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THIRUNAVUKARASU.H
13MY12
1
 Wear
− mechanical;
− corrosive-mechanical.
Criteria: wear resistance (by mass/volume, relative)
 Methods of surface reinforcement
− surface alloying and hardening;
− coatings (sprayed coatings, vapor deposited coatings,
cladded coatings, galvanic coatings, diffusion coatings);
− metal cladding (bimetal materials).
2
3
4
 CHEMICAL
 ELECTROCHEMICAL
 THERMOCHEMICAL
 THERMOCOATING
 VAPOR DEPOSITION
 MECHANICAL
5
6
 CHEMICAL
 ELECTROCHEMICAL
 THERMOCOATING
 VAPOR DEPOSITION
 MECHANICAL
7
cold gas
spraying
(CGS)
laser spraying
(LS)
molten-metal
flame
spraying
Thermal spraying
Typical structure of a coating
8
9
10
- flame temperature:
• acetylene/oxygen 3160 ºC;
• propane/oxygen 2850 ºC;
• hydrogen/oxygen 2660 ºC.
- sprayed materials:
• wire: metals and metal alloys;
• powder: pure metals, alloys, oxides,
cermets,
composite powders.
11
• temperature inside the arc: 6500 ºC;
• voltage 18 – 40 V, current 50 – 150 A;
• sprayed materials: electroconductive
alloys,
ceramics can be deposited, when using
core wires.
12
• plasma temperature: up to
30000 ºC.
• virtually all existing
materials.
13
• Fe, Ni, Co, Cr based alloys,
stainless steels, cermets
14
• virtually all metal alloys,
cermets and ceramics.
15
• flame temperature: 4000 ºC.
16
• gas temperature: 3000 ºC;
• sprayed materials: virtually all existing
materials, in practice mostly carbide/metal
and carbide / self-fluxing alloy mixtures.
17
• gas temperature: under the
phase transition temperature;
• sprayed materials: pure Al, Zn, Cu, Ni
and babbites.
18
ThermalEnergy
Kinetic Energy
WARCS
PS
FS
HVOF
CS
Wirearc Spray
Plasma Spray
Flame Spray
High velocity oxy fuel
Cold Spray
Melt or partially melt
Solid
19
Spray technology Velocity, m/s Porosity, % Adhesion, MPa
Flame spraying
• powder
• wire
30
180
6 – 15 17 – 70
15 – 20
Arc spraying 240 2 – 8 40
Plasma spraying (different
modifications)
240 – 1200 < (0,5 – 2) 20 – 70
Detonation gun spraying 910 < 1 ≥ 100
HVOF, HVAF 610 – 1500 < 0,5 62 – 83
Cold spraying 500 – 1200 1 – 3 30 – 100
20
Sprayed material Spraying technology Hardness, HV
Chrome steel Flame spraying (wire) 500 – 600
PTA 800 – 850
NiAl alloy Flame spraying 200 – 250
Copper Flame spraying (powder) 150
Stellite Flame spraying (powder)/HVOF 460 – 770
PTA 290 – 590
MCrAlY Plasma spraying 400
Self-fluxing alloy (NiCrSiB) Flame spraying/HVOF 250 – 780
PTA 360 – 820
WC-Co Plasma spraying
(powder)/HVOF
1100 – 1300
Al2O3 Plasma spraying 1800 – 2000
21
22
HV0.3
23
0
100
200
300
400
500
600
700
800
1 2 3 4 5 6
WeightLoss(mg)
7PSZ
Al2O3
Cr2O3
22x
32x 21x
APS HVOF APS HVOF APS HVOF
24
25
 wear resistant coatings
(pumps, compressors,
camshafts, etc.) –
except for cold
spraying;
 corrosion resistant
coatings (pipelines,
building constructions,
etc.);
26
 temperature resistant
and dielectrical coatings
(gas turbines, flue
tubes);
 antifriction coatings
(sliding bearings);
 size restoration (shafts,
bearings, etc.)
