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Carbohydrates
CARBOHYDRATES
• (glycans) have the following basic composition:
I
(CH2O)n or H - C - OH
I
• CARBOHYDRATE is defined as polyhydroxy aldehyde or
ketones subunits.
• It contains aldehyde :
• H-C=O
• And Keto :
• C=O
• These are also called sacchrides.
• It is a group of organic compounds having carbon, oxygen and
hydrogen thus called “Hydrated carbons” .
SOURCES:
• Green plants Grains
• Milk Beans
• Fruits Sugar canes
TYPES OF CARBOHYDRATES:
 Monosaccharides - simple sugars with multiple OH groups.
Based on number of carbons (3, 4, 5, 6), a monosaccharide is a
triose, tetrose, pentose or hexose.
 Disaccharides - 2 monosaccharides covalently linked.
 Oligosaccharides - a few monosaccharides covalently linked.
 Polysaccharides - polymers consisting of chains of
monosaccharide or disaccharide units.
MONOSACCHRIDES:
• These are called “Simple Sugars”, because they can not be
hydrolysed further into simple sugars.
• Their general formula is “Cn H2n On .
• They are white crystalline solids with sweet taste and soluble
in water.
• They are present in various fruits and vegetables.
• Chemically these are polyhydroxy aldehyde or ketones.
• These are found naturally from 3 to 7 C-atoms.
• These can be:
• Triose (3C)
• Tetrose (4C)
• Pentose (5C)
• Hexose (6C).
Aldoses (e.g., glucose) have an
aldehyde group at one end
Ketoses (e.g., fructose) have a
keto group, usually at C2.
C
C OHH
C HHO
C OHH
C OHH
CH2OH
D-glucose
OH
C HHO
C OHH
C OHH
CH2OH
CH2OH
C O
D-fructose
EXAMPLES OF MONOSACCHRIDES:
• GLUCOSE:
• Basic sub-unit of other larger carbohydrate molecules.
• Molecular formula C6H12O6.
• Make ring and linear structure.
• Two types :
• Alpha glucose; having OH group downside of the ring.
• Beta glucose; having OH group upside of the ring.
FRUCTOSE:
• Also known as "Fruit Sugar“.
• It is a simple ketonic monosaccharide found in many plants.
• In combined state with Glucose , it gives a Disacchride
“sucrose”.
• Glucose +fructose= sucrose.
Structure of fructose:
Galactose :
• Also called Milk sugar.
• It is a monosacchride with less sweet in test than glucose.
• In combined state with Glucose it gives a Disacchride
“lactose”.
Structure of Galactose
Disacchrides :
• A disaccharide is a sugar (a carbohydrate) composed of
two monosaccharides and water molecule is removed.
• These are soluble in water.
• General formula is C12H22O11.
• These are crystalline , less sweet than monossacrides.
Polysachrides :
• Polysaccharides are complex carbohydrates, composed of 10
to up to several thousand monosaccharides arranged in chains.
• The most common monosaccharide in polysaccharides
are glucose, fructose, galactose and mannose.
• These are tasteless , and sparingly soluble in water.
• These are usually branched and have high molecular weight.
• It can be categorised into:
• Structural polysacchride : includes cellulose and chitin.
• Functional polysacchride : includes glycogen and starch.
Starch:
• These are found in white powder as dry state.
• Tasteless and odorless.
• Insoluble in water.
• Made up of the lareg chain of alpha-glucose.
• Generall formula is (C6H10O5)n.
• It can be classified into:
• Amylose :
These have unbranched chain of glucose molecule.
Soluble in hot water.
• Amylopectin:
These have branched chain of glucose molecule.
Insoluble in water.
H O
OH
H
OHH
OH
CH2OH
H
O H
H
OHH
OH
CH2OH
H
O
HH H O
O
H
OHH
OH
CH2OH
H
H H O
H
OHH
OH
CH2OH
H
OH
HH O
O
H
OHH
OH
CH2OH
H
O
H
1
6
5
4
3
1
2
amylose
H O
OH
H
OHH
OH
CH2OH
H
O H
H
OHH
OH
CH2OH
H
O
HH H O
O
H
OHH
OH
CH2
H
H H O
H
OHH
OH
CH2OH
H
OH
HH O
O
H
OHH
OH
CH2OH
H
O
H
O
1 4
6
H O
H
OHH
OH
CH2OH
H
H H O
H
OHH
OH
CH2OH
H
H
O
1
OH
3
4
5
2
amylopectin
Functions of starch:
• Dietry function of starch is to convert glucose into energy for
body and brain.
