In this study, heavy metals (Cd, Pb, Cr, Zn, Cu and Ni) concentrations were determined in soil samples taken from Pilafu, Shiwa, Fadama-rake and Damdrai along Hong major road using Atomic absorption spectrophotometer. The determined concentrations were used to investigate their influence on human health risk through ingestion, inhalation and dermal exposure path ways. The result revealed that the extent of human health risk varied with exposure path ways, Metal species and sample area. The target hazard quotient for all the elements through each exposure path way were observed to be >1, except Zn in ingestion for adults and in dermal for children and also Cu for children in dermal. However, the health index values for adults were observed to be much higher than the children for THQinh and THQdermal. But for THQing the HI values for children were observed to be higher than the adults. While in inhalation exposure path way all the cancer risk index values were observed to be higher in adults than in children except Ni which is higher in children than in adults. The combine effect for each exposure path way shows high possibility of carcinogenic risk by inhalation route. Indicating some concern about the expansion of unregulated settlements along heavy traffic highways.
This document is a seminar report on arsenic contamination of groundwater submitted by Mayank Saxena to the Department of Civil Engineering at IIT Banaras Hindu University under the guidance of Prof. Devendra Mohan. The report reviews the nature and health impacts of arsenic contamination globally, with a focus on Asia. It discusses the physical and chemical properties of arsenic, how it naturally contaminates groundwater, and its distribution across various continents and regions including Asia, Europe, Australia, North America, and South America. Areas heavily affected in Asia include Bangladesh, West Bengal in India, parts of China, Pakistan, and others.
Occurrence and classification and function of alkaloidsJasmineJuliet
ย
Alkaloids introduction, Alkaloids classification, Alkaloids function, pharmaceutical applications of alkaloids, Examples of alkaloids, Some review questions related to alkaloids.
Bhasmas and gutikas are Ayurvedic medicinal preparations. Bhasmas involve calcining metals, minerals, or animal products through a special process to create fine powders. Their preparation is a multi-step process involving purification and repeated grinding and sealing in cow dung pits. Gutikas are pill preparations made by combining plant, mineral, or animal drugs along with binders. They are produced through a process of grinding ingredients into a paste and rolling into pills, which can be used for up to two years. Both bhasmas and gutikas aim to provide stable, potent forms of ingredients for medical use according to Ayurvedic principles.
The document discusses the heterocyclic compound pyrrole. It begins by introducing heterocyclic compounds and classifying pyrrole as a five-membered heterocyclic compound containing one nitrogen atom. The structure of pyrrole is described as aromatic with delocalized pi electrons. Pyrrole can be prepared through various methods including from furan or by the Paal-Knorr synthesis. Pyrrole exhibits properties of both a weak acid and base and undergoes electrophilic aromatic substitution. Important medicinal compounds containing pyrrole rings include procyclidine, an anti-muscarinic drug.
Heterocyclic compounds _ Organic Chemistry _ B. Pharm.AZCPh
ย
This document discusses the properties, synthesis, reactions, and medicinal uses of several aromatic heterocyclic compounds including pyrrole, furan, thiophene, pyrazole, imidazole, oxazole, thiazole, pyridine, azepines, quinoline, and isoquinoline. For each compound, the key topics covered are their aromatic properties, common methods of synthesis such as the Paal-Knorr reaction and Hantzsch synthesis, typical reactions like electrophilic substitution and reduction, and some medicinal applications.
This document summarizes the synthesis of 7-Hydroxy-4-Methyl Coumarin via the Pechmann condensation reaction of resorcinol and ethyl acetoacetate in the presence of concentrated sulfuric acid. Coumarins are an important class of compounds that are found in plants and have various medical applications such as antimicrobial and antitumor properties. The procedure involves cooling concentrated sulfuric acid to below 5ยฐC and adding a solution of resorcinol and ethyl acetoacetate dropwise, followed by workup to obtain an impure product that is recrystallized from ethanol.
The document discusses f-block elements, which are elements where extra electrons fill the (n-2)f orbitals. They are classified into two blocks: lanthanides which have electrons filling the 4f orbitals, and actinides which have electrons filling the 5f orbitals. The lanthanides include elements from lanthanum to lutetium, which have electronic configurations of (n-2)f1-14(n-1)d0-1ns2. The actinides include elements from actinium to lawrencium. They are radioactive, show various oxidation states, and react with water and acids to produce hydrogen gas.
This document discusses heavy metals and provides information on several specific heavy metals. It lists the densities of common heavy metals and substances, with mercury, lead, and cadmium among the heaviest. Heavy metals are defined as having densities over 5g/cm3 and occurring in the middle to bottom of the periodic table. The document then discusses the bioaccumulation and biomagnification of heavy metals in organisms and food chains. It also explains that heavy metals are more toxic when bonded to short carbon chains. Information is provided on the sources, toxicity and health effects of cadmium, chromium, arsenic, and lead in the environment and human body.
This document is a seminar report on arsenic contamination of groundwater submitted by Mayank Saxena to the Department of Civil Engineering at IIT Banaras Hindu University under the guidance of Prof. Devendra Mohan. The report reviews the nature and health impacts of arsenic contamination globally, with a focus on Asia. It discusses the physical and chemical properties of arsenic, how it naturally contaminates groundwater, and its distribution across various continents and regions including Asia, Europe, Australia, North America, and South America. Areas heavily affected in Asia include Bangladesh, West Bengal in India, parts of China, Pakistan, and others.
Occurrence and classification and function of alkaloidsJasmineJuliet
ย
Alkaloids introduction, Alkaloids classification, Alkaloids function, pharmaceutical applications of alkaloids, Examples of alkaloids, Some review questions related to alkaloids.
Bhasmas and gutikas are Ayurvedic medicinal preparations. Bhasmas involve calcining metals, minerals, or animal products through a special process to create fine powders. Their preparation is a multi-step process involving purification and repeated grinding and sealing in cow dung pits. Gutikas are pill preparations made by combining plant, mineral, or animal drugs along with binders. They are produced through a process of grinding ingredients into a paste and rolling into pills, which can be used for up to two years. Both bhasmas and gutikas aim to provide stable, potent forms of ingredients for medical use according to Ayurvedic principles.
The document discusses the heterocyclic compound pyrrole. It begins by introducing heterocyclic compounds and classifying pyrrole as a five-membered heterocyclic compound containing one nitrogen atom. The structure of pyrrole is described as aromatic with delocalized pi electrons. Pyrrole can be prepared through various methods including from furan or by the Paal-Knorr synthesis. Pyrrole exhibits properties of both a weak acid and base and undergoes electrophilic aromatic substitution. Important medicinal compounds containing pyrrole rings include procyclidine, an anti-muscarinic drug.
Heterocyclic compounds _ Organic Chemistry _ B. Pharm.AZCPh
ย
This document discusses the properties, synthesis, reactions, and medicinal uses of several aromatic heterocyclic compounds including pyrrole, furan, thiophene, pyrazole, imidazole, oxazole, thiazole, pyridine, azepines, quinoline, and isoquinoline. For each compound, the key topics covered are their aromatic properties, common methods of synthesis such as the Paal-Knorr reaction and Hantzsch synthesis, typical reactions like electrophilic substitution and reduction, and some medicinal applications.
This document summarizes the synthesis of 7-Hydroxy-4-Methyl Coumarin via the Pechmann condensation reaction of resorcinol and ethyl acetoacetate in the presence of concentrated sulfuric acid. Coumarins are an important class of compounds that are found in plants and have various medical applications such as antimicrobial and antitumor properties. The procedure involves cooling concentrated sulfuric acid to below 5ยฐC and adding a solution of resorcinol and ethyl acetoacetate dropwise, followed by workup to obtain an impure product that is recrystallized from ethanol.
The document discusses f-block elements, which are elements where extra electrons fill the (n-2)f orbitals. They are classified into two blocks: lanthanides which have electrons filling the 4f orbitals, and actinides which have electrons filling the 5f orbitals. The lanthanides include elements from lanthanum to lutetium, which have electronic configurations of (n-2)f1-14(n-1)d0-1ns2. The actinides include elements from actinium to lawrencium. They are radioactive, show various oxidation states, and react with water and acids to produce hydrogen gas.
This document discusses heavy metals and provides information on several specific heavy metals. It lists the densities of common heavy metals and substances, with mercury, lead, and cadmium among the heaviest. Heavy metals are defined as having densities over 5g/cm3 and occurring in the middle to bottom of the periodic table. The document then discusses the bioaccumulation and biomagnification of heavy metals in organisms and food chains. It also explains that heavy metals are more toxic when bonded to short carbon chains. Information is provided on the sources, toxicity and health effects of cadmium, chromium, arsenic, and lead in the environment and human body.
The document discusses Pearson's Hard and Soft Acid and Base (HSAB) theory, which states that hard acids prefer to bond with hard bases and soft acids prefer to bond with soft bases. It provides examples of hard and soft ligands and metal ions. Key points include:
- Hard metals have high charge, small size, and are not easily polarized, while soft metals are the opposite.
- The theory can be used to explain the bonding preferences of ambidentate ligands like thiocyanate based on whether they bond to hard or soft metals through nitrogen or sulfur.
- The theory has applications in explaining reactivity patterns in inorganic reactions, organic reactions involving acids and bases of different hardness, and precipitation reactions.
Arsenic is a heavy metal occurring naturally in the environment. It's low concentration is important for various life processes on the Earth but the misuse and overexploitation of mineral resources caused the arsenic contamination to natural resources, which in turn get exposed to living beings causing various toxicity problems and severe health issues. Arsenic has not remained an important mineral for sustaining life but it becomes a category pollutant for which heavy precautions should be taken to avoid an exposure.
