6 The Born Haber Cycle

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The Born-Haber cycle summarizes the standard enthalpy changes that occur during the formation of an ionic crystal from its gaseous constituent elements. It relates the standard enthalpy of sublimation, bond dissociation, electron affinity, and lattice energy to the standard enthalpy of atomization through Hess's law. For example, in forming NaCl, the standard enthalpy of atomization for sodium and chlorine contributes -411 kJ, which is balanced by the energy absorbed in ion formation, bond breaking, and crystal lattice formation.

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-411 = 109 + 121 + 449 – 364 +  H l Ө Where  H l Ө = standard lattice energy of NaCl = -726 KJ/mol

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Electrochemistry Basics Table of Contents 1. Introduction 2. Voltaic Cells-Galvanic Cells 3. Cell Potential 4. Balancing Redox Reactions 5. Rules for Assigning Oxidation states 6. Additional Materials 6.1. I. Conversion 6.2. II. Free Energy & Cell Potential 6.3. III. Nernst equation 6.4. At Equilibrium 7. Terminology 8. Reference 9. Outside Links 10. Contributors As the name suggests, electrochemistry is the study of changes that cause electrons to move. This movement of electrons is called electricity. In electrochemistry, electricity can be generated by movements of electrons from one element to another in a reaction known as a redox reaction or oxidation-reduction react

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