Solutions!
Classification of Matter
Matter
Pure
Substances
Mixtures
Homogeneous
Mixtures
Heterogeneous
Mixtures
Elements Compounds
Also called
solutions
Also called
suspensions
Solution
• A homogeneous mixture of 2
or more substances in a single
physical state (phase).
• Exist in all 3 phases.
Parts of a Solution
• Solute = dissolved substance.
• Solvent = dispersing medium.
Identify the solute
and solvent in each
picture.
Solute = ? Solvent = ?
Hints to identify solute & solvent
• Solute – changes phase,
substance you have less of
• Solvent – substance you have the
most of, maintains phase
Aqueous Solutions
• Water is the
solvent.
• Transition
metals form
brightly
colored
solutions.
Soluble
• Soluble – capable of being
dissolved.
• A substance that dissolves in
another substance is soluble in
that substance.
Insoluble
• A substance that does not
dissolve in another substance.
Amounts that can dissolve
• Solubility = maximum amount of 1
substance that will dissolve in a given
amount of another substance.
• LIMITS to the amounts of most liquid
or solid solutes that will dissolve in a
given solvent.
• Temperature and pressure can affect
solubility.
Factors that affect the rate of
dissolving
• Rate of dissolving is different from
the amount that will dissolve!
• Rate is how fast. Several factors
influence rate of dissolving.
–Temperature
–Stirring or Agitation
–Surface Area of Solute
–Amount of solute already dissolved.
Dissolving
• Dissolving is a physical change.
• All physical & chemical changes
are accompanied by changes in
energy.
Equations for Dissolving
C6H12O6(s)  C6H12O6(aq)
NaCl(s)  Na+(aq) + Cl-(aq)
source
Covalent substances dissolve to
produce molecules in solution.
Ionic substances dissolve to
produce ions in solution.
Movie: Dissolution of NaCl
Solvation
• Interaction between the solvent
molecules and the solute particles.
Solute particles are surrounded by
solvent particles in the dissolving
process.
• Solute particles may be ions, polar
molecules, or nonpolar molecules.
• Solvent molecules may be polar or
nonpolar.
Hydration
• Specific name for the solvent-
solute interaction when the
solvent is water.
Hydration of
chloride ion.
Also called a
molecule-ion
interaction.
The solute-
solvent
interaction must
be greater than
the interaction
between solute
particles for
dissolving to
occur.
Molecule-ion interaction
Solubility
• Amount of solute that will dissolve in
a specific solvent at a given
TEMPERATURE and PRESSURE.
• Determined experimentally.
• Units:
grams solute per 100 grams solvent
Solubility Curves of Selected Solids
Solubility
traces for
most but not
all solids have
+’ve slopes.
The hotter the
solvent, the
more solute
dissolves.
Why do we heat the water up when
making rock candy?
Solubility Curves of Selected Gases
Solubility
traces for all
gases have
–’ve slopes.
Why do fish like cold water?
Why do you see
bubbles form on
the side of the
beaker as the
water warms up?
(It’s not hot
enough to boil.)
Vocabulary Interlude
• Miscible: two liquids that will mix in
any amounts.
–Water and ethanol are miscible in all
proportions.
• Immiscible: Liquids that cannot mix
–Oil and water are immiscible.
Oil & H2O are immiscible.
Types of Solutions
Matter
Pure Substances Mixtures
Homogeneous
Mixtures =
Solutions
Heterogeneous
Mixtures
Elements Compounds
Conduct current
Nonconductor
Electricity
• What do you need to conduct
electricity?
Mobile charged particles!!!!
Vocabulary Interlude
• Electrolyte: A substance that dissolves in
water to form a solution that conducts
electricity. (There are ions in the solution.)
• Nonelectrolyte: A substance that
dissolves in water to form a solution that
does not conduct electricity. (There are
neutral molecules in solution.)
Electrolyte vs. Nonelectrolyte
Which solution conducts a current?
Dilute vs. Concentrated
• Tell you relative amount of solute in
solvent.
• Concentrated – relatively large
amounts of solute.
• Dilute – relatively small amounts
of solute.
Which solution
is the most
dilute? The
most
concentrated?
How do you
know?
The stronger the color, the more
concentrated the solution.
Which solution
is more
concentrated?
More dilute?
What can you
say about the
number of
solute particles
in pictures b and
c? It’s the same!
Unsaturated Solution
• Has less solute than the
maximum amount that will
dissolve at that temperature and
pressure.