Pharmacognosy of traditional drugs in IndiaJegan Nadar
ย
This document provides information on 13 traditional drugs of India - Chirata, Shatavari, Kalmeg, Tinospora, Punarnava, Karela, Guggul, Brahmi, Neem, Tulsi, Amla. For each drug, it summarizes the synonym, biological source, geographical source, macroscopic characteristics, chemical constituents, and uses. The document contains detailed information on the traditional medicinal plants and herbs commonly used in Ayurveda and Indian traditional medicine systems.
Sonia Singh, an assistant professor at GLA University, gave a presentation on the pharmacognosy and phytochemistry of coriander. Coriander consists of the dried ripe fruits of Coriandrum sativum, which are cultivated in parts of Europe, Africa, and India. The fruit is yellowish-brown and spherical, containing volatile oils that are aromatic and spicy. Microscopic examination shows the fruit has a dorsal ridge and commissural surface, with epicarp cells containing calcium oxalate crystals. The chemical constituents include volatile oils like linalool, terpenes, and fatty acids. Therapeutically, coriander is used as a carminative, digestive aid, and
Heterocyclic Compounds Part -IV (Pyrrole) by Dr Pramod R Padolepramod padole
ย
The document discusses electrophilic substitution reactions of pyrrole. It explains that electrophilic substitution in pyrrole occurs preferentially at the 2-position and 5-position. This is because attack of an electrophile at the 2-position forms a more stable carbocation intermediate due to greater delocalization of positive charge through three resonance structures compared to only two structures for attack at the 3-position. Specific electrophilic substitution reactions of pyrrole discussed include halogenation, nitration, sulphonation, and Friedel-Crafts acetylation. Reaction conditions and products are provided for converting pyrrole to halogenated, nitro, and sulfonated derivatives.
Aloe emodin is an anthraquinone compound found naturally in aloe vera plants and other plants such as rhubarb. It can be isolated from aloe sap through refluxing with hydrochloric acid and ferric chloride, followed by extraction with toluene. Identification and quantification of aloe emodin can be done using techniques such as thin layer chromatography and HPLC. Aloe emodin has various pharmacological effects including anticancer and anti-inflammatory properties, but also potential hepatotoxicity and nephrotoxicity. It is used as a laxative but may also help suppress breast cancer cell proliferation.
The document discusses checking the pH values of various fruit juices and doing a comparative study of their effects on health. It provides information on:
- What pH measures and how it is measured in aqueous solutions
- The importance of pH measurements in various fields
- How pH indicators can be used to measure pH
- Some key facts about oranges, pineapples, and lemons/limes and their health effects such as supporting digestion, reducing inflammation, and providing antioxidants.
Ground water Arsenic Contamination in IndiaDr Sayan Das
ย
Extent, related research and remedication meassures
Chemistry of arsenic, Use of arsenic, reference value , Oxidation method, Ion exchange method, Membrane method
The document describes a 4-stage process for extracting alkaloids from plant materials:
1) The plant material is rendered alkaline by mixing with substances like lime or ammonia to free alkaloids from acids and tannins.
2) The freed alkaloids are then extracted using an organic solvent like chloroform through hot percolation.
3) The solvent extract is shaken with dilute sulfuric acid, converting alkaloids to alkaloidal sulfates water-soluble in water.
4) The aqueous solution is made alkaline with ammonia, precipitating the free alkaloids while ammonium sulfates remain in solution.
Heavy metals such as mercury, cadmium, chromium, and lead were discussed in the document. These metals can enter the environment from natural and human sources and persist indefinitely. While some heavy metals are essential in small amounts, higher concentrations can be toxic. Exposure to heavy metals can occur through food, water, air and cause health effects like organ damage and cancer. Current research studies analyzed heavy metal levels in foods, soils and plants in the Philippines and found levels exceeding safety limits.
Minamata is a city located in the Kumamoto prefecture, Japan. The Chisso Corporation, basically a fertilizer and chemicals producer started to release its waste into the Minamata river. This affected the whole Minamata community since the concentration Mercury became high.
The document discusses heavy metals, which are defined as metallic elements that are relatively dense and toxic in low concentrations. Common heavy metals include aluminum, antimony, arsenic, barium, bismuth, cadmium, lead, mercury, nickel, uranium, and tin. Heavy metals enter the human body through food and water. While some heavy metals like iron and zinc are essential nutrients, others such as cadmium and lead are highly toxic even in small amounts. Sources of heavy metal exposure include mining, industrial waste, vehicle emissions, and food/water contamination. The document provides details on specific heavy metals like cadmium, chromium, arsenic, and lead, their sources, and health effects.
Identification of alcohol content in asava and arista.pptxKartik Tiwari
ย
1. The document discusses the preparation and properties of Asava and Arishta, which are Ayurvedic herbal formulations produced through a fermentation process. Key steps include soaking herbs in sugars like honey or jaggery for a specified period of time to allow extraction of active compounds and alcohol generation.
2. Asava and Arishta have several beneficial properties like increased stability, potency, and bioavailability of compounds due to the constant low level of alcohol. They produce rapid therapeutic effects at low doses.
3. The preparation process for Arishta involves making an herbal decoction, adding jaggery or honey, and sealing the mixture in containers for fermentation. Asava preparation skips
This document provides information on the toxicity of heavy metals such as arsenic, cadmium, chromium, and mercury. It defines heavy metals and lists common examples. It describes the acute and chronic toxicity of each metal, including their mechanisms of action and common symptoms. Sources of exposure for each metal are provided. The document discusses treatment for toxicity, focusing on chelation therapy and use of chelating agents like EDTA, DMSA, DMPS, and Dimercaprol to remove heavy metals from the body.
This document provides an overview of pericyclic reactions, including:
1. It classifies pericyclic reactions into four main categories: electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and ene reactions.
2. It discusses the Woodward-Hoffmann rules for determining the stereochemistry of pericyclic reactions under thermal and photochemical conditions.
3. It provides examples of specific pericyclic reactions, such as the Diels-Alder reaction and sigmatropic shifts, analyzing the frontier molecular orbitals involved.
8. the d and f block elements anil-hssliveTariq Beigh
ย
Transition elements have partially filled d orbitals. They are divided into four series based on which atomic orbital their valence electrons fill. Transition elements have varying properties based on their position in the periodic table, including decreasing then increasing atomic radius, increasing then decreasing melting points, and variable but regularly changing ionization energies. They form colored ions and complexes due to their partially filled d orbitals, and exhibit magnetic properties based on unpaired electrons. Transition elements also act as catalysts and form interstitial compounds and alloys.
Honey is a sugar secretion produced by bees from the nectar of various flowers. It is a saturated solution of sugars like glucose, fructose and sucrose. The color ranges from pale yellow to brown depending on the floral source. Honey has a sweet taste with faint acidity and contains enzymes, proteins, vitamins and pollen grains. Common adulterants are invert sugar, sucrose and glucose which alter honey's chemical properties like specific rotation. Honey is used as a sweetener and demulcent in cough syrups, creams and foods due to its nutritional and antimicrobial qualities.
BORAZINE- structure, preparation and propertiesMn2555
ย
1. Borazine is called inorganic benzene because it has a planar hexagonal structure like benzene with alternating B and N atoms.
2. Borazine undergoes addition reactions readily unlike benzene due to the polarity in its B-N bonds from the difference in electronegativity between B and N atoms.
3. Borazine can be synthesized in the laboratory by heating a mixture of LiBH4 and NH4Cl in vacuum at 230ยฐC, which yields 30% borazine.
This is Sumaiya Nahid hail from Chittagong, Bangladesh.It's my M.Pharm (Thesis) presentation slide. This is the total display of my hard works.I tried my best to summarize my one year enthusiastic workings.Any suggestions and corrections will be cordially accepted. Thank you all.
Utilization of radioactive isotopes in biosynthetic pathwayPOOJA KHANPARA
ย
This document discusses using radioactive isotopes to study biogenesis by grafting mutant plant strains and observing enzymatic reactions, including reactions involving methyl magnesium bromide, hydroxy magnesium bromide, and acetic acid.
Human Health Risk Assessment of Industry Derived Heavy Metals Exposure to Com...Premier Publishers
ย
In this study, heavy metals (Zn, Cd, Pb and Cu) concentrations in soil within the vicinity of six diferent industries (International Textile, Chikki holdent Industries, Pz Cusson, 7up bottling company, Clay Industries and Chemstar industry) in Lagos State were used to investigate their influence on human health risk through ingestion, inhalation and dermal exposure pathways. The result revealed that the extent of human health risk varied with exposure pathways, Metal species and industry type. The Hazard Quotient derived from the inhalation are much higher than the US environmental protection agency guide lines value. The values of health index for various heavy metals and the multiple exposure pathway for all the industries were higher than the thresh value of 1. The ingestion pathway, which account for 65.41% and 97.18% health index for adult and children respectively was the dominant exposure route for all the metals to local residents. The cancer risk index falls within the acceptable limit with the exception of Cd for adult as well as Pb for both adult and children through inhalation. The dermal exposure pathway which account for 99.9% total cancer risk index for both adult and children was the dominant exposure route. The range of cancer risk was calculated and the results showed higher risk than an acceptable value of US environmental protection agency (1E-06 โ 1E-04) indicating some concern about building houses, markets and farms near the industries.
