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Carbohydrates

   5/12/2010
What are carbohydrates food?
• Carbohydrates are the main source of energy for
  the body.
• Those carbohydrates come from the plant-
  based foods that we eat.
• We can either use carbohydrates right away for
  your energy needs or your body can convert
  them into fat to use later.
• There are three types of carbohydrates: - sugars,
  starches and fiber.
Chemistry of carbohydrate
• No matter how big they are, all carbohydrates are
  made of carbon, hydrogen and oxygen with the
  general formula of Cm(H2O)n.
• Or The empirical or simplest formula of any
  carbohydrate is (CH2O)n.
• This formula looks like carbon water just as
  carbohydrate suggests hydrated or watered carbon.
• The formula tells us that all carbohydrates are made
  of carbon, hydrogen, and oxygen atoms in a 1:2:1
  ratio.
For example, a simple little sugar
  molecule like glucose is made up
  of six carbon atoms, 12 hydrogen
  atoms and 6 oxygen atoms.
   It is shaped like a hexagon and has
  the formula C6(H2O)6.




D-glucose
• A      large     starch
  molecule can be made
  of many little sugar
  molecules     attached
  together, which forms
  a long chain.
• The little m and n in
  our general formula,
  Cm(H2O)n, can run into
  the hundreds.
Simple sugars
         • are little molecules made up of
           one or two sugar units.
         • In nutrition, the most basic
           simple sugar is glucose, C6(H2O)6,
           and it is the type of sugar our
           bodies and brains use for energy
           every day.
         • Glucose      is      called     a
           monosaccharide, which means
D-glucose "single sugar.“.
• Other monosaccharides include
             fructose, galactose, and ribose.
           • Fructose is found in fruits and
             in vegetables.
fructose   • Galactose is found in milk and
           • Ribose is best known as a
             component in ribonucleic acid,
             which is a part of genetic
             transcription and is found in the
             cells in our bodies.
• it is important to know that the single
  sugars glucose, fructose and galactose
  can form different combinations to
  become disaccharides, a term that
  means "two sugars." These sugars
  include:
• Lactose (milk sugar) .
• Sucrose (table sugar).
• Maltose (malt sugar).
• Lactose (milk sugar)
  is made up of
  glucose and
  galactose molecules.
  People who are
  "lactose intolerant"
  can't digest this
  sugar properly.
• sucrose:-
• is comprised of
glucose and fructose
molecules.
• This is the white
powdery or granular
substance we
typically refer to as
"sugar" when we are
cooking or baking.
• Maltose (malt sugar) is
  produced during the
  malting of cereals such
  as barley.
• An average healthy diet should have half of
  your     daily    calories    coming     from
  carbohydrates.
• One gram of carbohydrate, whether is it is
  sugar or starch, contains 4 calories. One slice
  of bread has about 12 -15 grams of
  carbohydrates.
• One typical chocolate bar may have about 50
  grams of carbohydrates.
• A medium potato has about 35 grams of
  carbohydrates.
• Simple sugars are water-soluble and
  sucrose, or table sugar, is easy to digest.
• The individual glucose and fructose
  molecules are quickly absorbed into the
  bloodstream via the small intestine.
• This can be a problem for people with
  diabetes or metabolic syndrome who
  have to watch their blood sugar, or
  blood glucose levels.
Chemistry of carbohydrate
• No matter how big they are, all carbohydrates are
  made of carbon, hydrogen and oxygen with the
  general formula of Cm(H2O)n.
• Or The empirical or simplest formula of any
  carbohydrate is (CH2O)n.
• This formula looks like carbon water just as
  carbohydrate suggests hydrated or watered carbon.
• The formula tells us that all carbohydrates are made
  of carbon, hydrogen, and oxygen atoms in a 1:2:1
  ratio.
Sumary
• Carbohydrates consist of the elements carbon (C),
  hydrogen (H) and oxygen (O) with a ratio of hydrogen twice
  that of carbon and oxygen.
• Carbohydrates include sugars, starches, cellulose and many
  other compounds found in living organisms.
• In their basic form, carbohydrates are simple sugars or
  monosaccharides.
• These simple sugars can combine with each other to form
  more complex carbohydrates.
• The combination of two simple sugars is a disaccharide.
• Carbohydrates consisting of two to ten simple sugars are
  called oligosaccharides,
• and those with a larger number are called polysaccharides.
• These simple sugars can combine with
  each other to form more complex
  carbohydrates.
• The combination of two simple sugars is
  a disaccharide.
• Carbohydrates consisting of two to ten
  simple sugars are called
  oligosaccharides,( Oligo = Few) (2- 10 C)
• and those with a larger number are
  called polysaccharides
Sugars
• Sugars are white crystalline
  carbohydrates that are soluble in water
  and generally have a sweet taste.
• Monosaccharides are simple sugars
• Many saccharide structures differ only
  in the orientation of the hydroxyl groups
  (-OH).
• This slight structural difference makes a
  big difference in the biochemical
  properties, organoleptic properties
  (e.g., taste), and in the physical
  properties such as melting point and
  Specific Rotation (how polarized light is
  distorted).
• A chain form
                                                 monosaccharides that
                                                 has a carbonyl group
                                                 (c=o) on an end carbon
                                                 forming an aldehyde
                                                 group (-CHO) is
                                                 classified as an aldos
                                               • When the Carbonyl
                An aldehyde.
R is the group attached to the blue aldehyde
                                                 group is on an inner
                    group                        atom forming a ketone
                                                 , is called as a ketenes




Formaldehyde, the simplest aldehyde
                                                       ketenes
• Physical Properties of sucrose (table sugar). It is
  a simple sugar (although not a monosaccharide).
  Monosaccharides and other smaller sugars have
  the following properties in common with
  sucrose:
1. They are colorless crystalline solids. They
   usually appear white.
2. They are soluble in water (why?), only slightly
   soluble in ethanol and insoluble in nonpolar
   compounds.
3. They taste sweet. However, each sugar has its
   own distinct flavor.
4. Most are optically active ‫نشطة ضوئيا‬
• Sugar contains 4carbons is called =tetroses
• Sugar contains 5 carbons is called =pentoses
• Sugar contains 6carbons is called =hexoses
• Sugar contains 7carbons is called =heptoses
Monosaccharide classifications based on the number of carbons
Tetroses




                         D-Threose
D-Erythrose
Pentose




  D-Ribose        D-Arabinose




D-Xylose           D-Lyxose
• The ring form of ribose is a
                component of
                ribonucleic acid (RNA).
              • Deoxyribose, which is
                missing an oxygen at
  Ribose        position 2, is a component
                of deoxyribonucleic acid (DNA)
              • In nucleic acids, the
                hydroxyl group attached to
                carbon number 1 is replaced
                with nucleotide bases.
Deoxyribose
Hexoses
• Hexoses, such as the ones illustrated
  here, have the molecular formula
  C6H12O6.
D-Allose     D-Altrose        D-Glucose    D-Mannose




   D-Idose                                D-Talose
                     D-Galactose
• Structures that have
                                      opposite configurations of
                                      a hydroxyl group at only
D-Tagatose(a ketose)   D-Fructose
                                      one position, such as
                                      glucose and mannose, are
                                      called epimers.
                                    • Glucose, also called
Fructose
                                      dextrose, is the most
                       Galactose
                                      widely distributed sugar
                                      in the plant and animal
                                      kingdoms and it is the
                                      sugar present in blood as
Mannose
                                      "blood sugar".
• The chain form of
                glucose is a polyhydric
                aldehyde, meaning
                that it has multiple
                hydroxyl groups and an
                aldehyde group.
              • Fructose, also called
                levulose or "fruit
 D-Fructose     sugar", is shown here
                in the chain and ring
                forms.
