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CHEMISTRY
PROJECT
CARBOHYDRATES
• Primarily produced by plants (simplest form: glucose )and form very large group of
naturally occurring organic compounds.
• Mainly compounds of Carbon , Hydrogen and Oxygen.
• They were considered to be hydrates of carbon {Cx(H2O)y} and the name
carbohydrates was derived.
• But acetic acid , rhamnose and many more compounds do not fit this definition.
• Chemically, the carbohydrates may be defined as optically active polyhydroxy
aldehydes or ketones.
PHYSICAL PROPERTIES
• Carbohydrates are white solids.
• Sprangly soluble in organic solvents.
• More soluble in water.
• Carbohydrates which are sweet in taste are called Sugars. (Except: polysaccharides-
they are non-sugars).
• The common sugar used in homes: sucrose, sugar present in milk : Lactose, sugar
present in fruits: fructose.
• Carbohydrates are known as saccharides ( Greek: sackaron means sugar).
CLASSIFICATION ON THE BASIS OF
THEIR BEHAVIOR ON HYDROLYSIS
MONOSACCHARIDES:
• cannotbehydrolysedfurther to give simpler unit of
poly hydroxy aldehyde or ketone.
• About 20 monosaccharides are known to occur in
nature .
• Examples are glucose, fructose, ribose, etc
OLIGOSACCHARIDES:
• Carbohydrates that yield two to ten
monosaccharide units, on hydrolysis.
• further classified as disaccharides(2),
trisaccharides(3) , tetrasaccharides(4), etc.,
depending upon the number of monosaccharides,
they provide on hydrolysis.
• the most common are disaccharides.
• For example, one molecule of sucrose on hydrolysis
hydrolysis gives one molecule of glucose and one
molecule of fructosewhereas maltose gives two
molecules of only glucose.
POLYSACCHARIDES:
• which yield a large number of
monosaccharide units on hydrolysis
• examples are starch, cellulose, glycogen,
gums, etc.
• Polysaccharides are not sweet in taste, hence
they are alsocalled non-sugars.
SUGARS
REDUCING SUGARS
• Sugars in which aldehydes and ketonic
groups are free.
• Which can reduce Tollen’s Reagent ,
Fehling’s solution and Benedict solution.
• Possesses either α- hydroxy aldehyde
or α- hydroxy ketone.
• All monosaccharides ( either aldose or
ketose )and diasaccharides (except
sucrose ) are reducing.
NON. REDUCING SUGARS
• If reducing groups ( aldehydic or ketonic
groups) of monosaccharides are bonded.
• Which do not reduce Tollen’s Reagent ,
Fehling’s solution and Benedict solution.
• All polysaccharides and sucrose.
MONOSACCHARIDES:
IF ALDEHYDE GP. IS PRESENT- ALDOSE.
IF KETO GP. IS PRESENT- KETOSE.
Glucose:
• Present in sweet fruits and honey .
• Ripe grapes contain glucose in large amounts.
• Most abundant organic compound on earth.
• It is Aldohexose and is known as dextrose.
• Preparation of glucose:–
1. From sucrose (Cane sugar): If sucrose is boiled with
dilute HCl or H2SO4 in alcoholic solution, glucose
and fructose are obtained in equal amounts.
Sucrose Glucose. +. Fructose
2. From starch: Commercially glucose is obtained by
hydrolysis ofstarch by boiling it with dilute H2SO4 at
393 K under pressure.
3. Starch or cellulose. Glucose
Fructose:
• Fructose is an important ketohexose.
• It is obtained along with glucose by the
hydrolysis of disaccharide, sucrose.
• It is a natural monosaccharide found in fruits,
fruits, honey and vegetables.
• In its pure form it is used as a sweetner.
• Fructose also has the molecular formula
C6H12O6 and on the basis of its reactions it
was found to contain a ketonic functional
group at carbon number 2 and six carbons in
straight chain as in the case of glucose. It
belongs to D-series and is a laevorotatory
compound. It is appropriately written as D-(–
)-fructose.
OLIGOSACCHARIDES:
DISACCHARIDES
DISACCHARIDES ON HYDROLYSIS W ITH DILUTE ACIDS OR ENZYMES YIELD T W O
MOLECULES OF EITHER THE SAME OR DIFFERENT MONOSACCHARIDES.
