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ALKENE
C C Atom carbon 2, 4 Atom carbon 2, 4
C C Atom carbon 2, 4 Atom carbon 2, 4
C C Atom carbon 2, 6 Atom carbon 2, 6
H Atom hydrogen 1 C C Atom carbon 2, 6 Atom carbon 2, 6
H Atom hydrogen 2 C C Atom carbon 2, 7 Atom carbon 2, 6
H H Atom hydrogen 2 C C Atom carbon 2, 7 Atom carbon 2, 6
H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 6
H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 6
H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 7
H H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 7
H H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 8
It is classified as unsaturated  hydrocarbons. (An unsaturated hydrocarbon contains at least one double covalent bonds between carbon atoms). Alkenes are hydrocarbons with the general formula : CnH2n	     where n =  2, 3, ……, ∞ Every alkene has a carbon-carbon double covalent bond, C = C    in its molecule.
H H H C C H Example : Formation of an ethene molecule (a) Ethene, C2H4 H H C C H H  Structural formula for ethane, C2H4 ,[object Object],atoms in a molecule because       …………………….  bond is formed between two carbon atoms. double
Naming of Alkenes The name of straight chain alkenes are also made up of two component parts : (i) Stem/root : indicates the number of carbon atoms in the longest continuous carbon chain. The names of stems for the first nine straight alkanes are : eth, prop, but, pent, hex, hept, oct, non anddec (ii) Suffix/ ending : indicates the group of the compound. For alkene, the suffix is ‘ene’ because  it belongs to the alkene group.
4.Naming of Alkenes a)   Naming the straight chainalkene : (i)  Determine the longest carbon chain containing double bond. give the stem name according to the number of carbon atoms ;  eth, prop, but, pent, hex, hept, oct, non anddec (ii)   Add  the suffix  “ene” at the end of the name. (iii) Number the carbon atoms from the end nearer to the double bond and give the double bond the smaller number.
[object Object],Activity 6 :- Complete the  table below : 5.Physical properties of Alkenes are similar to alkanes
Activity 7 :- Complete the following table :
[object Object],Ethene, propene and but-1-ene are ………………….. Pent-1-ene  to non-1-ene are ………………….. and dec-1-ene is ………………….. ,[object Object]
 As the number of carbon atoms per molecule increases, the molecular size of alkene …………………., the ………………….. the intermolecular  forces, more ………………….. energy is needed to ………………….. this forces, the melting and boiling points …………………..gas liquid solid Low  weak Low  increases Stronger  overcome Heat  increases
6.Chemical properties of Alkenes more (a) Alkenes are chemically ………………….. reactive than alkanes because of the existence of double covalent bond between two carbon  atoms. Almost all of the chemical reactions of alkene occur at the double bond. (b) The chemical reactions of alkenes are : I : Combustion Reaction ,[object Object],Alkene	+	O2	->	CO2	+	H2O   Carbon dioxide water
Activity 8 :- 1.Balance the following equations : C2H4	  +   	O2	->      CO2	+	H2O C3H6       +  	O2	->	CO2	+	H2O C4H8	  +  	O2	->	CO2	+	H2O 2.Write the balanced equation for combustion reaction of : Pentene:……………………………………………………… Hexene:……………………………………………………… Octene:…………………………………………………………
[object Object],Example :  2C2H4+ 3O2 	2C   + 2CO   +    2H2O or C2H4+ 2O22CO  +    2H2O
Addition reaction II : Addition Reaction ,[object Object],An addition reaction is a reaction in which other atoms are added to each carbon atom of the ……………….. bond,  [C = C ] to form ………………..  covalent bond product [ C - C ]. double  Single                           C = C             +   XY                  	C     C XY                (unsaturated)                                         (saturated )
Simple molecules like hydrogen, H2 ; hydrogen chloride, HCl ; water, H2O or halogens, [F2, Cl2, Br2, I2]  can be added to the double bond.   (i)	Addition of  Hydrogen (Hydrogenation) ,[object Object]
Hydrogenation is used to prepare an alkane (saturated compound) from an alkene (unsaturated compound) in industry.Example :  Ni / Pt 180 C Ethene	                                                          Ethane +     H2
(ii)	Addition of  Halogen (Halogenation) ,[object Object],(nocatalystorultraviolet light needed) Example :  + Br2 Ethene                        (bromine water)  ,[object Object]
This reaction is used to distiguish a saturated hydrocarbon and unsaturated hydrocarbon. 1,2-dibromoethane
C2H4 gas Bromine water (nocatalystorultraviolet light needed)
before after alkene Alkane
Which is alkene?