              • Fructose and glucose
                are the main
                carbohydrate
                constituents of honey.
Fructose
Heptoses

                • Sedoheptulose has
                  the same structure
                  as fructose, but it
                  has one extra
                  carbon.

Sedoheptulose
Chain and Ring forms
             • Many simple
               sugars can exist in
               a chain form or a
               ring form, as
               illustrated by the
               hexoses above.
             • The ring form is
               favored in
               aqueous
               solutions, and the
               mechanism of ring
               formation is
               similar for most
               sugars.
• The glucose ring form is
  created when the
  oxygen on carbon
  number 5 links with the
  carbon comprising the
  carbonyl group (carbon
  number 1) and transfers
  its hydrogen to the
  carbonyl oxygen to
  create a hydroxyl group.
• The rearrangement
  produces alpha glucose
  when the hydroxyl
  group is on the opposite
  side of the -CH2OH
  group
• or beta glucose when the hydroxyl group is
  on the same side as the -CH2OH group.
  Isomers, such as these, which differ only in
  their configuration about their carbonyl
  carbon atom are called anomers.
• The little D in the name derives from the fact
  that natural glucose is dextrorotary, i.e., it
  rotates polarized light to the right
• Those forming six-sided rings, like glucose,
  are called pyranoses.
Stereochemistry
• Saccharides with identical functional groups but
  with different spatial configurations have different
  chemical and biological properties.
• Stereochemistry is the study of the arrangement of
  atoms in three-dimensional space.
• Stereoisomers are compounds in which the atoms
  are linked in the same order but differ in their
  spatial arrangement.
• Compounds that are mirror images of each other
  but are not identical, comparable to left and right
  shoes, are called enantiomers.
Sugar Alcohols, Amino Sugars, and
            Uronic Acids
• Sugars may be modified by natural or
  laboratory processes into compounds that
  retain the basic configuration of
  saccharides, but have different functional
  groups.
• Sugar alcohols, also known as polyols,
  polyhydric alcohols, or polyalcohols, are the
  hydrogenated forms of the aldoses or
  ketoses.
• For example, glucitol, also known as sorbitol,
  has the same linear structure as the chain
  form of glucose, but the aldehyde (-CHO)
  group is replaced with a -CH2OH group.
• Other common sugar alcohols include the
  monosaccharides erythritol and xylitol and
  the disaccharides lactitol and maltitol.
• Sugar alcohols have about half the calories of
  sugars and are frequently used in low-calorie
  or "sugar-free" products.
• Xylitol, which has the hydroxyl groups
  oriented like xylose, is a very common
  ingredient in "sugar-free" candies and
  gums because it is approximately as
  sweet as sucrose, but contains 40% less
  food energy.
• Although this sugar alcohol appears to
  be safe for humans, xylitol in relatively
  small doses can cause seizures, liver
  failure, and death in dogs.
Amino sugars
     • or aminosaccharides
       replace a hydroxyl
       group with an amino
       (-NH2) group.
       Glucosamine is an
       amino sugar used to
       treat cartilage damage
       and reduce the pain
       and progression of
       arthritis.
Uronic acids
     • have a carboxyl group (-
       COOH) on the carbon that
       is not part of the ring. Their
       names retain the root of
       the monosaccharides, but
       the -ose sugar suffix is
       changed to -uronic acid. For
       example, galacturonic acid
       has the same configuration
       as galactose, and the
       structure of glucuronic acid
       corresponds to glucose
•
    Sugar and Cotton
    are Carbohydrates
‫‪Obesity and metabolic syndrome‬‬
   ‫• ترتبط كل من زيادة الوزن والسمنة بظاهرة مقاومة‬
       ‫الجسم لألنسولين التي سوف تسبب في عوامل‬
‫المخاطر العنقودية لمرض القلب ‪Cluster risk factors‬‬
                ‫‪ of cardio- vascular‬المعروفة باسم‬
   ‫‪ syndrome metabolic‬أو ( ‪(syndrome X‬والتي‬
                               ‫تسبب األمراض التالية:‬
                       ‫1. النوبة القلبية ‪.Heart attack‬‬
                          ‫2. السكتة الدماغية ‪. Stroke‬‬
‫كمية عالية من الدهون حول البطن‬     ‫•‬
         ‫تركيز سكر الدم أعلى من 011 ملجم / 001 مل.‬      ‫•‬
       ‫جليسيرات الثالثية أعلى من 051 ملجم / 001 مل.‬     ‫•‬
‫البروتين الدهني عالي الكثافة في الدم أقل من 04 ملجم /‬   ‫•‬
                                            ‫001 مل.‬
                       ‫ضغط الدم 031 / 58 أو أعلى.‬       ‫•‬
                  ‫تسبب هذه المتالزمة متالزمة المبيض‬     ‫•‬
‫‪Polycystic Ovarian Syndrome‬‬
‫• وتسبب متالزمة المبيض للمرأة المشاكل التالية:-‬
                                 ‫1. إختفاء العادة الشهرية.‬
                                                 ‫2. العفم.‬
                                      ‫3. أمراض الجلدية.‬
                    ‫4. نمو غزير للشعر في الوجه والجسم.‬
                                      ‫5. فقد شعر الرأس.‬
‫6. حالة ما قبل األصابة بداء السكري(2) وداء السكري (2).‬
Complex Carbohydrates
• Complex carbohydrates are long chains of the
  single sugar units.
• For example, the complex carbohydrate we
  know as starch is made up of many glucose
  units.
• These complex carbohydrates can be in the
  shape of long chains, or the chains can form
  branches.
• The complex carbohydrates include:
The basic chemical formula of     • Starch, the energy storage
the starch molecule is              form of carbohydrates
(C6H10O5)n. Starch is a             found in plants, especially
polysaccharide comprising           in the seeds and roots.
glucose monomers joined in a
1,4 linkages. The simplest form   • Starch is made up of many
of starch is the linear polymer     glucose units linked
amylose.                            together.
                                  • Starchy food examples
                                    include rice, wheat, corn,
                                    carrots and potatoes.
                                  • Starches are not water-
                                    soluble and require
                                    digestive enzymes called
                                    amylases to break them
                                    apart.
• Glycogen, the energy
  storage form of
  glucose found in the
  muscles and livers of
  animals.
• We don't consume
  any carbohydrates
  when you eat meats;
  however, the amount
  of glycogen in animal
  tissue at the time of
  slaughter does affect
  the pH of meat.
• Cellulose, the structural component of
  plants.
• Cellulose helps plants keep their shape; so,
  cellulose acts like a plant skeleton.
• We are unable to digest cellulose; however
  cellulose is one of the important
  components of fiber, along with lignin,
  chitin, pectin, beta- glucan , inulin and
  oligosaccharides.
• Dietary starch and cellulose are the
  complex carbohydrates that are important
  in nutrition.
• Potatoes, dry beans, grains, rice, corn,
  squash and peas contain a large amounts
  of starch.
• Vegetables like broccoli, cauliflower,
  asparagus, lettuces and other greens are
  not starchy.
• Carbohydrates and Metabolism
• The body begins the process of breaking
  carbohydrates down into their individual
  monosaccharides almost before we start to eat them.
• When you smell the delicious aroma of fresh-baked
  bread or think about that tasty chocolate that you're
  about to consume, your mouth begins to water.
• Since table sugar is water-soluble, it begins to
  dissolve in the saliva in mouth.
• Saliva also contains a small amount of amylase, which
  is an enzyme that starts to break starch down into
  glucose while you are chewing.
• Carbohydrate digestion is continued in the small
  intestine where pancreatic amylase is secreted,
  which breaks down the rest of the
  carbohydrates.
• The individual monosaccharides are then
  absorbed into the blood stream.
• Once in the blood, the monosaccharides are
  either used for energy, stored in the liver and
  muscles as glycogen, or if there is more energy
  available than you can use, they are converted
  and stored as fat.