THE TW O MONOSACCHARIDES ARE JOINED TOGETHER BY AN OXIDE LINKAGE FORMED BY
THE LOSS OF A WATER M OLECULE . SUCH A LINKAGE BETW EEN TW O MONOSACCHARIDE
UNITS THROUGH OX YGEN ATOM IS CALLED GLYCOSIDE LINKAGE.
(i) Sucrose:
• One of the common disaccharides is sucrose which
on hydrolysis gives equimolar mixture of D-(+)-
glucose and D-(-) fructose. These two
monosaccharides are held together by a glycosidic
linkage between C1 of a-D-glucose and C2 of b-D-
fructose.
Maltose:
• composed of two a-D-glucose units in which C1 of
one glucose (I) is linked to C4 of another glucose
unit (II). The free aldehyde group can be produced
at C1 of second glucose in solution and it shows
reducing properties so it is a reducing sugar.
POLYSACCHARIDES
Lactose:-
• It is more commonly known as milk sugar since this
disaccharide is found in milk. It is composed of b-D-
galactose and b-D-glucose. The linkage is between C1 of
galactose and C4 of glucose. Free aldehyde group may be
produced at C-1 of glucose unit, hence it is also a reducing
sugar.
: most commonly encountered carbohydrates in nature.
They mainly act as the food storage or structural materials.
Starch:
• Starch is the main storage
polysaccharide of plants.It is a polymer
of a-glucose and consists of two
components— Amylose and
Amylopectin.
Cellulose:
• Cellulose occurs exclusively in plants and it is the
most abundant organic substance in plant
kingdom. It is a predominant constituent of cell
wall of plant cells. Glycogen:–It is also known
as animal starch because
its structure is similar to
amylopectin and is rather
more highly branched. It is
present in liver, muscles
and brain. When the body
needs glucose, enzymes
break the glycogen down
to glucose.
IMPORTANCE OF CARBOHYDRATES
• Carbohydrates are essential for life in
both plants and animals.
• They form a major portion of our food.
• Honey has been used for a long time
as an instant source of energy by
‘Vaids’ in ayurvedic system of
medicine.
• Carbohydrates are used as storage
molecules as starch in plants and
glycogen in animals.
• Cell wall of bacteria and plants is
made up of cellulose.
• We build furniture, etc. from cellulose
in the form of wood and clothe
ourselves with cellulose in the form of
cotton fibre.
• They provide raw materials for many
important industries like textiles, paper,
lacquers and breweries.
THANK. YOU.

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chemistry project copy.pptx

  • 2. CARBOHYDRATES • Primarily produced by plants (simplest form: glucose )and form very large group of naturally occurring organic compounds. • Mainly compounds of Carbon , Hydrogen and Oxygen. • They were considered to be hydrates of carbon {Cx(H2O)y} and the name carbohydrates was derived. • But acetic acid , rhamnose and many more compounds do not fit this definition. • Chemically, the carbohydrates may be defined as optically active polyhydroxy aldehydes or ketones.
  • 3. PHYSICAL PROPERTIES • Carbohydrates are white solids. • Sprangly soluble in organic solvents. • More soluble in water. • Carbohydrates which are sweet in taste are called Sugars. (Except: polysaccharides- they are non-sugars). • The common sugar used in homes: sucrose, sugar present in milk : Lactose, sugar present in fruits: fructose. • Carbohydrates are known as saccharides ( Greek: sackaron means sugar).
  • 4. CLASSIFICATION ON THE BASIS OF THEIR BEHAVIOR ON HYDROLYSIS MONOSACCHARIDES: • cannotbehydrolysedfurther to give simpler unit of poly hydroxy aldehyde or ketone. • About 20 monosaccharides are known to occur in nature . • Examples are glucose, fructose, ribose, etc OLIGOSACCHARIDES: • Carbohydrates that yield two to ten monosaccharide units, on hydrolysis. • further classified as disaccharides(2), trisaccharides(3) , tetrasaccharides(4), etc., depending upon the number of monosaccharides, they provide on hydrolysis. • the most common are disaccharides. • For example, one molecule of sucrose on hydrolysis hydrolysis gives one molecule of glucose and one molecule of fructosewhereas maltose gives two molecules of only glucose. POLYSACCHARIDES: • which yield a large number of monosaccharide units on hydrolysis • examples are starch, cellulose, glycogen, gums, etc. • Polysaccharides are not sweet in taste, hence they are alsocalled non-sugars.
