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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3362
Analysis of Physico Chemical Parameters of Underground Water Sample
from Selected Area of Satna District (M.P.)
Nahid Usmani 1, R. S. Nigam2
1Assistant Professor, Department of Chemistry, AKS University Satna, M.P., India
2Dean, Department of Chemistry, AKS University Satna, M.P., India
------------------------------------------------------------------------***-----------------------------------------------------------------------
ABSTRACT - Water is a vital resource for human survival but due to increase population,agricultural practices,industrialization,
man- made activities, water is being highly polluted with different contaminants. So that it is necessary to study current status of
physico-chemical characteristics of water quality parameters. The completeanalysisofdrinkingwatersamples werecarriedoutin
different areas of satna district. (M.P.)India. The present work is aimed to estimate quality for the ground water of Satna City.
Different physico-chemical parameters such as temperature, salinity, alkalinity, Oxidation Reduction Potential (ORD) TDS, EC,
hardness, pH, DO, BOD, COD, used for testing of water quality. It seems in the result that physico-chemical parametersofthewater
were within the permissible limits and was not found to be good for human health.
Keywords: Ground water, water quality parameters, Physico-chemical Parameter.
INTRODUCTION
The quality of water is a vital concern for mankind, since it is directly linked with human welfare. Increase in urbanization,
industrialization, agriculture activity and varioushumanactivitieshaveincreasedthe pollutionofsurface water&groundwater.As
the safe and potable drinking water is needed. Various treatment methods are adopted to raise the quality of drinking water.
Pollution of water is a serious problem in India. As almost 70 percent of surface water resources and groundwater reserves are
contaminated by biological, toxic, organic, and inorganic pollutants.
During the past two decades, investigators have taken a seriouslook attheenvironmental effectsofdumps.Asrainwaterinfiltrates
through trash in dump, it accumulates an ample assortment of chemical and biological substances. In many cases, these sources
have been rendered unsafe for human consumption as well as for other activities, such as irrigation and industrial needs. This
shows that degraded water quality can contribute to water scarcity as limits its availability for both human use and for the
ecosystem.
Groundwater is used for domestic and industrial water supply and also for irrigation purposes in all over the world. Inthelastfew
decades, there has been a tremendous increase in the demand for fresh water due to rapid growth of population and the
accelerated pace of industrialization. According to WHO organization, about 80% of all thediseasesinhuman beings arecausedby
polluted water. Once the groundwater is contaminated, its quality cannot be restored back easily and means to protect it. Water
quality analysis one of the most effective tools to communicate information on the quality of water to the concerned citizens and
policy makers.
In this context paper, we aim to analyze the physico-chemical properties of bore well water collected from different areasofSatna
district.
MATERIALS AND METHODS
All chemical used for testing are of analytical grade. In order to investigate the water quality different areas from Satna district
were chosen for sample collection, during march 2019. The samples were collected in sterile glass bottles, brought to the
laboratory, processed within 1-3 hrs and stored at −20°C for further analysis. Before sampling, all the bottles were washed
thoroughly with the detergent, tap water and ethanol then distilled water. Chemical parameters were determined by using
standard methods immediately after taking them into the laboratory.
The locations and sources of water samples are given in Table 1.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3363
TABLE 1: WATER SAMPLES FROM DIFFERENT PLACES IN SATNA DISTRICT (M.P.)(INDIA)
S.No. SAMPLE SOURCE SAMPLE SITE (SATNA District M.P)
1 Bore well water VIRAT NAGAR
2 Bore well water ARJUN NAGAR
3 Bore well water MAHARANA PRATAP NAGAR
4 Bore well water JIVAN JYOTI COLONY
5 Bore well water PUSPRAJ COLONY
6 Bore well water RAJENDRA NAGAR
7 Bore well water GHANSHYAM VIHAR COLONY
8 Bore well water JAWAHAR NAGAR
9 Bore well water SHERGANJ
Determination of pH and water temperature
The pH and temperature of water samples were measured at the time of collection. The pH of all water samples was measured at
the time of collection by using portable battery operated pH meter .The calibration was carried out with three standard buffer
solution of pH4.0 ,7.0 and 9.2. The pH of the sample should lie between 7.72 to 8.82. The sample temperature was determined at
the same time by portable thermometer.