• The storage of glucose is triggered by
  insulin, which forces the body to store
  any extra blood sugar as glycogen.
• People with diabetes or metabolic
  syndrome either can't produce enough
  insulin or they are not sensitive enough
  to the insulin they produce and need to
  regulate their blood sugar with
  medications, insulin or dietary
  changes.
• Body prefers to use glucose as the
  main source of fuel for daily activity.
• Muscles need glucose to move and
  organs need glucose to function,
  including your brain.
• While the body can make glucose
  from extra dietary protein and fats
  you may eat, it is suggested that half
  of your daily calories come from
  carbohydrates.
• Try to get carbohydrates from
  healthy sources such as whole
  grains, fruits and vegetables.
• Cookies, sodas, candy and other
  sweets are not so healthy
• An average healthy diet should
  have half of your daily calories
  coming from carbohydrates.
• One gram of carbohydrate, whether
  is it is sugar or starch, contains four
  calories.
• One slice of bread has about 1215-
  grams of carbohydrates.
• One typical chocolate bar may have
  about 50 grams of carbohydrates.
• A medium potato has about 35
  grams of carbohydrates.
• Although all carbohydrates have 4 calories
  per gram, some sources of carbohydrates
  are better for your diet than others.
• Fruits, vegetables, legumes, nuts, seeds
  and grains are healthier than candy, sodas
  and pastries.
• Why? The healthy carbohydrate sources
  have great amounts of vitamins, minerals,
  Phytochemicals and fiber, all of which are
  vital to good health.
• Candy, sodas, pastries and other
  junk foods usually are poor sources
  of nutrients and sometimes we refer
  to these foods as having "empty
  calories.“
• This means the foods have lots of
  calories with little or no nutrition.
• Since you need half of your calories from
  carbohydrates, you can calculate how many you
  need per day.
• For example, let's say a person needs 2,000
  calories per day. That means that 1,000 calories
  should come from carbohydrates (2,000 X 0.5).
• Since each gram of carbohydrate has 4 calories,
  then you divide 1,000 by four (1,000/4) to get
  250.
• A person who needs 2,000 calories each day
  needs about 250 grams of carbohydrates per
  day.
• Of those 250 grams, about 10 percent
  can come from added table sugar and
  sweeteners.
• That would be about 25 grams for a
  2,000 calorie per day diet.
• That would equal about half of a candy
  bar, or less than one can of sugary soda.
• Unfortunately many people exceed that
  amount every day.
• In order to meet your carbohydrate
  requirement each day, you need to
  know how many carbohydrates are in all
  of the foods you eat.
• It really is impossible to list every
  carbohydrate containing food here,
  however, here are some approximate
  amounts from common examples:
• One slice of bread - 12.5 grams total, of
  which 10 grams are starch and less than one
  gram is fiber.
• One cup of pasta - 43 grams total, of which
  36 grams are starch and 2.5 grams are fiber.
• One medium apple - 19 grams total, of which
  eight grams are starch and three grams are
  fiber
• One Snickers candy bar - 63.5 total grams, of
  which 53 grams are sugar, two grams are
  fiber.
• One cup of raisin bran cereal - 43 grams
  total, of which seven grams are fiber, 17
  grams are starch and 16 grams are sugar
  .
• One cup of sugar frosted corn flake
  cereal - 28 grams total, of which 15
  grams are starch, one gram is fiber, 12
  grams are sugar.
• 240 ml serving of low fat milk - 12 grams
  total, of which 12 grams are lactose .
• One cup broccoli - six grams total, of
  which 2.5 grams are fiber and 1.5
  grams are sugar.
• One cup green beans - eight grams
  total, of which four grams are fiber
• One cup sweet corn - 31 grams total,
  of which 21 grams are starch, three
  grams are fiber
• Two cups lettuce - two grams total, of which
  one gram is fiber
• One cup asparagus - four grams total, of
  which two grams are fiber
• One medium orange - 15 grams total, of
  which three grams are fiber
• One half medium grapefruit - nine grams
  total, of which 1.5 grams are fiber
• One medium chocolate chip cookie - 16
  grams total, of which seven grams are sugar
• One cup strawberries - 12 grams total, of
  which three grams are fiber
• One cup blueberries - 21 grams total, of
  which four grams are fiber and 15 grams
  are sugar
• One medium tomato - five grams total, of
  which 1.5 grams are fiber
• One medium potato with skin - 29 grams
  total, of which three grams are fiber, 25
  grams are starch
• One cup carrots - 12 grams total, of which
  3.5 grams are fiber and two grams are
  starch
• One slice of an apple pie - 40 grams total,
  of which 18 grams are sugar
• One cup of orange juice - 26 grams total,
  of which 21 grams are from fruit sugars
• One cup of dry beans like pinto beans or
  navy beans - 47 grams total, of which 19
  grams are fiber, 28 grams are starch
The Importance Of Carbohydrates
Carbohydrates take the form of sugars,
 oligosaccharides, starches and fibres
 and are one of the three major macro-
 nutrients which supply the body with
 energy (fat and protein being the
 others). There is now good evidence
 that at least 55% of our daily calories
 should come from carbohydrates(1).
Whereas it is important to maintain an
  appropriate balance between calorie intake
  and expenditure, scientific studies suggest
  that:
• A diet containing an optimum level of
  carbohydrates may help prevent body fat
  accumulation
• Starch and sugars provide readily accessible
  fuel for physical performance
• Dietary fiber, which is a carbohydrate, helps
  keep the bowel functioning correctly
• Apart from the direct benefits of
  carbohydrates for the body, they are found in a
  wide range of foods which themselves bring a
  variety of other important nutrients to the
  diet. For this reason it is recommended that
  carbohydrates be supplied from diverse food
  sources to ensure that the overall diet contains
  adequate nutrients
• It is also important to remember that
  carbohydrates contribute to the taste, texture
  and appearance of foods and help to make the
  diet more varied and enjoyable.
Sugars
•
  Glucose and fructose are simple sugars or
  monosaccharides and can be found in fruits, berries,
  vegetables and honey.
• When two simple sugars combine, they form
  disaccharides.
• Table sugar or sucrose is a combination of glucose and
  fructose and occurs naturally both in sugar beet,
  sugar cane and fruits.
• Lactose is the main sugar in milk and dairy products
  and maltose is a disaccharide occurring in malt
• Polyols are so-called sugar alcohols.
  They do occur naturally but most are
  made commercially by the
  transformation of sugars.
• Isomalt is the most commonly used
  polyol and is derived from sucrose.
  Polyols are sweet and can be used in
  foods in a similar way to sugars
  although they can have a laxative effect
  when eaten in large quantities
Oligosaccharides
• When 3 to 9 sugar units combine they form
  oligosaccharides.
• Maltodextrins contain up to 9 glucose units and
  are produced commercially by the partial
  hydrolysis (or breakdown) of starch.
• They are less sweet than mono- or
  disaccharides.
• Raffinose, stachyose and fructo-
  oligosaccharides are found only in small
  amounts in certain pulses, grains and
  vegetables.
Polysaccharides
More than 10 and sometimes even up to
   several thousand sugar units are needed to
   form polysaccharides.
Starch is the main energy reserve in root
   vegetables and cereals.
It comprises long chains of glucose and occurs
   as granules whose size and shape vary
   according to the plant in which it is
   contained.
• Non-starch polysaccharides are the
  main components of dietary fiber.
• They include; cellulose, hemicelluloses,
  pectins and gums.
• Cellulose is the major component of
  plant cell walls and consists of several
  thousand glucose units.
• The separate components of dietary
  fibber have different physical structures
  and properties.
