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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1071
EVALUATION OF WATER QUALITY OF KHARUN RIVER STRETCH
NEAR THE RAIPUR CITY
Dr. S. R. Mise1 , Sadik Mujawar2
1Professor, Dept. Of civil engineering, PDA College of Engineering, Kalaburagi, Karnataka, India
2PG student, Dept. of civil engineering, PDA College of Engineering, Kalaburagi, Karnataka, India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - In the same means that no 2 human bodies
are alike, no 2 bodies of water are a similar. Ponds across a
street from one another will usually have completely
different physical and chemical characteristics even
supposing they're separated by solely some feet. Very
similar to tests performed at a doctor’s workplace, skilled
environmentalists will use water quality parameters to
assess the health of a water body and confirm what every
specific water body may have.
Water is vitally important to each facet of our lives.
Observance of the quality of surface water can facilitate
defend our waterways from pollution. Water quality
problems influence human and environmental health,
therefore the more we monitor our water the better we
will be able to recognize and prevent contamination
issues. The assessment of water quality of Kharun River
becoming important because of various reasons. So many
studies have suggested the water quality improvement
programs for the Kharun River. Still the Kharun river has
been neglected. In the present study, it is found that the
river stretch near the Jamrao has severely polluted
whereas the river stretch found of good quality near Jheet
ufra area.
Key Words: Water quality, physico-chemical assessment,
physico-chemical parameters, Water pollution, Kharun
River
1.INTRODUCTION
Rivers are the utmost important water resources for
domestic, industrial and irrigation purposes. Importance
of water, in maintaining a healthy as well as a prosperous
nation in healthy environment is understood from the
existence of the civilization on this globe. Water resources
are primarily accustomed satisfying the daily desires of
living world in and around them. The stream receives
domestic and different wastes frequently. The largest
source of water pollution in India is untreated sewage.
Other sources of pollution include agricultural runoff and
unregulated small scale industry. Rivers have transitioned
from being the arteries of this life supporting system to
changing into the stagnant storehouses of our
development waste, that has led a few rivers to even stop
flowing. Environmental Flows as a concept evolved for this
very crisis management, which brings in the voices of the
voiceless backed by the developments in the scientific
understanding of our ecosystem.
The assessment of water quality of Kharun River
becoming utmost important because of various reasons
like rapid urbanization, agricultural and industrial waste,
sewage water comprises of domestic, medical and other
wastes due to anthropogenic activities. Open defecation is
another reason behind the pollution of river water. More
than a half of the population living near the river defecates
in open and takes bath in the river bank. Rapid
urbanization and industrialization have pessimal
contribution to the polluted state of Raipur city, because of
which it gained third rank in the list of polluted cities of
India. . Raipur's 'Smart City' proposal document
mentioned that the Kharun river is being threatened by
pollution from the industries which are on the outskirts of
the city. Raipur is the major commercial center and
upcoming business hub of Chhattisgarh. Thus, the Kharun
River stretch was selected for the study.
Surface water inflow into the State of Chhattisgarh (India)
is through four major interstate rivers Ganga, Mahanadi,
Godavari, and Narmada. The river waters are utilized for
irrigation, urban water supply and aquaculture. The
estimated surface water available for use is around 41,720
Million Cubic Meter (MCM). In Chhattisgarh, surface water
is mostly of good quality, but pollution is increasing in
major towns due to increasing urbanization. Rivers such
as Shivnath, Hasdeo, Indrawati, Kharun etc. are found to
be polluted at different stretches due to industrial,
domestic and agricultural pollution.
2. MATERIALS AND METHODS
2.1 Study area
Kharun river basin forms a part of Seonath (A tributary of
Mahanadi) river basin. It is situated inside the Seonath
basin of well-known Mahanadi river basin in Chhattisgarh.
It is a non-perennial river, originating from village
Petechua of Balod Tehsil in the south-east of Durg district
and after flowing about 164 km joins Seonath river near
Somnath in the north. The total catchment area of Kharun
river is 4191 km2, lying upstream to the point where the
river merges with Seonath river and is situated between
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1072
the geographical co-ordinates 20°33’30” - 21°33’38”N
latitude and 81°17’ 51” E - 81°55’ 25” E longitude.
2.2 Sampling and Analysis
The study area for the Kharun river water quality
assessment was taken along its stretch of 25 kilometers,
depending upon the site conditions, the importance of the
site and access to those sites for sampling purpose. For the
water sampling of Kharun river in Raipur, total 7 locations
(named as in Table 2.1) were fixed along the stretch falling
under the urban area. Depending upon the site conditions,
Kharun river stretch is divided into multiple stretches.
Each of the stretch is identified with all point sources
which can be industrial effluent outfalls, domestic sewage
outfalls etc. Characterization is done by sample collection
and analysis. The water samples were collected for three
seasons viz., Summer, Post-monsoon, Winter, and samples
were analyzed for 13 physicochemical parameters. The
parameters like pH, Electrical conductivity and Dissolved
oxygen, TDS were monitored on site using portable
measuring devices and other parameters were analyzed in
the laboratory. Water samples were collected in stopper
fitted polyethylene bottles and refrigerated at 4°C in order
to be analyzed as soon as possible.
Table 2.1: List of Sampling locations
Location Notation
Near Jheet ufra RK1
Near Raweli RK2
Near Jamrao RK3
Near Mundara RK4
Near kathadih RK5
Near Gughwa Ufra RK6
Near Keshav Farms RK7
The water samples were analyzed for the
following 13 water quality parameters: (1) pH (2)
Electrical Conductivity (EC) (3) Total dissolved solid (TDS)
(4) Turbidity (5) Total Alkalinity (6) Total Hardness (7)
Dissolved oxygen (DO) (8) Chemical oxygen demand
(COD) (9) Biochemical oxygen demand (BOD). (10) Sulfate
(11) phosphorous (12) Ammonia nitrogen (13) Nitrate
nitrogen.
pH of the water sample was carried out using Thermo
Scientific Orion Star 3-Star Plus benchtop meter. The DO,
EC, TDS of the water sample were evaluated using Hach
HQ30d portable multiparameter meter with their
respective probes. The turbidity of water sample was
measured using Hach 2100P IS Portable turbidimeter.