Physicochemical Analysis, Heavy Metals Contaminants and Health Risks Assessme...PriyankaKilaniya
ย
The increasing exposure of humans to Harmattan dust is becoming a growing concern, especially in Northern Nigeria. This study aimed to identify the heavy metal contaminants, assess the associated health risks, and evaluate the physicochemical properties of the Harmattan dust. During the sample collection period, which took place from December 2023 to February 2024, Harmattan dust samples were collected from 20 different locations, 4.5 cm above the ground, using cleaned Petri dishes. The composite samples from each month were analyzed using standard analytical techniques and AAS to examine the physicochemical properties and heavy metal contamination, respectively. The results of the physicochemical examination, which included pH, organic matter, organic carbon, electrical conductivity, and moisture content, showed a significant difference (p โฅ 0.05), using statistical tools. However, there was no significant difference in the concentration of heavy metals such as pb, Cd, Ni, Zn, Cu, and Cr among the samples collected in December, January, and February. The concentration of pb and Ni was high in December and January, at 78 mg/kg and 73 mg/kg, respectively, while Ni was at 108 mg/kg and 80 mg/kg for December and January, respectively. The health risk assessment, using the model developed by EPA for children and adults, showed that Cu, Ni, and pb had a hazard index of 1.305, 1.098, and 1.205, and 1.050, respectively. Therefore, Cu and Ni pose health risks for children, while pb poses health risks for both children and adults. Protective measures, such as face masks, during the Harmattan period may help protect people from direct exposure to these heavy metals.
The document discusses Pearson's Hard and Soft Acid and Base (HSAB) theory, which states that hard acids prefer to bond with hard bases and soft acids prefer to bond with soft bases. It provides examples of hard and soft ligands and metal ions. Key points include:
- Hard metals have high charge, small size, and are not easily polarized, while soft metals are the opposite.
- The theory can be used to explain the bonding preferences of ambidentate ligands like thiocyanate based on whether they bond to hard or soft metals through nitrogen or sulfur.
- The theory has applications in explaining reactivity patterns in inorganic reactions, organic reactions involving acids and bases of different hardness, and precipitation reactions.
Arsenic is a heavy metal occurring naturally in the environment. It's low concentration is important for various life processes on the Earth but the misuse and overexploitation of mineral resources caused the arsenic contamination to natural resources, which in turn get exposed to living beings causing various toxicity problems and severe health issues. Arsenic has not remained an important mineral for sustaining life but it becomes a category pollutant for which heavy precautions should be taken to avoid an exposure.
Pharmacognosy of traditional drugs in IndiaJegan Nadar
ย
This document provides information on 13 traditional drugs of India - Chirata, Shatavari, Kalmeg, Tinospora, Punarnava, Karela, Guggul, Brahmi, Neem, Tulsi, Amla. For each drug, it summarizes the synonym, biological source, geographical source, macroscopic characteristics, chemical constituents, and uses. The document contains detailed information on the traditional medicinal plants and herbs commonly used in Ayurveda and Indian traditional medicine systems.
Sonia Singh, an assistant professor at GLA University, gave a presentation on the pharmacognosy and phytochemistry of coriander. Coriander consists of the dried ripe fruits of Coriandrum sativum, which are cultivated in parts of Europe, Africa, and India. The fruit is yellowish-brown and spherical, containing volatile oils that are aromatic and spicy. Microscopic examination shows the fruit has a dorsal ridge and commissural surface, with epicarp cells containing calcium oxalate crystals. The chemical constituents include volatile oils like linalool, terpenes, and fatty acids. Therapeutically, coriander is used as a carminative, digestive aid, and
Heterocyclic Compounds Part -IV (Pyrrole) by Dr Pramod R Padolepramod padole
ย
The document discusses electrophilic substitution reactions of pyrrole. It explains that electrophilic substitution in pyrrole occurs preferentially at the 2-position and 5-position. This is because attack of an electrophile at the 2-position forms a more stable carbocation intermediate due to greater delocalization of positive charge through three resonance structures compared to only two structures for attack at the 3-position. Specific electrophilic substitution reactions of pyrrole discussed include halogenation, nitration, sulphonation, and Friedel-Crafts acetylation. Reaction conditions and products are provided for converting pyrrole to halogenated, nitro, and sulfonated derivatives.
Aloe emodin is an anthraquinone compound found naturally in aloe vera plants and other plants such as rhubarb. It can be isolated from aloe sap through refluxing with hydrochloric acid and ferric chloride, followed by extraction with toluene. Identification and quantification of aloe emodin can be done using techniques such as thin layer chromatography and HPLC. Aloe emodin has various pharmacological effects including anticancer and anti-inflammatory properties, but also potential hepatotoxicity and nephrotoxicity. It is used as a laxative but may also help suppress breast cancer cell proliferation.
The document discusses checking the pH values of various fruit juices and doing a comparative study of their effects on health. It provides information on:
- What pH measures and how it is measured in aqueous solutions
- The importance of pH measurements in various fields
- How pH indicators can be used to measure pH
- Some key facts about oranges, pineapples, and lemons/limes and their health effects such as supporting digestion, reducing inflammation, and providing antioxidants.
Ground water Arsenic Contamination in IndiaDr Sayan Das
ย
Extent, related research and remedication meassures
Chemistry of arsenic, Use of arsenic, reference value , Oxidation method, Ion exchange method, Membrane method
The document describes a 4-stage process for extracting alkaloids from plant materials:
1) The plant material is rendered alkaline by mixing with substances like lime or ammonia to free alkaloids from acids and tannins.
2) The freed alkaloids are then extracted using an organic solvent like chloroform through hot percolation.
3) The solvent extract is shaken with dilute sulfuric acid, converting alkaloids to alkaloidal sulfates water-soluble in water.
4) The aqueous solution is made alkaline with ammonia, precipitating the free alkaloids while ammonium sulfates remain in solution.
Heavy metals such as mercury, cadmium, chromium, and lead were discussed in the document. These metals can enter the environment from natural and human sources and persist indefinitely. While some heavy metals are essential in small amounts, higher concentrations can be toxic. Exposure to heavy metals can occur through food, water, air and cause health effects like organ damage and cancer. Current research studies analyzed heavy metal levels in foods, soils and plants in the Philippines and found levels exceeding safety limits.
Minamata is a city located in the Kumamoto prefecture, Japan. The Chisso Corporation, basically a fertilizer and chemicals producer started to release its waste into the Minamata river. This affected the whole Minamata community since the concentration Mercury became high.
The document discusses heavy metals, which are defined as metallic elements that are relatively dense and toxic in low concentrations. Common heavy metals include aluminum, antimony, arsenic, barium, bismuth, cadmium, lead, mercury, nickel, uranium, and tin. Heavy metals enter the human body through food and water. While some heavy metals like iron and zinc are essential nutrients, others such as cadmium and lead are highly toxic even in small amounts. Sources of heavy metal exposure include mining, industrial waste, vehicle emissions, and food/water contamination. The document provides details on specific heavy metals like cadmium, chromium, arsenic, and lead, their sources, and health effects.
Identification of alcohol content in asava and arista.pptxKartik Tiwari
ย
1. The document discusses the preparation and properties of Asava and Arishta, which are Ayurvedic herbal formulations produced through a fermentation process. Key steps include soaking herbs in sugars like honey or jaggery for a specified period of time to allow extraction of active compounds and alcohol generation.
2. Asava and Arishta have several beneficial properties like increased stability, potency, and bioavailability of compounds due to the constant low level of alcohol. They produce rapid therapeutic effects at low doses.
3. The preparation process for Arishta involves making an herbal decoction, adding jaggery or honey, and sealing the mixture in containers for fermentation. Asava preparation skips
This document provides information on the toxicity of heavy metals such as arsenic, cadmium, chromium, and mercury. It defines heavy metals and lists common examples. It describes the acute and chronic toxicity of each metal, including their mechanisms of action and common symptoms. Sources of exposure for each metal are provided. The document discusses treatment for toxicity, focusing on chelation therapy and use of chelating agents like EDTA, DMSA, DMPS, and Dimercaprol to remove heavy metals from the body.
This document provides an overview of pericyclic reactions, including:
1. It classifies pericyclic reactions into four main categories: electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and ene reactions.
2. It discusses the Woodward-Hoffmann rules for determining the stereochemistry of pericyclic reactions under thermal and photochemical conditions.
3. It provides examples of specific pericyclic reactions, such as the Diels-Alder reaction and sigmatropic shifts, analyzing the frontier molecular orbitals involved.
8. the d and f block elements anil-hssliveTariq Beigh
ย
Transition elements have partially filled d orbitals. They are divided into four series based on which atomic orbital their valence electrons fill. Transition elements have varying properties based on their position in the periodic table, including decreasing then increasing atomic radius, increasing then decreasing melting points, and variable but regularly changing ionization energies. They form colored ions and complexes due to their partially filled d orbitals, and exhibit magnetic properties based on unpaired electrons. Transition elements also act as catalysts and form interstitial compounds and alloys.
Honey is a sugar secretion produced by bees from the nectar of various flowers. It is a saturated solution of sugars like glucose, fructose and sucrose. The color ranges from pale yellow to brown depending on the floral source. Honey has a sweet taste with faint acidity and contains enzymes, proteins, vitamins and pollen grains. Common adulterants are invert sugar, sucrose and glucose which alter honey's chemical properties like specific rotation. Honey is used as a sweetener and demulcent in cough syrups, creams and foods due to its nutritional and antimicrobial qualities.
BORAZINE- structure, preparation and propertiesMn2555
ย
1. Borazine is called inorganic benzene because it has a planar hexagonal structure like benzene with alternating B and N atoms.
2. Borazine undergoes addition reactions readily unlike benzene due to the polarity in its B-N bonds from the difference in electronegativity between B and N atoms.
3. Borazine can be synthesized in the laboratory by heating a mixture of LiBH4 and NH4Cl in vacuum at 230ยฐC, which yields 30% borazine.
This is Sumaiya Nahid hail from Chittagong, Bangladesh.It's my M.Pharm (Thesis) presentation slide. This is the total display of my hard works.I tried my best to summarize my one year enthusiastic workings.Any suggestions and corrections will be cordially accepted. Thank you all.