Carbohydrates In The Body
The main function of carbohydrates is to
 provide energy, but they also play an
 important role in the structure and
 function of the body organs and nerve
 cells
• Energy source and storage
• Starches and sugars are the main energy-
  providing carbohydrate sources and supply 4
  kilocalories (17 kilojoules) per gram.
• To utilize this energy all carbohydrates need to
  be broken down to glucose after which they are
  transported to their place of use.
• Disaccharides are broken down by digestive
  enzymes into simple sugars.
• The body also needs the help of digestive
  enzymes to break down the long chains of
  starches into their constituent sugars, which are
  then absorbed into the bloodstream.
• Glucose can also be converted to glycogen, a
  polysaccharide similar to starch, which is stored in
  the liver and the muscles and is a readily available
  source of energy for the body.
• The brain needs to use glucose as an energy source,
  since it cannot use fat for this purpose.
• It is for this reason that the level of glucose in the
  blood must be constantly maintained above the
  minimum level.
• Glucose may come directly from dietary
  carbohydrates or from glycogen stores.
• Several hormones, including insulin, work rapidly to
  regulate the flow of glucose to and from the blood
  to keep it at a steady level.
The glycaemic index (GI)
• When a carbohydrate food is eaten there is a
  corresponding rise and subsequent decrease in
  blood glucose level known as the glycaemic
  response.
• This response is relevant, for example, to
  appetite control, sports nutrition and those with
  diabetes.
• A number of factors influence the rate and
  duration of the glycaemic response. It depends
  on:
1. The specific food:
• The nature and the form of the carbohydrate
  as some are more digestible than others The
  cooking and processing methods used which
  can change the digestibility. Other nutrients
  in the food such as fat or protein that can
  slow the digestion rate.
2. The individual person:
• their metabolism
• the time of day the carbohydrate is ingested
• The impact of different carbohydrate-
  containing foods on the glycaemic
  response of the body is classified
  according to a standardized amount of
  glucose.
• This measurement is called the
  glycaemic index, (GI).
Gut function and dietary fiber
• The body is unable to digest dietary fibre and
  some oligosaccharides in the small intestine.
• Fibre helps to ensure good gut function by
  increasing the physical bulk in the bowel and
  stimulating the intestinal transit.
• Once the indigestible carbohydrate passes into
  the large intestine, some types of fiber such as
  gums and pectins and the oligosaccharides are
  fermented (broken down) by the gut microflora.
• This also increases the overall mass in the bowel
  and has a beneficial effect on the make up of this
  microflora.
Body Weight Regulation
• People eating a diet high in carbohydrates are
  less likely to accumulate body fat compared with
  those who follow a low carbohydrate/high-fat
  diet.
• The reasons for this observation are threefold: It
  could be due to the lower energy density of high
  carbohydrate diets, as carbohydrates have less
  calories weight for weight than fats. Fiber-rich
  foods also tend to be bulky and physically filling
  therefore less calories may be consumed.
• Studies have found that carbohydrates, both in
  the form of starch and sugars, work quickly to
  aid satiety and that those consuming high
  carbohydrate diets are therefore less likely to
  overeat.
• The inclusion of plenty of carbohydrate rich
  foods appears to help regulate the appetite.
• Many foods with a lower glycaemic index may
  be particularly satisfying as they are slowly.
• It has also been confirmed that very little
  dietary carbohydrate is converted to body fat
  mainly because it is a very inefficient process for
  the body.
• Instead carbohydrate tends to be preferentially
  used an energy by the body
• It is increasingly evident that diets high
  in carbohydrate, as compared with
  those high in fat, reduce the likelihood
  of developing obesity.
• Starch and sugars have not been found
  to have different effects on weight
  control.
• In fact, in several studies, high sugar
  consumers have been found to be
  slimmer than low sugar consumers.
Diabetes
•
  Diabetes is a metabolic disorder whereby the
  body cannot regulate blood glucose levels
  properly.
• There is no evidence that sugar consumption is
  linked to the development of any type of
  diabetes.
• However there is now good evidence that
  obesity and physical inactivity increase the
  likelihood of developing non-insulin dependent
  diabetes, which usually occurs in middle age
• Weight reduction is usually necessary and is the
  primary dietary aim for people with non-insulin
  dependent (Type II) diabetes.
• Consuming a wide range of carbohydrate foods is
  an acceptable part of the diet of all diabetics, and
  the inclusion of low glycaemic index foods is
  beneficial as they help regulate blood glucose
  control.
• Most recommendations for the dietary
  management of diabetes allow a modest amount
  of ordinary sugar as the inclusion of sugar with a
  meal has little impact on either blood glucose or
  insulin concentrations in people with diabetes.
Dental Health
• The incidence of tooth decay is influenced by
  a number of factors.
• These include: degree of oral hygiene and
  plaque removal carried out,
• availability of fluoride,
• type of food eaten,
• frequency of consumption of any
  fermentable carbohydrate
• genetic factors
• Foods containing sugars or starch can be broken
  down by the enzymes and bacteria in the mouth
  to produce acid which attacks the enamel of the
  teeth.
• However it is not the amount of sugar or other
  carbohydrate that is important but how often
  they are consumed.
• After an acid challenge, saliva provides a natural
  repair process which rebuilds the enamel.
• When carbohydrate-containing foods are
  consumed too frequently, or nibbled over time,
  this natural repair process is overwhelmed and
  the risk of tooth decay is increased
• However in recent years the availability
  of fluoride and the widespread use of
  good oral hygiene practices have been
  widely heralded as responsible for the
  low rate of tooth decay in today's
  children and adolescents.
• This improvement has happened
  independent of any change in sugar or
  fermentable carbohydrate intake.
• Keeping plaque bacteria at bay and
  strengthening the teeth with fluoride
  reduces the risk of decay.
• The research now available in the 1990's
  allows a more rational approach to the
  role of sugar and other carbohydrates in
  dental caries.
• It is now recommended that
  programmes to prevent dental caries
  focus on fluoridation, adequate oral
  hygiene and a varied diet, and not on
  sugar intake alone.
Getting Active
• There is now substantial evidence that
  carbohydrates can improve the performance
  of athletes.
• During high intensity exercise, carbohydrates
  are the main fuel for the muscles.
• By consuming high levels of carbohydrate
  before, during and after training or an event,
  glycogen stores are kept well stocked.
• These stocks help the athlete to perform for
  longer and help their bodies sustain the
  effort.
• The vital role of physical activity in
  maintaining health and fitness in the general
  population is now recognized.
• There is no doubt that many people would
  benefit from increasing their activity level as
  it helps in the regulation of body weight.
• It also reduces the risk of developing
  diseases such as heart disease and diabetes.
• For those who want to keep fit and active, a
  well-balanced high-carbohydrate diet is
  recommended.
Carbohydrate Recommendation
• Carbohydrates in all shapes and forms are good for
  your health.
• They can help to control body weight, especially
  when combined with exercise, are vital for proper
  gut function and are an important fuel for the brain
  and active muscles.
• Neither starch nor sugar have been found to have
  any special role in the development of serious
  diseases such as diabetes, and the role of sugar in
  the development of tooth decay is less important
  in today's fluoride and oral hygiene aware
  populations.
• The recent report from the World
  Health Organization and the Food and
  Agriculture Organization of the United
  Nations on Carbohydrates in Human
  Nutrition makes many
  recommendations for health
  professionals and research scientists,
  but the most important messages for
  the public are:
• the most important messages for the public are:
1. That the many health benefits of dietary
   carbohydrates should be recognized and
   promoted. Carbohydrates provide more than
   energy alone.
2. An optimum diet contains at least 55% of
   energy from carbohydrates for all those over
   two years of age.
3. A wide range of carbohydrate-containing foods
   should be consumed so that the diet is
   sufficient in essential nutrients and dietary
   fiber.