Alkalinity of sample is determined by titration method,
whose procedure is in accordance to Central Pollution
Control Board (CPCB) guide manual for water and waste-
water analysis. Hardness is determined by the EDTA
method. The Chemical Oxygen demand of the water
sample is determined using titrimetric and colorimetric
method using COD digester. The concentration of
Ammonia Nitrogen is determined using Ammonium Probe.
The concentration of Nitrate Nitrogen in water is
determined using Cadmium Reduction Method. The sulfate
concentration is determined by SulfaVer4 Hach method.
The total phosphate concentration is determined by Acid
Persulfate digestion method.
3. RESULTS AND DISCUSSION
The water samples from the Kharun River are collected
and analyzed for different water quality parameters
during different seasons. The results are shown in tables
3.1, 3.2 and 3.3.
The pH of water samples of seven monitoring stations is
measured for three seasons viz., summer, post-monsoon
and winter. It was observed that although there is slight
variation in pH, but it is within the prescribed limits. The
results of pH varied from 6.98 to 8.3 (Chart - 3.1) may be
due to joining of untreated municipal sewage with the
river water, the pH indicates that the water samples are
almost neutral to sub-alkaline in nature. The average value
for Kharun river found 7.64. The highest pH value 8.3 was
observed in RK1 sample in summer.
Chart - 3.1: Seasonal Variation of pH
6.00
6.50
7.00
7.50
8.00
8.50
RK1 RK2 RK3 RK4 RK5 RK6 RK7
pH
Sampling locations
Summer season Post Monsoon season
Winter season Avg
8.3
6.98
7.64
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1073
The EC value is an index that represents the concentration
of soluble salts in water. The EC variation is shown in
chart - 3.2. The highest value 1376µS/cm is found in RK3
sample during summer season may be due to low flow
during summer and inflow of a wastewater nallah near the
site and lowest value 126.6 µS/cm found at RK1 site. The
average EC 406.83 µS/cm of all the samples and of all the
seasons found greater than the prescribed limit.
Chart - 3.2: Seasonal Variation of EC
Table 3.1: Concentrations of water quality parameters of Kharun River for Summer season
Sr.
No.
Parameters
Sampling sites
Min Max Mean SD CV%
RK1
RK
2
RK3 RK4 RK5 RK6 RK7
1 pH 8.3
8.0
3
7.5 7.2 7.53 7.71 8.08 7.2 8.3 7.76 0.39 5.00
2 EC (µS/cm)
138.
8
527
137
6
495 683
559.
4
589.
2
138.
8
137
6
624.0
6
373.2
4
59.81
3 TDS (mg/L) 69.3
77.
9
433
326.
8
329.
4
281.
3
295 69.3 433
258.9
6
135.6
5
52.38
4
Alkalinity (mg/L as
CaCO3)
61.1 85 357 208
183.
5
187.
7
143.
9
61.1 357
175.1
7
97.03 55.39
5 Hardness(mg/L as CaCO3) 56.8 143 276 281 157
183.
1
183.
5
56.8 281
182.9
1
77.95 42.61
6 COD (mg/L) 8 12 88 49 68 43 21 8 88 41.29 29.82 72.23
7 BOD (mg/L) 7.5 9.3 43.3 22.6 43.4 28.3 9.8 7.5 43.4 23.46 15.58 66.44
8 DO (mg/L) 8.7 8.1 1.7 7.7 5.3 6.9 10.7 1.7 10.7 7.01 2.87 40.85
9 Sulfate (mg/L) 0.3 1.3 4.9 5.6 7.9 7.7 23.4 0.3 23.4 7.30 7.67
105.1
3
10
Ammonical
Nitrogen(mg/L)
0.13
1.6
6
24.4 10.3 10.7 2.2 1.9 0.13 24.4 7.33 8.67
118.3
7
11 Nitrate Nitrogen (mg/L) 0.6 1.9 9.3 2.3 1.6 3.6 1.5 0.6 9.3 2.97 2.94 98.80
12 Phosphorous (mg/L) 0.27
3.5
6
0.4 2.33 2.73 2.81 1.13 0.27 3.56 1.89 1.29 68.16
13 Turbidity (NTU) 6.6
3.7
7
17.9 5.3 11.2 0.7 5.1 0.7 17.9 7.22 5.67 78.48
Table 3.2: Concentrations of water quality parameters of Kharun River for Post - monsoon season
Sr.
No.
Parameters
Sampling sites
Min Max Mean SD CV%
RK1 RK2 RK3 RK4 RK5 RK6 RK7
1 pH 7.6 7.91 7.12 7.56 7.61 7.83 7.8 7.12 7.91 7.63 0.26 3.44
1376
126.6
0
200
400
600
800
1000
1200
1400
1600
RK1 RK2 RK3 RK4 RK5 RK6 RK7
EC(µS/cm)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
406.83
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1074
2 EC (µS/cm)
126.
6
132.
1
389.
3
157
169.
1
155.
3
188.
7
126.
6
389.
3
188.3
0
91.1
1
48.38
3 TDS (mg/L) 88.1 88.3 253
101.
7
105
101.
9
128.
7
88.1 253
123.8
1
58.5
6
47.29
4
Alkalinity (mg/L as
CaCO3)
89.2 93 213 101 108 103 108 89.2 213
116.4
6
43.1
6
37.06
5
Hardness(mg/L as
CaCO3)
84 99 178 99 104 99.2 117 84 178
111.4
6
30.9
0
27.72
6 COD (mg/L) 3 6 35 28 30 21 13 3 35 19.43
12.3
9
63.79
7 BOD (mg/L) 3.3 4.5 19 12.7 19.8 13.4 5.8 3.3 19.8 11.21 6.81 60.74
8 DO (mg/L) 7.3 6.9 1.3 8.4 6.7 8.3 7.7 1.3 8.4 6.66 2.45 36.79
9 Sulfate (mg/L) 1 1 9.3 1.7 2.4 2.3 2.6 1 9.3 2.90 2.90 99.86
10
Ammonical
Nitrogen(mg/L)
0.21 0.27 6.2 0.69 0.79 0.5 0.33 0.21 6.2 1.28 2.18
169.6
1
11 Nitrate nitrogen (mg/L) 1.5 1.1 3.5 1.4 1.4 1.2 1.9 1.1 3.5 1.71 0.83 48.27
12 Phosphorous (mg/L) 0.22 3.51 0.4 2.66 2.97 3.44 1.38 0.22 3.51 2.08 1.40 67.32
13 Turbidity (NTU) 7.6 1.4 6.7 3 5.2 1.8 6.3 1.4 7.6 4.57 2.49 54.54
Table 3.3: Concentrations of water quality parameters of Kharun River for Winter season
Sr.