iii)Addition of  Hydrogen Halide [ HX HCl, HBr, HI ] ,[object Object],Example :                    C2H4     	+   	HCl       ->         C2H5Cl  Ethene                  Hydrogen chloride         Chloroethane                   C3H6     	+   	HBr            ->          PropeneHydrogen bromide        ………………….
Activity 9 :- Complete the equation and draw the structural formulae for all the reactants and products in the equation below : 1	(a)	C3H6   +   H2   ->   C3H8 	(b)	C4H8   +   H2   ->   ………. 	(c)	……….   +   H2   ->   C6H14 2	(a)	C3H6   +   Br2   ->   C3H6Br2 (b)	C4H8   +   Cl2   ->   ………. 	(c)	……….   +   I2   ->   C6H12I2
iv)Addition of Oxidizing agent : (Oxidation reaction) ,[object Object]
AcidifiedPotassium dichroromate(VI), K2Cr2O7 solution
In this reaction, two hydroxyl, -OH  groups are added to the carbon-carbon  ……………………  in an alkene molecule.
An alkene……………………  the ………………… colour of acidified potassium manganate(VII)solution //the orangesolution of acidified Potassium dicrhoromate(VI), K2Cr2O7turns to ……………………This reaction is used to distiguish a ……………………   hydrocarbon and ……………………  hydrocarbon double bond Decolorized  purple green saturated unsaturated
Example : KMnO4(aq) [Purple] Alkene Colourless KMnO4 C2H6 gas C2H4   +   H2O    +    [O]      ->    C2H4(OH)2 Ethene                                             	Ethan-1,2-diol colourless
Activity10 :- Propan-1,2-diol Ethan-1,2-diol ☺Complete the following  equation : (a) C3H6     +          H2O	    + 	[O]       ->   C3H6(OH)2 H     H (b)    H      C = C      H       +     H2O     +   [O]    -> H H H H C C OH OH
KMnO4
v)Addition of  Water (Hydration) ,[object Object],H3PO4 300 C / 60 atm Alkene	+	H2O			Alcohol Example : C2H4      +      H2O                       	C2H5OH  Etheneethanol H3PO4 300 C / 60 atm
alkene alcohol
Activity 11 :- ☺Complete the following  equation  H3PO4 300 C / 60 atm C3H6     +          H2O	  H3PO4 300 C / 60 atm +H20
[object Object],H3PO4 300 C / 60 atm CnH2n     +   H2O(g)                                 CnH2n+1OH   Alcohol  Alkene Example : C4H8      +    H2O                        H3PO4 300 C / 60 atm Butene
vi)Addition Polymerisation reaction ,[object Object]
The smallrepeating units of molecules that join together to form polymer are called …………………………polymer monomer n Ethene Polythene

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Alkane

  • 2.
  • 3. C C Atom carbon 2, 4 Atom carbon 2, 4
  • 4. C C Atom carbon 2, 4 Atom carbon 2, 4
  • 5. C C Atom carbon 2, 6 Atom carbon 2, 6
  • 6. H Atom hydrogen 1 C C Atom carbon 2, 6 Atom carbon 2, 6
  • 7. H Atom hydrogen 2 C C Atom carbon 2, 7 Atom carbon 2, 6
  • 8. H H Atom hydrogen 2 C C Atom carbon 2, 7 Atom carbon 2, 6
  • 9. H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 6
  • 10. H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 6
  • 11. H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 7
  • 12. H H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 7
  • 13. H H H H Atom hydrogen 2 C C Atom carbon 2, 8 Atom carbon 2, 8
  • 14. It is classified as unsaturated hydrocarbons. (An unsaturated hydrocarbon contains at least one double covalent bonds between carbon atoms). Alkenes are hydrocarbons with the general formula : CnH2n where n = 2, 3, ……, ∞ Every alkene has a carbon-carbon double covalent bond, C = C in its molecule.
