know more about nanomaterials and its apllication in future as well as current situation, and what wil we reserch on basis of nanomaterials and carbon structure and its aplication in such futuriastic manner.
Nano Material
Introduction and Synthesis
Nanomaterials describe, in principle, materials of which a single unit is sized (in at least one dimension) between 1 and 1000 nanometres (10ā9 meter) but is usually 1ā100 nm (the usual definition of nanoscale[1]).
Nanomaterials research takes a materials science-based approach to nanotechnology, leveraging advances in materials metrology and synthesis which have been developed in support of microfabrication research. Materials with structure at the nanoscale often have unique optical, electronic, or mechanical properties.
Nanomaterials are slowly becoming commercialized[2] and beginning to emerge as commodities.[3]
Novel effects can occur in materials when structures are formed with sizes comparable to any one of many possible length scales, such as the de Broglie wavelength of electrons, or the optical wavelengths of high energy photons. In these cases quantum mechanical effects can dominate material properties. One example is quantum confinement where the electronic properties of solids are altered with great reductions in particle size. The optical properties of nanoparticles, e.g. fluorescence, also become a function of the particle diameter. This effect does not come into play by going from macrosocopic to micrometer dimensions, but becomes pronounced when the nanometer scale is reached.
Nano Material
Introduction and Synthesis
Nanomaterials describe, in principle, materials of which a single unit is sized (in at least one dimension) between 1 and 1000 nanometres (10ā9 meter) but is usually 1ā100 nm (the usual definition of nanoscale[1]).
Nanomaterials research takes a materials science-based approach to nanotechnology, leveraging advances in materials metrology and synthesis which have been developed in support of microfabrication research. Materials with structure at the nanoscale often have unique optical, electronic, or mechanical properties.
Nanomaterials are slowly becoming commercialized[2] and beginning to emerge as commodities.[3]
Novel effects can occur in materials when structures are formed with sizes comparable to any one of many possible length scales, such as the de Broglie wavelength of electrons, or the optical wavelengths of high energy photons. In these cases quantum mechanical effects can dominate material properties. One example is quantum confinement where the electronic properties of solids are altered with great reductions in particle size. The optical properties of nanoparticles, e.g. fluorescence, also become a function of the particle diameter. This effect does not come into play by going from macrosocopic to micrometer dimensions, but becomes pronounced when the nanometer scale is reached.
Different types of methods can be used for the preparation of Magnetic Nanoparticles, their advantages and disadvantages and applications of the materials in various fields are given in the presentation
Different types of methods can be used for the preparation of Magnetic Nanoparticles, their advantages and disadvantages and applications of the materials in various fields are given in the presentation
Quantum dots were discovered in solids (glassĀ crystals) in 1980 by Russian physicistĀ Alexei EkimovĀ while working at the Vavilov State Optical Institute. In late 1982, American chemistĀ Louis E. Brus, then working at Bell Laboratories (and now a professor at Columbia University), discovered the same phenomenon in colloidal solutions (where small particles of one substance are dispersed throughout another; milk is a familiar example). These two scientists shared the Optical Society of America's 2006 R.W. Wood Prize for their pioneering work.
Fabrication and applications of quantum dots.pptxMuhammadHashami2
Ā
in this presentation i presented about quantum dots, chemical and physical methods that we can obtain or fabricates the quantum dots and also some important applications related to the quantum dots 's unique properties.
A letter is said to be informal when it is written in a friendly manner, to someone you are familiar with. Formal letters are written for official or professional communication. On the other hand, informal letters are used for casual or personal communication. There is a manner prescribed for writing formal letters.
ross-cultural communication is a field of study that looks at how people from differing cultural backgrounds communicate, in similar and different ways among themselves, and how they endeavor to communicate across cultures. Intercultural communication is a related field of study.
Communication is the act of conveying meanings from one entity or group to another through the use of mutually understood signs, symbols, and semiotic rules. The main steps inherent to all communication are: The formation of communicative motivation or reason. Message composition. Message encoding.
Social responsibility is an ethical framework and suggests that an entity, be it an organization or individual, has an obligation to act for the benefit of society at large. Social responsibility is a duty every individual has to perform so as to maintain a balance between the economy and the ecosystems.
Social responsibility is an ethical framework and suggests that an entity, be it an organization or individual, has an obligation to act for the benefit of society at large. Social responsibility is a duty every individual has to perform so as to maintain a balance between the economy and the ecosystems.
Personality development is the relatively enduring pattern of the thoughts, feelings, and behaviors that distinguish individuals from one another. The dominant view in the field of personality psychology today holds that personality emerges early and continues to change in meaningful ways throughout the lifespan
Professional ethics is defined as the personal and corporate rules that govern behavior within the context of a particular profession. An example of professional ethics is the American Bar Association's set of ethical rules that govern an attorney's moral obligations.Human values are the virtues that guide us to take into account the human element when we interact with other human beings. Human values are, for example, respect, acceptance, consideration, appreciation, listening, openness, affection, empathy and love towards other human beings
Successive Differentiation is the process of differentiating a given function successively times and the results of such differentiation are called successive derivatives. The higher order differential coefficients are of utmost importance in scientific and engineering applications.
Electromagnetism is a branch of physics involving the study of the electromagnetic force, a type of physical interaction that occurs between electrically charged particles. The electromagnetic force usually exhibits electromagnetic fields such as electric fields, magnetic fields, and light, and is one of the four fundamental interactions (commonly called forces) in nature. The other three fundamental interactions are the strong interaction, the weak interaction, and gravitation.[1] At high energy the weak force and electromagnetic force are unified as a single electroweak force.
A transformer is a static electrical device that transfers electrical energy between two or more circuits. A varying current in one coil of the transformer produces a varying magnetic flux, which, in turn, induces a varying electromotive force across a second coil wound around the same core. Electrical energy can be transferred between the two coils, without a metallic connection between the two circuits. Faraday's law of induction discovered in 1831 described the induced voltage effect in any coil due to changing magnetic flux encircled by the coil
Electrical Safety. Electrical hazards can cause burns, shocks and electrocution (death). Assume that all overhead wires are energized at lethal voltages. Never assume that a wire is safe to touch even if it is down or appears to be insulated.
