This document discusses different types of semiconductors including intrinsic and extrinsic semiconductors. N-type semiconductors are created by doping with group 5 elements like arsenic or phosphorus which donate extra electrons making electrons the majority carriers. P-type semiconductors are doped with group 3 elements like boron which accept electrons leaving holes as the majority carriers. Intrinsic semiconductors have equal numbers of electrons and holes while extrinsic semiconductors are doped to alter the balance of electrons and holes.

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2. Semiconductor Physics
Metals(Conductors)
Insulators
Semiconductors
N-Type Semiconductors
P-Type Semiconductors
Intrinsic Semiconductors
Extrinsic semiconductors

3. Metals(Conductors):
• The materials which easily allow the
flow of electric current through them
are called as conductors. Metals such
as copper, silver, iron, aluminum etc.
are good conductors of electricity.

4. Metals(Conductors)

5. Insulators
The materials which does not allow the flow of electric
current through them are called as insulators.
Insulators are also called as poor conductors of
electricity.

6. Insulators

7. Semiconductors
The material which has electrical conductivity
between that of a conductor and an insulator is
called as semiconductor. Silicon, germanium and
graphite are some examples of semiconductors.

8. Semiconductors

11. N-Type Semiconductors
 In addition to replacing one of the lattice atoms with a Group
3 atom, we can also replace it by an atom with five valence
electrons, such as the Group 5 atoms arsenic (As) or
phosphorus (P). In this case, the impurity adds five valence
electrons to the lattice where it can only hold four. This means
that there is now one excess electron in the lattice (see figure
below). Because it donates an electron, a Group 5 impurity is
called a donor. Note that the material remains electrically
neutral.

12. N-Type Semiconductors

13. Donor impurities donate negatively charged electrons
to the lattice, so a semiconductor that has been doped
with a donor is called an n-type semiconductor; "n"
stands for negative. Free electrons outnumber holes in
an n-type material, so the electrons are the majority
carriers and holes are the minority carriers.
N-Type Semiconductors

14. In a pure (intrinsic) Si or Ge semiconductor, each nucleus uses
its four valence electrons to form four covalent bonds with its
neighbors (see figure below). Each ionic core, consisting of the
nucleus and non-valent electrons, has a net charge of +4, and is
surrounded by 4 valence electrons. Since there are no excess
electrons or holes In this case, the number of electrons and
holes present at any given time will always be equal.
P-Type Semiconductors

15. P-Type Semiconductors

16. Now, if one of the atoms in the semiconductor lattice is
replaced by an element with three valence electrons, such
as a Group 3 element like Boron (B) or Gallium (Ga), the
electron-hole balance will be changed. This impurity will
only be able to contribute three valence electrons to the
lattice, therefore leaving one excess hole (see figure below).
Since holes will "accept" free electrons, a Group 3 impurity
is also called an acceptor.
P-Type Semiconductors

18. Because an acceptor donates excess holes, which are considered
to be positively charged, a semiconductor that has been doped
with an acceptor is called a p-type semiconductor; "p" stands for
positive. Notice that the material as a whole remains electrically
neutral. In a p-type semiconductor, current is largely carried by
the holes, which outnumber the free electrons. In this case, the
holes are the majority carriers, while the electrons are the
minority carriers.
P-Type Semiconductors

21. Intrinsic Semiconductors: An intrinsic semiconductor is made
up of a very pure semiconductor material i.e. it is the one
where the number of holes is equal to the number of electrons
in the conduction band
Extrinsic semiconductors:Extrinsic semiconductors are those
where a small amount of impurity has been added to the basic
intrinsic material. The phenomenon of adding an impurity to
the material is known as doping.