TOTAL DISSOLVED SOLIDS (TDS)
Total dissolved solids describe the amount of inorganic salts of calcium, magnesium, sodium etc. and small proportion of organic
matter present in the water.TDS values showed a considerable variability ranging from < 10 ppm to >1500 ppm. During the study
relative amount of solutes were high due to decrease in the water level in bore well. Solids may effectonwater qualityadverselyin
a number of ways. The TDS of all water samples were carried out at room temperature by using TDS meter.
ELECTRICAL CONDUCTIVITY (EC)
Electrical conductivity usually used for indicating the total concentration of ionized constituents of water. Conductivity is the
capacity of water to carry an electrical current and varies both with number and types of ions of the solution.
TOTAL HARDNESS
Hardness of water is an important consideration in determining the suitability of water for domestic and industrial uses. Total
hardness of water samples were carried out by using titration method with EDTA solution. Water sample with buffer solution
(10pH) was followed by the addition of 1 to 2 drops of indicator (EBT). Then, this solution was titratedagainstEDTA solutionfrom
burette, end point reddish to blue color. The degree of hardness of drinking water has been classified in terms of the equivalent
CaCO3 concentration as follows: Soft -0-60mg/l, Medium - 60-120 mg/l, Hard - 120-180 mg/l, Very hard - >180 mg/l.
DISSOVED OXYGEN (DO)-
Dissolved oxygen is the most important indicator of the health of water bodies and its capacity to support a balanced aquatic
ecosystem of plants and animals. Warm water released from industrial outlets,flowagesorstormsewerscanalsoreducedissolved
oxygen levels. Its deficiency directly affects the ecosystem of a river due to bioaccumulation and biomagnifications. This test was
carried out to evaluate the quantitative determination of chloride ions. This test was carried out by titrating given water sample
with silver nitrate solution; end point was yellow to brick red. Dissolved oxygen (DO) of water samples were carried out by using
titremetric method:
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3364
COD AND BOD-
COD is amount of oxygen required for the chemical oxidation of organic matter with the help of strong chemical oxidant.High COD
may cause oxygen depletion on account of decomposition of microbes to a level detrimental to aquatic life. The measure of COD
determines the quantities of organic matter found in water. This makes COD useful as an indicator of organic pollution in surface
water. Chemical oxygen demand (COD) of all water samples were carried out by using dichromate method.
BOD is a measure of the oxygen in the water that is required by the aerobic organisms. The biodegradation of organic materials
exerts oxygen tension in the water and increases the biochemical oxygen demand. BOD is a measure of organic material
contamination in water, specified in mg/L. Typically the test for BOD is conducted over a five-day period. Biochemical oxygen
demand (BOD) was carried out by using alkali azide method.
ALKALINITY-
Alkalinity is the measure of hydroxide and carbonate ion content of water sample. Alkalinity is also a measure of water buffering
capacity or its ability to resist changes in pH upon the addition of acids or bases. Bicarbonate represents the major form of
alkalinity in natural water. It is measured by titration with standard H2SO4 using indicator. Pink color of solution changes to
colorless. This is the indication of end point .it is expressed commonly asmilligramsperliterascalciumcarbonate(mg/l asCaCo3).
TABLE 2: RESULTS OF BORE WELL WATER ANALYSIS
S.No Sample site Tempe
rature
(O C)
pH Alkalini
ty
(mg/L)
Hardnes
s
(PPM)
ORD
(Mv)
TDS
(mg/L
)
EC
(ohm -
1)
Salinit
y
DO BOD COD
1 Virat nagar 19 8.82 210 280 117 223 455 1.0 3.8 48 221
2 Arjun nagar 20 8.73 240 220 110 404 809 1.0 4.1 65 268
3 Maharana
pratap
nagar
19 8.08 60 240 68 425 875 2.0 4.3 58 301
4 Jivan jyoti
colony
19 8.26 80 210 79 545 1092 2.1 4.6 59 155
5 Puspraj
colony
20 8.32 130 230 84 415 820 1.5 3.4 63 252
6 Rajendra
nagar
20 8.06 190 250 68 475 943 1.8 3.9 51 236
7 Ghanshyam
vihar colony
19 8.03 70 240 65 455 915 1.1 4.8 60 294
8 Jawahar
nagar
18 8..04 140 270 83 451 902 1.9 4.4 48 245
9 Sherganj 18 7.72 120 280 44 385 773 1.0 4.2 55 210
CONCLUSION
The effects of water pollution are not only devastating to people, but also to destroy aquatic life .Water quality isdependentonthe
type of the pollutant added and the nature of mineral found at particular zone of bore well. It diminishes the aesthetic quality of
water body. Eventually, it is a hazard to human health. Estimation of water quality parameters was done through appropriate
method and evaluates the quality of bore well water by quantitative analysis. The present paperundertakentoaccounttobringan
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3365
acute awareness among the people about the quality of water. Result of water quality estimation seems that most of the water
quality parameters slightly higher than standard groundwater quality status.