Utilization of radioactive isotopes in biosynthetic pathwayPOOJA KHANPARA
ย
This document discusses using radioactive isotopes to study biogenesis by grafting mutant plant strains and observing enzymatic reactions, including reactions involving methyl magnesium bromide, hydroxy magnesium bromide, and acetic acid.
Human Health Risk Assessment of Industry Derived Heavy Metals Exposure to Com...Premier Publishers
ย
In this study, heavy metals (Zn, Cd, Pb and Cu) concentrations in soil within the vicinity of six diferent industries (International Textile, Chikki holdent Industries, Pz Cusson, 7up bottling company, Clay Industries and Chemstar industry) in Lagos State were used to investigate their influence on human health risk through ingestion, inhalation and dermal exposure pathways. The result revealed that the extent of human health risk varied with exposure pathways, Metal species and industry type. The Hazard Quotient derived from the inhalation are much higher than the US environmental protection agency guide lines value. The values of health index for various heavy metals and the multiple exposure pathway for all the industries were higher than the thresh value of 1. The ingestion pathway, which account for 65.41% and 97.18% health index for adult and children respectively was the dominant exposure route for all the metals to local residents. The cancer risk index falls within the acceptable limit with the exception of Cd for adult as well as Pb for both adult and children through inhalation. The dermal exposure pathway which account for 99.9% total cancer risk index for both adult and children was the dominant exposure route. The range of cancer risk was calculated and the results showed higher risk than an acceptable value of US environmental protection agency (1E-06 โ 1E-04) indicating some concern about building houses, markets and farms near the industries.
Physicochemical Analysis, Heavy Metals Contaminants and Health Risks Assessme...PriyankaKilaniya
ย
The increasing exposure of humans to Harmattan dust is becoming a growing concern, especially in Northern Nigeria. This study aimed to identify the heavy metal contaminants, assess the associated health risks, and evaluate the physicochemical properties of the Harmattan dust. During the sample collection period, which took place from December 2023 to February 2024, Harmattan dust samples were collected from 20 different locations, 4.5 cm above the ground, using cleaned Petri dishes. The composite samples from each month were analyzed using standard analytical techniques and AAS to examine the physicochemical properties and heavy metal contamination, respectively. The results of the physicochemical examination, which included pH, organic matter, organic carbon, electrical conductivity, and moisture content, showed a significant difference (p โฅ 0.05), using statistical tools. However, there was no significant difference in the concentration of heavy metals such as pb, Cd, Ni, Zn, Cu, and Cr among the samples collected in December, January, and February. The concentration of pb and Ni was high in December and January, at 78 mg/kg and 73 mg/kg, respectively, while Ni was at 108 mg/kg and 80 mg/kg for December and January, respectively. The health risk assessment, using the model developed by EPA for children and adults, showed that Cu, Ni, and pb had a hazard index of 1.305, 1.098, and 1.205, and 1.050, respectively. Therefore, Cu and Ni pose health risks for children, while pb poses health risks for both children and adults. Protective measures, such as face masks, during the Harmattan period may help protect people from direct exposure to these heavy metals.
ORIGINAL PAPERRisk assessment of atmospheric heavy metals .docxgerardkortney
ย
ORIGINAL PAPER
Risk assessment of atmospheric heavy metals exposure
in Baotou, a typical industrial city in northern China
Kexin Li . Tao Liang . Lingqing Wang
Received: 11 March 2015 / Accepted: 1 September 2015 / Published online: 8 September 2015
! Springer Science+Business Media Dordrecht 2015
Abstract Industrial activities have led to serious air
pollution and the potentially toxic elements in atmo-
spheric particles can cause various health problems to
humans. In this study, inhalable particulate matter
(PM10) and fine particles (PM2.5) were collected from
four typical sites in Baotou, an industrial city in
northern China. We investigated both the mass
concentrations of particulate matter and the concen-
trations of heavy metals (Cr, Ni, Pb, Cd, Cu, Mn, Co,
and Zn) in the collected samples. We assessed the
public health risks associated with atmospheric heavy
metal exposure. The results showed that the mass
concentrations of PM2.5 and PM10 as well as these
heavy metal concentrations varied notably influenced
by the prevailing wind directions. Among the studied
metals, Zn, Mn, Pb, and Cr were the main metal
pollutants in both PM10 and PM2.5. The results of the
health assessment showed that the eight heavy metals
studied pose significant non-carcinogenic risks and Cr,
Cd, and Co pose lifetime lung cancer risks to local
residents, especially to children.
Keywords PM10 ! PM2.5 ! Heavy metals !
Health risk ! Baotou
Introduction
Mining activities are notorious for adverse environ-
mental impacts, including pollution, habitat loss, soil
erosion, and geological disasters (Salomons 1995;
Klukanovaฬ and Rapant 1999; Aguilar et al. 2004; Luฤฑฬs
et al. 2011). Among these environmental problems
caused by mining activities, the production and
dispersion of atmospheric particles has become a
great concern in recent years (Kaonga and Kgabi
2011; Chen et al. 2013; Serbula et al. 2014). Atmo-
spheric particulates are generated from numerous
sources, both natural and anthropogenic, but in areas
near mining, mining operations are considered the
largest contributor. The processes of mining, such as
crushing, grinding, excavating, smelting, and refining,
can produce large quantities of particulate matter
(PM), containing dangerously high levels of heavy
metals (Csavina et al. 2012).
Inhalable particulate matter (PM10), particularly
fine particles (PM2.5), have been shown to cause
adverse effects on human health, including asthma,
lung cancer, and cardiovascular diseases (Pope et al.
2002; Sanchez et al. 2009). Lung and other organ
injuries from atmospheric heavy metal exposure have
also been well-documented (Espinosa et al. 2001;
Cancio et al. 2008; Leili et al. 2008).
K. Li ! T. Liang (&) ! L. Wang (&)
Key Laboratory of Land Surface Pattern and Simulation,
Institute of Geographical Sciences and Natural Resources
Research, Chinese Academy of Sciences, Beijing 100101,
China
e-mail: [emailย protected]
L. Wang
e-mail: [emailย p.
Mobility and Distribution of Some Selected Trace Metals in Soil from Dumpsite...ijtsrd
ย
Mobility and distribution of some selected trace metal was carried out using Tessier et al 1979sequential extraction method and the results obtained shows from dumpsite A, samples taken from 0 - 5cm the result ranges from 0.56 - 21.56 , 0.34 - 40.66 , 1.34 - 29.18 , 0.06 to 45.91 and 0.37 - 12.95 for the exchangeable, Fe - Mn oxide, organic carbonate and residual fractions respectively. For the samples taken from 10 - 15cm at dumpsite A, the results of the fractions are 0.42 - 13.63 , 0.03 - 18.48 , 1.01 - 25.34 , 0.03 - 35.19 and 0.27 - 9.31 for exchangeable, Fe - Mn oxide, organic, carbonate and residual fractions. The results of dumpsite Bare 0.48-27.36 , 0.28-40.07 , 2.93-31.15 , 3.87-42.50 and 0.84-30.67 for exchangeable, Fe-Mn oxide, Organic, carbonate and residual fractions for sample taken from 0-5cm while for samples taken from 10 - 15cm the results show 0.32 - 36.38 , 0.23 - 16.49 , 0.53 - 15.83 , 1.53 - 34.88 and 0.04 - 5.27 for exchangeable Fe - Mn oxide, carbonate and residual fractions respectively. The dumpsite C has the concentration of the various fractions ranging from 0.25 - 18.34 , 2.73 to 15.58, 4.02 - 23.28 , 0.07 - 45.25 and 1.57 - 37.43 for exchangeable, Fe - Mn oxide, organic, carbonate and residual for samples taken from 0 - 5cm while for samples taken between 10 - 15cm the concentrations are 0.42 - 12 .62 0.80 - 11.59 , 2.16 - 17.33 , 9.86 - 34.48 and 0.99 - 32.99 respectively. Gube-Ibrahim Mercy Ayinya | Ibrahim Ezekiel Gube "Mobility and Distribution of Some Selected Trace Metals in Soil from Dumpsite in Lafia, Nasarawa State" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-3 | Issue-1 , December 2018, URL: http://www.ijtsrd.com/papers/ijtsrd19106.pdf
http://www.ijtsrd.com/chemistry/analytical-chemistry/19106/mobility-and-distribution-of-some-selected-trace-metals-in-soil-from-dumpsite-in-lafia-nasarawa-state/gube-ibrahim-mercy-ayinya
Assessment of Sulphur Dioxide Levels in Selected Sites in Athi River, Kenyaijtsrd
ย
Industrialization, economic growth, urbanization and population growth have been responsible for air pollution in developing countries. The discharge of harmful chemicals and increased combustion of fossil fuels, affect both the physical environment and the public health. Air pollution effects are both acute and chronic on human health, ranging from minor upper respiratory irritation to chronic respiratory and heart disease, lung cancer, acute respiratory infections in children and chronic bronchitis in adults. A study was conducted to assess the effect of sulfur dioxide on air quality at three sites in Athi River town, Kenya which included one non-industrial site. The air samples were collected by scrubbing them through appropriate trapping solutions and subsequently analyzed in the laboratory using colorimetric method. The meteorological parameters namely; temperature, relative humidity, wind speed and wind direction were also measured during the sampling exercise. The mean concentrations of sulphur dioxide at the various sampling sites during rainy season were: Shalom Hospital (602 -ยตg/m3); Vannilaz Restaurant (793 -ยตg/m3); Redeemed Gospel Church (861 -ยตg/m3) and Sabaki residential Estate (370 -ยตg/m3). The levels exceeded the guidelines recommended by WHO which has set a maximum of 500 -ยตg/m3, for 10 minutes exposure, however the levels at Sabaki residential Estate were low. Mean concentrations of sulphur dioxide during the dry season for Shalom Hospital, Vanillaz Restaurant, Redeemed Gospel church and Sabaki residential Estate were 863, 875,862 and 664 -ยตg/m3 respectively. The elevated levels of SO2 was associated with heavy vehicular traffic and the various industrial activities mainly cement manufacturing plants. Sulphur dioxide may also be emitted from diesel-powered vehicles and coal burning in the industries. The study revealed that Shalom Hospital, Vanillaz Restaurant and Redeemed Gospel Church were polluted with sulphur dioxide during the rainy season except Sabaki residential Estate but during the dry season all the sites were polluted with sulphur dioxide. Birgen J. | Wafula G. | Yusuf A. | Onyatta J."Assessment of Sulphur Dioxide Levels in Selected Sites in Athi River, Kenya" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-1 | Issue-5 , August 2017, URL: http://www.ijtsrd.com/papers/ijtsrd2320.pdf http://www.ijtsrd.com/engineering/computer-engineering/2320/assessment-of-sulphur-dioxide-levels-in--selected-sites-in-athi-river-kenya/birgen-j
Soil Remediation Technologies for Heavy Metals โ A ReviewDr. Amarjeet Singh
ย
Soil is a very vital necessity to the ecosystem and
human population. Due to the urbanization and
industrialization, the quality and the fertility of soil is
deteriorating. This has been a huge concern among countries
to discover the suitable yet effective solution to remediate the
soil as the contaminated soil may introduce unhealthy and
unsafe environment to society. One of the common pollutants
in soils are heavy metals and it is very challenging to
remediate as it is not biodegradable materials. Remediation
methods for metals can be classified to two categories; in-situ
remediation and ex-situ remediation. Studies show that
chemical remediation the most effective methods used.