References

• WHO/FAO (1998) Carbohydrates in human nutrition. FAO food and
  nutrition paper no. 66. FAO, Rome. Foster-Powell, K., Brand
• Miller, J. (1995), International tables of glycaemic index. American
  Journal of Clinical Nutrition. 62: 871S-93S. Hellerstein, M.K.,
• Christiansen, M., Kaempfer, S. et al (1991). Measurement of de novo
  hepatic lipogenesis in humans using stable isotopes. J. Clin.
• Invest. 87: 1841-1852. World Health Organisation (1998) Obesity -
  preventing and managing the global epidemic. Report of the WHO
  consultation on obesity. Geneva, June 97. Bolton-Smith C & Woodward
• M (1994). Dietary composition and fat to sugar ratios in relation to
  obesity. Int J Obesity 18;820-828. US Department of Health and Human
• Services (1996). Physical activity and health: a report of the Surgeon
  General, Atlanta, Georgia, USA. 7. Fejershov O. Concepts of dental caries
  and their consequences for understanding the disease. Community Dent.
  Oral Epidemiol. 1997; 25: 5-12.
Further Reading
• Dietary Starches and Sugars in Man: A
  comparison (1989). Edited by J. Dobbing, ILSI
  Human Nutrition Review series.
• ILSI Europe Concise Monographs Series:
  Nutritional and Health Aspects of Sugars:
  Evaluation of New Findings (1995).
• ILSI Europe Concise Monographs Series:
  Caries Preventative Strategies (1995).

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Carbohydrate

  • 1. Carbohydrates 5/12/2010
  • 2. What are carbohydrates food? • Carbohydrates are the main source of energy for the body. • Those carbohydrates come from the plant- based foods that we eat. • We can either use carbohydrates right away for your energy needs or your body can convert them into fat to use later. • There are three types of carbohydrates: - sugars, starches and fiber.
  • 3. Chemistry of carbohydrate • No matter how big they are, all carbohydrates are made of carbon, hydrogen and oxygen with the general formula of Cm(H2O)n. • Or The empirical or simplest formula of any carbohydrate is (CH2O)n. • This formula looks like carbon water just as carbohydrate suggests hydrated or watered carbon. • The formula tells us that all carbohydrates are made of carbon, hydrogen, and oxygen atoms in a 1:2:1 ratio.
  • 4. For example, a simple little sugar molecule like glucose is made up of six carbon atoms, 12 hydrogen atoms and 6 oxygen atoms. It is shaped like a hexagon and has the formula C6(H2O)6. D-glucose
  • 5. • A large starch molecule can be made of many little sugar molecules attached together, which forms a long chain. • The little m and n in our general formula, Cm(H2O)n, can run into the hundreds.
  • 6. Simple sugars • are little molecules made up of one or two sugar units. • In nutrition, the most basic simple sugar is glucose, C6(H2O)6, and it is the type of sugar our bodies and brains use for energy every day. • Glucose is called a monosaccharide, which means D-glucose "single sugar.“.
  • 7. • Other monosaccharides include fructose, galactose, and ribose. • Fructose is found in fruits and in vegetables. fructose • Galactose is found in milk and • Ribose is best known as a component in ribonucleic acid, which is a part of genetic transcription and is found in the cells in our bodies.
  • 8. • it is important to know that the single sugars glucose, fructose and galactose can form different combinations to become disaccharides, a term that means "two sugars." These sugars include: • Lactose (milk sugar) . • Sucrose (table sugar). • Maltose (malt sugar).
  • 9. • Lactose (milk sugar) is made up of glucose and galactose molecules. People who are "lactose intolerant" can't digest this sugar properly.
  • 10. • sucrose:- • is comprised of glucose and fructose molecules. • This is the white powdery or granular substance we typically refer to as "sugar" when we are cooking or baking.
  • 11. • Maltose (malt sugar) is produced during the malting of cereals such as barley.
  • 12. • An average healthy diet should have half of your daily calories coming from carbohydrates. • One gram of carbohydrate, whether is it is sugar or starch, contains 4 calories. One slice of bread has about 12 -15 grams of carbohydrates. • One typical chocolate bar may have about 50 grams of carbohydrates. • A medium potato has about 35 grams of carbohydrates.
  • 13. • Simple sugars are water-soluble and sucrose, or table sugar, is easy to digest. • The individual glucose and fructose molecules are quickly absorbed into the bloodstream via the small intestine. • This can be a problem for people with diabetes or metabolic syndrome who have to watch their blood sugar, or blood glucose levels.
  • 14. Chemistry of carbohydrate • No matter how big they are, all carbohydrates are made of carbon, hydrogen and oxygen with the general formula of Cm(H2O)n. • Or The empirical or simplest formula of any carbohydrate is (CH2O)n. • This formula looks like carbon water just as carbohydrate suggests hydrated or watered carbon. • The formula tells us that all carbohydrates are made of carbon, hydrogen, and oxygen atoms in a 1:2:1 ratio.
  • 15. Sumary • Carbohydrates consist of the elements carbon (C), hydrogen (H) and oxygen (O) with a ratio of hydrogen twice that of carbon and oxygen. • Carbohydrates include sugars, starches, cellulose and many other compounds found in living organisms. • In their basic form, carbohydrates are simple sugars or monosaccharides. • These simple sugars can combine with each other to form more complex carbohydrates. • The combination of two simple sugars is a disaccharide. • Carbohydrates consisting of two to ten simple sugars are called oligosaccharides, • and those with a larger number are called polysaccharides.
  • 16. • These simple sugars can combine with each other to form more complex carbohydrates. • The combination of two simple sugars is a disaccharide. • Carbohydrates consisting of two to ten simple sugars are called oligosaccharides,( Oligo = Few) (2- 10 C) • and those with a larger number are called polysaccharides
  • 17. Sugars • Sugars are white crystalline carbohydrates that are soluble in water and generally have a sweet taste. • Monosaccharides are simple sugars
  • 18. • Many saccharide structures differ only in the orientation of the hydroxyl groups (-OH). • This slight structural difference makes a big difference in the biochemical properties, organoleptic properties (e.g., taste), and in the physical properties such as melting point and Specific Rotation (how polarized light is distorted).
  • 19. • A chain form monosaccharides that has a carbonyl group (c=o) on an end carbon forming an aldehyde group (-CHO) is classified as an aldos • When the Carbonyl An aldehyde. R is the group attached to the blue aldehyde group is on an inner group atom forming a ketone , is called as a ketenes Formaldehyde, the simplest aldehyde ketenes
  • 20. • Physical Properties of sucrose (table sugar). It is a simple sugar (although not a monosaccharide). Monosaccharides and other smaller sugars have the following properties in common with sucrose: 1. They are colorless crystalline solids. They usually appear white. 2. They are soluble in water (why?), only slightly soluble in ethanol and insoluble in nonpolar compounds. 3. They taste sweet. However, each sugar has its own distinct flavor. 4. Most are optically active ‫نشطة ضوئيا‬
  • 21. • Sugar contains 4carbons is called =tetroses • Sugar contains 5 carbons is called =pentoses • Sugar contains 6carbons is called =hexoses • Sugar contains 7carbons is called =heptoses
  • 22. Monosaccharide classifications based on the number of carbons
  • 23. Tetroses D-Threose D-Erythrose
  • 24. Pentose D-Ribose D-Arabinose D-Xylose D-Lyxose
  • 25. • The ring form of ribose is a component of ribonucleic acid (RNA). • Deoxyribose, which is missing an oxygen at Ribose position 2, is a component of deoxyribonucleic acid (DNA) • In nucleic acids, the hydroxyl group attached to carbon number 1 is replaced with nucleotide bases. Deoxyribose
  • 26. Hexoses • Hexoses, such as the ones illustrated here, have the molecular formula C6H12O6.