27
28
29
30

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Thermal spraying

  • 2.  Wear − mechanical; − corrosive-mechanical. Criteria: wear resistance (by mass/volume, relative)  Methods of surface reinforcement − surface alloying and hardening; − coatings (sprayed coatings, vapor deposited coatings, cladded coatings, galvanic coatings, diffusion coatings); − metal cladding (bimetal materials). 2
  • 3. 3
  • 4. 4
  • 5.  CHEMICAL  ELECTROCHEMICAL  THERMOCHEMICAL  THERMOCOATING  VAPOR DEPOSITION  MECHANICAL 5
  • 6. 6
  • 7.  CHEMICAL  ELECTROCHEMICAL  THERMOCOATING  VAPOR DEPOSITION  MECHANICAL 7 cold gas spraying (CGS) laser spraying (LS) molten-metal flame spraying Thermal spraying
  • 8. Typical structure of a coating 8
  • 9. 9
  • 10. 10 - flame temperature: • acetylene/oxygen 3160 ºC; • propane/oxygen 2850 ºC; • hydrogen/oxygen 2660 ºC. - sprayed materials: • wire: metals and metal alloys; • powder: pure metals, alloys, oxides, cermets, composite powders.
  • 11. 11 • temperature inside the arc: 6500 ºC; • voltage 18 – 40 V, current 50 – 150 A; • sprayed materials: electroconductive alloys, ceramics can be deposited, when using core wires.
  • 12. 12 • plasma temperature: up to 30000 ºC. • virtually all existing materials.
  • 13. 13 • Fe, Ni, Co, Cr based alloys, stainless steels, cermets
  • 14. 14 • virtually all metal alloys, cermets and ceramics.
  • 16. 16 • gas temperature: 3000 ºC; • sprayed materials: virtually all existing materials, in practice mostly carbide/metal and carbide / self-fluxing alloy mixtures.
  • 17. 17 • gas temperature: under the phase transition temperature; • sprayed materials: pure Al, Zn, Cu, Ni and babbites.
  • 18. 18 ThermalEnergy Kinetic Energy WARCS PS FS HVOF CS Wirearc Spray Plasma Spray Flame Spray High velocity oxy fuel Cold Spray Melt or partially melt Solid
  • 19. 19
  • 20. Spray technology Velocity, m/s Porosity, % Adhesion, MPa Flame spraying • powder • wire 30 180 6 – 15 17 – 70 15 – 20 Arc spraying 240 2 – 8 40 Plasma spraying (different modifications) 240 – 1200 < (0,5 – 2) 20 – 70 Detonation gun spraying 910 < 1 ≥ 100 HVOF, HVAF 610 – 1500 < 0,5 62 – 83 Cold spraying 500 – 1200 1 – 3 30 – 100 20
  • 21. Sprayed material Spraying technology Hardness, HV Chrome steel Flame spraying (wire) 500 – 600 PTA 800 – 850 NiAl alloy Flame spraying 200 – 250 Copper Flame spraying (powder) 150 Stellite Flame spraying (powder)/HVOF 460 – 770 PTA 290 – 590 MCrAlY Plasma spraying 400 Self-fluxing alloy (NiCrSiB) Flame spraying/HVOF 250 – 780 PTA 360 – 820 WC-Co Plasma spraying (powder)/HVOF 1100 – 1300 Al2O3 Plasma spraying 1800 – 2000 21
  • 23. 23 0 100 200 300 400 500 600 700 800 1 2 3 4 5 6 WeightLoss(mg) 7PSZ Al2O3 Cr2O3 22x 32x 21x APS HVOF APS HVOF APS HVOF
  • 24. 24
  • 25. 25
  • 26.  wear resistant coatings (pumps, compressors, camshafts, etc.) – except for cold spraying;  corrosion resistant coatings (pipelines, building constructions, etc.); 26
  • 27.  temperature resistant and dielectrical coatings (gas turbines, flue tubes);  antifriction coatings (sliding bearings);  size restoration (shafts, bearings, etc.) 27
  • 28. 28
  • 29. 29
  • 30. 30