No.
Parameters
Sampling sites
Min Max Mean SD CV%
RK1 RK2 RK3
RK
4
RK
5
RK6 RK7
1 pH 8.05 7.81 6.98 7.3
7.2
3
7.36 7.91 6.98 8.05 7.52 0.40 5.34
2 EC (µS/cm)
125.
2
130.
1
541 515 501
507.
6
537
125.
2
541
408.1
3
192.1
6
47.08
3 TDS (mg/L) 61.9 65.5
278.
6
263 267 259
261.
5
61.9
278.
6
208.0
7
98.83 47.50
4
Alkalinity (mg/L as
CaCO3)
53.1 54 165 187 173 177 131 53.1 187
134.3
0
57.87 43.09
5 Hardness(mg/L as CaCO3) 54 63 163 157 155
166.
3
161 54
166.
3
131.3
3
49.96 38.04
6 COD (mg/L) 4 10 74 41 53 34 19 4 74 33.57 24.87 74.07
7 BOD (mg/L) 4.5 7.8 33.6
19.
5
30.
5
22.6 8.8 4.5 33.6 18.19 11.50 63.24
8 DO (mg/L) 9.2 8.7 0.9 6.5 5.4 7.9 12.9 0.9 12.9 7.36 3.71 50.39
9 Sulfate (mg/L) 0 1.4 4.5 4.7 7.1 7.5 23 0 23 6.89 7.62
110.6
1
10
Ammonical
Nitrogen(mg/L)
0.11
7
0.14
9
3.8
2.8
9
3.1 2.59 1.42
0.11
7
3.8 2.01 1.47 72.96
11 Nitrate nitrogen (mg/L) 0.45 1.6 7.8 2.8 1.7 2.2 0.9 0.45 7.8 2.49 2.47 98.92
12 Phosphorous (mg/L) 0.2 3.2 0.33
2.4
9
2.7
7
2.61 1.28 0.2 3.2 1.84 1.23 66.61
13 Turbidity (NTU) 5.3 3 16.2 4.9
10.
7
0.96 4.4 0.96 16.2 6.49 5.21 80.28
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1075
Chart – 3.3: Total dissolved solids
A high concentration of dissolved solids greatly affects the
taste of the drinking water. The observed values of TDS
nowhere exceeded the prescribed limits. The variation is
shown in Chart-3.3. The highest value 433 mg/L is found
for RK3 sample during summer season and lowest value
61.9 mg/L is found in RK1 sample in winter. The average
value for Kharun River found 196.95 mg/L which is below
the limit. Comparatively the highest values are found
during summer season because of reduction in water
flows during summer. TDS during each season were
almost same for samples of RK4, RK5, RK6 and RK7.
The alkalinity of water is its capacity to neutralize acid.
The amount of a strong acid needed to neutralize the
alkalinity is called the total alkalinity. The observed values
of Alkalinity nowhere reached the prescribed limits. The
variation is shown in chart - 3.4. The highest value 357
mg/L is found for sample RK3 in summer season may be
due to the discharge of domestic sewage at RK3 site, which
puts certain amounts of alkaline ions into the river system.
The lowest value 53.1 mg/L is found for RK1 sample.
Hardness of water is an essential parameter considered in
drinking water for satisfying potability. As water moves
through soil and rock, it dissolves very small amounts of
minerals and holds them in solution. The observed Total
hardness values vary from 54 to 281mg/L (chart - 3.5).
The highest value is found for sample RK4 in summer
season and lowest value is found in RK1 sample in winter.
The average value 141.9mg/L falls below the prescribed
limits.
DO is the dissolved gaseous form of oxygen. It is essential
for respiration of fish and other aquatic organisms. When
the water is polluted with large amount of organic matter,
a lot of dissolved oxygen would be rapidly consumed in
the biological aerobic decay which would affect the water
quality; the decreased dissolved oxygen in water would
affect the aquatic lives. The highest value 12.9 mg/L is
found in RK7 sample due to the lowest temperature in
winter season and the lowest 0.9 mg/L is found in RK3
sample after the confluence of a wastewater nallah which
discharges large amount of Organic matter into the river.
The values of DO for RK3 are very less and thus the COD
and BOD values are highest in the particular sample. BOD
values indicate a possibility of Organic pollution effect on
the water body. Almost All the values of BOD are found
highly exceeding the limits. BOD5 values of RK3 and RK5
are found very high in every season after confluence of a
nallah at both the sites. The highest BOD value 43.4 mg/L
is found for RK5 sample in summer and the lowest value
3.3 mg/L is found in RK1 sample in post monsoon season
due to greater distance from the point of contamination
hence the Organic content get dissolved. The average
values for DO, BOD and COD are higher than the
prescribed limits. Their variation is shown in chart 3.6, 3.7,
3.8 respectively.
All the COD values except for RK1 & RK2 for all seasons
are higher than the permissible limits. The highest value
88mg/L is found for RK3 site in summer season and
lowest value 3 mg/L is found in post-monsoon.
Chart - 3.4: Seasonal Variation of Alkalinity
0
50
100
150
200
250
300
350
400
450
500
RK1 RK2 RK3 RK4 RK5 RK6 RK7
TDSconc.(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
433
61.9
196.95
141.98
0
50
100
150
200
250
300
350
400
RK1 RK2 RK3 RK4 RK5 RK6 RK7
Alkalinity(mg/L)
asCaCO3
Sampling locations
Summer season Post Monsoon season
Winter season Avg
357
53.1
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
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Chart - 3.5: Seasonal Variation of Total Hardness
Chart - 3.6: Seasonal Variation of DO
Chart - 3.8: Seasonal Variation of COD
Chart - 3.7: Seasonal Variation of BOD
Sulfate is naturally existed in surface water as SO4
2-.
Biological oxidation of reduced Sulfur species to sulfate
increases its concentration in the water body. Discharge of
industrial wastes and domestic sewage in waters tends to
increase its concentration. The values of Sulfate
concentrations have nowhere reached the critical values
(Chart - 3.9). The higher value 23mg/L is found in RK7
sample during summer and winter seasons and it is found
that sample RK1 is completely free from sulfate
contaminations.
