HNO3 MANUFACTURING WITH PROCESS FLOW DIAGRAM

2.  From Chile saltpeter
NaNO3 and H2SO4 react to produce
NaHSO4 and HNO3
 Electric oxidation of air
N2 and O2 react (in the presence of
electricity) to form NO and more O2
Produces NO2 and then this is mixed
with water to produce HNO3

3.  By catalytic oxidation of ammonia
(Ostwald’s Process)

4. Fuming Nitric Acid
A red liquid made by bubbling NO2 gas
through concentrated HNO3
Concentrated Nitric Acid
It is of the density of 1.5, containing 98% HNO3
Strong Nitric Acid
It is of the density of 1.4, containing 65% HNO3

5.  Ammonia
 Water
 Air
 Catalyst (Platinum-rhodium gauze)

6.  Oxidation of ammonia
 Oxidation of nitric oxide
 Absorption of NO2

9.  Mixture of air & ammonia heated to
220˚C
 passed through a metal gauze made of
platinum (90%) & Rhodium (10%).
 3X10-4sec
 Reaction produces a lot of heat energy.
 Energy is used to keep reaction vessel
temp at 975-1225 K, typically 1200K

10. Side reaction: favored by high pressure and
over heated catalyst

11. Colourless nitrogen monoxide gas
produced from 1st stage is then reacted
with oxygen from the air to form brown
nitrogen dioxide gas (NO2).

12. The nitrogen dioxide is then dissolved
in water to produce nitric acid
NO2+H20 HNO3+HNO2
HNO2 + NO2 HNO3 + NO
Thus overall reaction
2NO2+H20 2HNO3+ NO

13. Prepare a flow chart to show the
sequence of processes used to convert
ammonia to concentrated nitric acid.
Write equations for significant chemical
reactions beside the appropriate
section of the flow chart.

14. During the Ostwald process, nitrogen
monoxide is made from ammonia at
about 900°C and then cooled to 30°C
before being reacted with air to make
nitrogen dioxide. Both these reactions
are exothermic. Why are the
temperatures used for these reactions
so different?

15. As the gas passes through the catalyst bed in
the converter during nitric acid manufacture,
its temperature increases. The gas must be
cooled before it is mixed with air.
 Why does the temperature of the gas rise?
 Why is it necessary to cool the gas?
 What side benefit is obtained from the need
to cool gases?

16. Describe two ways that expenses are
minimized in the Ostwald process.