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From the Editor's Desk
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Nanoparticles:Metalsand MetalAlloys,NanoMinerals:Nanoclays
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Nanomaterialand Nanostructures
PuneetMehrotra
ManagingDirector
1. Growth of CNT in a Stainless Steel Surface by Using Gold Nanoparticle as a Catalyst for
Corrosionless Implants
Shyamal Mandal 1
2. Application of Nanomaterials for Food Industry
Sandeep Rai, Anjali Bishnoi, Sunil Kkumar, Jinkal Mistry, Hitkam Pandya 6
3. Synthesis of High-Quality Single- and Double-Walled Carbon Nanotubes on Fe/MgO Catalysts
Hussain Arbai 25
4. MRF Computation to Identify Errors in Quantum Structures
E.N. Ganesh 28
5. Review of Influence of pH on Titanium Dioxide (TiO2)
Pulkit Mathur 38
Contents
IJNN (2016) 1–5 © JournalsPub 2016. All Rights Reserved Page 1
International Journal of Nanomaterials and Nanostructures
eISSN: 2455-5584
Vol. 2: Issue 2
www.journalspub.com
Growth of CNT in a Stainless Steel Surface by Using Gold
Nanoparticle as a Catalyst for Corrosionless Implants
Shyamal Mandal*
Department of Biomedical Engineering, North Eastern Hill University, Shillong, India
ABSTRACT
Now a day’s maximum implant are failure due to corrosion or infection. And the infection is
happened due to growth of Escheria coli, steptococus, miccrobacterium tuberculosis like
bacteria. Carbon nanotubes based stainless steel implant may be the promising outcome for
corrosion. Carbon nano tubes when irradiate with NIR will heat up to 70°C and it has been
demonstrate that folic acid adsorbed on carbon nano tubes allow specific binding to cancer
cells. And this cancer cells were destroyed upon NIR irradiation. Multiwall Carbon Nanotube
(diameter 40–300 nm) were synthesized on the stainless steel surface via chemical vapour
deposition method. Gold nano particles (size 1–30 nm) were used as a catalyst. The surface
morphology, microstructure and were investigated by scanning electron microscopy,
transmission electron microscopy. The interaction of a liquid in stainless steel surface is
defined by measured by contact angle (CA), on the basis of contact angle value the CNT
grown stainless steel surface defined as hydrophobic (øc < 90°). Most of the bacteria grown
in wet surface so the contact angle measurement is very important for testing the anti-
microbial property of that surface.
Keywords: antimicrobial, contact angle, corrosion less, Escheria coli, NIR irradiation
INTRODUCTION
Carbon Nanotube
CNT can be structurally considered as the
seamless rolling of carbon sheets in a
cylindrical form.
Depending on the number of carbon sheets
from which a single carbon monotube is
composed, the carbon nano tube are
classified as single – walled carbon
Nanotube (CWCNT) double wall carbon
nanotube (DWNT) and multi wall carbon
Nano tube (MWNTs) neglecting
hypothical ends the carbon nano tubes are
generally considered to be 1D structures
because of the large aspect ratios of the
cylinders (~104
–106
).
Synthesis of Carbon Nanotube
Based on the literature, the method of
synthesis of CNTs can be categorized in to
two groups:
(a) Physical deposition
(b) Chemical deposition
Physical Method
Under this main category the subcategory
of the physical deposition techniques are
describe below. Arc Discharge: in the arc
discharge method, first an inert-gas-
plasma is created at a low pressure.
Subsequently, an arc discharge is created
by passing high currents between two
carbon roads placed end to end
approximately.1 mm apart. Bacon in 1960,
used this method for the first time to grow
carbon whiskers (Figure 1).[1]
IJNN (2016) 6–24 © JournalsPub 2016. All Rights Reserved Page 6
International Journal of Nanomaterials and Nanostructures
eISSN: 2455-5584
Vol. 2: Issue 2
www.journalspub.com
Application of Nanomaterials for Food Industry
Sandeep Rai1,2*
, Anjali Bishnoi2
, Sunil Kumar2
, Jinkal Mistry1
, Hitkam Pandya1
1
GRP Limited, Panoli Industrial Estate, GIDC, Bharuch, Gujarat, India
2
Shroff S.R. Rotary Institute of Chemical Technology, Vataria, Ankleshwar, Bharuch, Gujarat, India
ABSTRACT
This review focuses on the use of nanomaterials in food industry. The topic of this review
highlights application of nanomaterials in processing, in packaging and as food contact
materials. This review also gives an insight on the food safety as well as regulation of
nanotechnologies for ensuring food safety. The food industry is in need of technologies,
which can be employed to produce fresh authentic, convenient and flavourful food products.
Products with prolonged shelf life and freshness along-with improving the quality of food are
the other major targets. In fact nanomaterials have revolutionized the food industry. Recent
development of smart packaging helped to optimize product shelf life using nanomaterials.
Such packaging systems based on nanomaterials can repair small holes/tears and can
suitably respond to environmental conditions such as temperature and moisture changes to
alert the customer in case the food is contaminated. Nanomaterials can provide answers to
practical solutions for modifying the permeation behaviour of foils by increasing barrier
properties. Nanomaterials can also be used to develop surfaces with antimicrobial and
antifungal properties which are capable of sensing and signalling microbiological and
biochemical changes in the nano-biodegradable packaging. The article also briefly highlight
the need of creating regulatory systems for managing risks associated with the use of
nanomaterials in the food industry.
