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REDOX REACTIONS A.k.a.  A study on why things explode
But I Know Every Rock and Tree and Creature… ,[object Object]
Oxidation of Food: What a Waste! ,[object Object],[object Object],[object Object]
Oxidation of… ,[object Object],[object Object],People!
What will I learn? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What is a redox reaction? ,[object Object],[object Object],[object Object],[object Object],[object Object]
Redox gain of electrons loss of electrons gain in hydrogen loss of hydrogen loss of oxygen gain in oxygen Reduction Oxidation
Oxidation and Reduction ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Oxidation and Reduction ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Oxidation and Reduction ,[object Object],[object Object],[object Object],[object Object],[object Object]
Oxidising and Reducing agent ,[object Object],[object Object]
Oxidising and Reducing Agents ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
List of common Oxidising and Reducing Agents ,[object Object],[object Object],[object Object]
Oxidation and Reduction in ‘A’ Level ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Common Oxidation States Chemical species Oxidation state and remarks  Any element eg Fe, O 2  , S 8 zero Oxygen in any compound  -2 except in peroxides example H 2 O 2  or Na 2 O 2   then oxygen atom has oxidation state of -1 or in F 2 O , then oxygen atom has oxidation state of +2 Fluorine in any compound -1  being most electronegative Hydrogen in any compound +1 except in metal hydrides example NaH then hydrogen atom has oxidation state of -1 as metals have a greater tendency to lose electrons Chlorine, bromine, iodine -ve oxidation state if bonded to less electronegative element eg  NaCl; then Cl = -1. +ve oxidation state if bonded to more electronegative element eg ClO -  , then Cl = +1; ClO 3 -  , then Cl = +5
Determine the oxidation state of… ,[object Object],[object Object],[object Object],[object Object]
Determine the oxidation state of… ,[object Object],[object Object],[object Object],[object Object],[object Object]
Determine the oxidation state of… ,[object Object],[object Object],[object Object],[object Object],[object Object]
Determine the oxidation state of… ,[object Object],[object Object],[object Object],[object Object],[object Object]
Determine the oxidation state of… ,[object Object],[object Object],[object Object],[object Object],[object Object]
Example 1 ,[object Object],[object Object],[object Object],[object Object],+7 +2 +2 +3
A Special Redox: Disproportionation ,[object Object],[object Object],0 +1 -1
Disproportionation Reaction ,[object Object],[object Object],[object Object],[object Object],-3 +5 +1
Non-redox reactions ,[object Object],[object Object]
Non-redox reactions ,[object Object],[object Object]
Non-redox reactions ,[object Object],[object Object],Tetraammine copper(II) complex (deep blue solution) ligand
Non-redox   reactions ,[object Object],[object Object]
Interlude: More real-life redox!
Balancing redox reactions ,[object Object]
Balancing redox reactions ,[object Object],[object Object]
Balancing redox reactions ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Oh yeah, the  blue  bottle… ,[object Object],[object Object],[object Object],[object Object],[object Object]
End of Lecture  1 of Redox “ I have never let my schooling interfere with my education.”  Mark Twain
The half-equation method ,[object Object]
The half-equation method ,[object Object]
The half-equation method ,[object Object],[object Object],[object Object],Reduced Oxidised
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object]
The half-equation method ,[object Object],[object Object],[object Object],x 2 x 5
The half-equation method ,[object Object],[object Object],[object Object],x 2 x 5
The half-equation method ,[object Object],[object Object],[object Object],x 2 x 5
The half-equation method ,[object Object],[object Object],[object Object],x 2 x 5
The half-equation method ,[object Object],+6H +
The half-equation method ,[object Object],[object Object],+6H +
The half-equation method ,[object Object],[object Object]

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Redox reactions

  • 1. REDOX REACTIONS A.k.a. A study on why things explode
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  • 7. Redox gain of electrons loss of electrons gain in hydrogen loss of hydrogen loss of oxygen gain in oxygen Reduction Oxidation
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  • 15. Common Oxidation States Chemical species Oxidation state and remarks Any element eg Fe, O 2 , S 8 zero Oxygen in any compound -2 except in peroxides example H 2 O 2 or Na 2 O 2 then oxygen atom has oxidation state of -1 or in F 2 O , then oxygen atom has oxidation state of +2 Fluorine in any compound -1 being most electronegative Hydrogen in any compound +1 except in metal hydrides example NaH then hydrogen atom has oxidation state of -1 as metals have a greater tendency to lose electrons Chlorine, bromine, iodine -ve oxidation state if bonded to less electronegative element eg NaCl; then Cl = -1. +ve oxidation state if bonded to more electronegative element eg ClO - , then Cl = +1; ClO 3 - , then Cl = +5
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  • 34. End of Lecture 1 of Redox “ I have never let my schooling interfere with my education.” Mark Twain
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