Nitrogen, in the forms of nitrate, nitrite, or ammonium, is
an essential nutrient for plant growth. Ammonia is an
indicator for elevated pollution from Organic substances.
Excess nitrogen can cause overstimulation of growth of
aquatic plants and algae. Excessive growth of these
organisms, in turn, can clog water intakes, use up
dissolved oxygen as they decompose, and block light to
deeper waters. Lake and reservoir eutrophication can
occur, which produces unsightly scums of algae on the
water surface. The high levels of nitrate and nitrite in
drinking water may cause serious illnesses such as
methemoglobinemia or “blue baby syndrome”, cancer
risks, increased starchy deposits, and hemorrhaging of the
spleen.
The results of Nitrate Nitrogen are found very less and
within the limits. The site RK3 which is near to the source
of contamination has the higher value 9.3mg/L. The lowest
value 0.45mg/L is found in RK1 sample.
The average result of Ammonia nitrogen is found
exceeding the prescribed limits. The highest value
24.4mg/L is found in RK3 sample in summer season
shows high level Organic contamination near the site. The
sample RK1 has the lowest value within the limits.
0
50
100
150
200
250
300
RK1 RK2 RK3 RK4 RK5 RK6 RK7
Hardness(mg/L)
asCaCO3
Sampling locations
Summer season Post Monsoon season
Winter season Avg
281
54
141.9
0
2
4
6
8
10
12
14
RK1 RK2 RK3 RK4 RK5 RK6 RK7
DO(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
12.9
0.9
7.01
0
20
40
60
80
100
RK1 RK2 RK3 RK4 RK5 RK6 RK7
COD(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
88
3
31.43
0
5
10
15
20
25
30
35
40
45
50
RK1 RK2 RK3 RK4 RK5 RK6 RK7
BOD(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
43.4
3.3
17.62
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
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The variation of NH3-N, NO3-N concentrations are shown
in fig. 3.10, 3.11.
As Phosphorus concentration in the water increases, the
growth of aquatic vegetation increases. The direct effects
of the excessive growth of aquatic vegetation can include a
reduction in the transmission of solar radiation and
production of toxins. A secondary effect is a decrease in
the dissolved oxygen in the water, when bacteria utilize
the oxygen while decomposing the increased amounts of
dead aquatic vegetation. These effects associated with
increased aquatic vegetation growth often have
detrimental effects on fish and other aquatic life. This
process is a form of eutrophication.
The results of total phosphate are also within the
permissible limits (Chart-3.12). The higher value
3.56mg/L is found in RK3 sample as a result of confluence
of a nallah near the site. The lowest value found in RK1
sample. The average value 1.96mg/L is also below the
limits.
Turbidity is widely concerned as an important parameter
for assessing the water quality. It is a measure of the
relative clarity or cloudiness of water. The occurrence of
turbidity may be permanent or seasonal. The observed
values of turbidity are found very high and almost equal in
summer and post monsoon seasons (chart-3.13). The
highest value 17.9NTU is found in RK3 site during the
summer season due to low flow in summer and joining of a
wastewater nallah at the site. The average value 6.10NTU
found more the than prescribed limit.
Chart - 3.9: Seasonal Variation of Sulfate
Chart - 3.10: Seasonal Variation of NH3-N
Chart - 3.11: Seasonal Variation of NO3-N
Chart - 3.12: Seasonal Variation of Total Phosphate
0
5
10
15
20
25
RK1 RK2 RK3 RK4 RK5 RK6 RK7
SO4(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
23.4
0
5.70
0
5
10
15
20
25
30
RK1 RK2 RK3 RK4 RK5 RK6 RK7
NH3-N(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
24.4
0.117
3.54
0
1
2
3
4
5
6
7
8
9
10
RK1 RK2 RK3 RK4 RK5 RK6 RK7
NO3-N(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
9.3
0.45
2.39
0
0.5
1
1.5
2
2.5
3
3.5
4
RK1 RK2 RK3 RK4 RK5 RK6 RK7
TotalP(mg/L)
Sampling locations
Summer season Post Monsoon season
Winter season Avg
3.56
0.2
1.94
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1078
Chart - 3.13: Seasonal Variation of Turbidity
4. CONCLUSIONS
On observing the seasonal variation, it can be
concluded that the Kharun River is heavily polluted during
the summer than other seasons. The flow reduction during
the summer season contributes to the deterioration of
water quality. The Kharun River near Jamrao is severly
polluted because of joining of a wastewater nallah near the
site. And it is found that the water quality is good near
Jheet ufra. Finally, it can be implied that the preventative
measures taken by the local authorities are still not
sufficient; it is clear that the domestic discharge and
activities on the banks of river are the major threats to
Kharun river’s water quality.
ACKNOWLEDGEMENT
I express my sincere respect and gratitude to my guide
who has given his valuable support, cooperation and
suggestions from time to time in successfully completing
this project and also towards my family, friends for their
ceaseless motivation and encouragement.
REFERENCES
[1] Smita Rout, Asit Kumar Behera, Aliva Patnaik, “Water
Quality Analysis of River Mahanadi in Sambalpur
City”, International Journal of Scientific and Research
Publications, , ISSN 2250-3153, Volume 6, Issue 2,
February 2016, pp 266-270.
[2] S. P. Gorde, M. V. Jadhav, “Assessment of Water
Quality Parameters: A Review”, Int. Journal of
Engineering Research and Applications,
www.ijera.com, ISSN : 2248-9622, Vol. 3, Issue 6, Nov-
Dec 2013, pp 2029-2035.
[3] Dr.Seema Tiwari, “Water Quality Parameters –A
Review”, International Journal of Engineering Science
Invention Research & Development; www.ijesird.com
e-ISSN: 2349-6185, Vol. I Issue IX, March 2015, pp
319-324.
[4] Anjali V Gopi, Dr. Harikumar P S, Akhil Nath G, “Water
Quality Index and Assessment of Physico – Chemical
Parameters Water samples, Calicut city, Kerala state,
India”, International Research Journal of Engineering
and Technology (IRJET) e-ISSN: 2395 -0056, Volume:
04, Issue: 05, May -2017, pp 3003-3006.
[5] USEPA approved HACH methods for water analysis.