Keywords: biodegradable, nanofoods, nanomaterials, nanotechnology, nanosensors
INTRODUCTION
Nanomaterials are the pillars of
nanoscience and nanotechnology.
Recently, nanomaterial research has
attracted great attention of scientists and
therefore field has seen exponential growth
over the last few years.
Nanomaterials are defined as very small, at
least in one dimension. In nanomaterial, at
least one dimension (width, length or
height) must be less than 100 nm.[1]
It is to
be highlighted that size of a nanomaterial
is one billionth of a meter or 1000 million
times smaller than a meter.
It is so small that it is 100,000 times
smaller than a diameter of a human hair.
Nanomaterials are of great interest because
of their unique properties.
The nanoparticles possess unique
mechanical, optical, magnetic and
electrical properties which are not
observed in their bulk counterparts.
Because of unique properties,
nanomaterials have potential for
applications in numerous fields such as
food, electronics, medicine, transportation,
textiles, etc.
IJNN (2016) 25-27 © JournalsPub 2016. All Rights Reserved Page 25
International Journal of Nanomaterials and Nanostructures
eISSN: 2455-5584
Vol. 2: Issue 2
www.journalspub.com
Synthesis of High-Quality Single- and Double-Walled Carbon
Nanotubes on Fe/MgO Catalysts
Hussain Arbai*
School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Narmak,
Tehran, Iran
ABSTRACT
In this study, Fe/MgO impetuses with three diverse iron substance (5, 10, and 15 wt.%) were
set up by three impetus readiness techniques: impregnation, arrangement burning union, and
co-calcination of metal nitrates. The subsequent impetuses were subjected to methane at
900°C so as to develop carbon nanotubes (CNTs). The powders and items were then
considered by X-beam diffraction (XRD), differential warm investigation (DTA), checking
and transmission electron microscopy (SEM and TEM), and Raman spectroscopy.
Development of MgFe2O4 after warming the impetuses to 900°C was affirmed by XRD. After
the development step, comparing pinnacles of MgFe2O4 vanished and metallic iron pinnacles
showed up, demonstrating that MgFe2O4 is the dependable stage for generation of iron
nanoparticles. HRTEM pictures demonstrated that the item on the 5 wt.% impetuses was for
the most part SWNTs and DWNTs with no proof of carbon nanofibers or multi-walled carbon
nanotubes on the co-calcination impetus. Moreover, ID/IG proportions acquired from Raman
spectra were all underneath 0.1, with the exception of one specimen, demonstrating the great
nature of the items.
Keywords: carbon nanotubes, catalysis, Raman spectra
INTRODUCTION
Due to their unique properties, single- and
double-walled carbon nanotubes (CNTs)
have found numerous applications in fields
such as catalysis, composites, and
electronics. However, commercialization
requires large-scale and cost-effective
synthesis processes. Catalytic chemical
vapor deposition (CCVD) has become
well-established as a very efficient
technique in such processes,[1,2]
which
requires the presence of a catalyst.
Several methods for the preparation of the
catalyst have been reported, as well as
different ways to modify the synthesis of
desired CNTs. Among them, impregnation
is perhaps the most common. Using this
method, Colomer et al.[3]
reported the
large-scale synthesis of SWNTs over
Fe/MgO, Co/MgO, and Ni/MgO catalysts.
Ago et al.[4]
synthesized single-walled
carbon nanotubes (SWNTs) and double-
walled carbon nanotubes (DWNTs) over
MgO-supported catalysts and reported that
the catalytic activity of Fe was higher than
with Ni and Co; this has been corroborated
elsewhere.[3,5]
Ning et al.[6]
synthesized
SWNTs and DWNTs over heat-treated
Fe/MgO catalysts and revealed that
hydrogen treatment has a very detrimental
effect on CNT quality. This adverse effect
of hydrogen was also reported by Ago et
al.,[7]
correlated to iron-particle coarsening
during the H2 reduction process. Recently,
the present authors reported successful
synthesis of CNTs over Fe/MgAl2O4
catalysts through CCVD without using
IJNN (2016) 28-37 © JournalsPub 2016. All Rights Reserved Page 28
International Journal of Nanomaterials and Nanostructures
eISSN: 2455-5584
Vol. 2: Issue 2
www.journalspub.com
MRF Computation to Identify Errors in Quantum Structures
E.N. Ganesh*
Department of ECE, Saveetha Engineering College, Chennai, India
ABSTRACT
As the present trend move towards the construction of circuits using Nano scale devices, the
probability rate of occurrence of errors in these devices are high. Therefore, detailed study is
required to identify the possibility of errors in these nanoarchitectures. In this paper we
propose two elegant methods namely Probabilistic based design methodology and Markov
random field approach to identify the occurrence of errors. Any arbitrary logic circuits can
be expressed using these methods and logic operation is achieved by maximizing the
probability of state configurations in logic networks. Maximizing the probability of state
configurations is equivalent to minimizing a form of energy that depends on neighbor nodes
in the network. Here, the logic circuits such as full adder, decoder, multiplexer, D and T type
FF are simulated using QCA automata tool and employed the above design methodologies to
find the errors in these devices. Finally we conclude that probabilistic design based approach
and MRF computation can dynamically be adopted to identify the structural and signal based
faults occurring in the quantum scale devices.