  • 5. SUGARS REDUCING SUGARS • Sugars in which aldehydes and ketonic groups are free. • Which can reduce Tollen’s Reagent , Fehling’s solution and Benedict solution. • Possesses either α- hydroxy aldehyde or α- hydroxy ketone. • All monosaccharides ( either aldose or ketose )and diasaccharides (except sucrose ) are reducing. NON. REDUCING SUGARS • If reducing groups ( aldehydic or ketonic groups) of monosaccharides are bonded. • Which do not reduce Tollen’s Reagent , Fehling’s solution and Benedict solution. • All polysaccharides and sucrose.
  • 6. MONOSACCHARIDES: IF ALDEHYDE GP. IS PRESENT- ALDOSE. IF KETO GP. IS PRESENT- KETOSE. Glucose: • Present in sweet fruits and honey . • Ripe grapes contain glucose in large amounts. • Most abundant organic compound on earth. • It is Aldohexose and is known as dextrose. • Preparation of glucose:– 1. From sucrose (Cane sugar): If sucrose is boiled with dilute HCl or H2SO4 in alcoholic solution, glucose and fructose are obtained in equal amounts. Sucrose Glucose. +. Fructose 2. From starch: Commercially glucose is obtained by hydrolysis ofstarch by boiling it with dilute H2SO4 at 393 K under pressure. 3. Starch or cellulose. Glucose
  • 7. Fructose: • Fructose is an important ketohexose. • It is obtained along with glucose by the hydrolysis of disaccharide, sucrose. • It is a natural monosaccharide found in fruits, fruits, honey and vegetables. • In its pure form it is used as a sweetner. • Fructose also has the molecular formula C6H12O6 and on the basis of its reactions it was found to contain a ketonic functional group at carbon number 2 and six carbons in straight chain as in the case of glucose. It belongs to D-series and is a laevorotatory compound. It is appropriately written as D-(– )-fructose.
  • 8. OLIGOSACCHARIDES: DISACCHARIDES DISACCHARIDES ON HYDROLYSIS W ITH DILUTE ACIDS OR ENZYMES YIELD T W O MOLECULES OF EITHER THE SAME OR DIFFERENT MONOSACCHARIDES. THE TW O MONOSACCHARIDES ARE JOINED TOGETHER BY AN OXIDE LINKAGE FORMED BY THE LOSS OF A WATER M OLECULE . SUCH A LINKAGE BETW EEN TW O MONOSACCHARIDE UNITS THROUGH OX YGEN ATOM IS CALLED GLYCOSIDE LINKAGE. (i) Sucrose: • One of the common disaccharides is sucrose which on hydrolysis gives equimolar mixture of D-(+)- glucose and D-(-) fructose. These two monosaccharides are held together by a glycosidic linkage between C1 of a-D-glucose and C2 of b-D- fructose. Maltose: • composed of two a-D-glucose units in which C1 of one glucose (I) is linked to C4 of another glucose unit (II). The free aldehyde group can be produced at C1 of second glucose in solution and it shows reducing properties so it is a reducing sugar.
  • 9. POLYSACCHARIDES Lactose:- • It is more commonly known as milk sugar since this disaccharide is found in milk. It is composed of b-D- galactose and b-D-glucose. The linkage is between C1 of galactose and C4 of glucose. Free aldehyde group may be produced at C-1 of glucose unit, hence it is also a reducing sugar. : most commonly encountered carbohydrates in nature. They mainly act as the food storage or structural materials. Starch: • Starch is the main storage polysaccharide of plants.It is a polymer of a-glucose and consists of two components— Amylose and Amylopectin. Cellulose: • Cellulose occurs exclusively in plants and it is the most abundant organic substance in plant kingdom. It is a predominant constituent of cell wall of plant cells. Glycogen:–It is also known as animal starch because its structure is similar to amylopectin and is rather more highly branched. It is present in liver, muscles and brain. When the body needs glucose, enzymes break the glycogen down to glucose.
  • 10. IMPORTANCE OF CARBOHYDRATES • Carbohydrates are essential for life in both plants and animals. • They form a major portion of our food. • Honey has been used for a long time as an instant source of energy by ‘Vaids’ in ayurvedic system of medicine. • Carbohydrates are used as storage molecules as starch in plants and glycogen in animals. • Cell wall of bacteria and plants is made up of cellulose. • We build furniture, etc. from cellulose in the form of wood and clothe ourselves with cellulose in the form of cotton fibre. • They provide raw materials for many important industries like textiles, paper, lacquers and breweries.