[6] Guide Manual for Water and Wastewater Analysis,
Central Pollution Control Board, New Delhi, India,
001-183 (2011).
0
2
4
6
8
10
12
14
16
18
20
RK1 RK2 RK3 RK4 RK5 RK6 RK7
TurbidityNTU
Sampling locations
Summer season Post Monsoon season
Winter season Avg
17.9
0.7
6.10

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Evaluation of Water Quality of Kharun River Stretch Near the Raipur City

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1071 EVALUATION OF WATER QUALITY OF KHARUN RIVER STRETCH NEAR THE RAIPUR CITY Dr. S. R. Mise1 , Sadik Mujawar2 1Professor, Dept. Of civil engineering, PDA College of Engineering, Kalaburagi, Karnataka, India 2PG student, Dept. of civil engineering, PDA College of Engineering, Kalaburagi, Karnataka, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - In the same means that no 2 human bodies are alike, no 2 bodies of water are a similar. Ponds across a street from one another will usually have completely different physical and chemical characteristics even supposing they're separated by solely some feet. Very similar to tests performed at a doctor’s workplace, skilled environmentalists will use water quality parameters to assess the health of a water body and confirm what every specific water body may have. Water is vitally important to each facet of our lives. Observance of the quality of surface water can facilitate defend our waterways from pollution. Water quality problems influence human and environmental health, therefore the more we monitor our water the better we will be able to recognize and prevent contamination issues. The assessment of water quality of Kharun River becoming important because of various reasons. So many studies have suggested the water quality improvement programs for the Kharun River. Still the Kharun river has been neglected. In the present study, it is found that the river stretch near the Jamrao has severely polluted whereas the river stretch found of good quality near Jheet ufra area. Key Words: Water quality, physico-chemical assessment, physico-chemical parameters, Water pollution, Kharun River 1.INTRODUCTION Rivers are the utmost important water resources for domestic, industrial and irrigation purposes. Importance of water, in maintaining a healthy as well as a prosperous nation in healthy environment is understood from the existence of the civilization on this globe. Water resources are primarily accustomed satisfying the daily desires of living world in and around them. The stream receives domestic and different wastes frequently. The largest source of water pollution in India is untreated sewage. Other sources of pollution include agricultural runoff and unregulated small scale industry. Rivers have transitioned from being the arteries of this life supporting system to changing into the stagnant storehouses of our development waste, that has led a few rivers to even stop flowing. Environmental Flows as a concept evolved for this very crisis management, which brings in the voices of the voiceless backed by the developments in the scientific understanding of our ecosystem. The assessment of water quality of Kharun River becoming utmost important because of various reasons like rapid urbanization, agricultural and industrial waste, sewage water comprises of domestic, medical and other wastes due to anthropogenic activities. Open defecation is another reason behind the pollution of river water. More than a half of the population living near the river defecates in open and takes bath in the river bank. Rapid urbanization and industrialization have pessimal contribution to the polluted state of Raipur city, because of which it gained third rank in the list of polluted cities of India. . Raipur's 'Smart City' proposal document mentioned that the Kharun river is being threatened by pollution from the industries which are on the outskirts of the city. Raipur is the major commercial center and upcoming business hub of Chhattisgarh. Thus, the Kharun River stretch was selected for the study. Surface water inflow into the State of Chhattisgarh (India) is through four major interstate rivers Ganga, Mahanadi, Godavari, and Narmada. The river waters are utilized for irrigation, urban water supply and aquaculture. The estimated surface water available for use is around 41,720 Million Cubic Meter (MCM). In Chhattisgarh, surface water is mostly of good quality, but pollution is increasing in major towns due to increasing urbanization. Rivers such as Shivnath, Hasdeo, Indrawati, Kharun etc. are found to be polluted at different stretches due to industrial, domestic and agricultural pollution. 2. MATERIALS AND METHODS 2.1 Study area Kharun river basin forms a part of Seonath (A tributary of Mahanadi) river basin. It is situated inside the Seonath basin of well-known Mahanadi river basin in Chhattisgarh. It is a non-perennial river, originating from village Petechua of Balod Tehsil in the south-east of Durg district and after flowing about 164 km joins Seonath river near Somnath in the north. The total catchment area of Kharun river is 4191 km2, lying upstream to the point where the river merges with Seonath river and is situated between