Keywords: energy, quantum structure, silicon
INTRODUCTION
Silicon based devices are fast approaching
their practical limits and according to
Moore’s law every couple of years there is
a double of no of transistors on a single
chip.[1]
Limitations such as lithography,
high fields effects, short channel effects
are dominating as the devices dimensions
are reduced. As a result many alternatives
to silicon-based devices are being explored
for the basis of developing new
nanoelectronic systems. Here we focus on
Nanotechnology concept of quantum cell
automata technology being developed by
Walus[2]
that attempts to create a general
computational functionality at the
nanoscale by controlling the position of
single electrons. The fundamental unit of
QCA cell is the QCA cell created with
four Quantum dots positioned at the
vertices of square. Electrons able to tunnel
between the quantum cells placed adjacent
to each other will interact. As a result,
polarization of one cell will be directly
affects the polarization of neighboring
cells. Therefore, an array of QCA cells
acts as a wire and is able to transmit
information from one end to another.
Therefore QCA cells can be used to
construct combinational logic circuits and
these circuits can be simulated using QCA
tool.
The fabrication of nanocircuits has been
limited to a few devices intended to
demonstrate only simple logic or memory
operations. However for larger network of
devices, there are no actual data to
measure the characteristics of these
devices. Practically it may be possible to
have the following two limitations at the
nanoscale levels.
First one, the device failure during
interconnections and next is operation near
IJNN (2016) 38-41© JournalsPub 2016. All Rights Reserved Page 38
International Journal of Nanomaterials and Nanostructures
eISSN: 2455-5584
Vol. 2: Issue 2
www.journalspub.com
Review of Influence of pH on Titanium Dioxide (TiO2)
Pulkit Mathur*
Department of Chemistry, Faculty of Sciences, University of Kinshasa, Kinshasa, Democratic Republic of
Congo
ABSTRACT
The anodic oxidation strategy has been utilized to get ready thin movies of titanium dioxide
(TiO2) in corrosive and soluble electrolytes. The impact of pH on the structure, the
morphology and the photograph reaction of the kept TiO2 has been assessed by measuring
the present thickness. The test comes about demonstrated that the photograph current
reaction was pH subordinate. The corrosive electrolytes being the best medium in creating
stable oxide movies with great grip to titanium metal substrate and great charging rate and
current thickness.
Keywords: anodic oxidation, photo response, pH values, titanium films
INTRODUCTION
The thin layers and nanoparticles of the
move metals oxide stir a major intrigue
these days both on the hypothetical and
exploratory perspective.
On the experimental plan, the
understanding of the behaviour of
transition metals from which they arise is
far from being satisfactory even though
these oxides show very interesting
properties. In their great majority these
oxides show not only a semiconducting
behaviour, but also a photo-catalytic
activity. This last property is particularly
very important in the photolysis of the
water, the decomposition of organic
pollutants, and the clean-up of the air.[1]
The precursory works of Brattan and
Garret on the physical behaviour of
semiconductors, more specifically some
germanium in contact with aqueous
solution are references in this field. The
reference regarding the metal
semiconductors of 3d oxides has for origin
the work realized by Fujishima and
Honda, whose were the first to use a single
crystalline TiO2 photo anode for electro-
catalytic decomposition of water under the
influence of the external applied anode
potential. The application of such as
anodic bias was found to increase the
photo-catalytic efficiency of TiO2 thin
layers for degrading undesirable pollutants
in aqueous solution.[2]
This works were realized in order to use
and store the solar energy and were the
starting point of several researches up
today.
Currently, researches are mainly focused
on three directions: 1) storage and use of
solar energy (photo-galvanic cells), 2)
photo-catalysis by induction of photo-
activated reactions by natural or artificial
catalyst, 3) the manufacturing of
electronic devices (sensors, nano-
components). Regarding to the two first
applications, titanium dioxide to its low
cost and toxicity is the one with quasi-
inalterability in the reaction medium; add
to that his low cost and toxicity.
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International Journal of Nanomaterials and Nanostructures

  • 1. Mechanical Engineering Electronics and Telecommunication Chemical Engineering Architecture Office No-4, 1 Floor, CSC, Pocket-E, Mayur Vihar, Phase-2, New Delhi-110091, India E-mail: info@journalspub.com ¬ International Journal of Thermal Energy and Applications ¬ International Journal of Production Engineering ¬ International Journal of Industrial Engineering and Design ¬ International Journal of Manufacturing and Materials Processing ¬ International Journal of Mechanical Handling and Automation « International Journal of Radio Frequency Design « International Journal of VLSI Design and Technology « International Journal of Embedded Systems and Emerging Technologies « International Journal of Digital Electronics « International Journal of Digital Communication and Analog Signals « International Journal of Housing and Human Settlement Planning « International Journal of Architecture and Infrastructure Planning « International Journal of Rural and Regional Planning Development « International Journal of Town Planning and Management Applied Mechanics 5 more... 1 more... 2 more... 2 more... 5 more... Computer Science and Engineering « International Journal of Wireless Network Security « International Journal of Algorithms Design and Analysis « International Journal of Mobile Computing Devices « International Journal of Software Computing and Testing « International Journal of Data Structures and Algorithms Nanotechnology « International Journal of Applied Nanotechnology « International Journal of Nanomaterials and Nanostructures « International Journals of Nanobiotechnology « International Journal of Solid State Materials « International Journal of Optical Sciences Physics « International Journal of Renewable Energy and its Commercialization « International Journal of Environmental Chemistry « International Journal of Agrochemistry « International Journal of Prevention and Control of Industrial Pollution Civil Engineering « International Journal of Water Resources Engineering « International Journal of Concrete Technology « International Journal of Structural Engineering and Analysis « International Journal of Construction Engineering and Planning Electrical Engineering « International Journal of Analog Integrated Circuits « International Journal of Automatic