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Chemistry
Chapter 3 - Section 2

              Solubility



                        
Water – The Universal Solvent
           •Many solutions have water as
           the solvent.
           •These solutions are called an
           aqueous solution.
           •Water dissolves many solutes
           and so scientists call it the
           universal solvent.
           •Why is water such a great
           solvent? Let’s find out.
Dissolving an Ionic Compound
Dissolving an Ionic Compound
       example: NaCl
Dissolving an Ionic Compound
        example: NaCl
The positive area of the water molecules surround
            the negative Chloride ions.




                        6
The negative area of the water molecules
   surround the positive sodium ions.
As the attractions from the water molecules and
 their motion pulls the ions apart, the sodium
            chloride crystal dissolves.
Dissolving a Molecular Compound
Dissolving a Molecular Compound
         example: sugar
Water molecules arrange themselves around the
sucrose molecules according to opposite polar
                    areas.




                     11
The attraction of the water molecules and their
motion overcome the attraction between sucrose
                    molecules.




                       12
The sucrose molecules dissolve as they are
separated from the other molecules and mix into
                   the water.




                      13
The sucrose molecules dissolve as they are
separated from the other molecules and mix into
                   the water.
What will
dissolve?
The spoon
  or the
 sugar??
Like Dissolves Like
•Polar solvents will dissolve polar solutes.
•Nonpolar solvents will dissolve nonpolar
solutes.

•Polar will not dissolves nonpolar and vice versa.
•Think about oil and water. Is the oil polar or
nonpolar?
How Much Will
  Dissolve?
How Much Will
              Dissolve?

•If you tried to dissolve a lot of sugar in a small glass
of water, not all of the sugar would dissolve.

•Solubility is the measurement of how much
solute dissolves in a given amount of solvent.

•Solubility is usually describes as how much can
dissolve in 100g of solvent at a given temperature.
Solubility
    in a
Liquid-Solid
  Solution
  Temperature is
   included here
     because the
    solubility of a
 solute changes as
the temperature of
     the solvent
       changes.
Solubility
    in a
Liquid-Solid
  Solution
   As you heat
  water, you can
 dissolve sugar in
 water faster rate,
 but also more
     sugar will
      dissolve.
Solubility
     in a
 Liquid-Gas
  Solution
In a liquid-gas solution,
 the opposite is true.

  As the temperature
increases, the solubility
     decreases.
Solubility
     in a
 Liquid-Gas
  Solution
  This is because the
 water molecules will
  be moving faster at
 higher temperatures.
 This movement will
 bump the gas out of
the solution, therefore
  decreases solubility.
Saturated Solutions
•If you add calcium
carbonate to 100g of water
at 25˚C, only 0.0014g will
dissolve. No more can
dissolve.
•This solution is called a
saturated solution.
•If the solution was a liquid-
solid solution, the extra solid
would settle on the bottom
of the container.
Saturated Solutions
•The solubility of sugar in 100g of water at
25˚C is 204g.
•If you had a solution with 50g of sugar in 100g
of water, the solution is called unsaturated.
More solute could dissolve.
Saturated Solutions
•A hot solvent can
usually hold more
solute then a
cooler one.
•If a saturated
solution cools, some
of the solute can fall
out of the solution.
Saturated Solutions
•A hot solvent can usually hold more solute then
a cooler one.
•If a saturated solution cools, some of the solute
can fall out of the solution.
• But if the solution is cooled slowly,
sometimes the excess solute remains dissolved for
a period of time. This solution is called
supersaturated.
Rate of Dissolving
•Solubility does not tell you how fast a solute will
dissolve.
•Some solutes will dissolve quickly, others take a long time
to dissolve.
•A solution dissolves faster when:
     ✴it is stirred
     ✴it is shaken
     ✴the temperature is increased

•How exactly do these factors help?
     ✴They increase the rate at which the surfaces of the

     solute come into contact with the solvent.
     ✴Increasing the area of contact between the solute

     and the solvent can also increase the rate of
     dissolving
Concentrated!
•The concentration of a solution tells you how
much solute is present compared to the amount of
solvent.
•When you are comparing the concentrations of
two solutions with the same type of solute and
solvent, you can use a simple description such as:
dilute or concentrated.
Concentrated!

•The Dead Sea is
5+ times saltier than
Earth's oceans. As
water evaporates,
salt is left behind.
When the
saturation point is
reached, the salt
forms these pillars.
Measuring
 Concentrations
•One way to give the
concentration is by using the
percentage of the volume
of the solution that is made
up of the solute.
Effects on Solute Particles
•Solute particles affect the physical properties
of the solvent, such as the boiling point or the
freezing point.
Effects on Solute Particles
•Adding a solute, such as NaCl, changes the way
the water molecules can arrange themselves. The
solute gets in the way.
Effects on Solute Particles
•To overcome this interference of the solute, a
lower temperature is needed for the solvent to
freeze.
Effects on Solute Particles

 •When a solvent begins to boil, the solvent
 molecules are gaining enough energy to move
 from the liquid state to the gaseous state.
Effects on Solute Particles

 •When a solute is introduced, its particles
 interfere with the evaporation of the solvent
 particles.
Effects on Solute Particles

 •For water and NaCl, the NaCl will block the
 H2O from escaping the liquid and becoming a
 gas.
Effects on Solute Particles

 •More energy is needed for the solvent
 particles to escape from the liquid, and the
 boiling point of the solution will be higher.

