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Chapter 5 “Electrons in Atoms”
Section 5.1 Models of the Atom ,[object Object],[object Object]
Section 5.1 Models of the Atom ,[object Object],[object Object]
Section 5.1 Models of the Atom ,[object Object],[object Object]
Section 5.1 Models of the Atom ,[object Object],[object Object]
Ernest Rutherford’s Model ,[object Object],[object Object],[object Object],[object Object]
Niels Bohr’s Model ,[object Object],[object Object],[object Object],[object Object]
The Bohr Model of the Atom Niels Bohr I pictured the electrons orbiting the nucleus much like planets orbiting the sun. However, electrons are found in  specific  circular paths around the nucleus, and can  jump  from  one level to another .
Bohr’s model ,[object Object],[object Object],[object Object],[object Object]
The Quantum Mechanical Model ,[object Object],[object Object],[object Object],[object Object]
Schrodinger’s Wave Equation Equation for the  probability  of a single electron being found along a single axis (x-axis) Erwin Schrodinger Erwin Schrodinger
[object Object],[object Object],[object Object],The Quantum Mechanical Model
[object Object],[object Object],[object Object],The Quantum Mechanical Model
[object Object],[object Object],[object Object],The Quantum Mechanical Model
Atomic Orbitals ,[object Object],[object Object],[object Object],[object Object]
Principal Quantum Number Generally symbolized by “n”, it denotes the shell (energy level) in which the electron is located.   Maximum number of electrons that can fit in an energy level is: 2n 2 How many e -  in level 2?  3?
Summary s p d f # of shapes  (orbitals) Maximum electrons Starts at energy level 1 2 1 3 6 2 5 10 3 7 14 4
By Energy Level ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
By Energy Level ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
By Energy Level ,[object Object],[object Object],[object Object],[object Object],[object Object]
Section 5.2 Electron Arrangement in Atoms ,[object Object],[object Object]
Section 5.2 Electron Arrangement in Atoms ,[object Object],[object Object]
aufbau diagram  - page 133 Aufbau is German for “building up” Increasing energy 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 3d 4d 5d 7p 6d 4f 5f
Electron Configurations… ,[object Object],[object Object],[object Object],[object Object]
Pauli Exclusion Principle No two electrons in an atom can have the same four quantum numbers. Wolfgang Pauli To show the different direction of spin, a pair in the same orbital is written as:
Quantum Numbers Each electron in an atom has a unique set of  4 quantum numbers  which describe it. ,[object Object],[object Object],[object Object],[object Object]
Electron Configurations ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Increasing energy 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 3d 4d 5d 7p 6d 4f 5f
[object Object],[object Object],Increasing energy 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 3d 4d 5d 7p 6d 4f 5f
[object Object],[object Object],Increasing energy 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 3d 4d 5d 7p 6d 4f 5f
[object Object],[object Object],Increasing energy 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 3d 4d 5d 7p 6d 4f 5f
[object Object],[object Object],[object Object],[object Object],Orbital notation Increasing energy 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 3d 4d 5d 7p 6d 4f 5f
[object Object],[object Object],[object Object]
Orbitals fill in an order  ,[object Object],[object Object],[object Object],[object Object],[object Object]
Write the electron configurations for these elements: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Chromium is actually: ,[object Object],[object Object],[object Object],[object Object],[object Object]
Copper’s electron configuration ,[object Object],[object Object],[object Object],[object Object],[object Object]
Irregular configurations of Cr and Cu Chromium steals a 4s electron to   make  its 3d sublevel  HALF FULL Copper steals a 4s electron to   FILL   its 3d sublevel
Valence Electrons ,[object Object],[object Object]
Valence Electrons ,[object Object],[object Object],[object Object]