Control System « International Journal of Electrical Machines & Drives « International Journal of Electrical Communication Engineering « International Journal of Integrated Electronics Systems and Circuits Material Sciences and Engineering « International Journal of Energetic Materials « International Journal of Bionics and Bio-Materials « International Journal of Ceramics and Ceramic Technology « International Journal of Bio-Materials and Biomedical Engineering Chemistry « International Journal of Photochemistry « International Journal of Analytical and Applied Chemistry « International Journal of Green Chemistry « International Journal of Chemical and Molecular Engineering « International Journal of Electro Mechanics and Mechanical Behaviour « International Journal of Machine Design and Manufacturing « International Journal of Mechanical Dynamics and Analysis « International Journal of Fracture and damage Mechanics « International Journal of Structural Mechanics and Finite Elements 5 more... 4 more... 3 more... Biotechnology « International Journal of Industrial Biotechnology and Biomaterials « International Journal of Plant Biotechnology « International Journal of Molecular Biotechnology « International Journal of Biochemistry and Biomolecules « International Journal of Animal Biotechnology and Applications 3 more... Nursing « International Journal of Immunological Nursing « International Journal of Cardiovascular Nursing « International Journal of Neurological Nursing « International Journal of Orthopedic Nursing « International Journal of Oncological Nursing 5 more... 4 more... Subm it Your A rticle2017 www.journalspub.com International Journal of Nanomaterials & Nanostructures IJNN JUL–DEC 2016 eISSN: 2455-5584
  • 2. International Journals Publisher JournalsPub is a multi-disciplinary international journal boosting innovative & eminence research work by Division of Dhruv Infosystems Pvt. Ltd. Launched in 2014 under the support and guidance by our Honorable EditorialBoard Members from renownedinstitutes. ObjectivesofJournalsPub  JournalsPub is international scholarly journal that publishes peer reviewed journal in the frontier areas of AppliedSciences,MedicalandEngineering.  JournalsPub publishes Original Research Papers, Review Papers, Popular Articles, Short Communications&CaseStudy.  Publishingspecialissues on Proceedingsof Conferences,SeminarsandSymposia.  JournalsPub Publishes issues twice a year (bi-annually) in English-language which is available online (openaccess)andinprintedversionwithagoaltopromoteanextensiveacademicawareness.  JournalsPub desires to set a good benchmark in the publishing industry by launching more than 100+ new International Journals to help the scientific community to enhance communication within the research communities and maintain a balance between the existing and emerging interdisciplinary technologies.  JournalsPub aims to provide quality research articles for Academic Researchers, Industrial Professionals, Engineers, Scientists, Professors, etc. working in the areas of Applied Sciences, Medical andEngineeringtocontributeandcommunicateinnovativework. SalientFeatures  An umbrellaof 100+ journalsthatcoversAppliedSciences,MedialandEngineeringArena.  The first and one of the rapidly emerging publication website in Country as well as overseas for its excellenceandexposure.  Universaltransmissionandreflectivity.  ARigorous, Fast andConstructivePeerReviewProcess  SpeedyPublicationof Manuscripts  EminentEditorialBoardMembersfromrenownedorganizations.  FreeRegistration,OnlineSubmission, Processing, Publication&OnlineAccessofManuscripts.  Thejournalpublishesnovelresearcharticleswithemphasison theoreticalandexperimentalwork. International Journal of Nanomaterials and Nanostructures
  • 3. JournalsPub (Division of Dhruv Infosystem Private Ltd.) having its Marketing office located at Office No. 4, First Floor, CSC pocket E Market, Mayur Vihar Phase II, New Delhi-110091, India is the Publisher of Journals. Statements and opinionsexpressedintheJournalreflecttheviews oftheAuthor(s) andarenottheopinionofJournalsPub unlessso stated. Subscription Information and Order Cost of Journal National Subscription Rs. 3000/-perJournal(includes2 printissues), SingleIssue copypurchaseRs.1800/copy International Subscription OnlineOnly- $99, PrintOnly-$149 (includes2printissues) Online+ Print-$199(includes2printissues +onlineaccessof publishedbackvolumes) To purchaseprintcompilationof backissues pleasesendyourqueryatinfo@journalspub.com Subscription must be prepaid. Rates outside the India include speed delivery charges. Prices subject to change without notice. Mode of Payment:At par cheque, Demand draft, and RTGS (payment to be made in favor of Dhruv Infosystems Pvt. ltd., payableatDelhi/NewDelhi. OnlineAccess Policy A). ForAuthors: In order to provide maximum citation and wide publicity to the authors work, JournalsPub also have OpenAccess Policy; Authors who would like to get their work open access can opt for Optional Open Access publication at nominal cost as follows: India,SARC andAfricanCountries:INR 1500 includingsinglehardcopyofAuthor's Journal. OtherCountries:USD 200includingsinglehardcopyofAuthor's Journal. B.) ForSubscribers: Online access will be activated within 72 hours of receipt of the payment (working days), subject to receipt of correct informationonuser details/StaticIPaddress of thesubscriber. The accesswillbeblocked: If the user requests for the same and furnishes valid reasons for blocking due to technical issue. Misuse of the access rights as pertheaccesspolicy. Advertising and Commercial Reprint Inquiries: JournalsPub with wide circulation and visibility offer an excellent media for showcasing/promotion of your products/services and the events-namely, Conferences, Symposia/Seminars etc.These journals have very high potential to deliver the message across the targeted audience regularly with each published issue. The advertisements on bulk subscriptions, gift subscriptions or reprint purchases for distribution etc. are also very welcome. LostIssue Claims:Pleasenotethefollowingwhen applyingfor lostor missingissues: Claims for print copies lost will be honored only after 45 days of the dispatch date and before publication of the next issue as perthefrequency. Tracking id for the speed post will be provided to all our subscribers and the claims for the missing Journals will be entertainedonlywiththeproofs whichwillbeverifiedatboththeends. Claimsfiledduetoinsufficient(or nonotice)of changeof address willnotbehonored. Change ofAddress of Dispatch should be intimated to JournalsPub at least 2 months prior to the dispatch schedule as per thefrequencyby mentioningsubscriberID andthesubscriptionID. Refundrequestswillnotbeentertained. LegalDisputes AllthelegaldisputesaresubjectedtoDelhiJurisdictiononly. If you haveanyquestions,pleasecontactthePublicationManagementTeam: info@journalspub.com;Tel:+910120-4347644.
