Carbohydrates can be classified as monosaccharides, disaccharides, oligosaccharides, or polysaccharides. Monosaccharides include glucose, fructose, and galactose. Disaccharides are two monosaccharides joined together, such as sucrose from glucose and fructose or lactose from glucose and galactose. Polysaccharides are long chains of monosaccharides and include starch, cellulose, and glycogen. Starch is used by plants for energy storage while glycogen serves the same function for animals. Cellulose provides structure to plant cell walls.
Introduction to Carbohydrates and its ChemistryDHANANJAY PATIL
A Comprehensive Introduction to Carbohydrates its chemistry, classification, qualitative tests an disorders related to its metabolism. This will give readers a overall insight to this topic. All types of queries and suggestions are most welcome
Introduction to Carbohydrates and its ChemistryDHANANJAY PATIL
A Comprehensive Introduction to Carbohydrates its chemistry, classification, qualitative tests an disorders related to its metabolism. This will give readers a overall insight to this topic. All types of queries and suggestions are most welcome
The topic is about carbohydreates.
This lecture will cover an introduction to carbohydrates, its classification and exmaples. it will also cover the difference between glycemic index, difference between complex vs simple carb and also what are the fuctions of carbohydrates. this content will be helpful for all categories of students. 2014 study published in JAMA and youtube sources helps me in preparing lecture.
These are major source of energy for living organisms.
Supplying a huge array of metabolic intermediates for biosynthetic reactions.
The structural elements in cell coat or connective tissues.
This explains the complex carbohydrates and chemistry of heterpolysaccharides. composition, distribution and its function is explained for each GAGs. brief notes on blood group ag is available. difference between proteoglycan and glycoprotein is explained in a essay way to understand. clinical importance is also added.
In general, carbohydrates are neutral chemical compounds containing the elements carbon, hydrogen and oxygen and have the empirical formula (CH2O)n, where n is 3 or more.
The topic is about carbohydreates.
This lecture will cover an introduction to carbohydrates, its classification and exmaples. it will also cover the difference between glycemic index, difference between complex vs simple carb and also what are the fuctions of carbohydrates. this content will be helpful for all categories of students. 2014 study published in JAMA and youtube sources helps me in preparing lecture.
These are major source of energy for living organisms.
Supplying a huge array of metabolic intermediates for biosynthetic reactions.
The structural elements in cell coat or connective tissues.
This explains the complex carbohydrates and chemistry of heterpolysaccharides. composition, distribution and its function is explained for each GAGs. brief notes on blood group ag is available. difference between proteoglycan and glycoprotein is explained in a essay way to understand. clinical importance is also added.
In general, carbohydrates are neutral chemical compounds containing the elements carbon, hydrogen and oxygen and have the empirical formula (CH2O)n, where n is 3 or more.
• CHO : CHO may be defined as polyhydroxy aldehyde,
ketones or acids and their derivatives.
• CHO : Based on their digestibility & solubility , the CHO
divided in to two parts
– Soluble CHO / easily digest - NFE ( Sugar, Starch,
Hemicelluloses)
– Insoluble CHO / less digest in non ruminant but digestible
in ruminant (Crude fibre, cellulose, Ligniin)
• Carbohydrates are neutral chemical compounds
containing the elements carbon, hydrogen & oxygen &
have empirical formula (CH2O)n where n is three or
more.
CARBOHYDRATES
Function of carbohydrates
• Important source of energy
• As important food reserves
• In the storage of Liver and muscle of the liver
Glycogen
Liver glycogen muscle glycogen
• In the seed →as starc
• Transfer of genetic characteristic of the cell
• Carbohydrates make the matrix of connective
tissue eg. Hyaluronic acid
• They make structural part of cartilage, bone
and tendons eg. Chondroitin sulphate
• Oxidation of protein & fat as they are
important component.
• Essential component of milk as lactose.
• It helpful in absorption of calcium &
phosphorus in younger animals.
• They help in peristaltic movement of food.
Classification of carbohydrates:
17
In nutrition, carbohydrates are classied into five groups:
• (1) monosaccharides (also known as simple sugars);
• (2) disaccharides (containing 2 monosaccharide units);
• (3) oligosaccharides (containing 3–10 monosaccharide
units);
• (4) polysaccharides (containing more than 10
monosaccharide units); and
• (5) conjugated carbohydrates. covalently bound to lipids or
proteins to form glycolipids or glycoproteins, respectively.
Polysaccharides are subdivided into
– Homopolysaccharides (containing only one type of
monosaccharide) and
– Heteropolysaccharides (containing more than one type of
monosaccharide).