Nonverbal communication is the process of sending and receiving messages without using words, either spoken or written. Also called manual language. Similar to the way that italicizing emphasizes written language, a nonverbal behavior may emphasize parts of a verbal message.
Internal communication is the transmission of information between organizational members or parts of the organization. It takes place across all levels and organizational units of an organization.
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) involves the interaction of infrared radiation with matter. It covers a range of techniques, mostly based on absorption spectroscopy. As with all spectroscopic techniques, it can be used to identify and study chemicals
know more about cathodic protection in such manner like some our basis of regular life and where we used parts of machine which is affected by water,air or some other things.
The Art of the Pitch: WordPress Relationships and SalesLaura Byrne
Ā
Clients donāt know what they donāt know. What web solutions are right for them? How does WordPress come into the picture? How do you make sure you understand scope and timeline? What do you do if sometime changes?
All these questions and more will be explored as we talk about matching clientsā needs with what your agency offers without pulling teeth or pulling your hair out. Practical tips, and strategies for successful relationship building that leads to closing the deal.
UiPath Test Automation using UiPath Test Suite series, part 4DianaGray10
Ā
Welcome to UiPath Test Automation using UiPath Test Suite series part 4. In this session, we will cover Test Manager overview along with SAP heatmap.
The UiPath Test Manager overview with SAP heatmap webinar offers a concise yet comprehensive exploration of the role of a Test Manager within SAP environments, coupled with the utilization of heatmaps for effective testing strategies.
Participants will gain insights into the responsibilities, challenges, and best practices associated with test management in SAP projects. Additionally, the webinar delves into the significance of heatmaps as a visual aid for identifying testing priorities, areas of risk, and resource allocation within SAP landscapes. Through this session, attendees can expect to enhance their understanding of test management principles while learning practical approaches to optimize testing processes in SAP environments using heatmap visualization techniques
What will you get from this session?
1. Insights into SAP testing best practices
2. Heatmap utilization for testing
3. Optimization of testing processes
4. Demo
Topics covered:
Execution from the test manager
Orchestrator execution result
Defect reporting
SAP heatmap example with demo
Speaker:
Deepak Rai, Automation Practice Lead, Boundaryless Group and UiPath MVP
"Impact of front-end architecture on development cost", Viktor TurskyiFwdays
Ā
I have heard many times that architecture is not important for the front-end. Also, many times I have seen how developers implement features on the front-end just following the standard rules for a framework and think that this is enough to successfully launch the project, and then the project fails. How to prevent this and what approach to choose? I have launched dozens of complex projects and during the talk we will analyze which approaches have worked for me and which have not.
Epistemic Interaction - tuning interfaces to provide information for AI supportAlan Dix
Ā
Paper presented at SYNERGY workshop at AVI 2024, Genoa, Italy. 3rd June 2024
https://alandix.com/academic/papers/synergy2024-epistemic/
As machine learning integrates deeper into human-computer interactions, the concept of epistemic interaction emerges, aiming to refine these interactions to enhance system adaptability. This approach encourages minor, intentional adjustments in user behaviour to enrich the data available for system learning. This paper introduces epistemic interaction within the context of human-system communication, illustrating how deliberate interaction design can improve system understanding and adaptation. Through concrete examples, we demonstrate the potential of epistemic interaction to significantly advance human-computer interaction by leveraging intuitive human communication strategies to inform system design and functionality, offering a novel pathway for enriching user-system engagements.
Essentials of Automations: Optimizing FME Workflows with ParametersSafe Software
Ā
Are you looking to streamline your workflows and boost your projectsā efficiency? Do you find yourself searching for ways to add flexibility and control over your FME workflows? If so, youāre in the right place.
Join us for an insightful dive into the world of FME parameters, a critical element in optimizing workflow efficiency. This webinar marks the beginning of our three-part āEssentials of Automationā series. This first webinar is designed to equip you with the knowledge and skills to utilize parameters effectively: enhancing the flexibility, maintainability, and user control of your FME projects.
Hereās what youāll gain:
- Essentials of FME Parameters: Understand the pivotal role of parameters, including Reader/Writer, Transformer, User, and FME Flow categories. Discover how they are the key to unlocking automation and optimization within your workflows.
- Practical Applications in FME Form: Delve into key user parameter types including choice, connections, and file URLs. Allow users to control how a workflow runs, making your workflows more reusable. Learn to import values and deliver the best user experience for your workflows while enhancing accuracy.
- Optimization Strategies in FME Flow: Explore the creation and strategic deployment of parameters in FME Flow, including the use of deployment and geometry parameters, to maximize workflow efficiency.
- Pro Tips for Success: Gain insights on parameterizing connections and leveraging new features like Conditional Visibility for clarity and simplicity.
Weāll wrap up with a glimpse into future webinars, followed by a Q&A session to address your specific questions surrounding this topic.
Donāt miss this opportunity to elevate your FME expertise and drive your projects to new heights of efficiency.
DevOps and Testing slides at DASA ConnectKari Kakkonen
Ā
My and Rik Marselis slides at 30.5.2024 DASA Connect conference. We discuss about what is testing, then what is agile testing and finally what is Testing in DevOps. Finally we had lovely workshop with the participants trying to find out different ways to think about quality and testing in different parts of the DevOps infinity loop.
PHP Frameworks: I want to break free (IPC Berlin 2024)Ralf Eggert
Ā
In this presentation, we examine the challenges and limitations of relying too heavily on PHP frameworks in web development. We discuss the history of PHP and its frameworks to understand how this dependence has evolved. The focus will be on providing concrete tips and strategies to reduce reliance on these frameworks, based on real-world examples and practical considerations. The goal is to equip developers with the skills and knowledge to create more flexible and future-proof web applications. We'll explore the importance of maintaining autonomy in a rapidly changing tech landscape and how to make informed decisions in PHP development.
