This document discusses terpenoids, which are secondary plant metabolites derived from isoprene units. It defines terpenoids and notes that they are optically active and composed of isoprene units, called isoprenoids. The document classifies terpenoids based on the number of isoprene units they contain, such as monoterpenoids containing two isoprene units. It also discusses the biosynthesis of terpenoids from acetyl CoA and mevalonic acid. In summary, the document provides background information on terpenoids, including their definition, classification, biosynthesis, and importance.
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Plants produce a vast and diverse organic compounds, which do not appear to participate directly in growth and development.These substances traditionally referred to as secondary metabolites which terpenes are one of them.
Study material for chemistry UG and PG students
Chapter No 05 Terpenoids, Study of natural product Chemistry of natural products, Pharmaceutical chemistry.
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Plants produce a vast and diverse organic compounds, which do not appear to participate directly in growth and development.These substances traditionally referred to as secondary metabolites which terpenes are one of them.
Study material for chemistry UG and PG students
Chapter No 05 Terpenoids, Study of natural product Chemistry of natural products, Pharmaceutical chemistry.
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Flavonoids are groups of polyphenolic compounds which are found in fruits, flowers, seeds & vegetable.
(named from the Latin word flavus meaning yellow, their colour in nature)
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Any substance which is made from natural or synthetic material or a combination of both used for creating pleasant odour or removed the undesired smell is known as perfumes.
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CONTENTS
INTRODUCTION
DEFFINATION
TERPENE- GENERAL INFORMATION
CHEMICAL COMPOUND
ISOPENOID OF PLANT AND ANIMAL
NATURAL CCURANCE
INDUSTRIAL PRODUCTS
NATUR OF ISOPRINOIDS
NATURAL PRODUCTS
SECONDARY METABOLITES
BRANCHED CHAIN ALCOHOL
STRUCTURAL CLASSIFICATION OF ISOPRENOIDS
HAID TO TAIL
TAIL TO TAIL
TYPES OF ISOPRENOIDES
ISOLATION AND IDENTIFICATIN OF ISOPRENOIDES
PURIFICATION
DETERMINATION
BIOSYNTHESIS OF ISOPRINOIDS
MEVOLANATED PATHWAY
NAN- MEVOLANATED PATHWAY
USES OF ISOPRENOIDES
OTHER APPLICATION
ISOPRINOID SYNTHESIS IN DNA REPLICATION AND CELL GROTH
OTHER MEMBRANE ASSOSIATED ISOPRINOIDS
CONCLUSION
REFRANCES
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2. Primary Metabolite Secondary Metabolites
1) Primary metabolites are essential
for life process. (Growth of the cells)
These are non-essential.
2)These are identified universally,
throughout the source.
These are seldom, like in some
portions of the source, like steam,
bark, etc.
3) These are produced continuously
during the growth phase and are
involved in primary metabolic
processes such as respiration and
photosynthesis, etc
These compounds do not have a
continuous production. However they
are produced during non-growth
phase of cells. (Synthetically).
4) Heavy mol.wt compounds. Low mol.wt compounds.
5) Structure cannot be
drawn.(Undefined)
Can be drawn. (Defined)
6) DNA, Proteins, carbohydrates, and
lipids are the main primary
metabolites.
Alkaloids, Terpenoid, phenolics,
sterols, steroids, essential oils and
lignins, etc
3. Definition
• Terpene – german word – terpentin –
mixture of isomeric hydrocarbon occur
in turpentine.
• The oxygenated derivatives of these
hydrocarbon like alcohol, aldehydes,
ketones were called as camphor.
• When terpenes are modified chemically
the resulting compounds are
terpenoids.
4. • Terpene represents only
hydrocarbon of molecular fomula
[C5H8]2
.
• Terpenoids with general formula
[C5H8] n as well as their
oxygenated, hydrogenated and
dehydrogenated derivatives.
• Terpenoids are optically active.
5. • The suffix ene signifies unsaturated
hydrocarbon so it is inappropriate to
include the compounds such as
alcohols, aldehydes and ketones.
• The terpenoids composed of isoprene
units they are called as isoprenoids.
• Major terphenoids occur in plant
kingdom but few obtain from other
source.
6. • Most of the fragrance component of
plant are volatile and isolated by steam
distillation is called as essential oil.
• Due to their pleasant smelling nature
the mono and sesquiterpenoids are of
considerable commercial importance
particularly in perfumery.
8. • The di and tri terpenoids are non
volatile obtained from gums and
resins of plant without perfumery
value.
• The tetra terpenoids constitute a
group of compounds called
carotenoids
• Rubber is the most important
polyterpenoid
9. Why terpenoids in pharmacy?
• Terpenoids shows
biological activity like
insecticidal, anthelmintic
and antiseptic action thus
useful in pharmacy.
10. Properties
• Colorless liquid lighter than water.
• Boils between 150 – 180 ◦ C
• Few are solids
• Optically active
• Unsaturated compound with one or
more double bond.
• It undergoes addition reaction,
Polymerization and dehydrogenation
12. Classification based on number of isoprene unit
Terpenoids no of isoprene Molecular formula
Hemiterpene or isoprene 1 C5H8
Monoterpenoids 2 C10H16
Sesquiterpenoids 3 C15 H24
Diterpenoids 4 C20 H32
Sesterterpenoids 5 C25H40
Triterpenoids 6 C 30 H48
Tetraterpenoids 8 C40H64
Polyterpenoids n [C5H8]n
13. Terpenoids subdivided into subclasses according
to number of rings present in the molecule
• Acyclic terpenoid– open chain-citral
• Monocyclic terpenoid – one ring - limonene
• Bicyclic terpenoid – two ring - camphor
• Tricyclic terpenoid- three ring
• Tetracyclic terpenoid – four ring