Saturated Solution
• No more solute will dissolve in it
at that temperature & pressure.
• Solubility = amount of solute
required to form a saturated
solution.
The solution is saturated when the
solute stops dissolving.
Dynamic Equilibrium = Saturated Solution
Microscopic
level: Rate of
dissolving =
Rate of
recrystallization.
Macroscopic
level: No
apparent
change.
Supersaturated Solution
• Contains more solute than a
saturated solution.
• VERY unstable.
• Have to be clever to make them
up.
Sodium Acetate Solution
Heat Pack
Temperature
Testing for saturation:
• Throw a crystal of the solute into
the solution and see what
happens.
3 possible results:
• Crystal dissolves
• No apparent change in crystal
• Bam! Suddenly have lots of solid
solute in beaker.
Unsaturated
solution.
Saturated
solution.
Supersaturated
solution.
What kind of solution was this?
How do the terms saturated,
unsaturated & supersaturated fit
in with the solubility curves?
• Saturated solutions have maximum solute that
will dissolve at that temperature. Points on
traces represent saturated solutions.
• All points above a trace represent
supersaturated solutions of that solute.
• All points below a trace represent unsaturated
solutions of that solute.
A
B
C
D
Characterize points
A, B, C, D with
respect to KNO3
trace using the
terms dilute &
concentrated, and
saturated,
unsaturated, or
supersaturated.
A = concentrated &
supersaturated.
D = dilute & unsaturated.
Summary of Dissolving
• Occurs at the surface of the solid.
• Involves an interaction between the
solute and the solvent.
• Interaction is called “solvation.”
• If water is the solvent, the interaction
is called “hydration.”
• Involves changes in energy.
Solubility Information
• Often presented in graphs
• Show the number of grams of a substance that
can be dissolved in water between 0oC and
100oC.
• Each trace represents a saturated solution.
– The space above each trace represents
supersaturated solutions.
– The space below each trace represents unsaturated
solutions.
Solubility Graphs
• Some traces have positive slopes; some
are negative.
• Most solids have a positive slope – the
hotter the water, the more solute
dissolves.
• All gases have a negative slope – the
hotter the water, the less gas dissolves.
– The colder the water, the more gas dissolves.

Unit12L00 Solution Vocab R15.ppt

  • 1.
  • 2.
  • 3.
    Solution • A homogeneousmixture of 2 or more substances in a single physical state (phase). • Exist in all 3 phases.
  • 4.
    Parts of aSolution • Solute = dissolved substance. • Solvent = dispersing medium.
  • 5.
    Identify the solute andsolvent in each picture.
  • 6.
    Solute = ?Solvent = ?
  • 7.
    Hints to identifysolute & solvent • Solute – changes phase, substance you have less of • Solvent – substance you have the most of, maintains phase
  • 8.
    Aqueous Solutions • Wateris the solvent. • Transition metals form brightly colored solutions.
  • 9.
    Soluble • Soluble –capable of being dissolved. • A substance that dissolves in another substance is soluble in that substance.
  • 10.
    Insoluble • A substancethat does not dissolve in another substance.
  • 11.
    Amounts that candissolve • Solubility = maximum amount of 1 substance that will dissolve in a given amount of another substance. • LIMITS to the amounts of most liquid or solid solutes that will dissolve in a given solvent. • Temperature and pressure can affect solubility.
  • 12.
    Factors that affectthe rate of dissolving • Rate of dissolving is different from the amount that will dissolve! • Rate is how fast. Several factors influence rate of dissolving. –Temperature –Stirring or Agitation –Surface Area of Solute –Amount of solute already dissolved.
  • 13.
    Dissolving • Dissolving isa physical change. • All physical & chemical changes are accompanied by changes in energy.
  • 14.
    Equations for Dissolving C6H12O6(s) C6H12O6(aq) NaCl(s)  Na+(aq) + Cl-(aq)
  • 15.
    source Covalent substances dissolveto produce molecules in solution.
  • 16.
    Ionic substances dissolveto produce ions in solution. Movie: Dissolution of NaCl
  • 18.
    Solvation • Interaction betweenthe solvent molecules and the solute particles. Solute particles are surrounded by solvent particles in the dissolving process. • Solute particles may be ions, polar molecules, or nonpolar molecules. • Solvent molecules may be polar or nonpolar.
  • 19.
    Hydration • Specific namefor the solvent- solute interaction when the solvent is water.
  • 20.
    Hydration of chloride ion. Alsocalled a molecule-ion interaction.
  • 21.