Chemical remediation and biological remediation are also
another two available options. Chemical remediation
methods can be categorized into four; chemical leaching,
chemical fixation, electrokinetic remediation and vitrify
technology. Biological remediation includes
phytoremediation, bioremediation and the combination of the
remediation are one of the most cost effective methods that
can be implemented especially in poor and middle income
countries as it involves natures such as plants and animals in
the process.
Environmental burden of heavy metal contamination levels (zikai wang ็ๅฒ็ชๅฏๆฌ 20...Alexander Decker
ย
The document analyzes heavy metal contamination levels in soils from two sites under sewage irrigation and a control site in Geriyo catchment, Nigeria. Heavy metal concentrations were highest at Site II, followed by Site I, with the control site having the lowest levels. Zinc, copper, cadmium, chromium and lead concentrations exceeded international standards at Site II. An index was used to assess contamination/pollution levels, finding the soils ranged from slight to excessive heavy metal pollution. Remediation through leaching and liming was recommended due to risks of negative effects on plants and groundwater contamination.
Environmental burden of heavy metal contamination levelsAlexander Decker
ย
The document analyzes heavy metal contamination levels in soils from two sites using sewage irrigation and a control site in Nigeria. At the sewage irrigation sites, concentrations of metals like Fe, Zn, Mn, Cu, Cd, Cr, and Pb were higher than the control site. The highest concentrations were found at Site II, with levels of Cu, Cd, Cr, and Pb exceeding international standards. Based on a contamination/pollution index, soils ranged from slight pollution to excessive heavy metal pollution, posing risks to plants and groundwater. Remediation through leaching and liming was recommended to reduce metal levels and ensure sustainable agriculture.
Heavy metal-contamination-in-solid-aerosols-and-top-soils-of-faisalabad-envio...Ijcem Journal
ย
This document summarizes a study analyzing heavy metal contamination in solid aerosols and top soils in Faisalabad, Pakistan. Atomic absorption spectrometry was used to analyze samples of solid aerosols and soils from 50 sites for levels of cadmium, copper, zinc and lead. The study found elevated levels of cadmium and lead in solid aerosols, and all four metals in soils, with concentrations highest in industrial and commercial areas. Statistical analysis showed significant variability between sites. The authors conclude that various industries are contributing heavy metals to the local environment and negatively impacting human health.
Quantification of Heavy Metals using Contamination and Pollution Index in Sel...IJEAB
ย
Many sites in urban cities are used for dumping of domestic, industrial and municipal wastes because of high human population density in the area. Most often, people use these dumpsites for growing of crops without knowing the level of heavy metal contamination in soils of these areas. This study evaluated the quantification and contamination level of heavy metals in some refuse dumpsites in communities of the State Nigeria. Three replicate soil samples were collected from the dumpsites and at 20 m away from the non - dumpsite which do not receive sewage water within the root zone of 0 โ 40 cm depth using soil auger sampler. Samples were analysed for soil properties and heavy metal concentrations using standard methods. The concentrations of the studied heavy metals (Cu, Pb, Zn and Cd) were compared with the permissible limits of other countries. Results showed that in the three studied locations, soil pH at dumpsites were 40 .6%, 39.4% and 38.9% higher than the values in the control sites while soil organic carbon were higher in the dumpsites by 50.1%, 31.3% and 41.1% as compared to the control sites. Cu concentrations at the three locations were below the standard limits of United Kingdom, European Union (EU), USA and WHO. The concentrations of the studied heavy metals passed the contamination stage and therefore will pose negative effect on plant and soil environment. Use of the dumpsite for crop cultivation or as compost materials should be avoided and construction of shallow wells near these areas should be discouraged.
POTENTIAL HEALTH RISK ASSESSMENT FOR SOIL AND AIR HEAVY METAL CONTAMINATION I...IAEME Publication
ย
The document presents the results of an environmental risk assessment for soil and air contamination by heavy metals in Baghdad, Iraq. Heavy metal concentrations were collected from previous studies of soil in residential, industrial, and commercial areas, and of air in residential and industrial areas. Potential health risks from exposure were calculated based on ingestion, dermal contact, and inhalation intake. Risks were highest for individual elements in both adults and children. Cumulative risk indices showed adults and children faced chronic health risks from exposure. The study aimed to assess health risks from heavy metals in Baghdad soil and air to compare to risks in other areas and identify risk-based remediation needs.
The document presents the results of an environmental risk assessment for soil and air contamination by heavy metals in Baghdad, Iraq. Heavy metal concentrations were collected from previous studies of soil in residential, industrial, and commercial areas, and of air in residential and industrial areas. Risk of non-carcinogenic and carcinogenic effects through ingestion, dermal contact and inhalation were calculated using EPA models. The risk assessment found the highest risks were for individual heavy metals in both adults and children. The cumulative risk index showed adults and children faced serious chronic health risks from contamination.
This document analyzes highway air pollution in Chennai, India. It aims to quantify the total number of vehicles, estimate road traffic and pollution loads, and compare measured and predicted carbon monoxide concentrations. The study finds that traffic is growing rapidly in Indian cities, leading to increased air pollution from vehicle exhaust. It measures ambient levels of pollutants like CO, HC, NOx, SO2 and SPM at various locations. The CALINE 4 model is used to predict CO concentrations, which are then statistically compared to observed values. The results help assess the impact of vehicular emissions on air quality and inform pollution management efforts.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
IRJET- Understanding the Soil Pollution Surrounding Municipal Solid Waste Lan...IRJET Journal
ย
1) The document analyzes soil samples from 100 sites within a 25 km2 area surrounding a municipal solid waste landfill in southwest Ahmedabad, India.
2) Heavy metal concentrations were measured in the soil samples, including copper, iron, nickel, cobalt, aluminum, arsenic, lead, chromium, cadmium, mercury, and zinc.
3) The results found elevated concentrations of some heavy metals, such as copper, iron, lead, and arsenic, in samples taken near the landfill, a major highway, and industrial areas, indicating pollution from these sources.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
This document summarizes a seminar presentation on using ornamental plants to improve air quality in cities. It discusses the importance of air quality to human and plant health, sources and types of air pollution, effects of air pollution on people and plants, and criteria for selecting plant species well-suited for controlling urban air pollution. It provides examples of research assessing how urban trees and greenery remove air pollutants. The document concludes that strategic planting of indigenous, pollution-tolerant species can help clean the air and create healthier urban environments.
The Effects of Cement Dust on Haematological Parameters of Cement Workers in ...iosrjce
ย
The effect of cement dust on exposed workers was conducted in Asaba Delta state Nigeria, to
delineate the occupational hazards posed by cement dust on haematological parameters. The assessment of
haematological parameters was performed in forty workers occupationally exposed to cement dust and forty
matched unexposed control. The accepted level of significance was p< 0.05. The results show that the
erythrocyte sedimentation count, haemoglobin concentration and packed cell volume were not significantly
different between the exposed and the control (p> 0.05). There was a significantly lower platelet count,
lymphocytes and total white blood cell count in the exposed workers relative to the control (p< 0.05). Apart from
the white blood cell count, the number of years of exposure did not significantly affect the other parameters.
The results from this study has shown that occupational exposure to cement dust has significant effects on some
haematological parameters while years of exposure was not a significant factor on the haematological
parameters of cement depot workers
Similar to Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria (20)
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In Benin, chilli pepper is a widely consumed as vegetable whose production requires the use of performant varieties. This work assessed, at Parakou and Malanville, the performance of six F1 hybrids of chilli including five imported (Laali, Laser, Nandi, Kranti, Nandita) and one local (De cayenne), in completely randomized block design at four replications and 15 plants per elementary plot. Agro-morphological data were collected and submitted to analysis of variance and factor analysis of mixed data. The results showed the effects of variety, location and their interactions were highly significant for most of the growth, earliness and yield traits. Imported hybrid varieties showed the best performances compared to the local one. Multivariate analysis revealed that 'De cayenne' was earlier, short in size, thin-stemmed, red fruits and less yielding (โ 1 t.ha-1). The imported hybrids LaaliF1 and KrantiF1 were of strong vegetative vigor, more yielding (> 6 t.ha-1) by developing larger, long and hard fruits. Other hybrids showed intermediate performances. This study highlighted the importance of imported hybrids in improving yield and preservation of chili fruits. However, stability and adaptation analyses to local conditions are necessary for their adoption.