  • 27. D-Allose D-Altrose D-Glucose D-Mannose D-Idose D-Talose D-Galactose
  • 28. • Structures that have opposite configurations of a hydroxyl group at only D-Tagatose(a ketose) D-Fructose one position, such as glucose and mannose, are called epimers. • Glucose, also called Fructose dextrose, is the most Galactose widely distributed sugar in the plant and animal kingdoms and it is the sugar present in blood as Mannose "blood sugar".
  • 29. • The chain form of glucose is a polyhydric aldehyde, meaning that it has multiple hydroxyl groups and an aldehyde group. • Fructose, also called levulose or "fruit D-Fructose sugar", is shown here in the chain and ring forms. • Fructose and glucose are the main carbohydrate constituents of honey. Fructose
  • 30. Heptoses • Sedoheptulose has the same structure as fructose, but it has one extra carbon. Sedoheptulose
  • 31. Chain and Ring forms • Many simple sugars can exist in a chain form or a ring form, as illustrated by the hexoses above. • The ring form is favored in aqueous solutions, and the mechanism of ring formation is similar for most sugars.
  • 32. • The glucose ring form is created when the oxygen on carbon number 5 links with the carbon comprising the carbonyl group (carbon number 1) and transfers its hydrogen to the carbonyl oxygen to create a hydroxyl group. • The rearrangement produces alpha glucose when the hydroxyl group is on the opposite side of the -CH2OH group
  • 33. • or beta glucose when the hydroxyl group is on the same side as the -CH2OH group. Isomers, such as these, which differ only in their configuration about their carbonyl carbon atom are called anomers. • The little D in the name derives from the fact that natural glucose is dextrorotary, i.e., it rotates polarized light to the right • Those forming six-sided rings, like glucose, are called pyranoses.
  • 34.
  • 35. Stereochemistry • Saccharides with identical functional groups but with different spatial configurations have different chemical and biological properties. • Stereochemistry is the study of the arrangement of atoms in three-dimensional space. • Stereoisomers are compounds in which the atoms are linked in the same order but differ in their spatial arrangement. • Compounds that are mirror images of each other but are not identical, comparable to left and right shoes, are called enantiomers.
  • 36.
  • 37. Sugar Alcohols, Amino Sugars, and Uronic Acids • Sugars may be modified by natural or laboratory processes into compounds that retain the basic configuration of saccharides, but have different functional groups. • Sugar alcohols, also known as polyols, polyhydric alcohols, or polyalcohols, are the hydrogenated forms of the aldoses or ketoses.
  • 38. • For example, glucitol, also known as sorbitol, has the same linear structure as the chain form of glucose, but the aldehyde (-CHO) group is replaced with a -CH2OH group. • Other common sugar alcohols include the monosaccharides erythritol and xylitol and the disaccharides lactitol and maltitol. • Sugar alcohols have about half the calories of sugars and are frequently used in low-calorie or "sugar-free" products.
  • 39. • Xylitol, which has the hydroxyl groups oriented like xylose, is a very common ingredient in "sugar-free" candies and gums because it is approximately as sweet as sucrose, but contains 40% less food energy. • Although this sugar alcohol appears to be safe for humans, xylitol in relatively small doses can cause seizures, liver failure, and death in dogs.
  • 40. Amino sugars • or aminosaccharides replace a hydroxyl group with an amino (-NH2) group. Glucosamine is an amino sugar used to treat cartilage damage and reduce the pain and progression of arthritis.
  • 41. Uronic acids • have a carboxyl group (- COOH) on the carbon that is not part of the ring. Their names retain the root of the monosaccharides, but the -ose sugar suffix is changed to -uronic acid. For example, galacturonic acid has the same configuration as galactose, and the structure of glucuronic acid corresponds to glucose
  • 42. Sugar and Cotton are Carbohydrates
  • 43. ‫‪Obesity and metabolic syndrome‬‬ ‫• ترتبط كل من زيادة الوزن والسمنة بظاهرة مقاومة‬ ‫الجسم لألنسولين التي سوف تسبب في عوامل‬ ‫المخاطر العنقودية لمرض القلب ‪Cluster risk factors‬‬ ‫‪ of cardio- vascular‬المعروفة باسم‬ ‫‪ syndrome metabolic‬أو ( ‪(syndrome X‬والتي‬ ‫تسبب األمراض التالية:‬ ‫1. النوبة القلبية ‪.Heart attack‬‬ ‫2. السكتة الدماغية ‪. Stroke‬‬
  • 44. ‫كمية عالية من الدهون حول البطن‬ ‫•‬ ‫تركيز سكر الدم أعلى من 011 ملجم / 001 مل.‬ ‫•‬ ‫جليسيرات الثالثية أعلى من 051 ملجم / 001 مل.‬ ‫•‬ ‫البروتين الدهني عالي الكثافة في الدم أقل من 04 ملجم /‬ ‫•‬ ‫001 مل.‬ ‫ضغط الدم 031 / 58 أو أعلى.‬ ‫•‬ ‫تسبب هذه المتالزمة متالزمة المبيض‬ ‫•‬ ‫‪Polycystic Ovarian Syndrome‬‬
  • 45. ‫• وتسبب متالزمة المبيض للمرأة المشاكل التالية:-‬ ‫1. إختفاء العادة الشهرية.‬ ‫2. العفم.‬ ‫3. أمراض الجلدية.‬ ‫4. نمو غزير للشعر في الوجه والجسم.‬ ‫5. فقد شعر الرأس.‬ ‫6. حالة ما قبل األصابة بداء السكري(2) وداء السكري (2).‬
  • 46. Complex Carbohydrates • Complex carbohydrates are long chains of the single sugar units. • For example, the complex carbohydrate we know as starch is made up of many glucose units. • These complex carbohydrates can be in the shape of long chains, or the chains can form branches. • The complex carbohydrates include:
  • 47. The basic chemical formula of • Starch, the energy storage the starch molecule is form of carbohydrates (C6H10O5)n. Starch is a found in plants, especially polysaccharide comprising in the seeds and roots. glucose monomers joined in a 1,4 linkages. The simplest form • Starch is made up of many of starch is the linear polymer glucose units linked amylose. together. • Starchy food examples include rice, wheat, corn, carrots and potatoes. • Starches are not water- soluble and require digestive enzymes called amylases to break them apart.
  • 48. • Glycogen, the energy storage form of glucose found in the muscles and livers of animals. • We don't consume any carbohydrates when you eat meats; however, the amount of glycogen in animal tissue at the time of slaughter does affect the pH of meat.
  • 49. • Cellulose, the structural component of plants. • Cellulose helps plants keep their shape; so, cellulose acts like a plant skeleton. • We are unable to digest cellulose; however cellulose is one of the important components of fiber, along with lignin, chitin, pectin, beta- glucan , inulin and oligosaccharides.
  • 50. • Dietary starch and cellulose are the complex carbohydrates that are important in nutrition. • Potatoes, dry beans, grains, rice, corn, squash and peas contain a large amounts of starch. • Vegetables like broccoli, cauliflower, asparagus, lettuces and other greens are not starchy.
  • 51. • Carbohydrates and Metabolism • The body begins the process of breaking carbohydrates down into their individual monosaccharides almost before we start to eat them. • When you smell the delicious aroma of fresh-baked bread or think about that tasty chocolate that you're about to consume, your mouth begins to water. • Since table sugar is water-soluble, it begins to dissolve in the saliva in mouth. • Saliva also contains a small amount of amylase, which is an enzyme that starts to break starch down into glucose while you are chewing.
  • 52. • Carbohydrate digestion is continued in the small intestine where pancreatic amylase is secreted, which breaks down the rest of the carbohydrates. • The individual monosaccharides are then absorbed into the blood stream. • Once in the blood, the monosaccharides are either used for energy, stored in the liver and muscles as glycogen, or if there is more energy available than you can use, they are converted and stored as fat.
