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Industrial Applications of
Toluene
ARTICLE WRITTEN AND PUBLISHED
BY
WWW.WORLDOFCHEMICALS.COM
Introduction
 Toluene is an aromatic hydrocarbon solvent and

natural sources of toluene include crude oil and
small quantities it is found in tolu tree.
 Toluene alternative names include
methylbenzene, toluol, anisen, phenyl
methane.Toluene is produced during the process of
making gasoline and other fuels from crude oil, in
making coke from coal, and as a by-product in the
manufacture of styrene.
Industrial Applications
 Toluene has numerous commercial and industrial

applications and is a solvent in
paints, lacquers, thinners, glues, correction fluid and
nail polish remover
 Toluene used in the printing and leather tanning
processes.
 Methylbenzene can also be used as a fullerene
indicator, and is a raw material for toluene
diisocyanate.
Toluene in carbon nanotubes, octane boosters
 Toluene as a solvent used in carbon nanotubes

like fullerenes. It is also used as cement for fine
polystyrene kits as. Biological usage of toluene
includes breaking or disrupting red blood cells in
order to extract hemoglobin in biochemistry
experiments.
 Toluene can be used as an octane booster
in gasoline fuels used in internal combustion
engines. Absolute toluene can be used as a fuel for
both two-stroke and four-stroke engines.
Toluene Cosmetic and Personal care applications
 One of the cosmetic and personal care products like

nail products containing toluene are applied to the
hard, largely impenetrable surface of the nail where a
smooth and glossy film is quickly formed upon
evaporation of the solvents.

 Methylbenzene is used to manufacture

benzene, urethane raw materials, and other organic
chemicals. It is used in the production of
pharmaceuticals, dyes, and cosmetic nail products. It
is used in agricultural sector against roundworms
and hookworms.
Toluene Natural Occurance
 Toluene occurs naturally at low levels from crude oil and

is usually produced in the processes of gasoline via a
catalytic reformer, in an ethylene cracker or making coke
from coal. It is widely used in industry, often as a
substitute for benzene.

 The methyl group which is present in methylbenzene

makes it around 25 times more reactive than benzene in
such reactions. Methylbenzene undergoes smooth
sulfonation to give p-toluenesulfonic acid, and
chlorination by Cl2 in the presence of FeCl3 to give ortho
and para isomers of chlorotoluene.
Toluene Harmful Effects
Toluene may have local as well as systemic harmful
effects. It may cause irritation of the eyes, respiratory
tract, and skin. Repeated or prolonged contact with the
liquid may cause removal of natural lipids from the skin
resulting in dry, fissured dermatitis.
Low-level, chronic exposure as well as acute exposure to
toluene may result in central nervous system depression
and decreased memory.
Other symptoms include
headache, dizziness, fatigue, muscular
weakness, drowsiness, and incoordination with
staggering gait, skin paresthesia, collapse, and coma.
Toluene Harmful Effects Cont …
 The rate of polluted gases in the atmosphere comprises

of dissolved organic compounds which affects the
environment apparently. One of the best methods to
reduce harmful gases in environment is bioreactors.
 The bioreactors are abundantly used to degrade those
substances depending upon various parameters and
suitable materials like packing material, microbes, etc.
 One such dissolved organic compound which is highly
toxic to human beings and also present in the gaseous
state is Toluene.
Toluene and Bioreactor
 A bioreactor is a vessel in which a chemical process is carried out. This process can

conducted either be aerobically or anaerobically. These bioreactors are commonly
cylindrical, capacity ranging in size from litres to cubic metres, and are made of
stainless steel material.












Bioreactor comprises of an
Air compressor
Oxygen tank
Dehumidifier
Activated carbon beds
Dynamic system for the generation of BTX vapours
Foam columns
Cell reservoir
Deformer
Controlling devices

 In the field of biochemical engineering, using various types of reactors, including an

airlift loop reactor, a bubble column reactor, a stirred tank reactor, and a jet loop
reactor etc.
Techniques used in treating Toluene
 Physiochemical treatment methods






Bio filtration
Bio degradation
Thermal oxidation
Catalytic oxidation

 All these biological treatment methods can convert toluene into





Carbon dioxide
Water
Salt
Biomass
Jet loop reactor - Volatile organic compound
degradation
 Jet loop reactor

 A jet loop reactor (JLR) contains a central draft tube inside the reactor. A bi

fluid (liquid and gas) nozzle is located at the top or bottom of the reactor in
a structure of two concentric cylinders. The gas delivered through one
cylinder is dispersed by the liquid jet stream, delivered through the other
cylinder.

 The liquid or gas can be circulated back to the reactor to increase the

concentration of the gas species in the liquid phase. In JLR toluene is
absorbed by circulating nonionic surfactants which is of polyoxyethylene
based (LA5 and LA7) Polyol- based and Surfactants.