Classification of Carbohydrates
• Monosaccharides
– Trioses (C3H6O3) Glyceraldehyde and dihydroxyacetone
– Tetroses (C4H8O4) Erythrose
– Pentoses (C5H10O5) Aarabinase, xylose, xylulose, ribose,
ribulose, and 5-deoxyribose
– Hexoses (C6H12O6) Glucose, fructose, galactose, and mannose
– Heptoses (C7H14O7) Sedoheptulose, mannoheptulose (in
avocados), and -glycero--manno-heptose
• Disaccharides Sucrose (-α-glucose and -α-fructose), lactose
(milk sugar; -α-glucose and -α-galactose), maltose, isomaltose,
cellobiose, α,α-trehalose, α,β-trehalose, and β,β-trehalose)
• Oligosaccharides
– Trisaccharides, Rafnose, kestose, maltotriose (three units of glucose),
planteose, and melezitose (in sweet exudates of many trees and in
insects), and panose (synthesized by microbes)
– Tetrasaccharides Stachyose and lychnose (1-α-galactosyl-rafnose)
18
• Polysaccharides
– Homoglycans
• Pentosans (C5H8O4)n, for example, arabans and xylans
• Hexosans (C6H12O6)n, for example, starch, cellulose,
mannans, levans, and glycogen
– Heteroglycansd Hemicelluloses, pectins, exudate
gums, seaweed polysaccharides (algin, carrageenans,
agar, aminopolysaccharides [e.g., chondroitin and
hyal
Any of a large group of organic compounds occurring in foods and living tissues and including sugars, starch, and cellulose. They contain hydrogen and oxygen in the same ratio as water (2:1) and typically can be broken down to release energy in the animal body.
Chemically, carbohydrates are defined as “optically active polyhydroxy aldehydes or ketones or the compounds which produce units of such type on hydrolysis”.
Carbohydrates : carbohydrates are polyhydroxy aldehyde or ketones, or substances that yield such compounds on hydrolysis. A carbohydrate is a biological molecule consisting of Carbon (C), Hydrogen (H), and Oxygen (O) atoms, usually with a hydrogen-oxygen atom ratio of 2:1 (as in water); in other words, with the empirical formula (CH2O)n. Simple carbohydrates are also known as "Sugars" or "Saccharides".
Depending upon the composition and complexity, carbohydrates are divided into four groups:
1. Monosaccharides
2. Disaccharides
3. Oligosaccharides
4. Polysaccharides
Monosaccharides: are simplest sugars, or the compounds which possess a free aldehyde (CHO) or ketone (C=O) group and two or more hydroxyl (OH) groups. They are simplest sugars and cannot be hydrolyzed further into smaller units. Examples of monosaccharides include:
1. Glucose
2. Fructose
3. Galactose
Disaccharides: Those sugars which yield two molecules of the same or different molecules of monosaccharides on hydrolysis are called Disaccharides. Three most common disaccharides of biological importance are:
1. Maltose
2. Lactose
3. Sucrose
Oligosaccharides: are compound sugars that yield more than two and less than ten molecules of the same or different monosaccharides on hydrolysis. Depending upon the number of monosaccharides units present in them oligosaccharides can be classified as Trisaccharides, Tetrasaccharides, Pentasaccharides and so on.
Polysaccharides: polysaccharides are polymers containing ten or more monosaccharides units attached together. Polysaccharides are also known as Glycans. Polysaccharides are further classified into:
1. Homopolysaccharides: are also known as homoglycans. Homopolysaccharides are polymer of same monosaccharide units. Example includes:
1. Starch
2. Glycogen
3. Cellulose
4. Inulin
5. Dextrin
6. Dextran
7. Chitin
Heteropolysaccharides: heteropolysaccharides are polysaccharides that contains different types of monosaccharides. Heteropolysaccharides can be classified as: GAG, AGAR, AGAROSE, PECTIN.
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3. • CARBOHYDRATE is defined as polyhydroxy aldehyde or
ketones subunits.
• It contains aldehyde :
• H-C=O
• And Keto :
• C=O
• These are also called sacchrides.
• It is a group of organic compounds having carbon, oxygen and
hydrogen thus called “Hydrated carbons” .
5. TYPES OF CARBOHYDRATES:
Monosaccharides - simple sugars with multiple OH groups.
Based on number of carbons (3, 4, 5, 6), a monosaccharide is a
triose, tetrose, pentose or hexose.
Disaccharides - 2 monosaccharides covalently linked.
Oligosaccharides - a few monosaccharides covalently linked.
Polysaccharides - polymers consisting of chains of
monosaccharide or disaccharide units.
6.
7. MONOSACCHRIDES:
• These are called “Simple Sugars”, because they can not be
hydrolysed further into simple sugars.
• Their general formula is “Cn H2n On .
• They are white crystalline solids with sweet taste and soluble
in water.
• They are present in various fruits and vegetables.
8. • Chemically these are polyhydroxy aldehyde or ketones.
• These are found naturally from 3 to 7 C-atoms.
• These can be:
• Triose (3C)
• Tetrose (4C)
• Pentose (5C)
• Hexose (6C).
9. Aldoses (e.g., glucose) have an
aldehyde group at one end
Ketoses (e.g., fructose) have a
keto group, usually at C2.