  • 4. International Journal of Nanomaterials and Nanostructures International Journal of Nanomaterial and Nanostructures is a comprehensive journal that covers all aspects of Nanomaterials and Nanostructures their integration into recent technologies that are the focus of ongoing research. Journal has a wider scope including all major advancement in the technology and design that are related to NanoMaterials and Nanostructures All articles presented here are peer-reviewed and are of good quality. Focus andScopeoftheJournal  Zero- One and two -Dimensional Nanostructures  Special Nanomaterials  Nanostructures Fabrication  Nanomaterials synthesis  Nanotopography  Nanocomposite  GML nanofilm  Nanocages  Nanofabrics  Nanofiber  Nanoflake  Nanoparticles: Metals and Metal Alloys  Nano Minerals: Nanoclays International Journal of Nanomaterials and Nanostructures is published twice a year (bi-annual) in India by JournalsPub is an imprint of Dhruv Infosystems Pvt. Ltd. The outlooks stated in the articles do not essentially reflect of the publisher. The publisher does not endorse the quality or value of the advertised/sponsored products described therein. Please consult full prescribing information before issuing aprescriptionfor anyproductsmentionedinthispublication. No part of this publication may be reproduced, stored in retrieval or transmitted in any form without written permissiontothepublisher. To cite any of the material contained in this journal, in English or translation, please use the full English reference at the beginning of each article. To reuse any of the material, please contact JournalsPub (info@journalspub.com).
  • 5. PUBLICATION MANAGEMENT TEAM INTERNAL MEMBERS Associate Manager Chairman Mr. Puneet Mehrotra Managing Director, JournalsPub, New Delhi Hidam Renubala Ankita Singh Deepika Bhadauria Rekha Rani Commissioning Editors Dr. Chhavi Goel Manisha Dhoble
  • 6. EDITORIAL BOARD MEMBERS Dr. Nitu R Katariya Rajiv Gandhi Technical University, Bhopal (M.P.) India, India Dr Kalaivani Thirunavukarasu SRM University, India Dr. Sohel Rana University of Minho, Campus de Azurem Portugal Dr. Alagiri Swamy SRM university Main Campus, India Dr. Alexander Samardak Far Eastern Federal University, Russian Federation Dr. Swapnadip De Meghnad Saha Institute Of Technology, India Dr Jay Singh Delhi Technological University, Delhi, India Dr. Tapas Kuila DST INSPIRE Faculty Fellow, India Dr. Suresh Kumar Kailas S. V. National Institute of Technology (SVNIT), India Dr. Lavanya khanna Thapar University, Patiala, India Dr. Saeed Khodabakhshi Research Institute of Petroleum Industry (RIPI) Tehran, Iran Dr Prashanthi Kovur University of Alberta, Canada Dr. Michael Loong Peng Tan Dept. of Electronics and Computer Engineering (ECE) Faculty of Electrical Enginering Universiti Teknologi Malaysia (UTM) Skudai Johor Malaysia Dr. Ajaya Kumar Singh Associate Professor Department of Chemistry (DST-FIST Sponsored) Govt. V. Y. T. PG. Autonomous College, (College with Potential for Excellence) Durg Chhattisgarh, India Dr. Dalvinder Singh Grewal Advisor, Sri Sukhmani Group of Institutions ChandigarhIn Dr. Neetha J. Shetty Associate Professor, Manipal college of dental sciences Mangalore, India Dr. Rajesh Das Associate Professor Haldia Institute of technology, Haldia Purba-Medinipur, West Bengal, India., India Dr. Aniruddha Chatterjee Deptment of Plastics and Polymers Technology University Institute of Chemical Technology, North Maharashtra University, Jalgaon India Dr. S. Krishnakumar Associate Professor, Department of Biomedical Engineering, Faculty of Bio and Chemical Engineering, Sathyabama University Chennai, India, India Dr. Bipin J. Agrawal, Dr. Bipin J. Agrawal (FTA(I), FISCA, FICER, FIJERIA, FIJMRAE, FANSF) Associate Professor Department of Textile Chemistry Faculty of Technology & Engineering The M. S. University of Baroda vadodara India Dr. Shobhna Vij niscair, nsl, new delhi, India Dr. Pradip Kumar Roy Assistant Professor Indian Institute of Technology (I.I.T.) – Banaras Hindu University (B.H.U.),Varanasi
  • 7. From the Editor's Desk Dear Readers, We would like to present, with great pleasure, the inaugural volume of a new scholarly journal, International Journal of Nanomaterials and Nanostructures. This journal is part of the Nanomaterials and Nanostructures and is devoted to the scope of present Nanotech and Material Sciences from theoretical aspects to application-dependent studies and the validationofemergingtechnologies. This new journal was planned and established to represent the growing needs of International Journal of Nanomaterials and Nanostructures as an emerging and increasingly vital field, now widely recognized as an integral part of scientific and technical investigations. Its mission is to become a voice of the Nanotech and MaterialSciencescommunity,addressing researchersand practitionersinthisarea. The core vision of International Journal of Nanomaterials and Nanostructured in JournalsPub is to propagate novel awareness and know-how for the profit of mankind ranging from the academic and professional research societies to industry practitioners in a range of topics in Nanotech and Material Sciences in general. Journals Pub acts as a pathfinder for the scientific community to published their papers atexcellently,well-time&successfully. International Journal of Nanomaterials and Nanostructured focuses on original high-quality research in the realm of Nanomaterial sciences and Material Structure. Zero- One and two -Dimensional Nanostructures,Special Nanomaterials, Nanostructures