 The toluene removal efficiency was 70 per cent in Tween 81. The removal

efficiency of toluene was not affected by Tween 81 which concentration is
observed by effects of liquid flow rate. Dissolving oxygen in the water is
found to be superior to other reactors interms of oxygen transfer rate per
unit power input.
References
 Find here Toluene chemical formula, Toluene

density, Toluene molecular weight, Toluene boiling
point
 http://www.worldofchemicals.com/wochem/pub/ch
emtoluene.html
 Toluene - Buy toluene, toluene solvents, toluene
manufacturers, toluene suppliers
 http://www.worldofchemicals.com/wocmanf/pub/fl
/chemtoluene.html

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Toluene and its industrial applications

  • 1. Industrial Applications of Toluene ARTICLE WRITTEN AND PUBLISHED BY WWW.WORLDOFCHEMICALS.COM
  • 2. Introduction  Toluene is an aromatic hydrocarbon solvent and natural sources of toluene include crude oil and small quantities it is found in tolu tree.  Toluene alternative names include methylbenzene, toluol, anisen, phenyl methane.Toluene is produced during the process of making gasoline and other fuels from crude oil, in making coke from coal, and as a by-product in the manufacture of styrene.
  • 3. Industrial Applications  Toluene has numerous commercial and industrial applications and is a solvent in paints, lacquers, thinners, glues, correction fluid and nail polish remover  Toluene used in the printing and leather tanning processes.  Methylbenzene can also be used as a fullerene indicator, and is a raw material for toluene diisocyanate.
  • 4. Toluene in carbon nanotubes, octane boosters  Toluene as a solvent used in carbon nanotubes like fullerenes. It is also used as cement for fine polystyrene kits as. Biological usage of toluene includes breaking or disrupting red blood cells in order to extract hemoglobin in biochemistry experiments.  Toluene can be used as an octane booster in gasoline fuels used in internal combustion engines. Absolute toluene can be used as a fuel for both two-stroke and four-stroke engines.
  • 5. Toluene Cosmetic and Personal care applications  One of the cosmetic and personal care products like nail products containing toluene are applied to the hard, largely impenetrable surface of the nail where a smooth and glossy film is quickly formed upon evaporation of the solvents.  Methylbenzene is used to manufacture benzene, urethane raw materials, and other organic chemicals. It is used in the production of pharmaceuticals, dyes, and cosmetic nail products. It is used in agricultural sector against roundworms and hookworms.
  • 6. Toluene Natural Occurance  Toluene occurs naturally at low levels from crude oil and is usually produced in the processes of gasoline via a catalytic reformer, in an ethylene cracker or making coke from coal. It is widely used in industry, often as a substitute for benzene.  The methyl group which is present in methylbenzene makes it around 25 times more reactive than benzene in such reactions. Methylbenzene undergoes smooth sulfonation to give p-toluenesulfonic acid, and chlorination by Cl2 in the presence of FeCl3 to give ortho and para isomers of chlorotoluene.
  • 7. Toluene Harmful Effects Toluene may have local as well as systemic harmful effects. It may cause irritation of the eyes, respiratory tract, and skin. Repeated or prolonged contact with the liquid may cause removal of natural lipids from the skin resulting in dry, fissured dermatitis. Low-level, chronic exposure as well as acute exposure to toluene may result in central nervous system depression and decreased memory. Other symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness, and incoordination with staggering gait, skin paresthesia, collapse, and coma.
  • 8. Toluene Harmful Effects Cont …  The rate of polluted gases in the atmosphere comprises of dissolved organic compounds which affects the environment apparently. One of the best methods to reduce harmful gases in environment is bioreactors.  The bioreactors are abundantly used to degrade those substances depending upon various parameters and suitable materials like packing material, microbes, etc.  One such dissolved organic compound which is highly toxic to human beings and also present in the gaseous state is Toluene.
  • 9. Toluene and Bioreactor  A bioreactor is a vessel in which a chemical process is carried out. This process can conducted either be aerobically or anaerobically. These bioreactors are commonly cylindrical, capacity ranging in size from litres to cubic metres, and are made of stainless steel material.           Bioreactor comprises of an Air compressor Oxygen tank Dehumidifier Activated carbon beds Dynamic system for the generation of BTX vapours Foam columns Cell reservoir Deformer Controlling devices  In the field of biochemical engineering, using various types of reactors, including an airlift loop reactor, a bubble column reactor, a stirred tank reactor, and a jet loop reactor etc.
  • 10. Techniques used in treating Toluene  Physiochemical treatment methods     Bio filtration Bio degradation Thermal oxidation Catalytic oxidation  All these biological treatment methods can convert toluene into     Carbon dioxide Water Salt Biomass
  • 11. Jet loop reactor - Volatile organic compound degradation  Jet loop reactor  A jet loop reactor (JLR) contains a central draft tube inside the reactor. A bi fluid (liquid and gas) nozzle is located at the top or bottom of the reactor in a structure of two concentric cylinders. The gas delivered through one cylinder is dispersed by the liquid jet stream, delivered through the other cylinder.  The liquid or gas can be circulated back to the reactor to increase the concentration of the gas species in the liquid phase. In JLR toluene is absorbed by circulating nonionic surfactants which is of polyoxyethylene based (LA5 and LA7) Polyol- based and Surfactants.  The toluene removal efficiency was 70 per cent in Tween 81. The removal efficiency of toluene was not affected by Tween 81 which concentration is observed by effects of liquid flow rate. Dissolving oxygen in the water is found to be superior to other reactors interms of oxygen transfer rate per unit power input.
  • 12. References  Find here Toluene chemical formula, Toluene density, Toluene molecular weight, Toluene boiling point  http://www.worldofchemicals.com/wochem/pub/ch emtoluene.html  Toluene - Buy toluene, toluene solvents, toluene manufacturers, toluene suppliers  http://www.worldofchemicals.com/wocmanf/pub/fl /chemtoluene.html