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Ozone Layer Depletion
Ozone Layer Facts...
Ozone Layer Depletion

 •
Lower stratosphere (above troposphere)

 •
Allows life to exist on Earth

 •
Serves as UV filter: 95% of harmful rays

 •
Without it: increased risk of cataracts,
   sunburn, skin cancer
A Closer Look at the causes of
             depletion
Depletion Caused By:

 •
 CFC’s, Halons, Bromine

 •
 CFC’s: Tom Midgely, GM chemist

 •
 Uses: refrigerants, propellants,
    cleaners, fumigants, blowing agents
    for Styrofoam

 •
 Inactive, easy to make, $28 billion
    industry: duPont lead producer at the
    time
How was the damage
             discovered?
•
Sherwood Rowland and Mario
  Molina in the 1970’s

•
Investigated years of atmospheric
  data rejected by computers

•
Shocked scientific community & the
  public

•
Powerful lobby against them
Some Atmospheric
Formation
of
Ozone            Chemistry...
O2
+
UV
light
‐>
2
O
O
+
O2
+
M
‐>
O3
+
M
(where
M

indicates
conservation
of
energy

and
momentum)

Anthropogenic
Destruction
of

Ozone
by
CFC’s
Cl
+
O3
‐>
ClO
+
O2
ClO
+
O
‐>
Cl
+
O2
Polar Vortex and The
                Cause of Antarctic
                       Hole

               •
 1984 Satellite data: 40-50% of Antarctic ozone lost
                  during spring and summer.

               •
 Polar vortex. Dark, frigid winter months: strong winds
                  create swirling masses of air in stratosphere.

               •
 Winds create suspended microscopic ice crystals that
                  serve as templates for CFC’s to catalyze breakdown of
                  ozone.
Polar Vortex
               •
 Similar, but less dramatic in Arctic.
Montreal Protocol of 1987

• Identified CFC’s for elimination first
• Less harmful HCFC’s and HFC’s later
• Bromine, Halons, Fumigants
• Multinational Fund
• Significant repair of ozone layer: 2050
The Larger Questions...
• Why was the Montreal Protocol so
  successful?
• Why has the Kyoto Protocol been less
  successful?
• Where is the line dividing economic
  prosperity and the environment?

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Ozone Layer Depletion

  • 2. Ozone Layer Facts... Ozone Layer Depletion • Lower stratosphere (above troposphere) • Allows life to exist on Earth • Serves as UV filter: 95% of harmful rays • Without it: increased risk of cataracts, sunburn, skin cancer
  • 3. A Closer Look at the causes of depletion Depletion Caused By: • CFC’s, Halons, Bromine • CFC’s: Tom Midgely, GM chemist • Uses: refrigerants, propellants, cleaners, fumigants, blowing agents for Styrofoam • Inactive, easy to make, $28 billion industry: duPont lead producer at the time
  • 4. How was the damage discovered? • Sherwood Rowland and Mario Molina in the 1970’s • Investigated years of atmospheric data rejected by computers • Shocked scientific community & the public • Powerful lobby against them
  • 5. Some Atmospheric Formation
of
Ozone Chemistry... O2
+
UV
light
‐>
2
O O
+
O2
+
M
‐>
O3
+
M
(where
M
 indicates
conservation
of
energy
 and
momentum) Anthropogenic
Destruction
of
 Ozone
by
CFC’s Cl
+
O3
‐>
ClO
+
O2 ClO
+
O
‐>
Cl
+
O2
  • 6. Polar Vortex and The Cause of Antarctic Hole • 1984 Satellite data: 40-50% of Antarctic ozone lost during spring and summer. • Polar vortex. Dark, frigid winter months: strong winds create swirling masses of air in stratosphere. • Winds create suspended microscopic ice crystals that serve as templates for CFC’s to catalyze breakdown of ozone. Polar Vortex • Similar, but less dramatic in Arctic.
  • 7. Montreal Protocol of 1987 • Identified CFC’s for elimination first • Less harmful HCFC’s and HFC’s later • Bromine, Halons, Fumigants • Multinational Fund • Significant repair of ozone layer: 2050
  • 8. The Larger Questions... • Why was the Montreal Protocol so successful? • Why has the Kyoto Protocol been less successful? • Where is the line dividing economic prosperity and the environment?

Editor's Notes

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