Valence Electrons ,[object Object],[object Object],[object Object],[object Object]
Electron-dot structures aka – Lewis Dot Structures ,[object Object],[object Object]
How to write an electron-dot structure ,[object Object],[object Object]
Ne F O N C B Be Li e -  Dot-diagram 1s 2 2s 2 2p 6 1s 2 2s 2 2p 5 1s 2 2s 2 2p 4 1s 2 2s 2 2p 3 1s 2 2s 2 2p 2 1s 2 2s 2 2p 1 1s 2 2s 2 1s 2 2s 1 Electron Config. 10 9 8 7 6 5 4 3 Atomic # Lithium Neon Flourine Oxygen Nitrogen Carbon Boron Berylium Element
Practice ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Section 5.3 Physics and the Quantum Mechanical Model ,[object Object],[object Object]
Section 5.3 Physics and the Quantum Mechanical Model ,[object Object],[object Object]
Section 5.3 Physics and the Quantum Mechanical Model ,[object Object],[object Object]
Section 5.3 Physics and the Quantum Mechanical Model ,[object Object],[object Object]
Light ,[object Object],[object Object],[object Object],[object Object],[object Object]
- Page 139 “ R  O  Y  G  B  I  V” Frequency Increases Wavelength Longer
Parts of a wave Origin Wavelength Amplitude Crest Trough
Electromagnetic radiation propagates through space as a wave moving at the speed of light. Equation: c =  c = speed of light, a constant  (2.998 x 10 8  m/s)    (nu) = frequency, in units of  hertz (hz or sec -1 )    (lambda) = wavelength, in  meters
Wavelength and Frequency ,[object Object],[object Object],[object Object],[object Object],[object Object]
- Page 140 Use Equation:  c = 
Radiowaves Microwaves Infrared  .   Ultra-violet X-Rays GammaRays Long Wavelength Short Wavelength Visible Light Low Energy High Energy Low  Frequency High Frequency
Wavelength Table Long  Wavelength = Low Frequency = Low ENERGY Short  Wavelength = High Frequency = High ENERGY
Atomic Spectra ,[object Object],[object Object]
If the light is not white ,[object Object],[object Object]
Atomic Spectrum ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
Light is a Particle? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The energy ( E  ) of electromagnetic radiation is  directly proportional  to the frequency (  ) of the radiation. Equation:   E = h  E  = Energy, in units of Joules (kg·m 2 /s 2 ) (Joule is the metric unit of energy) h  = Planck’s constant (6.626 x 10 -34  J·s)    = frequency, in units of hertz (hz, sec -1 )
The Math in Chapter 5 ,[object Object],[object Object],[object Object],[object Object]
Examples ,[object Object],[object Object],[object Object]
Explanation of atomic spectra ,[object Object],[object Object]
Changing the energy ,[object Object]
[object Object],Changing the energy
[object Object],Changing the energy
Experiment #6, page 49-
[object Object],[object Object],Changing the energy
{ { {
[object Object],[object Object],[object Object],[object Object],Ultraviolet Visible Infrared
What is light? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Wave-Particle Duality J.J. Thomson won the Nobel prize for describing the electron as a  particle . His son, George Thomson won the Nobel prize for describing the  wave-like nature  of the electron. The electron is a particle! The electron is an energy wave!
Confused?  You’ve Got Company! “ No familiar conceptions can be woven around the electron; something  unknown  is doing  we don’t know what .” Physicist Sir Arthur Eddington The Nature of the Physical World 1934
The physics of the very small ,[object Object],[object Object],[object Object]
Heisenberg Uncertainty Principle ,[object Object],[object Object],[object Object],[object Object]
Heisenberg Uncertainty Principle You can find out where the electron is, but not where it is going. OR… You can find out where the electron is going, but not where it is! “ One cannot simultaneously determine both the position and momentum of an electron.” Werner Heisenberg
It is more obvious with the very small objects ,[object Object],[object Object],[object Object]
Moving Electron Photon Before Electron  velocity changes Photon wavelength changes After Fig. 5.16, p. 145
End of Chapter 5

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Chemistry - Chp 5 - Electrons In Atoms - Powerpoint

  • 2.