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The chances of an investor in the stock market depends mainly on some certain decisions in respect to equilibrium prices, which is the condition of a system competing favorably and effectively. This paper considered a stochastic model which was latter transformed to non-linear ordinary differential equation where stock volatility was used as a key parameter. The analytical solution was obtained which determined the equilibrium prices. A theorem was developed and proved to show that the proposed mathematical model follows a normal distribution since it has a symmetric property. Finally, graphical results were presented and the effects of the relevant parameters were discussed.
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Chia is an emerging cash crop in Kenya and its production is inhibited by lack of agronomic management information. A field experiment was conducted in February-June and May-August 2021, to determine the influence of nitrogen and spacing on growth and yield of Chia. A randomized complete block design with a split plot arrangement was used with four nitrogen rates as the main plots (0, 40, 80, 120 kg N ha-1) and three spacing (30 cm x 15 cm (s1), 30 cm x 30 cm (s2), 50 cm x 50 cm (s3)). Application of 120 kg N ha-1 significantly increased (pโค0.05) vegetative growth and seed yield of Chia. Stem height, branches, stem diameter and leaves increased by 23-28%, 11-13%, 43-55% and 59-88% respectively. Spacing s3 significantly increased (pโค0.05) vegetative growth. An increase of 27-74%, 36-45% and 73-107% was recorded in number of leaves, stem diameter and dry weight, respectively. Chia yield per plant was significantly higher (pโค0.05) in s3. However, when expressed per unit area, s1 significantly produced higher yields. The study recommends 120 kg N ha-1 or higher nitrogen rates and a closer spacing of 15 cm x 30 cm as the best option for Chia production in Kenya.
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Multivariate Analysis of Tea (Camellia sinensis (L.) O. Kuntze) Clones on Mor...Premier Publishers
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Information on genetic variability for biochemical characters is a prerequisite for improvement of tea quality. Thirteen introduced tea clones characterized with objective; assessing tea clones based on morphological characters at Melko and Gera research stations. The study was conducted during 2017/18 cropping season on experimental plots in RCBD with three replications. Data recorded on morphological traits like days from pruning to harvest, height to first branch, stem diameter, leaf serration density, leaf length, leaf width, leaf size, petiole length, leaf ratio, internode length, shoot length, number of shoot, canopy diameter, hundred shoot weight, fresh leaf yield per tree. Cluster analysis of morphological trait grouped into four clusters indicated, the existence of divergence among the tested clones. The maximum inter-cluster distance was between clusters I and IV (35.27) while the minimum inter cluster distance was observed between clusters I and II (7.8).Principal components analysis showed that the first five principal components with eigenvalues greater than one accounted 86.45% for 15 morphological traits. Generally, the study indicated presence of variability for several morphological traits. However, high morphological variation between clones is not a guarantee for a high genetic variation; therefore, molecular studies need to be considered as complementary to biochemical studies.
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This research work was designed to examine nature of juvenile offences committed by juveniles, causes of juvenile delinquency, consequences of juvenile delinquency and remedies for juvenile delinquency in the context of Sub-Saharan Africa with specific reference to Eritrea. Left unchecked, juvenile delinquents on the streets engage in petty theft, take alcohol or drugs, rape women, rob people at night involve themselves in criminal gangs and threaten the public at night. To shed light on the problem of juvenile delinquency in the Sub-Saharan region data was collected through primary and secondary sources. A sample size of 70 juvenile delinquents was selected from among 112 juvenile delinquents in remand at the Asmara Juvenile Rehabilitation Center in the Eritrean capital. The study was carried out through coded self-administered questionnaires administered to a sample of 70 juvenile delinquents. The survey evidence indicates that the majority of the juvenile respondents come either from families constructed by unmarried couples or separated or divorced parents where largely the father is missing in the home or dead. The findings also indicate that children born out of wedlock, families led by single mothers, lack of fatherly role models, poor parental-child relationships and negative peer group influence as dominant causes of juvenile infractions. The implication is that broken and stressed families are highly likely to be the breeding grounds for juvenile delinquency. The survey evidence indicates that stealing, truancy or absenteeism from school, rowdy or unruly behavior at school, free-riding in public transportation, damaging the book of fellow students and beating other young persons are the most common forms of juvenile offenses. It is therefore, recommended that parents and guardians should exercise proper parental supervision and give adequate care to transmit positive societal values to children. In addition, the government, the police, prosecution and courts, non-government organizations, parents, teachers, religious leaders, education administrators and other stakeholders should develop a child justice system that strives to prevent children from entering deeper into the criminal justice process.
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Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria
1. Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria
Risk Assessment of Human Health by Heavy Metals Exposure
to Communities along Hong Major Road in Adamawa State,
Nigeria
Nachanaโa Timothy
Department of Chemistry, Adamawa State University, Mubi, Adamawa, Nigeria
Email: allen.dusa@gmail.com; Tel.: 08130976890
In this study, heavy metals (Cd, Pb, Cr, Zn, Cu and Ni) concentrations were determined in soil
samples taken from Pilafu, Shiwa, Fadama-rake and Damdrai along Hong major road using Atomic
absorption spectrophotometer. The determined concentrations were used to investigate their
influence on human health risk through ingestion, inhalation and dermal exposure path ways. The
result revealed that the extent of human health risk varied with exposure path ways, Metal species
and sample area. The target hazard quotient for all the elements through each exposure path way
were observed to be >1, except Zn in ingestion for adults and in dermal for children and also Cu
for children in dermal. However, the health index values for adults were observed to be much
higher than the children for THQinh and THQdermal. But for THQing the HI values for children
were observed to be higher than the adults. While in inhalation exposure path way all the cancer
risk index values were observed to be higher in adults than in children except Ni which is higher
in children than in adults. The combine effect for each exposure path way shows high possibility
of carcinogenic risk by inhalation route. Indicating some concern about the expansion of
unregulated settlements along heavy traffic highways.
Key words: Path way, Ingestion, Inhalation, Dermal, Nonโcarcinogenic, Cancer, Soil, metals.
.
INTRODUCTION
Environmental pollution by heavy metals has become a
global issue in the recent years as it affects public health.
Especially with the continue increase in anthropogenic
activities such as industries and urbanization which
releases pollutants in to the environment.
Soils polluted with heavy metals have become common
across the globe due to increase in geologic and
anthropogenic activities. These activities increased the
concentration of these elements to amount that are
harmful to both plants and animals (Chibuike and Obiora,
2014).
Traffic activities and industrialization are among the major
sources leading to heavy metal contamination in town
roadside soils due to their long-term accumulation (Fan et
al., 2012) Emission of heavy metals from traffic activities is
an important pollution source to roadside farmland
ecosystems. Pollution in developing nations is correlated
with the degree of industrialization, road traffic density and
emission (Filazi et al., 2003; Mlitan et al., 2013).
In addition to the greenhouse gas (GHG), vehicular
emissions were reported to contain cadmium, zinc, nickel,
sootโs and other particulate matters (Susuki and Ono,
2008; Atayese et al., 2009; Dehghani et al., 2018)
contributing to heavy metal overload in the nearby
roadside soils [Fan et al., 2012]. Cadmium for example is
mainly generated from burning of lubricating oil and from
wearing of tires. Similarly, wearing of tires in addition to the
galvanized components of vehicles are additional sources
contributing to Zn build up in the environment. Copper and
lead are by-product of brake wearing, exhaust gas and
worn-out metal alloys in the engine.
Soils and plants in nearby zone of roadside and industrial
areas display increased concentration of heavy metals,
serving in many cases as sinks of pollution loads (Addo et
Research Article
Vol. 4(2), pp. 095-101, December, 2019. ยฉ www.premierpublishers.org. ISSN: 1822-424X
International Journal of Toxicology and Environmental Health
2. Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria
Timothy N. 096
al., 2012; Williams et al., 2018; Mohammadi et al ., 2018).
Soils along roadside and around industries take up large
quantities of pollutants that exceeding the natural emission
levels (Timothy, 2019).
Recently, roadside soils have been an increasingly
important medium for assessing anthropogenic metal
concentrations. Heavy traffic from vehicular activities often
used as indicator of the level of roadside soil pollution by
vehicle derived heavy metals (Saleh et al., 2018;
Bwatanglang et al., 2019).
The environmental issues related to heavy metals
contamination are becoming serious in developing
countries. With the rapid industrialization and urbanization
trend, the increment of traffic activities substantially
contributes to the accumulations of heavy metals
discharged by vehicles in roadside environments. Heavy
metals pollution in agricultural areas owing to traffic
emissions may contaminate the crops growing near the
roadsides (Zeng 2008; Chen et al., 2010; Seifi et al., 2019).
In agricultural areas, uptake of heavy metals through the
soil-crop system could play a predominant role in human
exposure to heavy metals (Timothy, 2019). Heavy metals
present in the roadside soils may be transported through
the food chain, which may have a significant toxicity to both
plants and animals. Therefore farmers are advised not to
farm near the roadside in order to avoid heavy metal
transfer in both animal and human body through the food
chain. This study used heavy metal enrichment in roadside
soils as an indicator to the pollution levels generated by
vehicular activities with some attempt toward establishing
the ecological associated risk.
The aim of the study is to investigate the influence of heavy
metals (Cr, Ni, Cd, Pb, Zn and Cu) concentration in soil
along major road in Hong Adamawa State Nigeria on
human health risk through different exposure path ways.
The outcome of the study could serve as a guide in policy
making toward regulating the expansion of settlements
along roadside area.