Fabrication, Nanomaterials synthesis, Nanotopography, Nanocomposite,GML nanofilm, Nanocages, Nanofabrics ,Nanofiber, Nanoflake, Nanoparticles:Metalsand MetalAlloys,NanoMinerals:Nanoclays The Journal is intended as a forum for practitioners and researchers to share the techniques to share Nanomaterials,Nanostructuresand Materialsciencessolutionsinthearea. Many scientists and researchers have contributed to the creation and the success of the Nanomaterial and Nanostructures community. We are very thankful to everybody within that community who supported the idea of creating an innovative platform. We are certain that this issue will be followed by many others, reportingnewdevelopmentsinthefieldofNanomaterialsciencesandNanostructure This issue would not have been possible without the great support of the Editorial Board members, and we would like to express our sincere thanks to all of them. We would also like to express our gratitude to the editorialstaffofJournalsPub,who supported us ateverystageoftheproject. It is our hope that this fine collection of articles will be a valuable resource for International Journal of Nanomaterials and Nanostructures readers and will stimulate further research into the vibrant area of Nanomaterialand Nanostructures PuneetMehrotra ManagingDirector
  • 8. 1. Growth of CNT in a Stainless Steel Surface by Using Gold Nanoparticle as a Catalyst for Corrosionless Implants Shyamal Mandal 1 2. Application of Nanomaterials for Food Industry Sandeep Rai, Anjali Bishnoi, Sunil Kkumar, Jinkal Mistry, Hitkam Pandya 6 3. Synthesis of High-Quality Single- and Double-Walled Carbon Nanotubes on Fe/MgO Catalysts Hussain Arbai 25 4. MRF Computation to Identify Errors in Quantum Structures E.N. Ganesh 28 5. Review of Influence of pH on Titanium Dioxide (TiO2) Pulkit Mathur 38 Contents
  • 9. IJNN (2016) 1–5 © JournalsPub 2016. All Rights Reserved Page 1 International Journal of Nanomaterials and Nanostructures eISSN: 2455-5584 Vol. 2: Issue 2 www.journalspub.com Growth of CNT in a Stainless Steel Surface by Using Gold Nanoparticle as a Catalyst for Corrosionless Implants Shyamal Mandal* Department of Biomedical Engineering, North Eastern Hill University, Shillong, India ABSTRACT Now a day’s maximum implant are failure due to corrosion or infection. And the infection is happened due to growth of Escheria coli, steptococus, miccrobacterium tuberculosis like bacteria. Carbon nanotubes based stainless steel implant may be the promising outcome for corrosion. Carbon nano tubes when irradiate with NIR will heat up to 70°C and it has been demonstrate that folic acid adsorbed on carbon nano tubes allow specific binding to cancer cells. And this cancer cells were destroyed upon NIR irradiation. Multiwall Carbon Nanotube (diameter 40–300 nm) were synthesized on the stainless steel surface via chemical vapour deposition method. Gold nano particles (size 1–30 nm) were used as a catalyst. The surface morphology, microstructure and were investigated by scanning electron microscopy, transmission electron microscopy. The interaction of a liquid in stainless steel surface is defined by measured by contact angle (CA), on the basis of contact angle value the CNT grown stainless steel surface defined as hydrophobic (øc < 90°). Most of the bacteria grown in wet surface so the contact angle measurement is very important for testing the anti- microbial property of that surface. Keywords: antimicrobial, contact angle, corrosion less, Escheria coli, NIR irradiation INTRODUCTION Carbon Nanotube CNT can be structurally considered as the seamless rolling of carbon sheets in a cylindrical form. Depending on the number of carbon sheets from which a single carbon monotube is composed, the carbon nano tube are classified as single – walled carbon Nanotube (CWCNT) double wall carbon nanotube (DWNT) and multi wall carbon Nano tube (MWNTs) neglecting hypothical ends the carbon nano tubes are generally considered to be 1D structures because of the large aspect ratios of the cylinders (~104 –106 ). Synthesis of Carbon Nanotube Based on the literature, the method of synthesis of CNTs can be categorized in to two groups: (a) Physical deposition (b) Chemical deposition Physical Method Under this main category the subcategory of the physical deposition techniques are describe below. Arc Discharge: in the arc discharge method, first an inert-gas- plasma is created at a low pressure. Subsequently, an arc discharge is created by passing high currents between two carbon roads placed end to end approximately.1 mm apart. Bacon in 1960, used this method for the first time to grow carbon whiskers (Figure 1).[1]
  • 10. IJNN (2016) 6–24 © JournalsPub 2016. All Rights Reserved Page 6 International Journal of Nanomaterials and Nanostructures eISSN: 2455-5584 Vol. 2: Issue 2 www.journalspub.com Application of Nanomaterials for Food Industry Sandeep Rai1,2* , Anjali Bishnoi2 , Sunil Kumar2 , Jinkal Mistry1 , Hitkam Pandya1 1 GRP Limited, Panoli Industrial Estate, GIDC, Bharuch, Gujarat, India 2 Shroff S.R. Rotary Institute of Chemical Technology, Vataria, Ankleshwar, Bharuch, Gujarat, India ABSTRACT This review focuses on the use of nanomaterials in food industry. The topic of this review highlights application of nanomaterials in processing, in packaging and as food contact materials. This review also gives an insight on the food safety as well as regulation of nanotechnologies for ensuring food safety. The food industry is in need of technologies, which can be employed to produce fresh authentic, convenient and flavourful food