  • 53. • The storage of glucose is triggered by insulin, which forces the body to store any extra blood sugar as glycogen. • People with diabetes or metabolic syndrome either can't produce enough insulin or they are not sensitive enough to the insulin they produce and need to regulate their blood sugar with medications, insulin or dietary changes.
  • 54. • Body prefers to use glucose as the main source of fuel for daily activity. • Muscles need glucose to move and organs need glucose to function, including your brain. • While the body can make glucose from extra dietary protein and fats you may eat, it is suggested that half of your daily calories come from carbohydrates.
  • 55. • Try to get carbohydrates from healthy sources such as whole grains, fruits and vegetables. • Cookies, sodas, candy and other sweets are not so healthy • An average healthy diet should have half of your daily calories coming from carbohydrates.
  • 56. • One gram of carbohydrate, whether is it is sugar or starch, contains four calories. • One slice of bread has about 1215- grams of carbohydrates. • One typical chocolate bar may have about 50 grams of carbohydrates. • A medium potato has about 35 grams of carbohydrates.
  • 57. • Although all carbohydrates have 4 calories per gram, some sources of carbohydrates are better for your diet than others. • Fruits, vegetables, legumes, nuts, seeds and grains are healthier than candy, sodas and pastries. • Why? The healthy carbohydrate sources have great amounts of vitamins, minerals, Phytochemicals and fiber, all of which are vital to good health.
  • 58. • Candy, sodas, pastries and other junk foods usually are poor sources of nutrients and sometimes we refer to these foods as having "empty calories.“ • This means the foods have lots of calories with little or no nutrition.
  • 59. • Since you need half of your calories from carbohydrates, you can calculate how many you need per day. • For example, let's say a person needs 2,000 calories per day. That means that 1,000 calories should come from carbohydrates (2,000 X 0.5). • Since each gram of carbohydrate has 4 calories, then you divide 1,000 by four (1,000/4) to get 250. • A person who needs 2,000 calories each day needs about 250 grams of carbohydrates per day.
  • 60. • Of those 250 grams, about 10 percent can come from added table sugar and sweeteners. • That would be about 25 grams for a 2,000 calorie per day diet. • That would equal about half of a candy bar, or less than one can of sugary soda. • Unfortunately many people exceed that amount every day.
  • 61. • In order to meet your carbohydrate requirement each day, you need to know how many carbohydrates are in all of the foods you eat. • It really is impossible to list every carbohydrate containing food here, however, here are some approximate amounts from common examples:
  • 62. • One slice of bread - 12.5 grams total, of which 10 grams are starch and less than one gram is fiber. • One cup of pasta - 43 grams total, of which 36 grams are starch and 2.5 grams are fiber. • One medium apple - 19 grams total, of which eight grams are starch and three grams are fiber • One Snickers candy bar - 63.5 total grams, of which 53 grams are sugar, two grams are fiber.
  • 63. • One cup of raisin bran cereal - 43 grams total, of which seven grams are fiber, 17 grams are starch and 16 grams are sugar . • One cup of sugar frosted corn flake cereal - 28 grams total, of which 15 grams are starch, one gram is fiber, 12 grams are sugar. • 240 ml serving of low fat milk - 12 grams total, of which 12 grams are lactose .
  • 64. • One cup broccoli - six grams total, of which 2.5 grams are fiber and 1.5 grams are sugar. • One cup green beans - eight grams total, of which four grams are fiber • One cup sweet corn - 31 grams total, of which 21 grams are starch, three grams are fiber
  • 65. • Two cups lettuce - two grams total, of which one gram is fiber • One cup asparagus - four grams total, of which two grams are fiber • One medium orange - 15 grams total, of which three grams are fiber • One half medium grapefruit - nine grams total, of which 1.5 grams are fiber • One medium chocolate chip cookie - 16 grams total, of which seven grams are sugar
  • 66. • One cup strawberries - 12 grams total, of which three grams are fiber • One cup blueberries - 21 grams total, of which four grams are fiber and 15 grams are sugar • One medium tomato - five grams total, of which 1.5 grams are fiber • One medium potato with skin - 29 grams total, of which three grams are fiber, 25 grams are starch
  • 67. • One cup carrots - 12 grams total, of which 3.5 grams are fiber and two grams are starch • One slice of an apple pie - 40 grams total, of which 18 grams are sugar • One cup of orange juice - 26 grams total, of which 21 grams are from fruit sugars • One cup of dry beans like pinto beans or navy beans - 47 grams total, of which 19 grams are fiber, 28 grams are starch
  • 68. The Importance Of Carbohydrates Carbohydrates take the form of sugars, oligosaccharides, starches and fibres and are one of the three major macro- nutrients which supply the body with energy (fat and protein being the others). There is now good evidence that at least 55% of our daily calories should come from carbohydrates(1).
  • 69. Whereas it is important to maintain an appropriate balance between calorie intake and expenditure, scientific studies suggest that: • A diet containing an optimum level of carbohydrates may help prevent body fat accumulation • Starch and sugars provide readily accessible fuel for physical performance • Dietary fiber, which is a carbohydrate, helps keep the bowel functioning correctly
  • 70. • Apart from the direct benefits of carbohydrates for the body, they are found in a wide range of foods which themselves bring a variety of other important nutrients to the diet. For this reason it is recommended that carbohydrates be supplied from diverse food sources to ensure that the overall diet contains adequate nutrients • It is also important to remember that carbohydrates contribute to the taste, texture and appearance of foods and help to make the diet more varied and enjoyable.
  • 71. Sugars • Glucose and fructose are simple sugars or monosaccharides and can be found in fruits, berries, vegetables and honey. • When two simple sugars combine, they form disaccharides. • Table sugar or sucrose is a combination of glucose and fructose and occurs naturally both in sugar beet, sugar cane and fruits. • Lactose is the main sugar in milk and dairy products and maltose is a disaccharide occurring in malt
  • 72. • Polyols are so-called sugar alcohols. They do occur naturally but most are made commercially by the transformation of sugars. • Isomalt is the most commonly used polyol and is derived from sucrose. Polyols are sweet and can be used in foods in a similar way to sugars although they can have a laxative effect when eaten in large quantities
  • 73. Oligosaccharides • When 3 to 9 sugar units combine they form oligosaccharides. • Maltodextrins contain up to 9 glucose units and are produced commercially by the partial hydrolysis (or breakdown) of starch. • They are less sweet than mono- or disaccharides. • Raffinose, stachyose and fructo- oligosaccharides are found only in small amounts in certain pulses, grains and vegetables.
  • 74. Polysaccharides More than 10 and sometimes even up to several thousand sugar units are needed to form polysaccharides. Starch is the main energy reserve in root vegetables and cereals. It comprises long chains of glucose and occurs as granules whose size and shape vary according to the plant in which it is contained.
  • 75. • Non-starch polysaccharides are the main components of dietary fiber. • They include; cellulose, hemicelluloses, pectins and gums. • Cellulose is the major component of plant cell walls and consists of several thousand glucose units. • The separate components of dietary fibber have different physical structures and properties.
  • 76. Carbohydrates In The Body The main function of carbohydrates is to provide energy, but they also play an important role in the structure and function of the body organs and nerve cells
  • 77. • Energy source and storage • Starches and sugars are the main energy- providing carbohydrate sources and supply 4 kilocalories (17 kilojoules) per gram. • To utilize this energy all carbohydrates need to be broken down to glucose after which they are transported to their place of use. • Disaccharides are broken down by digestive enzymes into simple sugars. • The body also needs the help of digestive enzymes to break down the long chains of starches into their constituent sugars, which are then absorbed into the bloodstream.