MATERIALS AND METHODS
Study Area
Hong is situated in the North eastern part of Nigeria. It is
one of the 21 Local Government areas in Adamawa State.
Hong lies between coordinates 10ยฐ 13โ54โโN12ยฐ 55โ49โโE /
10.23ยฐN 12.93ยฐ E. The study area has a land area of about
480.65sq.km with population of about 169,183 people
(National Population Census 2006).
Figure 1: Map of Hong showing the sample points
Sample Collection
For the study, twenty four (24) soil samples were randomly
collected from four different locations along the major road
in Hong. Six surface soil samples were randomly collected
from each location. The respective sample points are
Pliafu, Shiwa, Fadama-reke and Damdrai (Figure 1). Soil
samples were pretreated and processed according to the
method described by Timothy (2019). The elemental
concentrations ( Cd, Pb, Zn, Cr, Ni and Cu) of the digested
soil samples were carried out using Atomic Absorption
Spectrophotometer (AAS) 210 VPG Buck Scientific Model.
Health Risk Characterization
The risk assessment processes were carried out to predict
the possible carcinogenic and noncarcinogenic risks that
may prompt up following the exposure of the heavy metals
in the soil to both the adults and children residing along the
major road in the study area. This was achieved by
integrating possible exposure path ways to quantitatively
estimate the likelihood of health hazard. The risk exposure
path ways involve taking the average daily intake (ADI) of
the toxic metals (mg/kg day) following either oral ingestion,
dermal contact, or inhalation route respectively using the
methods described in equations 1-3 (Bwatanglang et al.,
2019; Mehdi et al., 2019; Dehghania et al., 2019;
Kamarehie et al.,2019).
Sa m p le p o int
3. Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria
Int. J. Toxicol. Environ. Health 097
ADI ๐๐๐ =
10โ6ร C๐ ๐๐๐ร (๐๐๐R ร ๐ธ๐น ร ๐ธ๐ท)
(๐ต๐ ร ๐ด๐)
(1)
๐ด๐ท๐ผ๐๐โ =
๐ถ๐ ๐๐๐ร (๐๐โ๐ ร ๐ธ๐น ร ๐ธ๐ท)
(๐๐ธ๐น ร ๐ต๐ ร ๐ด๐)
(2)
๐ด๐ท๐ผ๐๐๐๐๐๐ =
10โ6ร ๐ถ๐ ๐๐๐ร (๐๐ด ร ๐ด๐น ร ๐ด๐ต๐ ร ๐ธ๐น ร ๐ธ๐ท)
(๐ต๐ ร ๐ด๐)
(3)
The ADIing, ADIinh, and ADIdermal stands for average
daily intake (ADI) for ingestion, inhalation and dermal
exposure path ways respectively, While Csoil is the
concentration of metal in the soil samples. Other
parameters and their corresponding functions are
described in Table 1 (Sun and Chen 2018; Timothy, 2019).
Target Hazard Quotient (THQ) was used to analyze the
potential non-carcinogenic effect of the metals in the soil
samples by relating the estimated ADI of each elements
with their reference dose (RfD) for each exposure path way
as described in equation 4 (Sun and Chen 2018; Qasemi
et al., 2019). The health index (HI), expressed as the sum
of the THQ as described in equation 5 is used in the study
to describe the cummulative non-carcinogenic effect
(DEA, 2010; USEP 1999). The RfD for each metal and for
each exposure path way are presented in Table 2.
Table 1. Exposure factors used for the health risk assessment through different exposure Path ways for soil
Factor Unit Children Adults
Body weight (BW) kg 15 60
Exposure frequency (EF) days/year 350 350
Exposure duration (ED) years 6 30
Ingestion rate (ingR) mg/day 200 100
Inhalation rate (inhRair) m3/day 10 20
Skin surface area (SA) m2 2100 5800
Soil adherence factor (AF) mg/cm2 0.2 0.7
Dermal Absorption factor (ABS) - 0.1 0.1
Particulate emission factor (PEF) m3/k 1.3 x 109 1.3 x 109
Conversion factor (CF) kg/mg 10-6 10-6
Average time (AT) days
For carcinogen 365 x 70 365 x 70
For non-carcinogens 365 x ED 365 x ED
(Bwatanglang et al., 2019)
Table 2. Reference doses (RfD) in (mg/kg-day) and Cancer Slope Factors (CSF) for the individual heavy metals per
exposure path ways
Elements RfDing RfDdermal RfDinh CSFing CSFdermal CSFinh
Cd 5.60E-04 5.00E-04 5.7E-05 3.80E-01 - 6.30E+00
Pb 3.60E-03 5.25E-04 3.52E-03 8.50E-03 - 4.20E-02
Cr 3.00E-03 6.00E-05 3.00E-05 5.00E-01 - 4.10E+01
Cu 3.70E-02 2.40E-02 4.02E-02 - - -
Zn 3.00E-01 7.50E-02 3.00E-01 - - -
Ni 2.00E-02 5.60E-03 - - - 8.40E-01
(Timothy, 2019)
The cancer risk index (CRI) which represents the
probability of developing any type of cancer over a lifetime
is calculated by integrating the ADI with the respective
cancer slope factors (CSF) for each metal. The description
is presented in equation 6 (Sun and Chen 2018; Rezaei et
al., 2019 ).
THQ = ADIi/RfDi (4)
HI=ฮฃTHQi (5)
CRI= ADIi x CSFi (6)
A THQ or HI < 1 signify no associated risk, meaning the
exposed population is unlikely to experience any adverse
health hazard. A level of concerns however exist, if the
THQ or HI >1 (Sun and Chen 2018). Furthermore, the CRI
is considered negligible if the CRI < 10-6, acceptable or
tolerable if CRI is 10-6<CRI <10-4, and similarly considered
high if the CRI > 10-4. Equation 7, provides a complete
picture of the cancer risk for an individual following the
combination of all the metals over a lifetime for all the
exposure path ways.
TCRI= CRI (ing) + CRI (inh) + CRI (dermal) (7)
Where, CRI (ing), CRI (inh), and CRI (dermal) are risks
contributions through ingestion, inhalation and dermal path
ways respectively (Kumunda et al., 2016).
RESULTS AND DISCUSSION
The mean concentration distribution of the heavy metals in
surface soil samples along Hong major road were
presented in Table 3. While the calculated ADIi values for
each element and for each exposure path way were
4. Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria
Timothy N. 098
presented in Table 4. Also the non-carcinogenic and
cancer risk posed by the presence of Cd, Pb, Zn, Cr, Ni
and Cu in soil samples along major road (Pliafu, Shiwa,
Fadama-reke and Damdrai) in Hong Adamawa state
through different exposure path ways (ingestion, inhalation
and dermal contact) were presented in Tables 5 and 6
respectively. The comprehensive result of non-
carcinogenic and cancer risk for various heavy metals and
the multiple exposure path ways for each area was
summarized in Tables 7 and 8 respectively.
Table 3: Mean concentration distribution of the heavy metals in surface soil samples along Hong major road (mg/kg)
Heavy Metals Sample location
Pliafu Shiwa Fadama Reke Damdrai Average
Cd 0.06ยฑ0.03 0.05ยฑ0.02 0.05ยฑ0.02 0.03ยฑ0.01 0.05
Pb 0.75ยฑ0.05 2.85ยฑ0.10 0.80ยฑ0.06 2.00ยฑ0.09 1.6
Zn 0.95ยฑ0.02 1.03ยฑ0.01 1.41ยฑ0.03 1.22ยฑ0.01 1.15
Cr 0.13ยฑ0.00 0.0 0.0 0.14ยฑ0.00 0.07
Ni 0.47ยฑ0.02 0.42ยฑ0.00 0.34ยฑ0.01 0.27ยฑ0.02 0.37
Cu 0.19ยฑ0.00 0.27ยฑ0.03 0.29ยฑ0.01 0.15ยฑ0.02 0.23
Total 2.55 4.62 2.94 3.81
All values represent mean ยฑ SD (Standard Deviation) of triplicates determinations.
Table 4: Average daily intake (ADI) values in mg/kg/day for adults and children in surface soil samples along Hong major
road
Elements ADIing ADIinh ADIdermal
Adults Children Adults Children Adults Children
Cd 8.75E-03 1.40E-02 1.35E12 5.38E11 3.55E-02 2.90E-03
Pb 2.80E-01 4.48E-01 4.74E13 1.72E13 1.37E-01 9.40E-02
Cr 1.22E-02 1.96E-02 1.88E12 7.54E11 4.97E-02 4.10E-03
Cu 4.02E-02 6.44E-02 6.19E12 2.48E12 1.63E-01 1.35E-02
Zn 2.01E-01 3.22E-01 3.09E13 1.24E13 8.17E-01 6.76E-02
Ni 6.47E-02 1.04E-01 9.96E12 3.98E13 2.66E-01 2.17E-02
AV. ADI 1.14E-01 1.62E-01 1.63E13 1.22E13 4.11E-01 3.39E-02
Table 5. Target Hazard quotient (THQ) values for heavy metals in adults and children for surface soil samples along Hong
major road for non-carcinogenic risk
Elements THQing THQinh THQdermal
Adults Children Adults Children Adults Children
Cd 15.63 25.00 2.36E15 9.43E14 71.00 5.80
Pb 77.77 124.44 1.34E16 4.88E15 260.95 179.04
Cr 4.07 6.533 6.26E16 1.25E16 828.33 68.33
Cu 1.09 1.74 2.28E14 6.16E13 6.79 0.56
Zn 0.67 1.07 1.03E14 4.13E13 10.89 0.96
Ni 3.24 5.20 - - 47.5 3.87
HI 102.45 163.97 7.86E16 1.84E16 1225.46 258.5
Table 6. Cancer risk index (CRI) values for heavy metals in adults and children for surface soil samples along Hong major
road
Elements CRIing CRIinh CRIdermal
Adults Children Adults Children Adults Children
Cd 0.0033 0.0053 8.50E12 3.38E12 - -
Pb 0.0023 0.0380 1.99E12 7.22E11 - -
Cr 0.0061 0.0098 7.70E12 3.09E12 - -
Cu - - - - - -
Zn - - - - - -
Ni - - 8.36E12 3.34E13 - -
TCRI 0.0117 0.0531 2.65E13 4.05E13 - -
Table 7: Non-carcinogenic hazard indexes (HI) for the six heavy metals and the three exposures path ways for the sample
area
Sample area Pliafu Shiwa Fadama-reke Damdrai
Total Non-Carcinogenic Risk 1.99E14 3.60E14 2.29E14 2.96E14
5. Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria
Int. J. Toxicol. Environ. Health 099
Table 8: Cancer risks for the Six heavy metals and the three exposure pathways for the sample area
Sample area Pliafu Shiwa Fadama-reke Damdrai
Total Cancer Risk 3.61E14 6.54E14 4.17E14 5.38E14
The mean concentrations of the selected heavy metal
pollutants determined in the roadside surface soil samples
in Hong were presented in Table 3. There was observed
high concentration of Pb, followed by Zn, Ni, Cu, Cd and
Cr in all the four examined areas. This finding agrees with
the findings of Alexander et al. (2018) who state that the
concentrations of Pb and Zn were higher in roadside soils
compared to other heavy metals.
