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Stoichiometry, The Mole,
and Quantitative
                         Review our discussion of
Chemistry              mathematical applications to
                              chemistry: The mole and
                               Dimensional analysis.


•   How many atoms are
    in 12.00 grams of Iron?




                                      Nylon Rope
We tie together the concepts of Formula
        writing, identifying reactions, and
              quantitative chemistry

If we take a look again at the reaction
from the Types of Chemical Reactions
chapter between Cl2 and NaBr, this
time from a quantitative standpoint.

 Cl2 + 2 NaBr           Br2 + 2 NaCl



                                          Polypropylene knife handles
A Sample Problem...
                   Cl2
 +
   2 NaBr
 
    Br2
 +
   2 NaCl


If we react 5.00 grams of NaBr with excess Cl2, how many grams of Br2
will be formed?

Construct a pathway…

Grams Reactant-->Moles Reactant-->Moles Product-->Grams Product

The Solution...

5.00g NaBr x 1 mole NaBr/102.90 g NaBr x 1 mole Br2/2 mole NaBr x
159.80g Br2/1 mole Br2=

3.88 g Br2
Try This One...
     CaCl2
+
 Na2CO3        
 
   CaCO3
 + 2 NaCl

•   How many grams of CaCO3 will be formed if 8.00
    grams of CaCl2 are completely reacted with
    Na2CO3?


            Limestone formation
               in South Africa
Limiting Reactant Problems
     Ideally, each reactant in a reaction is
  completely used up. Sometimes, however,
   one reactant is used up before the other
   and the reaction stops. This is called the
               Limiting Reactant.

                   Let’s Take Another Look


         Cl2
 +
    2 NaBr
 
    Br2
 +
     2 NaCl
The Solution...
If we reacted 5.00 g of NaBr with 8.00 g of Cl2, how many grams of Br2 will be formed?
What is the limiting reactant? How many grams of excess reactant remain?

5.00g NaBr x 1 mole NaBr/102.90g NaBr x 1 mole Br2/2 mole NaBr x 159.80g Br2/1mole
Br2=

3.88g Br2
   
       *NaBr is the Limiting Reactant


8.00g Cl2 x 1 mole Cl2/70.90g Cl2 x 1 mole Cl2/1mole Br2 x 159.80g Br2/1 mole Br2=

18.03 g Br2
 
       *Cl2 is the excess reactant


3.88g Br2 x 1mole Br2/159.80 g Br2 x 1 mole Cl2/1mole Br2 x 70.90 g Cl2/1mole Cl2=

1.72 g Cl2 needed

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Stoichiometry

  • 1. Stoichiometry, The Mole, and Quantitative Review our discussion of Chemistry mathematical applications to chemistry: The mole and Dimensional analysis. • How many atoms are in 12.00 grams of Iron? Nylon Rope
  • 2. We tie together the concepts of Formula writing, identifying reactions, and quantitative chemistry If we take a look again at the reaction from the Types of Chemical Reactions chapter between Cl2 and NaBr, this time from a quantitative standpoint. Cl2 + 2 NaBr Br2 + 2 NaCl Polypropylene knife handles
  • 3. A Sample Problem... Cl2 + 2 NaBr Br2 + 2 NaCl If we react 5.00 grams of NaBr with excess Cl2, how many grams of Br2 will be formed? Construct a pathway… Grams Reactant-->Moles Reactant-->Moles Product-->Grams Product The Solution... 5.00g NaBr x 1 mole NaBr/102.90 g NaBr x 1 mole Br2/2 mole NaBr x 159.80g Br2/1 mole Br2= 3.88 g Br2
  • 4. Try This One... CaCl2 + Na2CO3 CaCO3 + 2 NaCl • How many grams of CaCO3 will be formed if 8.00 grams of CaCl2 are completely reacted with Na2CO3? Limestone formation in South Africa
  • 5. Limiting Reactant Problems Ideally, each reactant in a reaction is completely used up. Sometimes, however, one reactant is used up before the other and the reaction stops. This is called the Limiting Reactant. Let’s Take Another Look Cl2 + 2 NaBr Br2 + 2 NaCl
  • 6. The Solution... If we reacted 5.00 g of NaBr with 8.00 g of Cl2, how many grams of Br2 will be formed? What is the limiting reactant? How many grams of excess reactant remain? 5.00g NaBr x 1 mole NaBr/102.90g NaBr x 1 mole Br2/2 mole NaBr x 159.80g Br2/1mole Br2= 3.88g Br2 *NaBr is the Limiting Reactant 8.00g Cl2 x 1 mole Cl2/70.90g Cl2 x 1 mole Cl2/1mole Br2 x 159.80g Br2/1 mole Br2= 18.03 g Br2 *Cl2 is the excess reactant 3.88g Br2 x 1mole Br2/159.80 g Br2 x 1 mole Cl2/1mole Br2 x 70.90 g Cl2/1mole Cl2= 1.72 g Cl2 needed

Editor's Notes

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