This talk is aimed at encouraging a more independent approach to using PHP frameworks, moving towards a more flexible and future-proof approach to PHP development.
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...DanBrown980551
Ā
Do you want to learn how to model and simulate an electrical network from scratch in under an hour?
Then welcome to this PowSyBl workshop, hosted by Rte, the French Transmission System Operator (TSO)!
During the webinar, you will discover the PowSyBl ecosystem as well as handle and study an electrical network through an interactive Python notebook.
PowSyBl is an open source project hosted by LF Energy, which offers a comprehensive set of features for electrical grid modelling and simulation. Among other advanced features, PowSyBl provides:
- A fully editable and extendable library for grid component modelling;
- Visualization tools to display your network;
- Grid simulation tools, such as power flows, security analyses (with or without remedial actions) and sensitivity analyses;
The framework is mostly written in Java, with a Python binding so that Python developers can access PowSyBl functionalities as well.
What you will learn during the webinar:
- For beginners: discover PowSyBl's functionalities through a quick general presentation and the notebook, without needing any expert coding skills;
- For advanced developers: master the skills to efficiently apply PowSyBl functionalities to your real-world scenarios.
Software Delivery At the Speed of AI: Inflectra Invests In AI-Powered QualityInflectra
Ā
In this insightful webinar, Inflectra explores how artificial intelligence (AI) is transforming software development and testing. Discover how AI-powered tools are revolutionizing every stage of the software development lifecycle (SDLC), from design and prototyping to testing, deployment, and monitoring.
Learn about:
ā¢ The Future of Testing: How AI is shifting testing towards verification, analysis, and higher-level skills, while reducing repetitive tasks.
ā¢ Test Automation: How AI-powered test case generation, optimization, and self-healing tests are making testing more efficient and effective.
ā¢ Visual Testing: Explore the emerging capabilities of AI in visual testing and how it's set to revolutionize UI verification.
ā¢ Inflectra's AI Solutions: See demonstrations of Inflectra's cutting-edge AI tools like the ChatGPT plugin and Azure Open AI platform, designed to streamline your testing process.
Whether you're a developer, tester, or QA professional, this webinar will give you valuable insights into how AI is shaping the future of software delivery.
Kubernetes & AI - Beauty and the Beast !?! @KCD Istanbul 2024Tobias Schneck
Ā
As AI technology is pushing into IT I was wondering myself, as an āinfrastructure container kubernetes guyā, how get this fancy AI technology get managed from an infrastructure operational view? Is it possible to apply our lovely cloud native principals as well? What benefitās both technologies could bring to each other?
Let me take this questions and provide you a short journey through existing deployment models and use cases for AI software. On practical examples, we discuss what cloud/on-premise strategy we may need for applying it to our own infrastructure to get it to work from an enterprise perspective. I want to give an overview about infrastructure requirements and technologies, what could be beneficial or limiting your AI use cases in an enterprise environment. An interactive Demo will give you some insides, what approaches I got already working for real.
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdf91mobiles
Ā
91mobiles recently conducted a Smart TV Buyer Insights Survey in which we asked over 3,000 respondents about the TV they own, aspects they look at on a new TV, and their TV buying preferences.
From Daily Decisions to Bottom Line: Connecting Product Work to Revenue by VP...
Ā
Nanomaterials
1. What is Nanotechnology?
ā¢ The study of the controlling of matter on an atomic and
molecular scale. Generally nanotechnology deals with structures
sized between 1 to 100 nanometer in at least one dimension, and
involves developing or modifying materials or devices within
that size.
3. Disruptive Apps: Materials
ā¢ Fiber that is stronger than spider web
ā¢ Metal 100 xās stronger than steel, 1/6 weight
ā¢ Catalysts that respond more quickly and to more agents
ā¢ Plastics that conduct electricity
ā¢ Coatings that are nearly frictionless ā(Shipping Industry)
ā¢ Materials that change color and transparency on demand.
ā¢ Materials that are self repairing, self cleaning, and never need repainting.
ā¢ Nanoscale powders that are five times as light as plastic but provide the
same radiation protection as metal.
4. ā¢ Fuel cell technology becomes cost effective within 3 years.
ā¢ Batteries that store more energy and are much more efficient
ā¢ Plastics and paints that will store solar power and convert to energy for $1 per
watt.
Continueā¦..
5. ā¢ Nanostructured materials are classified as Zero
dimensional, one dimensional, two dimensional, three
dimensional nanostructures.
(a) 0 D spheres and clusters, (b) 1 D nanofibers, wires, and rods (c)2 D films, plates and networks, (d) 3D nanomaterials
Classification of Nanomaterials
6. Examples of Nanomaterials
Au nanoparticle Buckminsterfullerene FePt nanosphere
Titanium nanoflower Silver nanocubes SnO2 nanoflower
7. Quantum dots
ā¢ Quantum dots (QD) are nanoparticles/structures that
exhibit 3 dimensional quantum confinement, which leads to
many unique optical and transport properties.
Lin-Wang Wang, National Energy Research
Scientific Computing Center at Lawrence Berkeley
National Laboratory. <http://www.nersc.gov>
GaAs Quantum dot containing just 465 atoms.
8. Quantum dots properties
ā¢ Quantum dots are usually regarded as
semiconductors by definition.
ā¢ Similar behavior is observed in some metals.
Therefore, in some cases it may be acceptable
to speak about metal quantum dots.
ā¢ Typically, quantum dots are composed of groups
II-VI, III-V, and IV-VI materials.
ā¢ QDs are bandgap tunable by size which means
their optical and electrical properties can be
engineered to meet specific applications.
9. Quantum Confinement
Definition:
ā¢ Quantum Confinement is the spatial confinement of
electron-hole pairs (excitons) in one or more dimensions
within a material.