    The solute- solvent interaction must begreater than the interaction between solute particles for dissolving to occur. Molecule-ion interaction
  • 22.
    Solubility • Amount ofsolute that will dissolve in a specific solvent at a given TEMPERATURE and PRESSURE. • Determined experimentally. • Units: grams solute per 100 grams solvent
  • 23.
    Solubility Curves ofSelected Solids Solubility traces for most but not all solids have +’ve slopes. The hotter the solvent, the more solute dissolves.
  • 24.
    Why do weheat the water up when making rock candy?
  • 25.
    Solubility Curves ofSelected Gases Solubility traces for all gases have –’ve slopes. Why do fish like cold water?
  • 26.
    Why do yousee bubbles form on the side of the beaker as the water warms up? (It’s not hot enough to boil.)
  • 27.
    Vocabulary Interlude • Miscible:two liquids that will mix in any amounts. –Water and ethanol are miscible in all proportions. • Immiscible: Liquids that cannot mix –Oil and water are immiscible.
  • 28.
    Oil & H2Oare immiscible.
  • 29.
    Types of Solutions Matter PureSubstances Mixtures Homogeneous Mixtures = Solutions Heterogeneous Mixtures Elements Compounds Conduct current Nonconductor
  • 30.
    Electricity • What doyou need to conduct electricity? Mobile charged particles!!!!
  • 31.
    Vocabulary Interlude • Electrolyte:A substance that dissolves in water to form a solution that conducts electricity. (There are ions in the solution.) • Nonelectrolyte: A substance that dissolves in water to form a solution that does not conduct electricity. (There are neutral molecules in solution.)
  • 32.
    Electrolyte vs. Nonelectrolyte Whichsolution conducts a current?
  • 33.
    Dilute vs. Concentrated •Tell you relative amount of solute in solvent. • Concentrated – relatively large amounts of solute. • Dilute – relatively small amounts of solute.
  • 34.
    Which solution is themost dilute? The most concentrated? How do you know? The stronger the color, the more concentrated the solution.
  • 36.
    Which solution is more concentrated? Moredilute? What can you say about the number of solute particles in pictures b and c? It’s the same!
  • 37.
    Unsaturated Solution • Hasless solute than the maximum amount that will dissolve at that temperature and pressure.
  • 38.
    Saturated Solution • Nomore solute will dissolve in it at that temperature & pressure. • Solubility = amount of solute required to form a saturated solution.
  • 39.
    The solution issaturated when the solute stops dissolving.
  • 40.
    Dynamic Equilibrium =Saturated Solution Microscopic level: Rate of dissolving = Rate of recrystallization. Macroscopic level: No apparent change.
  • 41.
    Supersaturated Solution • Containsmore solute than a saturated solution. • VERY unstable. • Have to be clever to make them up. Sodium Acetate Solution Heat Pack Temperature
  • 43.
    Testing for saturation: •Throw a crystal of the solute into the solution and see what happens.
  • 44.
    3 possible results: •Crystal dissolves • No apparent change in crystal • Bam! Suddenly have lots of solid solute in beaker. Unsaturated solution. Saturated solution. Supersaturated solution.
  • 45.
    What kind ofsolution was this?
  • 46.
    How do theterms saturated, unsaturated & supersaturated fit in with the solubility curves? • Saturated solutions have maximum solute that will dissolve at that temperature. Points on traces represent saturated solutions. • All points above a trace represent supersaturated solutions of that solute. • All points below a trace represent unsaturated solutions of that solute.
  • 47.
    A B C D Characterize points A, B,C, D with respect to KNO3 trace using the terms dilute & concentrated, and saturated, unsaturated, or supersaturated. A = concentrated & supersaturated. D = dilute & unsaturated.
  • 48.
    Summary of Dissolving •Occurs at the surface of the solid. • Involves an interaction between the solute and the solvent. • Interaction is called “solvation.” • If water is the solvent, the interaction is called “hydration.” • Involves changes in energy.
  • 50.
    Solubility Information • Oftenpresented in graphs • Show the number of grams of a substance that can be dissolved in water between 0oC and 100oC. • Each trace represents a saturated solution. – The space above each trace represents supersaturated solutions. – The space below each trace represents unsaturated solutions.
  • 51.
    Solubility Graphs • Sometraces have positive slopes; some are negative. • Most solids have a positive slope – the hotter the water, the more solute dissolves. • All gases have a negative slope – the hotter the water, the less gas dissolves. – The colder the water, the more gas dissolves.