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3.2 Solubility

  • 1. Chemistry Chapter 3 - Section 2 Solubility 
  • 2. Water – The Universal Solvent •Many solutions have water as the solvent. •These solutions are called an aqueous solution. •Water dissolves many solutes and so scientists call it the universal solvent. •Why is water such a great solvent? Let’s find out.
  • 4. Dissolving an Ionic Compound example: NaCl
  • 5. Dissolving an Ionic Compound example: NaCl
  • 6. The positive area of the water molecules surround the negative Chloride ions. 6
  • 7. The negative area of the water molecules surround the positive sodium ions.
  • 8. As the attractions from the water molecules and their motion pulls the ions apart, the sodium chloride crystal dissolves.
  • 10. Dissolving a Molecular Compound example: sugar
  • 11. Water molecules arrange themselves around the sucrose molecules according to opposite polar areas. 11
  • 12. The attraction of the water molecules and their motion overcome the attraction between sucrose molecules. 12
  • 13. The sucrose molecules dissolve as they are separated from the other molecules and mix into the water. 13
  • 14. The sucrose molecules dissolve as they are separated from the other molecules and mix into the water.
  • 16. Like Dissolves Like •Polar solvents will dissolve polar solutes. •Nonpolar solvents will dissolve nonpolar solutes. •Polar will not dissolves nonpolar and vice versa. •Think about oil and water. Is the oil polar or nonpolar?
  • 17. How Much Will Dissolve?
  • 18. How Much Will Dissolve? •If you tried to dissolve a lot of sugar in a small glass of water, not all of the sugar would dissolve. •Solubility is the measurement of how much solute dissolves in a given amount of solvent. •Solubility is usually describes as how much can dissolve in 100g of solvent at a given temperature.
  • 19. Solubility in a Liquid-Solid Solution Temperature is included here because the solubility of a solute changes as the temperature of the solvent changes.
  • 20. Solubility in a Liquid-Solid Solution As you heat water, you can dissolve sugar in water faster rate, but also more sugar will dissolve.
  • 21. Solubility in a Liquid-Gas Solution In a liquid-gas solution, the opposite is true. As the temperature increases, the solubility decreases.
  • 22. Solubility in a Liquid-Gas Solution This is because the water molecules will be moving faster at higher temperatures. This movement will bump the gas out of the solution, therefore decreases solubility.
  • 23. Saturated Solutions •If you add calcium carbonate to 100g of water at 25˚C, only 0.0014g will dissolve. No more can dissolve. •This solution is called a saturated solution. •If the solution was a liquid- solid solution, the extra solid would settle on the bottom of the container.
  • 24. Saturated Solutions •The solubility of sugar in 100g of water at 25˚C is 204g. •If you had a solution with 50g of sugar in 100g of water, the solution is called unsaturated. More solute could dissolve.
  • 25. Saturated Solutions •A hot solvent can usually hold more solute then a cooler one. •If a saturated solution cools, some of the solute can fall out of the solution.
  • 26.
  • 27. Saturated Solutions •A hot solvent can usually hold more solute then a cooler one. •If a saturated solution cools, some of the solute can fall out of the solution. • But if the solution is cooled slowly, sometimes the excess solute remains dissolved for a period of time. This solution is called supersaturated.
  • 28. Rate of Dissolving •Solubility does not tell you how fast a solute will dissolve. •Some solutes will dissolve quickly, others take a long time to dissolve. •A solution dissolves faster when: ✴it is stirred ✴it is shaken ✴the temperature is increased •How exactly do these factors help? ✴They increase the rate at which the surfaces of the solute come into contact with the solvent. ✴Increasing the area of contact between the solute and the solvent can also increase the rate of dissolving
  • 29. Concentrated! •The concentration of a solution tells you how much solute is present compared to the amount of solvent. •When you are comparing the concentrations of two solutions with the same type of solute and solvent, you can use a simple description such as: dilute or concentrated.
  • 30. Concentrated! •The Dead Sea is 5+ times saltier than Earth's oceans. As water evaporates, salt is left behind. When the saturation point is reached, the salt forms these pillars.
  • 31. Measuring Concentrations •One way to give the concentration is by using the percentage of the volume of the solution that is made up of the solute.
  • 32. Effects on Solute Particles •Solute particles affect the physical properties of the solvent, such as the boiling point or the freezing point.
  • 33. Effects on Solute Particles •Adding a solute, such as NaCl, changes the way the water molecules can arrange themselves. The solute gets in the way.
  • 34. Effects on Solute Particles •To overcome this interference of the solute, a lower temperature is needed for the solvent to freeze.
  • 35. Effects on Solute Particles •When a solvent begins to boil, the solvent molecules are gaining enough energy to move from the liquid state to the gaseous state.
  • 36. Effects on Solute Particles •When a solute is introduced, its particles interfere with the evaporation of the solvent particles.
  • 37. Effects on Solute Particles •For water and NaCl, the NaCl will block the H2O from escaping the liquid and becoming a gas.
  • 38. Effects on Solute Particles •More energy is needed for the solvent particles to escape from the liquid, and the boiling point of the solution will be higher.

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