ā 1D confinement: Quantum Wells
ā 2D confinement: Quantum Wire
ā 3D confinement: Quantum Dot
ā¢ Quantum confinement is more prominent in
semiconductors because they have an energy gap in
their electronic band structure.
ā¢ Metals do not have a bandgap, so quantum size effects
are less prevalent. Quantum confinement is only
observed at dimensions below 2 nm.
10. Quantum Confinement
ā¢ Recall that when atoms are brought together in
a bulk material the number of energy states
increases substantially to form nearly continuous
bands of states.
N
Energy
Energy
11. Quantum Confinement
ā¢ The reduction in the number of atoms in a material
results in the confinement of normally delocalized energy
states.
ā¢ Electron-hole pairs become spatially confined when the
diameter of a particle approaches the de Broglie
wavelength of electrons in the conduction band.
ā¢ As a result the energy difference between energy bands
is increased with decreasing particle size.
Energy
Eg
Eg
12. Quantum Confinement
ā¢ This is very similar to the famous particle-in-a-box scenario
and can be understood by examining the Heisenberg
Uncertainty Principle.
ā¢ The Uncertainty Principle states that the more precisely one
knows the position of a particle, the more uncertainty in its
momentum (and vice versa).
ā¢ Therefore, the more spatially confined and localized a particle
becomes, the broader the range of its momentum/energy.
ā¢ This is manifested as an increase in the average energy of
electrons in the conduction band = increased energy level
spacing = larger bandgap
ā¢ The bandgap of a spherical quantum dot is increased from its
bulk value by a factor of 1/R2, where R is the particle radius.*
* Based upon single particle solutions of the schrodinger wave equation valid for R< the exciton bohr ra
13. Quantum Confinement
ā¢ What does this mean?
ā Quantum dots are bandgap tunable by size. We can
engineer their optical and electrical properties.
ā Smaller QDs have a large bandgap.
ā Absorbance and luminescence spectrums are blue
shifted with decreasing particle size.
Energy
650 nm555 nm
14. Quantum Dots (QD)
ā¢ Nanocrystals (2-10 nm) of
semiconductor compounds
ā¢ Small size leads to
confinement of excitons
(electron-hole pairs)
ā¢ Quantized energy levels
and altered relaxation
dynamics
ā¢ Examples: CdSe, PbSe,
PbTe, InP
Eg
16. QD Synthesis: Colloidal
Methods
Journal of Chemcial Education. Vol. 82 No.11 Nov 2005
ā¢ Example: CdSe quantum dots
ā¢ 30mg of Elemental Se and 5mL of octadecene are
used to create a stock precursor Se solution.
ā¢ 0.4mL of Trioctylphosphine oxide (TOPO) is added to
the Se precursor solution to disassociate and cap the
Se.
ā¢ Separately, 13mg of CdO, 0.6mL of oleic acid and
10mL of octadecene were combined and heated to
225oC
ā¢ Once the CdO solution reaches 225oC, room-
temperature Se precursor solution was added. Varying
the amount of Se solution added to the CdO solution
will result in different sized QDs.
17. QD color with size
Journal of Chemcial Education. Vol. 82 No.11 Nov 2005
18. Applications of QDs: Biological
ā¢ Biological Tagging and Labeling
ā Biological assays and microarrays
ā Labeling of cells and intracellular structures
ā in vivo and in vitro imaging
ā Pathogen and Toxin detection
19. Applications of QDs: Biological
ā¢ Biological Tagging
ā Organic fluorophores such as genetically encoded
fluorescent protein, like GFP, or chemically
synthesized fluorescent dyes have been the most
common way of tagging biological entities.
ā Some limitations of organic fluorophores:
ā¢ do not continuously fluoresce for extended periods
of time
ā¢ Degrade or photo-bleach
ā¢ are not optimized for multicolor applications
20. Applications of QDs: Biological
ā¢ The unique optical properties of quantum dots
make them suitable for biological tagging and
labeling applications.
ā¢ QDs are excellent fluorophores.
ā Fluorescence is a type of luminescence in which the
absorption of an incident photon triggers the emission
of a lower energy or longer wavelength photon.
ā Quantum dots absorb over a broad spectrum and
fluoresce over a narrow range of wavelengths. This is
tunable by particle size.
ā So, a single excitation source can be used to excite
QDs of different colors making them ideal for imaging
multiple targets simultaneously.
21. Applications of QDs: Biological
Absorption and emission Spectra of CdSe/ZnS QDs
compared to Rhodamine, a common organic die.
ā The absorption spectrum (dashed lines) of the QD (green) is
very broad, whereas that of the organic die (orange) is narrow.
ā Conversely, the emission spectrum (solid lines) of the QD is
more narrow than that of the organic die
Jyoti K. Jaiswal and Sanford M. Simon. Potentials and pitfalls of fluorescent quantum
dots for biological imaging. TRENDS in Cell Biology Vol.14 No.9 September 2004
22. ā¢ A broad absorption and narrow emission spectrum means a single
excitation source can be used to excite QDs of different colors making
them ideal for imaging multiple targets simultaneously.
Gao, Xiaohu. "In vivo cancer targeting and imaging
with." Nature Biotechnology 22(2004): 8.
Applications of QDs: Biological
CdSe/ZnS QDs used to image cancer cells in a live mouse.
23. Applications of QDs: Biological
ā¢ Quantum dots are an attractive alternative to traditional
organic dies because of their high quantum yield and
photostability.
ā¢ Quantum Yield = # emitted photons / # absorbed
photons.
ā Quantum dots have a high quantum yield because they have a
high density of energy states near the bandgap.
ā A higher quantum yield means a brighter emission. The quantum
yield of some QDs is 20 times greater than traditional organic
fluorophores.
ā¢ Photostability is a fluorophoreās resistance to
photobleaching or photochemical degradation due to
prolonged exposure to the excitation source.
