesticide’s sorption occurs?
  • 5.
  • 6.
  • 7. Hydrogeographic (HP) map of Puerto Rico North Coastal Limestone Aquifer South Coastal Alluvial Aquifer Chemico-pharmaceutical industries High urban development
  • 8. Sampling areas and Soil Series Selected Tiburones Catano Aguilita
  • 9.
  • 10. Soil properties CCE-Calcium carbonate equivalen; WHC-Water holding capacityt Soil Series pH CCE % Clay % Silt % Sand % WHC Aguilita 8.18 63.13 47.68 22.88 29.44 45 Cata ñ o 8.60 14.01 4.56 3.36 92.08 22 Tiburones 4.07 0.84 17.44 2.84 79.72 38
  • 11. Organic matter properties HA-humic acid; FA-fulvic acid; 1 mg/50g soil; OC-organic carbon Soil Series HA mg 1 FA mg 1 HA/FA OC % Fat mg/kg OC Aguilita 600 590 1.0 4.08 950 Cata ñ o 25 84 0.3 0.53 161 Tiburones 990 490 2.0 7.93 2730
  • 12. Fulvic and Humic acid properties E4/E6-absorbance ratio at 400 and 600 nm Soil Series E4/E6 Total Acidity (meq/g humic) HA FA HA FA Aguilita 5.5 10.0 1.4 2.8 Cata ñ o 4.9 6.5 ND 0.44 Tiburones 3.2 10.4 1.6 3.2
  • 13. Potentiometric tiltration of Fulvic acid -COOH Phenolic OH
  • 14. Potentiometric tiltration of Humic acid Non clearly defined acidic group protons
  • 15. Derivative spectrum of Humic acid (100ug/mL) Aguilita Catano Tiburones
  • 16. Derivative spectrum of Fulvic acid (100ug/mL) Aguilita Catano Tiburones
  • 17. Main functional groups of Fulvic acids ( β -humus) identified by ATR-IR Aguiliita Catano Tiburones Benzene rings Hydroxy groups Aromatic C-H Si-H C=O C-O
  • 18. Main functional groups of Humic acids identified by ATR-IR Aguiliita Catano Tiburones
  • 19. Structure of pesticides Metolachlor Carbofuran Chloroacetanilide Carbamate
  • 20. Chemical and physical properties of Metolachlor and Carbofuran MET-metolachlor; CAR-carbofuran Name Family Sol. (mg/L) Koc (mL/g) Kow pK b MET cloroacetanilide 530 200 2820 NA CAR carbamate 700 14-160 17-26 NA
  • 21. Sorption isotherms for Metolachlor
  • 22. Soil sorption coefficient Soil Series Metolachlor Kd Aguilita 3.6 Cata ñ o 1.2 Tiburones 9.3
  • 23.
  • 24.
  • 25.