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1072 the geographical co-ordinates 20°33’30” - 21°33’38”N latitude and 81°17’ 51” E - 81°55’ 25” E longitude. 2.2 Sampling and Analysis The study area for the Kharun river water quality assessment was taken along its stretch of 25 kilometers, depending upon the site conditions, the importance of the site and access to those sites for sampling purpose. For the water sampling of Kharun river in Raipur, total 7 locations (named as in Table 2.1) were fixed along the stretch falling under the urban area. Depending upon the site conditions, Kharun river stretch is divided into multiple stretches. Each of the stretch is identified with all point sources which can be industrial effluent outfalls, domestic sewage outfalls etc. Characterization is done by sample collection and analysis. The water samples were collected for three seasons viz., Summer, Post-monsoon, Winter, and samples were analyzed for 13 physicochemical parameters. The parameters like pH, Electrical conductivity and Dissolved oxygen, TDS were monitored on site using portable measuring devices and other parameters were analyzed in the laboratory. Water samples were collected in stopper fitted polyethylene bottles and refrigerated at 4°C in order to be analyzed as soon as possible. Table 2.1: List of Sampling locations Location Notation Near Jheet ufra RK1 Near Raweli RK2 Near Jamrao RK3 Near Mundara RK4 Near kathadih RK5 Near Gughwa Ufra RK6 Near Keshav Farms RK7 The water samples were analyzed for the following 13 water quality parameters: (1) pH (2) Electrical Conductivity (EC) (3) Total dissolved solid (TDS) (4) Turbidity (5) Total Alkalinity (6) Total Hardness (7) Dissolved oxygen (DO) (8) Chemical oxygen demand (COD) (9) Biochemical oxygen demand (BOD). (10) Sulfate (11) phosphorous (12) Ammonia nitrogen (13) Nitrate nitrogen. pH of the water sample was carried out using Thermo Scientific Orion Star 3-Star Plus benchtop meter. The DO, EC, TDS of the water sample were evaluated using Hach HQ30d portable multiparameter meter with their respective probes. The turbidity of water sample was measured using Hach 2100P IS Portable turbidimeter. Alkalinity of sample is determined by titration method, whose procedure is in accordance to Central Pollution Control Board (CPCB) guide manual for water and waste- water analysis. Hardness is determined by the EDTA method. The Chemical Oxygen demand of the water sample is determined using titrimetric and colorimetric method using COD digester. The concentration of Ammonia Nitrogen is determined using Ammonium Probe. The concentration of Nitrate Nitrogen in water is determined using Cadmium Reduction Method. The sulfate concentration is determined by SulfaVer4 Hach method. The total phosphate concentration is determined by Acid Persulfate digestion method. 3. RESULTS AND DISCUSSION The water samples from the Kharun River are collected and analyzed for different water quality parameters during different seasons. The results are shown in tables 3.1, 3.2 and 3.3. The pH of water samples of seven monitoring stations is measured for three seasons viz., summer, post-monsoon and winter. It was observed that although there is slight variation in pH, but it is within the prescribed limits. The results of pH varied from 6.98 to 8.3 (Chart - 3.1) may be due to joining of untreated municipal sewage with the river water, the pH indicates that the water samples are almost neutral to sub-alkaline in nature. The average value for Kharun river found 7.64. The highest pH value 8.3 was observed in RK1 sample in summer. Chart - 3.1: Seasonal Variation of pH 6.00 6.50 7.00 7.50 8.00 8.50 RK1 RK2 RK3 RK4 RK5 RK6 RK7 pH Sampling locations Summer season Post Monsoon season Winter season Avg 8.3 6.98 7.64
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1073 The EC value is an index that represents the concentration of soluble salts in water. The EC variation is shown in chart - 3.2. The highest value 1376µS/cm is found in RK3 sample during summer season may be due to low flow during summer and inflow of a wastewater nallah near the site and lowest value 126.6 µS/cm found at RK1 site. The average EC 406.83 µS/cm of all the samples and of all the seasons found greater than the prescribed limit. Chart - 3.2: Seasonal Variation of EC Table 3.1: Concentrations of water quality parameters of Kharun River for Summer season Sr. No. Parameters Sampling sites Min Max Mean SD CV% RK1 RK 2 RK3 RK4 RK5 RK6 RK7 1 pH 8.3 8.0 3 7.5 7.2 7.53 7.71 8.08 7.2 8.3 7.76 0.39 5.00 2 EC (µS/cm) 138. 8 527 137 6 495 683 559. 4 589. 2 138. 8 137 6 624.0 6 373.2 4 59.81 3 TDS (mg/L) 69.3 77. 9 433 326. 8 329. 4 281. 3 295 69.3 433 258.9 6 135.6 5 52.38 4 Alkalinity (mg/L as CaCO3) 61.1 85 357 208 183. 5 187. 7 143. 9 61.1 357 175.1 7 97.03 55.39 5 Hardness(mg/L as CaCO3) 56.8 143 276 281 157 183. 1 183. 5 56.8 281 182.9 1 77.95 42.61 6 COD (mg/L) 8 12 88 49 68 43 21 8 88 41.29 29.82 72.23 7 BOD (mg/L) 7.5 9.3 43.3 22.6 43.4 28.3 9.8 7.5 43.4 23.46 15.58 66.44 8 DO (mg/L) 8.7 8.1 1.7 7.7 5.3 6.9 10.7 1.7 10.7 7.01 2.87 40.85 9 Sulfate (mg/L) 0.3 1.3 4.9 5.6 7.9 7.7 23.4 0.3 23.4 7.30 7.67 105.1 3 10 Ammonical Nitrogen(mg/L) 0.13 1.6 6 24.4 10.3 10.7 2.2 1.9 0.13 24.4 7.33 8.67 118.3 7 11 Nitrate Nitrogen (mg/L) 0.6 1.9 9.3 2.3 1.6 3.6 1.5 0.6 9.3 2.97 2.94 98.80 12 Phosphorous (mg/L) 0.27 3.5 6 0.4 2.33 2.73 2.81 1.13 0.27 3.56 1.89 1.29 68.16 13 Turbidity (NTU) 6.6 3.7 7 17.9 5.3 11.2 0.7 5.1 0.7 17.9 7.22 5.67 78.48 Table 3.2: Concentrations of water quality parameters of Kharun River for Post - monsoon season Sr. No. Parameters Sampling sites Min Max Mean SD CV% RK1 RK2 RK3 RK4 RK5 RK6 RK7 1 pH 7.6 7.91 7.12 7.56 7.61 7.83 7.8 7.12 7.91 7.63 0.26 3.44 1376 126.6 0 200 400 600 800 1000 1200 1400 1600 RK1 RK2 RK3 RK4 RK5 RK6 RK7 EC(µS/cm) Sampling locations Summer season Post Monsoon season Winter season Avg 406.83