24. Applications of QDs: Biological
X. Michalet, et al. Quantum Dots for Live Cells, in Vivo Imaging,
and Diagnostics Science 307, 538 (2005)
Common QD Materials, their size and emitted wavelengths
25. Applications of QDs: Biological
Bioconjugated QDs:
ā¢ The surface of QDs can be functionalized with affinity ligands: antibodies,
peptides, or small-molecule drug inhibitors, to target specific types of cells for in
vivo or in vitro imaging.
ā¢ The affinity ligands are not bound directly to the surface of the quantum
dots. They are usually connected to a linker molecule referred to as a capping
ligand or coordinating ligand.
ā¢ Polymers such as poly ethylene glycol (PEG) may be introduced to reduce
nonspecific binding of the affinity ligands.
Gao, Xiaohu. "In vivo cancer targeting and imaging
with." Nature Biotechnology 22(2004): 8.
26. Applications of QDs: Biological
Bioconjugated QDs:
ā¢ The surface of QDs can be functionalized with affinity ligands: antibodies,
peptides, or small-molecule drug inhibitors, to target specific types of cells for in
vivo or in vitro imaging.
ā¢ The affinity ligands are not bound directly to the surface of the quantum
dots. They are usually connected to a linker molecule referred to as a capping
ligand or coordinating ligand.
ā¢ Polymers such as poly ethylene glycol (PEG) may be introduced to reduce
nonspecific binding of the affinity ligands.
Gao, Xiaohu. "In vivo cancer targeting and imaging
with." Nature Biotechnology 22(2004): 8.
27. Applications of QDs: Biological
Bioconjugated QDs:
ā¢ The coordinating ligands serve a dual purpose:
1. To bind the affinity ligands to the surface of the QD.
2. To encapsulate the quantum dot in a protective layer that
prevents enzymatic degradation and aggregation.
ā¢ The coordinating ligands dictate the hydrodynamic
behavior of the QD and are chosen according to the
desired biocompatibility.
ā¢ Common coordinating ligands:
ā¢ Avidin-biotin complex
ā¢ Protein A or protein G
ā¢ Simple polymers and amphiphilic lipids
28. Applications of QDs
Jyoti K. Jaiswal and Sanford M. Simon. Potentials and pitfalls of fluorescent
quantum
dots for biological imaging. TRENDS in Cell Biology Vol.14 No.9 September
2004
QDs conjugated with antibody molecules (blue) by using avidin (purple) or
protein A (green) as linkers. Between 10 and 15 linker molecules can be
attached covalently or electrostatically to a single QD, which facilitates the
binding of many or a few antibody molecules on each QD.
29. Applications of QDs: Biological
DNA assays and microarrays
Each pixel contains a different DNA sequence
Fluorescence observed if sample binds
QD-functionalized DNA
Image source: Wikipedia: Gene Expression Profiling
BioMems Applications Overview
SCME: www.scme-nm.org
30. Applications of QDs: Light
Emitters
ā¢ The discovery of quantum dots has led to the
development of an entirely new gamut of materials for
the active regions in LEDs and laser diodes.
ā¢ Indirect gap semiconductors that donāt luminesce in their
bulk form such as Si become efficient light emitters at
the nanoscale due quantum confinement effects.
ā¢ The study of QDs has advanced our understanding of
the emission mechanisms in conventional LED materials
such as InGaN, the active region of blue LEDs.
ā¢ The high radiative-recombination efficiency of epitaxial
InGaN is due to self-assembled, localized, In rich
clusters that behave like QDs.
31. Additional Applications of QDs
ā¢ New applications for QDs are continuously
being discovered.
ā¢ For example: Solar cells that incorporate
QDs may lead to more efficient light
harvesting and energy conversion.
32. Quantum Dot Solar Cells
Possible benefits of using quantum dots (QD):
ā¢ āHot carrierā collection: increased voltage due
to reduced thermalization
ā¢ Multiple exciton generation: more than one
electron-hole pair per photon absorbed
ā¢ Intermediate bands: QDs allow for absorption
of light below the band gap, without
sacrificing voltage
MRS Bulletin 2007, 32(3), 236.
33. QDs: Collect Hot Carriers
Eg
Conduction
Band
Valence
Band
1. Tune QD absorption (band gap)
to match incident light.
2. Extract carriers without loss of
voltage due to thermalization.
Band structure of bulk semi-
conductors absorbs light having
energy > Eg. However, photo-
generated carriers thermalize to
band edges.
34. QDs: Multiple Exciton Generation
In bulk semiconductors:
1 photon = 1 exciton
Eg
In QDs:
1 photon = multiple excitons
Impact ionization
The thermalization of the
original electron-hole pair
creates another pair.
Absorption of one photon of light
creates one electron-hole pair,
which then relaxes to the band
edges.
35. QDs: Multiple Exciton Generation
1 2 3 4 5
Photon Energy (Ehv/Eg)
QuantumEff(%)
100
150
200
250
300
Quantum efficiency for
exciton generation: The
ratio of excitons produced
to photons absorbed
>100% means multiple
exciton generation
Occurs at photon energies
(Ehv) much greater than the
band gap (Eg)
36. QDs: Intermediate Bands
Eg
Intermediate
band formed
by an array of
QDs
Conventional band structure does
not absorb light with energy < Eg
Intermediate bands in the band gap
allow for absorption of low energy light
41. 1-D Electronic Structures: Carbon Nanotubes
Wrapping vector:
2211 anann
ļ²ļ²ļ²
ļ«ļ½
Diameter: 0.0783nm21
2
2
2
1 nnnnd ļ«ļ«ļ½
The folding of the sheet controls the electronic properties of the nanotubes.
42. D = diameter of the nanotube
The component of the wave vector perpendicular to the CNT long
axis is quantized
D
n
k
2
ļ½ļ
Metallic behavior: the allowed values of intersect the k points at which the
conduction and valence bands meet.
CNTs can behave either like metal or semiconductors depending on their
chirality.