• In plants they store glucose.
• Chemically modified and unmodified starch used for
papermaking.
• Vegetable starch mix into into water used for laundery
purpose.
Cellulose:
• It is a polysacchride made up of the linear chain of several
glucose molecules.
• Mainly it consists of beta-glucose.
• It has no taste and no odor.
• Highly insoluble in water.
• Digestable by herbivores.
• Generall formula is (C6H10O5)n.
Chemical structure of cellulose:
Functions of cellulose:
• Provide shape to plant cell wall.
• Produces lignin which makes the wood of tree so strong.
• Powdered cellulose are used as inactive fillers in drug tablets.
• Used for textile purpose made from cotton and linen.
GLYCOGEN:
• It is also called animal starch.
• It is a multibranched polyscchride.
• In dry state ,present in white powder.
• Insoluble in water.
• Found in the form of granules in the cytosol in many cell
types.
• Generall formula is C24H42O21.
• Made up of the alpha-glucose molecules,
• Present in liver cells with 8%.
• Present in muscles with 1%,
• In kidney low amount is found.
H O
OH
H
OHH
OH
CH2OH
H
O H
H
OHH
OH
CH2OH
H
O
HH H O
O
H
OHH
OH
CH2
H
H H O
H
OHH
OH
CH2OH
H
OH
HH O
O
H
OHH
OH
CH2OH
H
O
H
O
1 4
6
H O
H
OHH
OH
CH2OH
H
H H O
H
OHH
OH
CH2OH
H
H
O
1
OH
3
4
5
2
glycogen
Functions of glycogen:
• The main function of glycogen is as a secondary long-term
energy-storage molecule.
• In liver : regulates to maintain blood glucose level.
• In muscles : provide energy to muscles .
Chitin :
• A long-chain polymer of an N-acetylglucosamine.
• Chitin is a modified polysaccharide that contains nitrogen; it
is synthesized from units of N-acetyl-D-glucosamine.
• Found in the cell walls of certain fungi and algae.
• Formula = (C8H13O5N)n
Functions of chitin:
• It makes the cell wall of fungi and algae.
• Chitin is a good inducer of defense mechanisms in plants.
• It accelerates healing of wood in humans.
• Chemically modified chitin used in food processing and as an
additive to thicken and stablize food.

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Carbohydrates ppt

  • 2. CARBOHYDRATES • (glycans) have the following basic composition: I (CH2O)n or H - C - OH I
  • 3. • CARBOHYDRATE is defined as polyhydroxy aldehyde or ketones subunits. • It contains aldehyde : • H-C=O • And Keto : • C=O • These are also called sacchrides. • It is a group of organic compounds having carbon, oxygen and hydrogen thus called “Hydrated carbons” .
  • 4. SOURCES: • Green plants Grains • Milk Beans • Fruits Sugar canes
  • 5. TYPES OF CARBOHYDRATES:  Monosaccharides - simple sugars with multiple OH groups. Based on number of carbons (3, 4, 5, 6), a monosaccharide is a triose, tetrose, pentose or hexose.  Disaccharides - 2 monosaccharides covalently linked.  Oligosaccharides - a few monosaccharides covalently linked.  Polysaccharides - polymers consisting of chains of monosaccharide or disaccharide units.
  • 6.
  • 7. MONOSACCHRIDES: • These are called “Simple Sugars”, because they can not be hydrolysed further into simple sugars. • Their general formula is “Cn H2n On . • They are white crystalline solids with sweet taste and soluble in water. • They are present in various fruits and vegetables.
  • 8. • Chemically these are polyhydroxy aldehyde or ketones. • These are found naturally from 3 to 7 C-atoms. • These can be: • Triose (3C) • Tetrose (4C) • Pentose (5C) • Hexose (6C).
  • 9. Aldoses (e.g., glucose) have an aldehyde group at one end Ketoses (e.g., fructose) have a keto group, usually at C2. C C OHH C HHO C OHH C OHH CH2OH D-glucose OH C HHO C OHH C OHH CH2OH CH2OH C O D-fructose
  • 10. EXAMPLES OF MONOSACCHRIDES: • GLUCOSE: • Basic sub-unit of other larger carbohydrate molecules. • Molecular formula C6H12O6. • Make ring and linear structure. • Two types : • Alpha glucose; having OH group downside of the ring. • Beta glucose; having OH group upside of the ring.
  • 11.
  • 12.