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1074 2 EC (µS/cm) 126. 6 132. 1 389. 3 157 169. 1 155. 3 188. 7 126. 6 389. 3 188.3 0 91.1 1 48.38 3 TDS (mg/L) 88.1 88.3 253 101. 7 105 101. 9 128. 7 88.1 253 123.8 1 58.5 6 47.29 4 Alkalinity (mg/L as CaCO3) 89.2 93 213 101 108 103 108 89.2 213 116.4 6 43.1 6 37.06 5 Hardness(mg/L as CaCO3) 84 99 178 99 104 99.2 117 84 178 111.4 6 30.9 0 27.72 6 COD (mg/L) 3 6 35 28 30 21 13 3 35 19.43 12.3 9 63.79 7 BOD (mg/L) 3.3 4.5 19 12.7 19.8 13.4 5.8 3.3 19.8 11.21 6.81 60.74 8 DO (mg/L) 7.3 6.9 1.3 8.4 6.7 8.3 7.7 1.3 8.4 6.66 2.45 36.79 9 Sulfate (mg/L) 1 1 9.3 1.7 2.4 2.3 2.6 1 9.3 2.90 2.90 99.86 10 Ammonical Nitrogen(mg/L) 0.21 0.27 6.2 0.69 0.79 0.5 0.33 0.21 6.2 1.28 2.18 169.6 1 11 Nitrate nitrogen (mg/L) 1.5 1.1 3.5 1.4 1.4 1.2 1.9 1.1 3.5 1.71 0.83 48.27 12 Phosphorous (mg/L) 0.22 3.51 0.4 2.66 2.97 3.44 1.38 0.22 3.51 2.08 1.40 67.32 13 Turbidity (NTU) 7.6 1.4 6.7 3 5.2 1.8 6.3 1.4 7.6 4.57 2.49 54.54 Table 3.3: Concentrations of water quality parameters of Kharun River for Winter season Sr. No. Parameters Sampling sites Min Max Mean SD CV% RK1 RK2 RK3 RK 4 RK 5 RK6 RK7 1 pH 8.05 7.81 6.98 7.3 7.2 3 7.36 7.91 6.98 8.05 7.52 0.40 5.34 2 EC (µS/cm) 125. 2 130. 1 541 515 501 507. 6 537 125. 2 541 408.1 3 192.1 6 47.08 3 TDS (mg/L) 61.9 65.5 278. 6 263 267 259 261. 5 61.9 278. 6 208.0 7 98.83 47.50 4 Alkalinity (mg/L as CaCO3) 53.1 54 165 187 173 177 131 53.1 187 134.3 0 57.87 43.09 5 Hardness(mg/L as CaCO3) 54 63 163 157 155 166. 3 161 54 166. 3 131.3 3 49.96 38.04 6 COD (mg/L) 4 10 74 41 53 34 19 4 74 33.57 24.87 74.07 7 BOD (mg/L) 4.5 7.8 33.6 19. 5 30. 5 22.6 8.8 4.5 33.6 18.19 11.50 63.24 8 DO (mg/L) 9.2 8.7 0.9 6.5 5.4 7.9 12.9 0.9 12.9 7.36 3.71 50.39 9 Sulfate (mg/L) 0 1.4 4.5 4.7 7.1 7.5 23 0 23 6.89 7.62 110.6 1 10 Ammonical Nitrogen(mg/L) 0.11 7 0.14 9 3.8 2.8 9 3.1 2.59 1.42 0.11 7 3.8 2.01 1.47 72.96 11 Nitrate nitrogen (mg/L) 0.45 1.6 7.8 2.8 1.7 2.2 0.9 0.45 7.8 2.49 2.47 98.92 12 Phosphorous (mg/L) 0.2 3.2 0.33 2.4 9 2.7 7 2.61 1.28 0.2 3.2 1.84 1.23 66.61 13 Turbidity (NTU) 5.3 3 16.2 4.9 10. 7 0.96 4.4 0.96 16.2 6.49 5.21 80.28
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1075 Chart – 3.3: Total dissolved solids A high concentration of dissolved solids greatly affects the taste of the drinking water. The observed values of TDS nowhere exceeded the prescribed limits. The variation is shown in Chart-3.3. The highest value 433 mg/L is found for RK3 sample during summer season and lowest value 61.9 mg/L is found in RK1 sample in winter. The average value for Kharun River found 196.95 mg/L which is below the limit. Comparatively the highest values are found during summer season because of reduction in water flows during summer. TDS during each season were almost same for samples of RK4, RK5, RK6 and RK7. The alkalinity of water is its capacity to neutralize acid. The amount of a strong acid needed to neutralize the alkalinity is called the total alkalinity. The observed values of Alkalinity nowhere reached the prescribed limits. The variation is shown in chart - 3.4. The highest value 357 mg/L is found for sample RK3 in summer season may be due to the discharge of domestic sewage at RK3 site, which puts certain amounts of alkaline ions into the river system. The lowest value 53.1 mg/L is found for RK1 sample. Hardness of water is an essential parameter considered in drinking water for satisfying potability. As water moves through soil and rock, it dissolves very small amounts of minerals and holds them in solution. The observed Total hardness values vary from 54 to 281mg/L (chart - 3.5). The highest value is found for sample RK4 in summer season and lowest value is found in RK1 sample in winter. The average value 141.9mg/L falls below the prescribed limits. DO is the dissolved gaseous form of oxygen. It is essential for respiration of fish and other aquatic organisms. When the water is polluted with large amount of organic matter, a lot of dissolved oxygen would be rapidly consumed in the biological aerobic decay which would affect the water quality; the decreased dissolved oxygen in water would affect the aquatic lives. The highest value 12.9 mg/L is found in RK7 sample due to the lowest temperature in winter season and the lowest 0.9 mg/L is found in RK3 sample after the confluence of a wastewater nallah which discharges large amount of Organic matter into the river. The values of DO for RK3 are very less and thus the COD and BOD values are highest in the particular sample. BOD values indicate a possibility of Organic pollution effect on the water body. Almost All the values of BOD are found highly exceeding the limits. BOD5 values of RK3 and RK5 are found very high in every season after confluence of a nallah at both the sites. The highest BOD value 43.4 mg/L is found for RK5 sample in summer and the lowest value 3.3 mg/L is found in RK1 sample in post monsoon season due to greater distance from the point of contamination hence the Organic content get dissolved. The average values for DO, BOD and COD are higher than the prescribed limits. Their variation is shown in chart 3.6, 3.7, 3.8 respectively. All the COD values except for RK1 & RK2 for all seasons are higher than the permissible limits. The highest value 88mg/L is found for RK3 site in summer season and lowest value 3 mg/L is found in post-monsoon. Chart - 3.4: Seasonal Variation of Alkalinity 0 50 100 150 200 250 300 350 400 450 500 RK1 RK2 RK3 RK4 RK5 RK6 RK7 TDSconc.(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 433 61.9 196.95 141.98 0 50 100 150 200 250 300 350 400 RK1 RK2 RK3 RK4 RK5 RK6 RK7 Alkalinity(mg/L) asCaCO3 Sampling locations Summer season Post Monsoon season Winter season Avg 357 53.1
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1076 Chart - 3.5: Seasonal Variation of Total Hardness Chart - 3.6: Seasonal Variation of DO Chart - 3.8: Seasonal Variation of COD Chart - 3.7: Seasonal Variation of BOD Sulfate is naturally existed in surface water as SO4 2-. Biological oxidation of reduced Sulfur species to sulfate increases its concentration in the water body. Discharge of industrial wastes and domestic sewage in waters tends to increase its concentration. The values of Sulfate concentrations have nowhere reached the critical values (Chart - 3.9). The higher value 23mg/L is found in RK7 sample during summer and winter seasons and it is found that sample RK1 is completely free from sulfate contaminations. Nitrogen, in the forms of nitrate, nitrite, or ammonium, is an essential nutrient for plant growth. Ammonia is an indicator for elevated pollution from Organic substances. Excess nitrogen can cause overstimulation of growth of aquatic plants and algae. Excessive growth of these organisms, in turn, can clog water intakes, use up dissolved oxygen as they decompose, and block light to deeper waters. Lake and reservoir eutrophication can occur, which produces unsightly scums of algae on the water surface. The high levels of nitrate and nitrite in drinking water may cause serious illnesses such as methemoglobinemia or “blue baby syndrome”, cancer risks, increased starchy deposits, and hemorrhaging of the spleen. The results of Nitrate Nitrogen are found very less and within the limits. The site RK3 which is near to the source of contamination has the higher value 9.3mg/L. The lowest value 0.45mg/L is found in RK1 sample. The average result of Ammonia nitrogen is found exceeding the prescribed limits. The highest value 24.4mg/L is found in RK3 sample in summer season shows high level Organic contamination near the site. The sample RK1 has the lowest value within the limits. 