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Measure of a randomness or
disorderness
A perfect crystal has zero entropy at a
temperature of absolute zero.
System(DS) = 0 at 0 K
DSuniverse = DSsystem + DSsurroundings > 0
A change in order is a change in the number
of ways of arranging the particles, and it is a
key factor in determining the direction of a
spontaneous process.
Entropy of an ideal gas:
S = k ln W
 Intrinsic property
Entropy change
Entropy transfer + Entropy generation
 It can be created but cannot be destroyed
 Total entropy of a system + surroundings
cannot be reduced
 More disorganized a system the higher its entropy
 Defined using Clausius inequality
where Q =differential heat transfer
T =absolute temperature
 The Increase of Entropy Principle which states that
the entropy for an isolated system (or a system plus
its surroundings) is always increases or, at best,
remains the same
Entropy Balance is used to determine the Change in entropy
of a system as follows:
Entropy change = Entropy Transfer + Entropy
Generation
where,
Entropy change = DS = S2 - S1
Entropy Transfer = Transfer due to Heat (Q/T) + Entropy
flow due to mass flow (misi – mese)
Entropy Generation = Sgen 0
Entropy
Entropy
Entropy
Entropy

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Juaristi, Jon. - El canon espanol. El legado de la cultura española a la civi...
 

Entropy

  • 1.
  • 2. Measure of a randomness or disorderness
  • 3. A perfect crystal has zero entropy at a temperature of absolute zero. System(DS) = 0 at 0 K DSuniverse = DSsystem + DSsurroundings > 0
  • 4. A change in order is a change in the number of ways of arranging the particles, and it is a key factor in determining the direction of a spontaneous process. Entropy of an ideal gas: S = k ln W
  • 5.  Intrinsic property Entropy change Entropy transfer + Entropy generation  It can be created but cannot be destroyed  Total entropy of a system + surroundings cannot be reduced
  • 6.  More disorganized a system the higher its entropy  Defined using Clausius inequality where Q =differential heat transfer T =absolute temperature  The Increase of Entropy Principle which states that the entropy for an isolated system (or a system plus its surroundings) is always increases or, at best, remains the same
  • 7. Entropy Balance is used to determine the Change in entropy of a system as follows: Entropy change = Entropy Transfer + Entropy Generation where, Entropy change = DS = S2 - S1 Entropy Transfer = Transfer due to Heat (Q/T) + Entropy flow due to mass flow (misi – mese) Entropy Generation = Sgen 0