products. Products with prolonged shelf life and freshness along-with improving the quality of food are the other major targets. In fact nanomaterials have revolutionized the food industry. Recent development of smart packaging helped to optimize product shelf life using nanomaterials. Such packaging systems based on nanomaterials can repair small holes/tears and can suitably respond to environmental conditions such as temperature and moisture changes to alert the customer in case the food is contaminated. Nanomaterials can provide answers to practical solutions for modifying the permeation behaviour of foils by increasing barrier properties. Nanomaterials can also be used to develop surfaces with antimicrobial and antifungal properties which are capable of sensing and signalling microbiological and biochemical changes in the nano-biodegradable packaging. The article also briefly highlight the need of creating regulatory systems for managing risks associated with the use of nanomaterials in the food industry. Keywords: biodegradable, nanofoods, nanomaterials, nanotechnology, nanosensors INTRODUCTION Nanomaterials are the pillars of nanoscience and nanotechnology. Recently, nanomaterial research has attracted great attention of scientists and therefore field has seen exponential growth over the last few years. Nanomaterials are defined as very small, at least in one dimension. In nanomaterial, at least one dimension (width, length or height) must be less than 100 nm.[1] It is to be highlighted that size of a nanomaterial is one billionth of a meter or 1000 million times smaller than a meter. It is so small that it is 100,000 times smaller than a diameter of a human hair. Nanomaterials are of great interest because of their unique properties. The nanoparticles possess unique mechanical, optical, magnetic and electrical properties which are not observed in their bulk counterparts. Because of unique properties, nanomaterials have potential for applications in numerous fields such as food, electronics, medicine, transportation, textiles, etc.
  • 11. IJNN (2016) 25-27 © JournalsPub 2016. All Rights Reserved Page 25 International Journal of Nanomaterials and Nanostructures eISSN: 2455-5584 Vol. 2: Issue 2 www.journalspub.com Synthesis of High-Quality Single- and Double-Walled Carbon Nanotubes on Fe/MgO Catalysts Hussain Arbai* School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Narmak, Tehran, Iran ABSTRACT In this study, Fe/MgO impetuses with three diverse iron substance (5, 10, and 15 wt.%) were set up by three impetus readiness techniques: impregnation, arrangement burning union, and co-calcination of metal nitrates. The subsequent impetuses were subjected to methane at 900°C so as to develop carbon nanotubes (CNTs). The powders and items were then considered by X-beam diffraction (XRD), differential warm investigation (DTA), checking and transmission electron microscopy (SEM and TEM), and Raman spectroscopy. Development of MgFe2O4 after warming the impetuses to 900°C was affirmed by XRD. After the development step, comparing pinnacles of MgFe2O4 vanished and metallic iron pinnacles showed up, demonstrating that MgFe2O4 is the dependable stage for generation of iron nanoparticles. HRTEM pictures demonstrated that the item on the 5 wt.% impetuses was for the most part SWNTs and DWNTs with no proof of carbon nanofibers or multi-walled carbon nanotubes on the co-calcination impetus. Moreover, ID/IG proportions acquired from Raman spectra were all underneath 0.1, with the exception of one specimen, demonstrating the great nature of the items. Keywords: carbon nanotubes, catalysis, Raman spectra INTRODUCTION Due to their unique properties, single- and double-walled carbon nanotubes (CNTs) have found numerous applications in fields such as catalysis, composites, and electronics. However, commercialization requires large-scale and cost-effective synthesis processes. Catalytic chemical vapor deposition (CCVD) has become well-established as a very efficient technique in such processes,[1,2] which requires the presence of a catalyst. Several methods for the preparation of the catalyst have been reported, as well as different ways to modify the synthesis of desired CNTs. Among them, impregnation is perhaps the most common. Using this method, Colomer et al.[3] reported the large-scale synthesis of SWNTs over Fe/MgO, Co/MgO, and Ni/MgO catalysts. Ago et al.[4] synthesized single-walled carbon nanotubes (SWNTs) and double- walled carbon nanotubes (DWNTs) over MgO-supported catalysts and reported that the catalytic activity of Fe was higher than with Ni and Co; this has been corroborated elsewhere.[3,5] Ning et al.[6] synthesized SWNTs and DWNTs over heat-treated Fe/MgO catalysts and revealed that hydrogen treatment has a very detrimental effect on CNT quality. This adverse effect of hydrogen was also reported by Ago et al.,[7] correlated to iron-particle coarsening during the H2 reduction process. Recently, the present authors reported successful synthesis of CNTs over Fe/MgAl2O4 catalysts through CCVD without using