REFERENCE-
1.Uma maheshwari, S .Ccme , “Water Quality Index in River Cauvery Basin at Talakadu, South India”. Volume-6, Issue-1, Jan-Mar-
2016. International journal of plant, Animal and Environmental Sciences.
2. Journal of Global Biosciences Vol. 5(9),” Integrated Water Resources Managementin theFacultyofNatural Science,Universityof
the Western Cape”. 2016,http://mutagens.co.in 4567 degree of Magister Scientiae, pp. 41.
3. Sneka Lata, K., Jesu, A. Dheenadayalan, M.S., “Seasonal variation of Cauvery river due to discharged Industrial effluents at
Pallipalayam in Namakkal”. 2015,8 (3), 380 – 388.
4. Nagamani C. “Physico-chemical analysis of water samples”. International Journal of ScientificandEngineeringResearch,2015,6:
2149.
5. Venkatachalapathy, R.and Karthikeyan,P.Physical,“Chemical andEnvironmental StudiesonCauveryRiverinPartsofTamil Nadu
(Mettur and Bhavani)”. Universal Journal of Environmental Research and Technology, (3), 3: 415-422, 2013, World Health
Organization (WHO, 1993) Guidelines.
6. S.P. Gorde and M.V. Jadhav, “Assessment of Water Quality Parameters: A Review”. Journal of Engineering Research and
Applications, 3(6), 2029-2035, 2013.
7. Cobbina, S.J.; Nyame, F.K.; Obiri, S.,“Groundwater Quality in the Sahelian Region of Northern Ghana, West Africa”. Res.J.Environ.
Earth. Sci. 2012, 4, 482–491.
8. Sharma Shraddha1, Vishwakarma Rakesh2, Dixit Savita3 and Jain Praveen4 “EVALUATION OF WATER QUALITY OFNARMADA
RIVER WITH REFERENCE TO PHYSCOCHEMICAL PARAMETERS AT HOSHANGABAD CITY, MP, INDIA” . Research Journal of
Chemical Sciences Vol. 1(3) June (2011) ISSN 2231-606X

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IRJET- Analysis of Physico Chemical Parameters of Underground Water Sample from Selected Area of Satna District (M.P.)

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3362 Analysis of Physico Chemical Parameters of Underground Water Sample from Selected Area of Satna District (M.P.) Nahid Usmani 1, R. S. Nigam2 1Assistant Professor, Department of Chemistry, AKS University Satna, M.P., India 2Dean, Department of Chemistry, AKS University Satna, M.P., India ------------------------------------------------------------------------***----------------------------------------------------------------------- ABSTRACT - Water is a vital resource for human survival but due to increase population,agricultural practices,industrialization, man- made activities, water is being highly polluted with different contaminants. So that it is necessary to study current status of physico-chemical characteristics of water quality parameters. The completeanalysisofdrinkingwatersamples werecarriedoutin different areas of satna district. (M.P.)India. The present work is aimed to estimate quality for the ground water of Satna City. Different physico-chemical parameters such as temperature, salinity, alkalinity, Oxidation Reduction Potential (ORD) TDS, EC, hardness, pH, DO, BOD, COD, used for testing of water quality. It seems in the result that physico-chemical parametersofthewater were within the permissible limits and was not found to be good for human health. Keywords: Ground water, water quality parameters, Physico-chemical Parameter. INTRODUCTION The quality of water is a vital concern for mankind, since it is directly linked with human welfare. Increase in urbanization, industrialization, agriculture activity and varioushumanactivitieshaveincreasedthe pollutionofsurface water&groundwater.As the safe and potable drinking water is needed. Various treatment methods are adopted to raise the quality of drinking water. Pollution of water is a serious problem in India. As almost 70 percent of surface water resources and groundwater reserves are contaminated by biological, toxic, organic, and inorganic pollutants. During the past two decades, investigators have taken a seriouslook attheenvironmental effectsofdumps.Asrainwaterinfiltrates through trash in dump, it accumulates an ample assortment of chemical and biological substances. In many cases, these sources have been rendered unsafe for human consumption as well as for other activities, such as irrigation and industrial needs. This shows that degraded water quality can contribute to water scarcity as limits its availability for both human use and for the ecosystem. Groundwater is used for domestic and industrial water supply and also for irrigation purposes in all over the world. Inthelastfew decades, there has been a tremendous