  • 78. • Glucose can also be converted to glycogen, a polysaccharide similar to starch, which is stored in the liver and the muscles and is a readily available source of energy for the body. • The brain needs to use glucose as an energy source, since it cannot use fat for this purpose. • It is for this reason that the level of glucose in the blood must be constantly maintained above the minimum level. • Glucose may come directly from dietary carbohydrates or from glycogen stores. • Several hormones, including insulin, work rapidly to regulate the flow of glucose to and from the blood to keep it at a steady level.
  • 79. The glycaemic index (GI) • When a carbohydrate food is eaten there is a corresponding rise and subsequent decrease in blood glucose level known as the glycaemic response. • This response is relevant, for example, to appetite control, sports nutrition and those with diabetes. • A number of factors influence the rate and duration of the glycaemic response. It depends on:
  • 80. 1. The specific food: • The nature and the form of the carbohydrate as some are more digestible than others The cooking and processing methods used which can change the digestibility. Other nutrients in the food such as fat or protein that can slow the digestion rate. 2. The individual person: • their metabolism • the time of day the carbohydrate is ingested
  • 81. • The impact of different carbohydrate- containing foods on the glycaemic response of the body is classified according to a standardized amount of glucose. • This measurement is called the glycaemic index, (GI).
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  • 85. Gut function and dietary fiber • The body is unable to digest dietary fibre and some oligosaccharides in the small intestine. • Fibre helps to ensure good gut function by increasing the physical bulk in the bowel and stimulating the intestinal transit. • Once the indigestible carbohydrate passes into the large intestine, some types of fiber such as gums and pectins and the oligosaccharides are fermented (broken down) by the gut microflora. • This also increases the overall mass in the bowel and has a beneficial effect on the make up of this microflora.
  • 86. Body Weight Regulation • People eating a diet high in carbohydrates are less likely to accumulate body fat compared with those who follow a low carbohydrate/high-fat diet. • The reasons for this observation are threefold: It could be due to the lower energy density of high carbohydrate diets, as carbohydrates have less calories weight for weight than fats. Fiber-rich foods also tend to be bulky and physically filling therefore less calories may be consumed.
  • 87. • Studies have found that carbohydrates, both in the form of starch and sugars, work quickly to aid satiety and that those consuming high carbohydrate diets are therefore less likely to overeat. • The inclusion of plenty of carbohydrate rich foods appears to help regulate the appetite. • Many foods with a lower glycaemic index may be particularly satisfying as they are slowly. • It has also been confirmed that very little dietary carbohydrate is converted to body fat mainly because it is a very inefficient process for the body. • Instead carbohydrate tends to be preferentially used an energy by the body
  • 88. • It is increasingly evident that diets high in carbohydrate, as compared with those high in fat, reduce the likelihood of developing obesity. • Starch and sugars have not been found to have different effects on weight control. • In fact, in several studies, high sugar consumers have been found to be slimmer than low sugar consumers.
  • 89. Diabetes • Diabetes is a metabolic disorder whereby the body cannot regulate blood glucose levels properly. • There is no evidence that sugar consumption is linked to the development of any type of diabetes. • However there is now good evidence that obesity and physical inactivity increase the likelihood of developing non-insulin dependent diabetes, which usually occurs in middle age
  • 90. • Weight reduction is usually necessary and is the primary dietary aim for people with non-insulin dependent (Type II) diabetes. • Consuming a wide range of carbohydrate foods is an acceptable part of the diet of all diabetics, and the inclusion of low glycaemic index foods is beneficial as they help regulate blood glucose control. • Most recommendations for the dietary management of diabetes allow a modest amount of ordinary sugar as the inclusion of sugar with a meal has little impact on either blood glucose or insulin concentrations in people with diabetes.
  • 91. Dental Health • The incidence of tooth decay is influenced by a number of factors. • These include: degree of oral hygiene and plaque removal carried out, • availability of fluoride, • type of food eaten, • frequency of consumption of any fermentable carbohydrate • genetic factors
  • 92. • Foods containing sugars or starch can be broken down by the enzymes and bacteria in the mouth to produce acid which attacks the enamel of the teeth. • However it is not the amount of sugar or other carbohydrate that is important but how often they are consumed. • After an acid challenge, saliva provides a natural repair process which rebuilds the enamel. • When carbohydrate-containing foods are consumed too frequently, or nibbled over time, this natural repair process is overwhelmed and the risk of tooth decay is increased
  • 93. • However in recent years the availability of fluoride and the widespread use of good oral hygiene practices have been widely heralded as responsible for the low rate of tooth decay in today's children and adolescents. • This improvement has happened independent of any change in sugar or fermentable carbohydrate intake. • Keeping plaque bacteria at bay and strengthening the teeth with fluoride reduces the risk of decay.
  • 94. • The research now available in the 1990's allows a more rational approach to the role of sugar and other carbohydrates in dental caries. • It is now recommended that programmes to prevent dental caries focus on fluoridation, adequate oral hygiene and a varied diet, and not on sugar intake alone.
  • 95. Getting Active • There is now substantial evidence that carbohydrates can improve the performance of athletes. • During high intensity exercise, carbohydrates are the main fuel for the muscles. • By consuming high levels of carbohydrate before, during and after training or an event, glycogen stores are kept well stocked. • These stocks help the athlete to perform for longer and help their bodies sustain the effort.
  • 96. • The vital role of physical activity in maintaining health and fitness in the general population is now recognized. • There is no doubt that many people would benefit from increasing their activity level as it helps in the regulation of body weight. • It also reduces the risk of developing diseases such as heart disease and diabetes. • For those who want to keep fit and active, a well-balanced high-carbohydrate diet is recommended.
  • 97. Carbohydrate Recommendation • Carbohydrates in all shapes and forms are good for your health. • They can help to control body weight, especially when combined with exercise, are vital for proper gut function and are an important fuel for the brain and active muscles. • Neither starch nor sugar have been found to have any special role in the development of serious diseases such as diabetes, and the role of sugar in the development of tooth decay is less important in today's fluoride and oral hygiene aware populations.
  • 98. • The recent report from the World Health Organization and the Food and Agriculture Organization of the United Nations on Carbohydrates in Human Nutrition makes many recommendations for health professionals and research scientists, but the most important messages for the public are:
  • 99. • the most important messages for the public are: 1. That the many health benefits of dietary carbohydrates should be recognized and promoted. Carbohydrates provide more than energy alone. 2. An optimum diet contains at least 55% of energy from carbohydrates for all those over two years of age. 3. A wide range of carbohydrate-containing foods should be consumed so that the diet is sufficient in essential nutrients and dietary fiber.
  • 100. References • WHO/FAO (1998) Carbohydrates in human nutrition. FAO food and nutrition paper no. 66. FAO, Rome. Foster-Powell, K., Brand • Miller, J. (1995), International tables of glycaemic index. American Journal of Clinical Nutrition. 62: 871S-93S. Hellerstein, M.K., • Christiansen, M., Kaempfer, S. et al (1991). Measurement of de novo hepatic lipogenesis in humans using stable isotopes. J. Clin. • Invest. 87: 1841-1852. World Health Organisation (1998) Obesity - preventing and managing the global epidemic. Report of the WHO consultation on obesity. Geneva, June 97. Bolton-Smith C & Woodward • M (1994). Dietary composition and fat to sugar ratios in relation to obesity. Int J Obesity 18;820-828. US Department of Health and Human • Services (1996). Physical activity and health: a report of the Surgeon General, Atlanta, Georgia, USA. 7. Fejershov O. Concepts of dental caries and their consequences for understanding the disease. Community Dent. Oral Epidemiol. 1997; 25: 5-12.
  • 101. Further Reading • Dietary Starches and Sugars in Man: A comparison (1989). Edited by J. Dobbing, ILSI Human Nutrition Review series. • ILSI Europe Concise Monographs Series: Nutritional and Health Aspects of Sugars: Evaluation of New Findings (1995). • ILSI Europe Concise Monographs Series: Caries Preventative Strategies (1995).