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 Diethyl Ether is an ether class of organic
compound. Basically, it has characteristics of
colourless, volatile, sweet solvent-like smelling
chemical. Diethyl Ether finds common use as a
solvent as well as in various household products.
 It is a colourless, highly volatile flammable
liquid. It is commonly used as a solvent in
laboratories and as a starting fluid for some
engines. Diethyl ether is also a common solvent
for the Grignard reaction in addition to other
reactions involving organometallic reagents.
www.worldofchemicals.com
 It is used extensively in the chemical industry and as an
aerosol propellant. Diethyl ether was formerly used as a general
anaesthetic, until non-flammable drugs were developed, such as
halothane. It has been used as a recreational drug to cause
intoxication.
 It has been used for decades as an energy source in various
countries like China, Japan, Korea, Egypt, and Brazil.
 Domestically it can be produced from a variety of feedstocks,
including biogas from organic waste. Because of its lack of carbon-
to-carbon bonds, using Diethyl ether as an alternative to diesel
can virtually eliminate particulate emissions and potentially
negate the need for costly diesel particulate filters. Diethyl ether
has a high cetane number of 85-96 and is used as a starting fluid,
in combination with petroleum distillates for gasoline and Diesel
engines because of its high volatility and low flash point.
www.worldofchemicals.com
 Diethyl ether can be prepared both in
laboratories and on an industrial scale by the
process called acid ether synthesis.
 Ethanol is mixed with a strong acid like sulfuric
acid (H2SO4).This strong acid dissociates in the
aqueous environment producing
H3O+(hydronium ions).
 Later a hydrogen ion protonates the
electronegative oxygen atom of the ethanol,
giving the ethanol molecule a positive charge.
C2H5OH + H3O+ → C2H5OH2
+ + H2O
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 A nucleophilic oxygen atom of unprotonated ethanol displaces a
water molecule from the protonated (electrophilic) ethanol
molecule, producing water, a hydrogen ion and diethyl ether.
C2H5OH2
+ + CH3CH2OH → H2O + H+ + C2H5OC2H5
 This reaction must be carried out at temperatures lower than
150°C in order to ensure that an elimination product (ethylene) is
not a product of the reaction. At higher temperatures, ethanol will
dehydrate to form ethylene.
 The reaction to make diethyl ether is reversible, so eventually, an
equilibrium between reactants and products is achieved. Getting a
good yield of ether, which in turn requires that ether is distilled out
of the reaction mixture before it reverts to ethanol.
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ThankYou
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Industrial production of diethyl ether

  • 2.  Diethyl Ether is an ether class of organic compound. Basically, it has characteristics of colourless, volatile, sweet solvent-like smelling chemical. Diethyl Ether finds common use as a solvent as well as in various household products.  It is a colourless, highly volatile flammable liquid. It is commonly used as a solvent in laboratories and as a starting fluid for some engines. Diethyl ether is also a common solvent for the Grignard reaction in addition to other reactions involving organometallic reagents. www.worldofchemicals.com
  • 3.  It is used extensively in the chemical industry and as an aerosol propellant. Diethyl ether was formerly used as a general anaesthetic, until non-flammable drugs were developed, such as halothane. It has been used as a recreational drug to cause intoxication.  It has been used for decades as an energy source in various countries like China, Japan, Korea, Egypt, and Brazil.  Domestically it can be produced from a variety of feedstocks, including biogas from organic waste. Because of its lack of carbon- to-carbon bonds, using Diethyl ether as an alternative to diesel can virtually eliminate particulate emissions and potentially negate the need for costly diesel particulate filters. Diethyl ether has a high cetane number of 85-96 and is used as a starting fluid, in combination with petroleum distillates for gasoline and Diesel engines because of its high volatility and low flash point. www.worldofchemicals.com
  • 4.  Diethyl ether can be prepared both in laboratories and on an industrial scale by the process called acid ether synthesis.  Ethanol is mixed with a strong acid like sulfuric acid (H2SO4).This strong acid dissociates in the aqueous environment producing H3O+(hydronium ions).  Later a hydrogen ion protonates the electronegative oxygen atom of the ethanol, giving the ethanol molecule a positive charge. C2H5OH + H3O+ → C2H5OH2 + + H2O www.worldofchemicals.com
  • 5.  A nucleophilic oxygen atom of unprotonated ethanol displaces a water molecule from the protonated (electrophilic) ethanol molecule, producing water, a hydrogen ion and diethyl ether. C2H5OH2 + + CH3CH2OH → H2O + H+ + C2H5OC2H5  This reaction must be carried out at temperatures lower than 150°C in order to ensure that an elimination product (ethylene) is not a product of the reaction. At higher temperatures, ethanol will dehydrate to form ethylene.  The reaction to make diethyl ether is reversible, so eventually, an equilibrium between reactants and products is achieved. Getting a good yield of ether, which in turn requires that ether is distilled out of the reaction mixture before it reverts to ethanol. www.worldofchemicals.com
  • 6. ThankYou To read this article follow the link: http://www.worldofchemicals.com/556/chemistry-articles/industrial-production-of-diethyl-ether.html www.worldofchemicals.com