ļk
43. Development of electronic properties
as a function of cluster size
Each band has a width that reflects the interaction between atoms,
with a bandgap between the conduction and the valence bands that
reflects the original separation of the bonding ad antibonding states.
44. pz electrons hybridize to form Ļ e Ļ* valence and conduction bands
that are separated by an energy gap of about 1V (semiconductor).
For certain high simmetry directions (the K points in the reciprocal
lattice) the material behaves like a metal.
Conduction in CNTs
Apex: at this point CB
meets VB for graphene
sheets (metal-like
behavior)
Allowed statesļK
ļk wave vector perpendicular to the
CNT long axis
45. Field effect transistor made from
a single semiconducting CNT
connecting source and drain
connectors.
46. Semiconductor Nanowires
ā¢ Ga-P/Ga-As p/n nanojunctions
Copyright Stuart Lindsay 2009
(IOP)
TEM images
Line profiles of the
composition through
the junction region
47. from rice.edu
Single walled
carbon nanotube
(single sheet of
carbon atoms)
Multiwalled
carbon nanotube
(several sheets
of carbon atoms)
Carbon nanotubes can be formed from a
single sheet of C atoms or several sheets
48. Carbon sheets can also be rolled up in different
directions to give different types of nanotubes.
51. Carbon Nanotubes Applications
Carbon nanotubes are strong and light at the same time. It makes
them a perfect choice for using as reinforcing additive in composite
fibers, to make them extremely strong and electrically conductive
simultaneously.
There is enormous potential for the nanotubes to used in the design
and development of space elevators, bulletproof wear, clothing and
others.
Also, the sufficient electrical and thermal conductivity of carbon
nanotubes makes them potentially useful in revolutionizing the industry
with use in solar cells, as sensors, in batteries, and in transistors.
52. Carbon Nanotubes
ā¢ 4 nm width (smaller diameter than DNA)
ā¢ 100xās stronger than steel 1/6 weight
ā¢ Thermal/electrically conductive
ā¢ Metallic and Semi-Conductive
53. Graphene
Graphene is classified as a semi-metal and is an allotrope of carbon.
It is a 2-dimensional, single layer of graphite, made of 6 carbon
molecules join with others to form a perfect hexagonal lattice-shaped
structure. Incidentally, graphene is the fundamental structural element
of other carbon allotropes, including carbon nanotubes.
Graphene is extremely malleable and elastic. Since it is only one-
atom-thick, graphene is nearly transparent however it is also an
excellent electrical and thermal conductor.
Graphene is very thin and flexible yet is highly conductive. Hence, it
finds potential application as a transparent conductor for use in
photovoltaic cells and other types of flexible electronic devices.
Also, its larger ratio of surface area to mass makes it excellent
potential for use in energy storage or chemical sensing.
54. BuckyBalls ā C60
ā¢ Roundest and most symmetrical molecule known to man
ā¢ Compressed ā becomes stronger than diamond
ā¢ Third major form of pure carbon
ā¢ Heat resistance and electrical conductivity
55. Top - Down
method
High energy
Ball Milling
Lithography
Gas
condensation
Severe plastic
deformation
Synthesis of Nanomaterials
56. Synthesis of
Nanomaterials
Top - down
method
(Destruction)
Bottom-up
method
(Construction)
Synthesis of Nanomaterials
To synthesize nanomaterials, either to assemble atoms together or to dis-assemble (Break or
dissociate) bulk solids into finer pieces until they are constituted of only few atoms.
59. Mechanical Grinding (Physical Method)
Mechanical milling is achieved using high energy shaker, planetary ball, or tumbler mills
Energy transferred to the powder from refractory depends on the
ā¢ Rotational speed, size and number of the balls
ā¢ Ratio of the ball to powder mass
ā¢ The time of milling
ā¢ Milling atmosphere
Nanoparticle are produced by the shear action during grinding.
60. Wet Chemical Synthesis (Chemical Method)
Wet Chemical Synthesis
Top down method
(Electrochemical etching)
Bottom up method
(Sol-gel)
ā¢ In Top down method single crystals are etched in an aqueous solution for producing
nanomaterials, e.g., synthesis of porous silicon by electrochemical etching.
ā¢ In Bottom up method (Sol-gel, precipitation etc.) materials containing the desired
precursors are mixed in a controlled fashion to form a colloidal solution.
61. Sol-gel process
The sol-gel process may be described as:
āFormation of network (oxide) through poly-
condensation reactions of a molecular precursor in a
liquid.ā
One of the highly attractive features of the sol-gel process
is the possibility to shape the material into any desired form
such as monoliths, films, fibers, and monosized powders,
and subsequently to convert it into a ceramic material by
heat treatment.
62. What is a Sol?
A sol is a stable dispersion of colloidal particles or polymers in a solvent.
A sol consists of a liquid with solid particles which are not dissolved, but do
not agglomerate or sediment. The particles may be amorphous or crystalline.
(An aerosol is particles in a gas phase, while a sol is particles in a liquid).
Agglomeration of small particles are due to van der Waals forces and a tendency
to decrease the total surface energy. Van der Waals forces are weak, and extend
only for a few nanometers.
In order to counter the van der Waals interactions, repulsive forces must be
established.
May be accomplished by:
Electrostatic repulsion. By adsorption of charged species onto the surface
of the particles, repulsion between the particles will increase and agglomeration
will be prevented. Most important for colloidal systems.
Steric hindrance. By adsorbing a thick layer of organic molecules, the
particles are prevented from approaching each other reducing the role of the van
der Waals forces. Works best in concentrated dispersions. Branched adsorbates
works best. Usual for nanomaterials.
63. What is a gel?
A gel consists of a three dimensional continuous
network, which encloses a liquid phase.
In a colloidal gel, the network is built from agglomeration
of colloidal particles. In a polymer gel the particles have a
polymeric sub-structure made by aggregates of sub-
colloidal particles.
