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Naming Ionic Compounds
Part 3: Naming Cations and Anions
By Shawn P. Shields, Ph.D.
This work is licensed by Shawn P. Shields-Maxwell under a Creative Commons
Attribution-NonCommercial-ShareAlike 4.0 International License.
Learning to Name Ionic Compounds
In part 2, we learned to write the
empirical formula for ionic compounds.
Our example: KBr
In order to name this compound, we need to
know how to name cations and anions
separately.
Naming Cations
Rule 1: Naming main group cations
Cation names are the same as the
element name.
For instance, Na+ is a “sodium” cation
Mg2+ is a “magnesium” cation
Naming Transition Metal Cations
Rule 2: Naming transition metal cations:
Transition metal cations are named just like the main
group cations, except the charge on the ion is added in
Roman numerals in parentheses after the cation
(element) name.
For instance, Cu+ is a “copper (I)” cation
Cu2+ is a “copper (II)” cation
Caution: Do NOT indicate charges in parentheses for
main group cations, such as Na+, Mg2+, Al3+, etc. These
elements only have one cation charge.
Mini Quiz: Naming Cations
Name the following cations:
Au+
Ca2+
Fe2+
Al3+
HINT: Remember to identify whether an element a main
group metal or transition metal before naming the cation.

Mini Quiz Solution: Naming Cations
Name the following cations:
Au+ is a “gold (I)” cation
Mini Quiz Solution: Naming Cations
Name the following cations:
Au+ is a “gold (I)” cation
Ca2+ is a “calcium” cation
Mini Quiz Solution: Naming Cations
Name the following cations:
Au+ is a “gold (I)” cation
Ca2+ is a “calcium” cation
Fe2+ is an “iron (II)” cation
Mini Quiz Solution: Naming Cations
Name the following cations:
Au+ is a “gold (I)” cation
Ca2+ is a “calcium” cation
Fe2+ is an “iron (II)” cation
Al3+ is an “aluminium” cation
NOTE: It is incorrect to name Al3+ as “aluminium (III)”
and Ca2+ as “calcium (II)”
Naming Anions
Rule 3: Naming anions
Anion names are formed from the root of
the element name with the suffix –ide
added.
For instance, Cl is formed from the element
chlorine.
Remove the –ine ending and add -ide
a “chloride” anion
Naming Anions
More examples:
F is formed from the element Fluorine.
Remove the –ine ending and add -ide
a “Fluoride” anion
O2 is formed from the element oxygen.
Remove the –ygen ending and add -ide
an “oxide” anion
Mini Quiz: Naming Anions
Name the following anions:
Br
S2
Se2
I
Mini Quiz Solutions: Naming Anions
Name the following anions:
Br is formed from bromine. Brom- is the root name of
the element. Remove the –ine and add –ide
“Bromide” anion
S2
Mini Quiz Solutions: Naming Anions
Name the following anions:
Br is formed from bromine. Brom- is the root name of
the element. Remove the –ine and add –ide
“Bromide” anion
S2 is formed from sulfur. Sulf- is the root name of
the element. Remove the –ur and add –ide
“Sulfide” anion
Mini Quiz Solutions: Naming Anions
Se2 is formed from selenium. Selen- is the root name of
the element. Remove the –ium and add -ide
“Selenide” anion
Mini Quiz Solutions: Naming Anions
Se2 is formed from selenium. Selen- is the root name of
the element. Remove the –ium and add -ide
“Selenide” anion
I is formed from iodine. Iod- is the root name of the
element. Remove the –ine and add -ide
“Iodide” anion

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Naming ionic compounds cations anions

  • 1. Naming Ionic Compounds Part 3: Naming Cations and Anions By Shawn P. Shields, Ph.D. This work is licensed by Shawn P. Shields-Maxwell under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
  • 2. Learning to Name Ionic Compounds In part 2, we learned to write the empirical formula for ionic compounds. Our example: KBr In order to name this compound, we need to know how to name cations and anions separately.
  • 3. Naming Cations Rule 1: Naming main group cations Cation names are the same as the element name. For instance, Na+ is a “sodium” cation Mg2+ is a “magnesium” cation
  • 4. Naming Transition Metal Cations Rule 2: Naming transition metal cations: Transition metal cations are named just like the main group cations, except the charge on the ion is added in Roman numerals in parentheses after the cation (element) name. For instance, Cu+ is a “copper (I)” cation Cu2+ is a “copper (II)” cation Caution: Do NOT indicate charges in parentheses for main group cations, such as Na+, Mg2+, Al3+, etc. These elements only have one cation charge.
  • 5. Mini Quiz: Naming Cations Name the following cations: Au+ Ca2+ Fe2+ Al3+ HINT: Remember to identify whether an element a main group metal or transition metal before naming the cation. 
  • 6. Mini Quiz Solution: Naming Cations Name the following cations: Au+ is a “gold (I)” cation
  • 7. Mini Quiz Solution: Naming Cations Name the following cations: Au+ is a “gold (I)” cation Ca2+ is a “calcium” cation
  • 8. Mini Quiz Solution: Naming Cations Name the following cations: Au+ is a “gold (I)” cation Ca2+ is a “calcium” cation Fe2+ is an “iron (II)” cation
  • 9. Mini Quiz Solution: Naming Cations Name the following cations: Au+ is a “gold (I)” cation Ca2+ is a “calcium” cation Fe2+ is an “iron (II)” cation Al3+ is an “aluminium” cation NOTE: It is incorrect to name Al3+ as “aluminium (III)” and Ca2+ as “calcium (II)”
  • 10. Naming Anions Rule 3: Naming anions Anion names are formed from the root of the element name with the suffix –ide added. For instance, Cl is formed from the element chlorine. Remove the –ine ending and add -ide a “chloride” anion
  • 11. Naming Anions More examples: F is formed from the element Fluorine. Remove the –ine ending and add -ide a “Fluoride” anion O2 is formed from the element oxygen. Remove the –ygen ending and add -ide an “oxide” anion
  • 12. Mini Quiz: Naming Anions Name the following anions: Br S2 Se2 I
  • 13. Mini Quiz Solutions: Naming Anions Name the following anions: Br is formed from bromine. Brom- is the root name of the element. Remove the –ine and add –ide “Bromide” anion S2
  • 14. Mini Quiz Solutions: Naming Anions Name the following anions: Br is formed from bromine. Brom- is the root name of the element. Remove the –ine and add –ide “Bromide” anion S2 is formed from sulfur. Sulf- is the root name of the element. Remove the –ur and add –ide “Sulfide” anion
  • 15. Mini Quiz Solutions: Naming Anions Se2 is formed from selenium. Selen- is the root name of the element. Remove the –ium and add -ide “Selenide” anion
  • 16. Mini Quiz Solutions: Naming Anions Se2 is formed from selenium. Selen- is the root name of the element. Remove the –ium and add -ide “Selenide” anion I is formed from iodine. Iod- is the root name of the element. Remove the –ine and add -ide “Iodide” anion