0 50 100 150 200 250 300 RK1 RK2 RK3 RK4 RK5 RK6 RK7 Hardness(mg/L) asCaCO3 Sampling locations Summer season Post Monsoon season Winter season Avg 281 54 141.9 0 2 4 6 8 10 12 14 RK1 RK2 RK3 RK4 RK5 RK6 RK7 DO(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 12.9 0.9 7.01 0 20 40 60 80 100 RK1 RK2 RK3 RK4 RK5 RK6 RK7 COD(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 88 3 31.43 0 5 10 15 20 25 30 35 40 45 50 RK1 RK2 RK3 RK4 RK5 RK6 RK7 BOD(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 43.4 3.3 17.62
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1077 The variation of NH3-N, NO3-N concentrations are shown in fig. 3.10, 3.11. As Phosphorus concentration in the water increases, the growth of aquatic vegetation increases. The direct effects of the excessive growth of aquatic vegetation can include a reduction in the transmission of solar radiation and production of toxins. A secondary effect is a decrease in the dissolved oxygen in the water, when bacteria utilize the oxygen while decomposing the increased amounts of dead aquatic vegetation. These effects associated with increased aquatic vegetation growth often have detrimental effects on fish and other aquatic life. This process is a form of eutrophication. The results of total phosphate are also within the permissible limits (Chart-3.12). The higher value 3.56mg/L is found in RK3 sample as a result of confluence of a nallah near the site. The lowest value found in RK1 sample. The average value 1.96mg/L is also below the limits. Turbidity is widely concerned as an important parameter for assessing the water quality. It is a measure of the relative clarity or cloudiness of water. The occurrence of turbidity may be permanent or seasonal. The observed values of turbidity are found very high and almost equal in summer and post monsoon seasons (chart-3.13). The highest value 17.9NTU is found in RK3 site during the summer season due to low flow in summer and joining of a wastewater nallah at the site. The average value 6.10NTU found more the than prescribed limit. Chart - 3.9: Seasonal Variation of Sulfate Chart - 3.10: Seasonal Variation of NH3-N Chart - 3.11: Seasonal Variation of NO3-N Chart - 3.12: Seasonal Variation of Total Phosphate 0 5 10 15 20 25 RK1 RK2 RK3 RK4 RK5 RK6 RK7 SO4(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 23.4 0 5.70 0 5 10 15 20 25 30 RK1 RK2 RK3 RK4 RK5 RK6 RK7 NH3-N(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 24.4 0.117 3.54 0 1 2 3 4 5 6 7 8 9 10 RK1 RK2 RK3 RK4 RK5 RK6 RK7 NO3-N(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 9.3 0.45 2.39 0 0.5 1 1.5 2 2.5 3 3.5 4 RK1 RK2 RK3 RK4 RK5 RK6 RK7 TotalP(mg/L) Sampling locations Summer season Post Monsoon season Winter season Avg 3.56 0.2 1.94
  • 8. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1078 Chart - 3.13: Seasonal Variation of Turbidity 4. CONCLUSIONS On observing the seasonal variation, it can be concluded that the Kharun River is heavily polluted during the summer than other seasons. The flow reduction during the summer season contributes to the deterioration of water quality. The Kharun River near Jamrao is severly polluted because of joining of a wastewater nallah near the site. And it is found that the water quality is good near Jheet ufra. Finally, it can be implied that the preventative measures taken by the local authorities are still not sufficient; it is clear that the domestic discharge and activities on the banks of river are the major threats to Kharun river’s water quality. ACKNOWLEDGEMENT I express my sincere respect and gratitude to my guide who has given his valuable support, cooperation and suggestions from time to time in successfully completing this project and also towards my family, friends for their ceaseless motivation and encouragement. REFERENCES [1] Smita Rout, Asit Kumar Behera, Aliva Patnaik, “Water Quality Analysis of River Mahanadi in Sambalpur City”, International Journal of Scientific and Research Publications, , ISSN 2250-3153, Volume 6, Issue 2, February 2016, pp 266-270. [2] S. P. Gorde, M. V. Jadhav, “Assessment of Water Quality Parameters: A Review”, Int. Journal of Engineering Research and Applications, www.ijera.com, ISSN : 2248-9622, Vol. 3, Issue 6, Nov- Dec 2013, pp 2029-2035. [3] Dr.Seema Tiwari, “Water Quality Parameters –A Review”, International Journal of Engineering Science Invention Research & Development; www.ijesird.com e-ISSN: 2349-6185, Vol. I Issue IX, March 2015, pp 319-324. [4] Anjali V Gopi, Dr. Harikumar P S, Akhil Nath G, “Water Quality Index and Assessment of Physico – Chemical Parameters Water samples, Calicut city, Kerala state, India”, International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056, Volume: 04, Issue: 05, May -2017, pp 3003-3006. [5] USEPA approved HACH methods for water analysis. [6] Guide Manual for Water and Wastewater Analysis, Central Pollution Control Board, New Delhi, India, 001-183 (2011). 0 2 4 6 8 10 12 14 16 18 20 RK1 RK2 RK3 RK4 RK5 RK6 RK7 TurbidityNTU Sampling locations Summer season Post Monsoon season Winter season Avg 17.9 0.7 6.10