  • 12. IJNN (2016) 28-37 © JournalsPub 2016. All Rights Reserved Page 28 International Journal of Nanomaterials and Nanostructures eISSN: 2455-5584 Vol. 2: Issue 2 www.journalspub.com MRF Computation to Identify Errors in Quantum Structures E.N. Ganesh* Department of ECE, Saveetha Engineering College, Chennai, India ABSTRACT As the present trend move towards the construction of circuits using Nano scale devices, the probability rate of occurrence of errors in these devices are high. Therefore, detailed study is required to identify the possibility of errors in these nanoarchitectures. In this paper we propose two elegant methods namely Probabilistic based design methodology and Markov random field approach to identify the occurrence of errors. Any arbitrary logic circuits can be expressed using these methods and logic operation is achieved by maximizing the probability of state configurations in logic networks. Maximizing the probability of state configurations is equivalent to minimizing a form of energy that depends on neighbor nodes in the network. Here, the logic circuits such as full adder, decoder, multiplexer, D and T type FF are simulated using QCA automata tool and employed the above design methodologies to find the errors in these devices. Finally we conclude that probabilistic design based approach and MRF computation can dynamically be adopted to identify the structural and signal based faults occurring in the quantum scale devices. Keywords: energy, quantum structure, silicon INTRODUCTION Silicon based devices are fast approaching their practical limits and according to Moore’s law every couple of years there is a double of no of transistors on a single chip.[1] Limitations such as lithography, high fields effects, short channel effects are dominating as the devices dimensions are reduced. As a result many alternatives to silicon-based devices are being explored for the basis of developing new nanoelectronic systems. Here we focus on Nanotechnology concept of quantum cell automata technology being developed by Walus[2] that attempts to create a general computational functionality at the nanoscale by controlling the position of single electrons. The fundamental unit of QCA cell is the QCA cell created with four Quantum dots positioned at the vertices of square. Electrons able to tunnel between the quantum cells placed adjacent to each other will interact. As a result, polarization of one cell will be directly affects the polarization of neighboring cells. Therefore, an array of QCA cells acts as a wire and is able to transmit information from one end to another. Therefore QCA cells can be used to construct combinational logic circuits and these circuits can be simulated using QCA tool. The fabrication of nanocircuits has been limited to a few devices intended to demonstrate only simple logic or memory operations. However for larger network of devices, there are no actual data to measure the characteristics of these devices. Practically it may be possible to have the following two limitations at the nanoscale levels. First one, the device failure during interconnections and next is operation near
  • 13. IJNN (2016) 38-41© JournalsPub 2016. All Rights Reserved Page 38 International Journal of Nanomaterials and Nanostructures eISSN: 2455-5584 Vol. 2: Issue 2 www.journalspub.com Review of Influence of pH on Titanium Dioxide (TiO2) Pulkit Mathur* Department of Chemistry, Faculty of Sciences, University of Kinshasa, Kinshasa, Democratic Republic of Congo ABSTRACT The anodic oxidation strategy has been utilized to get ready thin movies of titanium dioxide (TiO2) in corrosive and soluble electrolytes. The impact of pH on the structure, the morphology and the photograph reaction of the kept TiO2 has been assessed by measuring the present thickness. The test comes about demonstrated that the photograph current reaction was pH subordinate. The corrosive electrolytes being the best medium in creating stable oxide movies with great grip to titanium metal substrate and great charging rate and current thickness. Keywords: anodic oxidation, photo response, pH values, titanium films INTRODUCTION The thin layers and nanoparticles of the move metals oxide stir a major intrigue these days both on the hypothetical and exploratory perspective. On the experimental plan, the understanding of the behaviour of transition metals from which they arise is far from being satisfactory even though these oxides show very interesting properties. In their great majority these oxides show not only a semiconducting behaviour, but also a photo-catalytic activity. This last property is particularly very important in the photolysis of the water, the decomposition of organic pollutants, and the clean-up of the air.[1] The precursory works of Brattan and Garret on the physical behaviour of semiconductors, more specifically some germanium in contact with aqueous solution are references in this field. The reference regarding the metal semiconductors of 3d oxides has for origin the work realized by Fujishima and Honda, whose were the first to use a single crystalline TiO2 photo anode for electro- catalytic decomposition of water under the influence of the external applied anode potential. The application of such as anodic bias was found to increase the photo-catalytic efficiency of TiO2 thin layers for degrading undesirable pollutants in aqueous solution.[2] This works were realized in order to use and store the solar energy and were the starting point of several researches up today. Currently, researches are mainly focused on three directions: 1) storage and use of solar energy (photo-galvanic cells), 2) photo-catalysis by induction of photo- activated reactions by natural or artificial catalyst, 3) the manufacturing of electronic devices (sensors, nano- components). Regarding to the two first applications, titanium dioxide to its low cost and toxicity is the one with quasi- inalterability in the reaction medium; add to that his low cost and toxicity.
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