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  • 8. The Bohr Model of the Atom Niels Bohr I pictured the electrons orbiting the nucleus much like planets orbiting the sun. However, electrons are found in specific circular paths around the nucleus, and can jump from one level to another .
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  • 11. Schrodinger’s Wave Equation Equation for the probability of a single electron being found along a single axis (x-axis) Erwin Schrodinger Erwin Schrodinger
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  • 16. Principal Quantum Number Generally symbolized by “n”, it denotes the shell (energy level) in which the electron is located. Maximum number of electrons that can fit in an energy level is: 2n 2 How many e - in level 2? 3?
  • 17. Summary s p d f # of shapes (orbitals) Maximum electrons Starts at energy level 1 2 1 3 6 2 5 10 3 7 14 4
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  • 23. aufbau diagram - page 133 Aufbau is German for “building up” Increasing energy 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 3d 4d 5d 7p 6d 4f 5f
  • 24.
  • 25. Pauli Exclusion Principle No two electrons in an atom can have the same four quantum numbers. Wolfgang Pauli To show the different direction of spin, a pair in the same orbital is written as:
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  • 38. Irregular configurations of Cr and Cu Chromium steals a 4s electron to make its 3d sublevel HALF FULL Copper steals a 4s electron to FILL its 3d sublevel
  • 39.
  • 40.
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  • 44. Ne F O N C B Be Li e - Dot-diagram 1s 2 2s 2 2p 6 1s 2 2s 2 2p 5 1s 2 2s 2 2p 4 1s 2 2s 2 2p 3 1s 2 2s 2 2p 2 1s 2 2s 2 2p 1 1s 2 2s 2 1s 2 2s 1 Electron Config. 10 9 8 7 6 5 4 3 Atomic # Lithium Neon Flourine Oxygen Nitrogen Carbon Boron Berylium Element
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  • 51. - Page 139 “ R O Y G B I V” Frequency Increases Wavelength Longer
  • 52. Parts of a wave Origin Wavelength Amplitude Crest Trough
  • 53. Electromagnetic radiation propagates through space as a wave moving at the speed of light. Equation: c =  c = speed of light, a constant (2.998 x 10 8 m/s)  (nu) = frequency, in units of hertz (hz or sec -1 )  (lambda) = wavelength, in meters
  • 54.
  • 55. - Page 140 Use Equation: c = 
  • 56. Radiowaves Microwaves Infrared . Ultra-violet X-Rays GammaRays Long Wavelength Short Wavelength Visible Light Low Energy High Energy Low Frequency High Frequency
  • 57. Wavelength Table Long Wavelength = Low Frequency = Low ENERGY Short Wavelength = High Frequency = High ENERGY
  • 58.
  • 59.
  • 60.
  • 61.
  • 62.
  • 63. The energy ( E ) of electromagnetic radiation is directly proportional to the frequency (  ) of the radiation. Equation: E = h  E = Energy, in units of Joules (kg·m 2 /s 2 ) (Joule is the metric unit of energy) h = Planck’s constant (6.626 x 10 -34 J·s)  = frequency, in units of hertz (hz, sec -1 )
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  • 72. { { {
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  • 75. Wave-Particle Duality J.J. Thomson won the Nobel prize for describing the electron as a particle . His son, George Thomson won the Nobel prize for describing the wave-like nature of the electron. The electron is a particle! The electron is an energy wave!
  • 76. Confused? You’ve Got Company! “ No familiar conceptions can be woven around the electron; something unknown is doing we don’t know what .” Physicist Sir Arthur Eddington The Nature of the Physical World 1934
  • 77.
  • 78.
  • 79. Heisenberg Uncertainty Principle You can find out where the electron is, but not where it is going. OR… You can find out where the electron is going, but not where it is! “ One cannot simultaneously determine both the position and momentum of an electron.” Werner Heisenberg
  • 80.
  • 81. Moving Electron Photon Before Electron velocity changes Photon wavelength changes After Fig. 5.16, p. 145