increase in the demand for fresh water due to rapid growth of population and the accelerated pace of industrialization. According to WHO organization, about 80% of all thediseasesinhuman beings arecausedby polluted water. Once the groundwater is contaminated, its quality cannot be restored back easily and means to protect it. Water quality analysis one of the most effective tools to communicate information on the quality of water to the concerned citizens and policy makers. In this context paper, we aim to analyze the physico-chemical properties of bore well water collected from different areasofSatna district. MATERIALS AND METHODS All chemical used for testing are of analytical grade. In order to investigate the water quality different areas from Satna district were chosen for sample collection, during march 2019. The samples were collected in sterile glass bottles, brought to the laboratory, processed within 1-3 hrs and stored at −20°C for further analysis. Before sampling, all the bottles were washed thoroughly with the detergent, tap water and ethanol then distilled water. Chemical parameters were determined by using standard methods immediately after taking them into the laboratory. The locations and sources of water samples are given in Table 1.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3363 TABLE 1: WATER SAMPLES FROM DIFFERENT PLACES IN SATNA DISTRICT (M.P.)(INDIA) S.No. SAMPLE SOURCE SAMPLE SITE (SATNA District M.P) 1 Bore well water VIRAT NAGAR 2 Bore well water ARJUN NAGAR 3 Bore well water MAHARANA PRATAP NAGAR 4 Bore well water JIVAN JYOTI COLONY 5 Bore well water PUSPRAJ COLONY 6 Bore well water RAJENDRA NAGAR 7 Bore well water GHANSHYAM VIHAR COLONY 8 Bore well water JAWAHAR NAGAR 9 Bore well water SHERGANJ Determination of pH and water temperature The pH and temperature of water samples were measured at the time of collection. The pH of all water samples was measured at the time of collection by using portable battery operated pH meter .The calibration was carried out with three standard buffer solution of pH4.0 ,7.0 and 9.2. The pH of the sample should lie between 7.72 to 8.82. The sample temperature was determined at the same time by portable thermometer. TOTAL DISSOLVED SOLIDS (TDS) Total dissolved solids describe the amount of inorganic salts of calcium, magnesium, sodium etc. and small proportion of organic matter present in the water.TDS values showed a considerable variability ranging from < 10 ppm to >1500 ppm. During the study relative amount of solutes were high due to decrease in the water level in bore well. Solids may effectonwater qualityadverselyin a number of ways. The TDS of all water samples were carried out at room temperature by using TDS meter. ELECTRICAL CONDUCTIVITY (EC) Electrical conductivity usually used for indicating the total concentration of ionized constituents of water. Conductivity is the capacity of water to carry an electrical current and varies both with number and types of ions of the solution. TOTAL HARDNESS Hardness of water is an important consideration in determining the suitability of water for domestic and industrial uses. Total hardness of water samples were carried out by using titration method with EDTA solution. Water sample with buffer solution (10pH) was followed by the addition of 1 to 2 drops of indicator (EBT). Then, this solution was titratedagainstEDTA solutionfrom burette, end point reddish to blue color. The degree of hardness of drinking water has been classified in terms of the equivalent CaCO3 concentration as follows: Soft -0-60mg/l, Medium - 60-120 mg/l, Hard - 120-180 mg/l, Very hard - >180 mg/l. DISSOVED OXYGEN (DO)- Dissolved oxygen is the most important indicator of the health of water bodies and its capacity to support a balanced aquatic ecosystem of plants and animals. Warm water released from industrial outlets,flowagesorstormsewerscanalsoreducedissolved oxygen levels. Its deficiency directly affects the ecosystem of a river due to bioaccumulation and biomagnifications. This test was carried out to evaluate the quantitative determination of chloride ions. This test was carried out by titrating given water sample with silver nitrate solution; end point was yellow to brick red. Dissolved oxygen (DO) of water samples were carried out by using titremetric method:
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3364 COD AND BOD- COD is amount of oxygen required for the chemical oxidation of organic matter with the help of strong chemical oxidant.High COD may cause oxygen depletion on account of decomposition of microbes to a level detrimental to aquatic life. The measure of COD determines the quantities of organic matter found in water. This makes COD useful as an indicator of organic pollution in surface water. Chemical oxygen demand (COD) of all water samples were carried out by using dichromate method. BOD is a measure of the oxygen in the water that is required by the aerobic organisms. The biodegradation of organic materials exerts oxygen tension in the water and increases the biochemical oxygen demand. BOD is a measure of organic material contamination in water, specified in mg/L. Typically the test for BOD is conducted over a five-day period. Biochemical oxygen demand (BOD) was carried out by using alkali azide method. ALKALINITY- Alkalinity is the measure of hydroxide and carbonate ion content of water sample. Alkalinity is also a measure of water buffering capacity or its ability to resist changes in pH upon the addition of acids or bases. Bicarbonate represents the major form of alkalinity in natural water. It is measured by titration with standard H2SO4 using indicator. Pink color of solution changes to colorless. This is the indication of end point .it is expressed commonly asmilligramsperliterascalciumcarbonate(mg/l asCaCo3). TABLE 2: RESULTS OF BORE WELL WATER ANALYSIS S.No Sample site Tempe rature (O C) pH Alkalini ty (mg/L) Hardnes s (PPM) ORD (Mv) TDS (mg/L ) EC (ohm - 1) Salinit y DO BOD COD 1 Virat nagar 19 8.82 210 280 117 223 455 1.0 3.8 48 221 2 Arjun nagar 20 8.73 240 220 110 404 809 1.0 4.1 65 268 3 Maharana pratap nagar 19 8.08 60 240 68 425 875 2.0 4.3 58 301 4 Jivan jyoti colony 19 8.26 80 210 79 545 1092 2.1 4.6 59 155 5 Puspraj colony 20 8.32 130 230 84 415 820 1.5 3.4 63 252 6 Rajendra nagar 20 8.06 190 250 68 475 943 1.8 3.9 51 236 7 Ghanshyam vihar colony 19 8.03 70 240 65 455 915 1.1 4.8 60 294 8 Jawahar nagar 18 8..04 140 270 83 451 902 1.9 4.4 48 245 9 Sherganj 18 7.72 120 280 44 385 773 1.0 4.2 55 210 CONCLUSION The effects of water pollution are not only devastating to people, but also to destroy aquatic life .Water quality isdependentonthe type of the pollutant added and the nature of mineral found at particular zone of bore well. It diminishes the aesthetic quality of water body. Eventually, it is a hazard to human health. Estimation of water quality parameters was done through appropriate method and evaluates the quality of bore well water by quantitative analysis. The present paperundertakentoaccounttobringan
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3365 acute awareness among the people about the quality of water. Result of water quality estimation seems that most of the water quality parameters slightly higher than standard groundwater quality status. REFERENCE- 1.Uma maheshwari, S .Ccme , “Water Quality Index in River Cauvery Basin at Talakadu, South India”. Volume-6, Issue-1, Jan-Mar- 2016. International journal of plant, Animal and Environmental Sciences. 2. Journal of Global Biosciences Vol. 5(9),” Integrated Water Resources Managementin theFacultyofNatural Science,Universityof the Western Cape”. 2016,http://mutagens.co.in 4567 degree of Magister Scientiae, pp. 41. 3. Sneka Lata, K., Jesu, A. Dheenadayalan, M.S., “Seasonal variation of Cauvery river due to discharged Industrial effluents at Pallipalayam in Namakkal”. 2015,8 (3), 380 – 388. 4. Nagamani C. “Physico-chemical analysis of water samples”. International Journal of ScientificandEngineeringResearch,2015,6: 2149. 5. Venkatachalapathy, R.and Karthikeyan,P.Physical,“Chemical andEnvironmental StudiesonCauveryRiverinPartsofTamil Nadu (Mettur and Bhavani)”. Universal Journal of Environmental Research and Technology, (3), 3: 415-422, 2013, World Health Organization (WHO, 1993) Guidelines. 6. S.P. Gorde and M.V. Jadhav, “Assessment of Water Quality Parameters: A Review”. Journal of Engineering Research and Applications, 3(6), 2029-2035, 2013. 7. Cobbina, S.J.; Nyame, F.K.; Obiri, S.,“Groundwater Quality in the Sahelian Region of Northern Ghana, West Africa”. Res.J.Environ. Earth. Sci. 2012, 4, 482–491. 8. Sharma Shraddha1, Vishwakarma Rakesh2, Dixit Savita3 and Jain Praveen4 “EVALUATION OF WATER QUALITY OFNARMADA RIVER WITH REFERENCE TO PHYSCOCHEMICAL PARAMETERS AT HOSHANGABAD CITY, MP, INDIA” . Research Journal of Chemical Sciences Vol. 1(3) June (2011) ISSN 2231-606X