The high concentration of Pb and Zn may be attributed to
metal construction works, tire wear, galvanized parts such
as fuel tanks, brake wear, welding of metals, exhaust gas
and worn metal alloys in the engine as well as mechanical
and dry cell battery workshop (Winther and Slentรธ, 2010)
which is a common practice alone the major roads in Hong
town. The heavy metals in urban roadside soil take their
origin from sources such as tire wear, vehicle emissions,
repairs, painting, panel beating, battery charging, iron-
bending, and discharges from industries, lubricating oil
and corrosion of vehicle parts (Akbar et al., 2016). Zn, Pb,
Cr, Cd, Cu and Ni come mainly from vehicular activities
such as tire wear, wear of brake linings, discharge from
battery, emission from gasoline vehicles, studded tires,
vulcanizing, smelting, soldering work and engine wear.
Corrosion of radiator, bushing and brake wirers and the
various types of friction materials and deicing chemicals
used on road surfaces for slipperiness control could
release metals such Ni, Cr, and Cu into the environment
(Alexander et al., 2018; Shinggu 2014).
Roadways and automobiles are considered to be one of
the largest sources of heavy metals. Lead, Zinc and
copper are three of the most common heavy metals
released from vehicle emission accounting for most of the
heavy metals in road runoff.
Based on the exposure factors listed in Table 1, the
calculated ADIi values for each element and for each
exposure path way (Table 4) for both the adults and
children were observed to fall in this order
Pb>Zn>Ni>Cu>Cr>Cd. However, these values were
observed to be higher than their RfD values (Table 2).
From the result, the average exposure dose of the three
exposure path ways for both adult and children observed
to increase in the order of ADIdermal<ADIing<ADIinh. The
overall result showed that adults are more susceptible to
higher level of exposure dose compared to the children
except in ingestion in which children were more exposed
(Table 4). This observation may be so because adult are
directly involved in the activities that produces such heavy
metals.
The target hazard quotient (THQ) (Table 5) for all the
elements following each exposure path way were
observed to be >1, except Zn in ingestion for adults and in
dermal for children and also Cu for children in dermal. The
THQing values for both the adults and children were
observed to follow the ranking Pb>Cd>Cr>Ni>Cu>Zn. The
THQinh values for both the adults and children observed
to follow the order Cr>Pb>Cd>Cu>Zn. While the exposure
through the dermal route were observed to follow the
ranking Cr>Pb>Cd>Ni>Zn>Cu for both adults and
children. The THQ < 1 recorded for Zn and Cu further
suggest no associated risk following either the ingestion or
dermal exposure for both the adults and children. However
The THQ>1 recorded for all the elements showed higher
risk associated following the ingestion, inhalation and
dermal exposure for both the adults and children. The non-
carcinogenic risks posed by combining the respective THQ
values for each exposure path way were observed to leads
to human health index (HI) values >1, which means there
is risk possibility associated with all the three exposure
path ways for both the adults and children. However, the
HI values for adults were observed to be much higher than
the children for THQinh and THQdermal suggesting that,
at a relatively high level of exposure, adults will be more
likely at risk than the children. But for THQing the HI values
for children were observed to be higher than the adults
suggesting that, at a relatively high level of exposure,
children will be more likely at risk than the adults this
finding agreed with the report of Bwatanglang et al.,(2019)
which could be linked to the higher intake rates per unit
body weight observed in children (Xiao et al., 2017; Sun
and Chen, 2018) The HI values were observed to fall in
this order HIinh>HIdermal>HIing. The result was observed
to fall in different category with the findings conducted on
the road dust in urban parks of Beinjing (Du et al., 2013)
and the road dust sample in the city of Duzce, Turkey
(Taลpฤฑnar and Bozkurt 2018).
The lifetime cancer risk index (CRI) for the adults and
children were presented in Table 6. The
carcinogenic risk was analyzed for Pb, Cd, Cr and Ni for
the ingestion and inhalation exposure path ways only. For
regulatory purposes, a cancer risk in the range of 10-6 to
10-4 are considered acceptable (Sun and Chen 2018).
From the results presented in the table, the CRI for both
ingestion and inhalation exposure path ways were
observed to be higher than the acceptable limit (< 10-4).
The CRIing for both age categories were observed to be
in the order of Cr >Pb >Cd and the CRIinh in the order
Ni>Cr>Cd>Pb. In all, the CRI for ingestion exposure path
ways were observed to be higher in children than the
adults. While in inhalation exposure path way all the CRI
values were observed to be higher in adults than in
children except Ni which is higher in children than in adults.
The combine effect for each exposure path ways show
high possibility of carcinogenic risk by inhalation route.
From the results it will suffice to say that children are more
susceptible to potential carcinogenic risk than the adults
6. Risk Assessment of Human Health by Heavy Metals Exposure to Communities along Hong Major Road in Adamawa State, Nigeria
Timothy N. 100
through ingestion route this could be as a result of their
skin been light as compare to the adult skin. Furthermore,
the inhalation exposure path way was observed to be the
major route compared to the lifetime TCRI by ingestion
exposure route. According to the results, the potential
carcinogenic risk following the ingestion route could come
from Cr exposure. Similarly, exposure to Ni could be the
likely source of carcinogenic risk by inhalation exposure
pathway.
The total non-carcinogenic indices (HI) for various heavy
metals and the multiple exposure path ways for each
sampling area were summarized in Table 7. The risk from
all the sampling area were higher than the thresh value of
1. The heavy metals in soils around all the sampling areas
will cause a problem as a result of high HI value.
Therefore, local residents should not settle near the road
side in order to reduce the effect of the toxicity on human
health.
The comprehensive assessment results of cancer risk in
the soils from different sampling area are shown in Table
8. The wide range of cancer risk was calculated from
3.61E14 - 6.54E14 in Pliafu and shiwa respectively. By the
US environmental protection agency, our results showed
higher risk than an acceptable value of 1E-06 โ 1E-04. The
total combined risk (TCR) show the following decreasing
order 6.54E14>5.38E14> 4.17E14>3.61E14 for
Shiwa>Damdrai> Fadama-reke>Pliafu respectively.
CONCLUSION
The influence of heavy metals (Cd, Pb, Cr, Zn, Cu and Ni)
concentration in soils around four different sample points
along major road in Hong on human health risk through
different exposure path ways was investigated. The result
revealed that the extent of human health risk varied with
exposure path way, metal species and sample area. The
calculated ADIi values for each element and for each
exposure path way for both the adults and children were
observed to fall in this order Pb>Zn>Ni>Cu>Cr>Cd. The
target hazard quotient (THQ) for all the elements following
each exposure path way were observed to be >1, except
Zn in ingestion for adults and in dermal for children and
also Cu for children in dermal. However, the HI values for
adults were observed to be much higher than the children
for THQinh and THQdermal suggesting that, at a relatively
high level of exposure, adults will be more likely at risk than
the children. The CRI for both ingestion and inhalation
exposure pathways were observed to be higher than the
acceptable limit (<10-4). Furthermore, the inhalation
exposure path way was observed to be the major route
compared to the lifetime TCRI by ingestion exposure
route. According to the results, the potential carcinogenic
risk following the ingestion route could come from Cr
exposure. Similarly, exposure to Ni could be the likely
source of carcinogenic risk by inhalation exposure path
way. The total non-carcinogenic indices (HI) for various
heavy metals and the multiple exposure path ways for
each sampling area were higher than the thresh value of
1. The heavy metals in soils around all the sampling area
will cause a problem as a result of high HI value. The
comprehensive assessment results of cancer risk in soils
from different sampling area and the multiple exposure
path ways show the following decreasing order
Shiwa>Damdrai> Fadama-reke>Pliafu. Therefore, local
residents should not settle near the road side in order to
reduce the effect of the toxicity of these heavy metals on
human health.
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Accepted 4 December 2019
Citation: Timothy N (2019). Risk Assessment of Human
Health by Heavy Metals Exposure to Communities along
Hong Major Road in Adamawa State, Nigeria. International
Journal of Toxicology and Environmental Health, 4(2):
095-101.
Copyright: ยฉ 2019 Timothy N. This is an open-access
article distributed under the terms of the Creative
Commons Attribution License, which permits unrestricted
use, distribution, and reproduction in any medium,
provided the original author and source are cited.