Generally, the sol particles may interact by van der Waals
forces or hydrogen bonds. A gel may also be formed from
linking polymer chains.
In most gel systems used for materials synthesis, the
interactions are of a covalent nature and the gel process is
irreversible. The
gelation process may be reversible if other interactions are
involved.
64. Why sol-gel synthesis?
Sol-gel synthesis may be used to prepare materials with a
variety of shapes, such as porous structures, thin fibers,
dense powders and thin films.
65. Sol gel synthesis
ā¢The idea behind sol-gel synthesis is to ādissolveā the
compound in a liquid in order to bring it back as a solid in a
controlled manner.
ā¢Multi component compounds may be prepared with a
controlled stoichiometry by mixing sols of different
compounds.
ā¢The sol-gel method prevents the problems with co-
precipitation, which may be inhomogeneous, be a gelation
reaction.
ā¢Enables mixing at an atomic level.
ā¢Results in small particles, which are easily sinterable.
67. Depending on the nature of the precursors sol-gel
process can be of two type:
a) the precursor is an aqueous solution of an
inorganic salt or,
b) a metal organic compound
68. Aqueous sol-gel Chemistry
Conversion of a precursor solution into an inorganic solid via inorganic
polymerization reactions induced by water.
In general, precursor (or starting compound) is an inorganic metal salt
(chloride, nitrate, sulfate etc) or a metal organic compound such as an
alkoxide.
(Alkoxides of Si, Ti, Al, Zr, (or, Fe, Ni, Co, Mn, Cu, Y, Nb, Taā¦ )
The sol-gel process consists of the following steps:
(i) Preparation of a homogeneous solution either by dissolution of metal
organic precursors in an organic solvent that is miscible with water, or
by dissolution of inorganic salts in water;
ii) conversion of the homogeneous solution into a sol by treatment with
a suitable reagent (generally water with or without any acid/base);
iii) aging;
iv) shaping;
and v) thermal treatment/sintering.
69. Aqueous sol-gel Chemistry p.2
The first step in a sol-gel reaction is the formation of an inorganic
polymer by hydrolysis and condensation reactions, i.e., the
transformation of the molecular precursor into a highly crosslinked
solid. Hydrolysis leads to a sol, a dispersion of colloidal particles in a
liquid, and further condensation results in a gel, an interconnected, rigid
and porous inorganic network enclosing a continuous liquid phase.
This transformation is called the sol-gel transition.
There are two possibilities to dry the gels. Upon removal of the pore
liquid under hypercritical conditions, the network does not collapse and
aerogels are produced.
When the gel is dried under ambient conditions, shrinkage of the pores
occurs, yielding a xerogel.
70. Xerogel and Aerogel
ā¢ If the gel is dried by evaporation, then the capillary
forces will result in shrinkage, the gel network will
collapse, and a xerogel is formed.
ā¢ If drying is performed under supercritical conditions,
the network structure may be retained and a gel
with large pores may be formed. This is called an
aerogel, and the density will be very low. A record
is < 0.005 g/cm3.
71. Aqueous sol-gel Chemistry p.3
The sol-gel conversion of metal alkoxides involves two
main reaction types: hydrolysis and condensation.
During hydrolysis, the alkoxide groups (-OR) are replaced
via the nucleophilic attack of the oxygen atom of a water
molecule under release of alcohol and the formation of a
metal hydroxide.
Condensation reactions between two hydroxylated metal
species leads to M-O-M bonds under release of water
(oxolation), whereas the reaction between a hydroxide and
an alkoxide leads to M-O-M bonds under release of an
alcohol (alkoxolation).
72. Aqueous sol-gel Chemistry p.4
ā¢ The chemical reactivity of metal alkoxides towards hydrolysis and
condensation depends mainly on the electronegativity of the metal
atom, its ability to increase the coordination number, the steric
hindrance of the alkoxy group, and on the molecular structure of the
metal alkoxides (monomeric or oligomeric). The amount of added
water in the hydrolysis step and how the water is added, determines,
whether the alkoxides are completely hydrolyzed or not and which
oligomeric intermediate species are formed. Additional parameters
are the polarity, the dipole moment, and the acidity of the solvent.
73. Non āaqueous sol-gel Chemistry
Nonaqueous processes can be divided into two general methodologies:
Surfactant directed and Solvent controlled.
ā¢ Surfactant-Directed vs. Solvent-Controlled
Surfactant-controlled synthesis routes involve the transformation of the
precursor species into the oxidic compound in the presence of
stabilizing ligands in a typical temperature range of 250 to 350 ā¦C.
Alternative to surfactants is the use of common organic solvents, which
act as reactant as well as control agent for particle growth, enabling the
synthesis of high-purity nanomaterials in surfactant-free medium.
In comparison to the synthesis of metal oxides in the presence of
surfactants, the solvent-controlled approaches are simpler, because the
initial reaction mixture just consists of two components, the metal oxide
precursor(s) and a common organic solvent.
75. Non āaqueous sol-gel Chemistry p.3
Equation 1 displays the condensation between metal halides and metal
alkoxides (formed upon the reaction of metal halides with alcohols) under
release of an alkyl halide. One of the early examples was the preparation of
anatase nanocrystals from titanium isopropoxide and titanium chloride.
Eq 2 (Ether elimination) leads to the formation of a MāOāM bond upon
condensation of two metal alkoxides under elimination of an organic ether. This
mechanism was reported for the formation of hafnium oxide nanoparticles.
The ester elimination process involves the reaction between metal
carboxylates and metal alkoxides (eq 3), as reported for zinc oxide, titania,and
ndium oxide.
Analogous to ester eliminations are amide eliminations. Reacting metal oleates
with amines, for example, enabled the controlled growth of titania nanorods.
In the case of ketones as solvents, the release of xygen usually involves aldol
condensation, where two carbonyl compounds react with each other with
elimination of water. The water molecules act as the oxygen-supplying agent
for metal oxide formation (eq 4).