  • 15.
  • 16. Naming of Alkenes The name of straight chain alkenes are also made up of two component parts : (i) Stem/root : indicates the number of carbon atoms in the longest continuous carbon chain. The names of stems for the first nine straight alkanes are : eth, prop, but, pent, hex, hept, oct, non anddec (ii) Suffix/ ending : indicates the group of the compound. For alkene, the suffix is ‘ene’ because it belongs to the alkene group.
  • 17. 4.Naming of Alkenes a) Naming the straight chainalkene : (i) Determine the longest carbon chain containing double bond. give the stem name according to the number of carbon atoms ; eth, prop, but, pent, hex, hept, oct, non anddec (ii) Add the suffix “ene” at the end of the name. (iii) Number the carbon atoms from the end nearer to the double bond and give the double bond the smaller number.
  • 18.
  • 19. Activity 7 :- Complete the following table :
  • 20.
  • 21. As the number of carbon atoms per molecule increases, the molecular size of alkene …………………., the ………………….. the intermolecular forces, more ………………….. energy is needed to ………………….. this forces, the melting and boiling points …………………..gas liquid solid Low weak Low increases Stronger overcome Heat increases
  • 22.
  • 23. Activity 8 :- 1.Balance the following equations : C2H4 + O2 -> CO2 + H2O C3H6 + O2 -> CO2 + H2O C4H8 + O2 -> CO2 + H2O 2.Write the balanced equation for combustion reaction of : Pentene:……………………………………………………… Hexene:……………………………………………………… Octene:…………………………………………………………
  • 24.
  • 25.
  • 26.
  • 27.
  • 28.
  • 29. Hydrogenation is used to prepare an alkane (saturated compound) from an alkene (unsaturated compound) in industry.Example : Ni / Pt 180 C Ethene Ethane + H2
  • 30.
  • 31.
  • 32. This reaction is used to distiguish a saturated hydrocarbon and unsaturated hydrocarbon. 1,2-dibromoethane
  • 33. C2H4 gas Bromine water (nocatalystorultraviolet light needed)
  • 36.
  • 37.
  • 38. Activity 9 :- Complete the equation and draw the structural formulae for all the reactants and products in the equation below : 1 (a) C3H6 + H2 -> C3H8 (b) C4H8 + H2 -> ………. (c) ………. + H2 -> C6H14 2 (a) C3H6 + Br2 -> C3H6Br2 (b) C4H8 + Cl2 -> ………. (c) ………. + I2 -> C6H12I2
  • 39.
  • 41. In this reaction, two hydroxyl, -OH groups are added to the carbon-carbon …………………… in an alkene molecule.
  • 42. An alkene…………………… the ………………… colour of acidified potassium manganate(VII)solution //the orangesolution of acidified Potassium dicrhoromate(VI), K2Cr2O7turns to ……………………This reaction is used to distiguish a …………………… hydrocarbon and …………………… hydrocarbon double bond Decolorized purple green saturated unsaturated
  • 43. Example : KMnO4(aq) [Purple] Alkene Colourless KMnO4 C2H6 gas C2H4 + H2O + [O] -> C2H4(OH)2 Ethene Ethan-1,2-diol colourless
  • 44. Activity10 :- Propan-1,2-diol Ethan-1,2-diol ☺Complete the following equation : (a) C3H6 + H2O + [O] -> C3H6(OH)2 H H (b) H C = C H + H2O + [O] -> H H H H C C OH OH
  • 45. KMnO4
  • 46.
  • 48.
  • 49. Activity 11 :- ☺Complete the following equation H3PO4 300 C / 60 atm C3H6 + H2O H3PO4 300 C / 60 atm +H20
  • 50.
  • 51.
  • 52. The smallrepeating units of molecules that join together to form polymer are called …………………………polymer monomer n Ethene Polythene
  • 53.
  • 54.
  • 55.
  • 56.
  • 57. Activity 12 :- ☺Polymerisation of propene, C3H6 n propene
  • 59. COMPARING PROPERTIES OF ALKANE WITH ALKENE (Using hexane and hexene in the laboratory)