C
C OHH
C HHO
C OHH
C OHH
CH2OH
D-glucose
OH
C HHO
C OHH
C OHH
CH2OH
CH2OH
C O
D-fructose
10. EXAMPLES OF MONOSACCHRIDES:
• GLUCOSE:
• Basic sub-unit of other larger carbohydrate molecules.
• Molecular formula C6H12O6.
• Make ring and linear structure.
• Two types :
• Alpha glucose; having OH group downside of the ring.
• Beta glucose; having OH group upside of the ring.
11.
12.
13.
14. FRUCTOSE:
• Also known as "Fruit Sugar“.
• It is a simple ketonic monosaccharide found in many plants.
• In combined state with Glucose , it gives a Disacchride
“sucrose”.
• Glucose +fructose= sucrose.
16. Galactose :
• Also called Milk sugar.
• It is a monosacchride with less sweet in test than glucose.
• In combined state with Glucose it gives a Disacchride
“lactose”.
18. Disacchrides :
• A disaccharide is a sugar (a carbohydrate) composed of
two monosaccharides and water molecule is removed.
• These are soluble in water.
• General formula is C12H22O11.
• These are crystalline , less sweet than monossacrides.
19.
20. Polysachrides :
• Polysaccharides are complex carbohydrates, composed of 10
to up to several thousand monosaccharides arranged in chains.
• The most common monosaccharide in polysaccharides
are glucose, fructose, galactose and mannose.
21. • These are tasteless , and sparingly soluble in water.
• These are usually branched and have high molecular weight.
• It can be categorised into:
• Structural polysacchride : includes cellulose and chitin.
• Functional polysacchride : includes glycogen and starch.
22. Starch:
• These are found in white powder as dry state.
• Tasteless and odorless.
• Insoluble in water.
• Made up of the lareg chain of alpha-glucose.
• Generall formula is (C6H10O5)n.
23.
24.
25. • It can be classified into:
• Amylose :
These have unbranched chain of glucose molecule.
Soluble in hot water.
• Amylopectin:
These have branched chain of glucose molecule.
Insoluble in water.
27. H O
OH
H
OHH
OH
CH2OH
H
O H
H
OHH
OH
CH2OH
H
O
HH H O
O
H
OHH
OH
CH2
H
H H O
H
OHH
OH
CH2OH
H
OH
HH O
O
H
OHH
OH
CH2OH
H
O
H
O
1 4
6
H O
H
OHH
OH
CH2OH
H
H H O
H
OHH
OH
CH2OH
H
H
O
1
OH
3
4
5
2
amylopectin
28. Functions of starch:
• Dietry function of starch is to convert glucose into energy for
body and brain.
• In plants they store glucose.
• Chemically modified and unmodified starch used for
papermaking.
• Vegetable starch mix into into water used for laundery
purpose.
29. Cellulose:
• It is a polysacchride made up of the linear chain of several
glucose molecules.
• Mainly it consists of beta-glucose.
• It has no taste and no odor.
• Highly insoluble in water.
• Digestable by herbivores.
• Generall formula is (C6H10O5)n.
32. Functions of cellulose:
• Provide shape to plant cell wall.
• Produces lignin which makes the wood of tree so strong.
• Powdered cellulose are used as inactive fillers in drug tablets.
• Used for textile purpose made from cotton and linen.
33. GLYCOGEN:
• It is also called animal starch.
• It is a multibranched polyscchride.
• In dry state ,present in white powder.
• Insoluble in water.
• Found in the form of granules in the cytosol in many cell
types.
• Generall formula is C24H42O21.
34. • Made up of the alpha-glucose molecules,
• Present in liver cells with 8%.
• Present in muscles with 1%,
• In kidney low amount is found.
35. H O
OH
H
OHH
OH
CH2OH
H
O H
H
OHH
OH
CH2OH
H
O
HH H O
O
H
OHH
OH
CH2
H
H H O
H
OHH
OH
CH2OH
H
OH
HH O
O
H
OHH
OH
CH2OH
H
O
H
O
1 4
6
H O
H
OHH
OH
CH2OH
H
H H O
H
OHH
OH
CH2OH
H
H
O
1
OH
3
4
5
2
glycogen
36.
37. Functions of glycogen:
• The main function of glycogen is as a secondary long-term
energy-storage molecule.
• In liver : regulates to maintain blood glucose level.
• In muscles : provide energy to muscles .
38. Chitin :
• A long-chain polymer of an N-acetylglucosamine.
• Chitin is a modified polysaccharide that contains nitrogen; it
is synthesized from units of N-acetyl-D-glucosamine.
• Found in the cell walls of certain fungi and algae.
• Formula = (C8H13O5N)n
39.
40. Functions of chitin:
• It makes the cell wall of fungi and algae.
• Chitin is a good inducer of defense mechanisms in plants.
• It accelerates healing of wood in humans.
• Chemically modified chitin used in food processing and as an
additive to thicken and stablize food.