  • 13.
  • 14. FRUCTOSE: • Also known as "Fruit Sugar“. • It is a simple ketonic monosaccharide found in many plants. • In combined state with Glucose , it gives a Disacchride “sucrose”. • Glucose +fructose= sucrose.
  • 16. Galactose : • Also called Milk sugar. • It is a monosacchride with less sweet in test than glucose. • In combined state with Glucose it gives a Disacchride “lactose”.
  • 18. Disacchrides : • A disaccharide is a sugar (a carbohydrate) composed of two monosaccharides and water molecule is removed. • These are soluble in water. • General formula is C12H22O11. • These are crystalline , less sweet than monossacrides.
  • 19.
  • 20. Polysachrides : • Polysaccharides are complex carbohydrates, composed of 10 to up to several thousand monosaccharides arranged in chains. • The most common monosaccharide in polysaccharides are glucose, fructose, galactose and mannose.
  • 21. • These are tasteless , and sparingly soluble in water. • These are usually branched and have high molecular weight. • It can be categorised into: • Structural polysacchride : includes cellulose and chitin. • Functional polysacchride : includes glycogen and starch.
  • 22. Starch: • These are found in white powder as dry state. • Tasteless and odorless. • Insoluble in water. • Made up of the lareg chain of alpha-glucose. • Generall formula is (C6H10O5)n.
  • 23.
  • 24.
  • 25. • It can be classified into: • Amylose : These have unbranched chain of glucose molecule. Soluble in hot water. • Amylopectin: These have branched chain of glucose molecule. Insoluble in water.
  • 26. H O OH H OHH OH CH2OH H O H H OHH OH CH2OH H O HH H O O H OHH OH CH2OH H H H O H OHH OH CH2OH H OH HH O O H OHH OH CH2OH H O H 1 6 5 4 3 1 2 amylose
  • 27. H O OH H OHH OH CH2OH H O H H OHH OH CH2OH H O HH H O O H OHH OH CH2 H H H O H OHH OH CH2OH H OH HH O O H OHH OH CH2OH H O H O 1 4 6 H O H OHH OH CH2OH H H H O H OHH OH CH2OH H H O 1 OH 3 4 5 2 amylopectin
  • 28. Functions of starch: • Dietry function of starch is to convert glucose into energy for body and brain. • In plants they store glucose. • Chemically modified and unmodified starch used for papermaking. • Vegetable starch mix into into water used for laundery purpose.
  • 29. Cellulose: • It is a polysacchride made up of the linear chain of several glucose molecules. • Mainly it consists of beta-glucose. • It has no taste and no odor. • Highly insoluble in water. • Digestable by herbivores. • Generall formula is (C6H10O5)n.
  • 30. Chemical structure of cellulose:
  • 31.
  • 32. Functions of cellulose: • Provide shape to plant cell wall. • Produces lignin which makes the wood of tree so strong. • Powdered cellulose are used as inactive fillers in drug tablets. • Used for textile purpose made from cotton and linen.
  • 33. GLYCOGEN: • It is also called animal starch. • It is a multibranched polyscchride. • In dry state ,present in white powder. • Insoluble in water. • Found in the form of granules in the cytosol in many cell types. • Generall formula is C24H42O21.
  • 34. • Made up of the alpha-glucose molecules, • Present in liver cells with 8%. • Present in muscles with 1%, • In kidney low amount is found.
  • 35. H O OH H OHH OH CH2OH H O H H OHH OH CH2OH H O HH H O O H OHH OH CH2 H H H O H OHH OH CH2OH H OH HH O O H OHH OH CH2OH H O H O 1 4 6 H O H OHH OH CH2OH H H H O H OHH OH CH2OH H H O 1 OH 3 4 5 2 glycogen
  • 36.
  • 37. Functions of glycogen: • The main function of glycogen is as a secondary long-term energy-storage molecule. • In liver : regulates to maintain blood glucose level. • In muscles : provide energy to muscles .
  • 38. Chitin : • A long-chain polymer of an N-acetylglucosamine. • Chitin is a modified polysaccharide that contains nitrogen; it is synthesized from units of N-acetyl-D-glucosamine. • Found in the cell walls of certain fungi and algae. • Formula = (C8H13O5N)n
  • 39.
  • 40. Functions of chitin: • It makes the cell wall of fungi and algae. • Chitin is a good inducer of defense mechanisms in plants. • It accelerates healing of wood in humans. • Chemically modified chitin used in food processing and as an additive to thicken and stablize food.