Literature examples include the synthesis of ZnO and TiO2 in acetone.
76. Liquid solid reactions (precipitation)
ā¢ In this method, ultrafine particles of the desired materials are produced by
precipitation from a solution. The presence of desired nuclei in the solution is
a necessary condition to initiate the process. TiO2 powders with particle sizes
in the range 70-300 nm have been prepared from titanium tetraisopropoxide
by this method. Similarly ZnS powders may be produced by reaction of
aqueous zinc salt solutions with thioacetamide.
Hydrothermal synthesis
ā¢ It is based on the ability of water an aqueous solutions to dilute the substances
at high temperatures and pressures, which are practically insoluble under
normal condition. These include oxides, silicates and sulphides. Autoclaves are
used for this purposes because they can withstand high temperature and
pressure for long period of time. The possible advantages of the process over
the other are the ability to create crystalline phase that are not stable at the
melting point. This method is used for the synthesis of materials which have
high vapor pressure near their melting point.
77. Gas phase synthesis of nanomaterials
ā¢ This method allow elegant way to control process parameter in order to be
able to produce size, shape, and chemical composition controlled
nanostructures.
ā¢ In conventional chemical vapor deposition (CVD) synthesis, gaseous
products either are allowed to react homogeneously or heterogeneously
depending on a particular application.
1. In homogeneous CVD, particles form in the gas phase and diffuse towards
a cold surface due to thermophoretic forces, and can either be scrapped of
from the cold surface to give nano powders or deposited on to a substrate
to yield what is called āparticulate filmsā.
2. In heterogeneous CVD, the solid is formed on the solid surface, which
catalyses the reaction and a dense film is formed.
78. Advantages of gas phase processes
ā¢ An excellent control of size, shape, crystallinity and chemical
composition .
ā¢ Highly pure materials can be obtained
ā¢ Multicomponent systems are relatively easy to form
ā¢ Easy control of the reaction mechanisms
Most of the synthesis routes are based on the production of
small clusters that can aggregate to form nano particles.
80. Flame assisted ultrasonic spray pyrolysis
ā¢ In this process precursors are nebulized and then unwanted components are burnt in
a flame to get required materials. ZrO2 has been obtained by this method from a
precursor of Zr(CH3 CH2 CH2O)4.
ā¢ This process is mainly used for synthesis of fumed silica.
ā¢ Silicon tetrachloride is heated in an oxy-hydrogen flame to give highly dispersed
silica. The resulting amorphous powder consists of spherical particles with sizes in
the range 7-40 nm.
ā¢ In combustion flame synthesis mixture of acetylene and oxygen or hydrogen and
oxygen supplies the energy to initiate the pyrolysis of precursor. This process is
widely used for industrial production of powders in large quantities, such as carbon
black, fumed silica, and titanium dioxide.
ā¢ At high pressure, highly agglomerated powders are produced which is
disadvantageous for subsequent processing. The basic ides for low pressure flame
synthesis is to reduce agglomeration. Aerosol scientists widely use this process.
ā¢ Exact control of the flame produces a flat flame front. Due to oxidative atmosphere
of the flame, this synthesis process is limited to the formation of the oxides.
82. Chemical vapour condensation (CVC)
ā¢ This technique involves pyrolysis of vapors of metal organic precursors in a
reduced pressure atmosphere.
ā¢ Nanoparticles of ZrO2, Y2O3, have been produced by this method.
ā¢ The evaporative source used in GPC is replaced by a hot reactor in the
Chemical vapor condensation method.
ā¢ Nanosized particles metals and ceramics can be obtained in good amounts
by adjusting the residence time of the precursor molecules, changing the gas
flow rate, pressure difference between the precursor delivery system and
the main chamber and the temperature of the reactor.
ā¢ The production capacities in CVC process are much higher than GPC
system.
83. ā¢ In addition to the formation of nanoparticles of a single precursor The
CVC reactor can also be used for the synthesis of mixture of nanoparticles
of two phases by supplying two precursors at the front end of the reactor,
and
ā¢ Coated nanoparticles like n-ZrO2 coated with n-Al2O3 or vice versa, by
supplying a second precursor at the second stage of the reactor.
84. Schematic diagram of set up for GPC system followed by consolidation in a
mechnical press or collection in an appropriate solvent media
85. Laser ablation
ā¢ This method is extensively used for preparation of nanoparticles and
particulate films.
ā¢ In this process a laser beam is used as the primary excitation source of
ablation for generating clusters directly from solid sample.
ā¢ The small dimension of the particles and the possibility to form thick films
make this process an efficient tool for the production of ceramic particles
and coatings.
ā¢ Synthesis of ZrO2, SnO2 nanoparticls thick films are synthesized using this
process.
ā¢ Synthesis of other materials such as lithium manganate, silicon and carbon
has also been carried out by this technique.
86. Thermolysis
ā¢ This method involves solvent free pyrolysis of a suitable precursor
material. One of the oldest nanomaterials, activated charcoal is
prepared using this method. Precursor materials are pyrolyzed at
600-900 Ā°C in the absence of air to obtain charcoal of specific
surface area.
ā¢ In the process the materials are carbonized in oxidizing atmosphere
of CO2,O2 or steam at 600-1200 Ā°C and activation is carried using
chemicals such as KOH, NaOH, ZnCl2 or phosphoric acid.
87. Solvothermal synthesis
ā¢ This is a versatile method for synthesizing nanomaterials at temperatures
below 200 C. This technique enables synthesis of crystalline products at
low temperature and also helps in control the size and morphology of the
resultant products.
Electrodeposition
ā¢ This technique involves creation of solid materials from electrochemical
reactions in liquid. A conducting substance is placed in liquid containing
electrolytes. When a potential is applied, redox reaction takes place and
the material is deposited as thin film at the cathode. Semiconductor ZnO
nanotube arrays are synthesized by direct electrochemical deposition from
aqueous solutions into the pore channels of anodically-formed alumina .