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International Journal of Research in Advent Technology, Vol.3, No.12, December 2015
E-ISSN: 2321-9637
Available online at www.ijrat.org
48
Water Quality Assesment of Physiochemical Properties
of Shivnath River in Durg District (Chhattisgarh)
Sonam Shukla, D.K. Pandey D.K. Mishra
Department of civil engineering, Manoharbhai Patel Institute of Engineering & Technology,
Gondia, Maharashtra.
Email: shukla.sonam22@yahoo.com
Abstract- A study was undertaken to determine the quality of water of Shivnath river in Rasmara region of
Durg district. The samples collected were analyzed for the physical properties like color, temperature, and odor,
chemical properties like pH, Total dissolved solids (TDS), sulphates, nitrates etc. All the above stated properties
were analyzed according to the guidelines provided by the Central Pollution Control Board, New Delhi, APHE,
BIS and WHO for both upstream and downstream sampling points to determine the effect of industrial as well as
domestic discharge on the quality of the river water. The results of different tests revels that, addition of
discharges into the river water has increased its pollution load. The pH of water has increased downstream.
Turbidity of the water is also quite high than the allowable limits. The DO, COD & BOD has also been found in
excess than the limit. Amount of calcium is 77.4 mg/l which is more than the allowable limits & faecal coliforms
were also found in larger amounts which are not permissible.
Index Terms- Surface water, Investigation, TDS, Nitrate (NO3-), World Health Organization (WHO), BIS,
Water Quality (WQ), Shivnath river .
1. INTRODUCTION
Water is an essential natural resource and is vital for
all forms of life. 70.9% of the Earth's surface is
covered by the water. 96.5% of the planet's water is
occupied in oceans, 1.7% in the form of groundwater,
1.7% in glaciers and the ice caps of Antarctica and
Greenland 0.001% in the air as vapor, clouds and
precipitation. Only 2.5% of the Earth's water is fresh
water, and 98.8% of that water is in ice and
groundwater [11]. Two-third of the human body is
constituted of water. For the survival of humans,
animals, plants & all other forms of life water is
absolutely essential. Therefore, it is necessary that the
water required for their needs must be free from any
form of impurities and should be hygienic [6].
Overexploitation of the precious reserve is caused due
to increasing population and urbanization. This has
increases a major concern for water engineers and
planners in recent years, to formulate effective
strategies and model for sustainable water resource
management.
India was once bestowed with abundant freshwater
reserves like various rivers & ground water reserves.
Due to population explosion and economic
development a serious problem of natural water
resource scarcity is being encountered in India.
Biological, toxic, organic, and inorganic pollutants
have contaminated 70% of India’s surface water
resources and are contaminating growing percent
age of its groundwater reserves also. In 1951 the
average annual freshwater was 5177 cubic meter
which is reduced to about 1869 cubic meters in 2001.
It is estimated that this will further come down to 1341
cubic meters in 2025 and 1140 cubic meters in 2050
[10]. Main reason behind this is dumping of untreated
municipal as well as industrial wastes directly into
natural water bodies. Besides this excessive use of
pesticides and fertilizers adds on the deterioration of
fresh water bodies [3]. Hence, good water
conservation techniques and water treatment methods
are required to be formulated in an effective manner to
maintain the water quality within standards.
Many small and big rivers co-originate in Chhattisgarh
state. Mahanadi River is the most important river of
the state and is also known as the life line of
Chhattisgarh. Shivnath River is the second important
river of the state & is the main tributary of Mahanadi
River [2]. Total length of flow of Shivnath river in
Chhattisgarh State is 290 km. It emerges from
Panbaras range situated at the height of 625 meters, at
Ambagarh tehsil of Rajnandgaon district. After
emerging from panabaras it flows about 40 km to the
north direction & then turns its flow towards east
direction at Ambagarh Chouky. Rajnandgaon, Durg
and Janjgir, Champa district are some of the main
areas situated at the bank of Shivnath River. Arpa,
Lilagar, Maniyari, Kharoon, Aabar, Surahi, Tandula
International Journal of Research in Advent Technology, Vol.3, No.12, December 2015
E-ISSN: 2321-9637
Available online at www.ijrat.org
49
etc are the main tributaries of shivnath River [2]. Due
to dumping of variety of wastes (industrial as well as
domestic) Shivnath is facing a huge problem of
pollution. The present study focuses on assessment of
impact of the discharges on the physicochemical and
microbiological quality of the Shivnath river water in
Durg district.
.
2. METHODOLOGY
• The analysis of water quality is carried out as per
APHA norms to establish the existing water quality.
• The existing water quality is then compared with the
water quality standards presented by the Central
Pollution Control Board, New Delhi, APHE, WHO &
BIS (IS:10500-2012) [7] [2] [5]. The description
analysis results of the physiochemical properties of the
collected water samples are given in Table 2.
The method used for studying physical, chemical &
bacteriological properties are listed in the following
table: (All the tests were carried out within 24 hours of
sample collection.) [1] [4] [6].
Table 1: Methods Used for Testing the Water
Characteristics.
Characteristics Method of Testing
pH pH Meter
Turbidity Turbidity Meter
Temperature (°C) Temperature sensitive probe
Calcium Titrimetric Method
Magnesium Hy. Calcution [TH-(CaH)] * 0.243
Nitrates PDA Method
Sulphates Spectrophotometer
Total Alkalinity Titrimetric Method
Total Hardness Titrimetric Method
TDS TDS Meter
DO Winkler's iodometric method
BOD Dilution Method
COD Acidic Oxidation + Potassium
dichromate
Faecal Coliforms Membrane Filter Method
3. SELECTION OF SAMPLING POINTS:
The sampling points were selected so as the water
samples represent the entire river study area.
Upstream Point: The Pulgaon Channel ( since it is one
of the major sources of industrial and domestic area
discharges ) joining into the river (Ganjpara, Durg),
Downstream Point: Near the NH-6, bypass shivnath
Railway bridge at Rasmara village (Rasmara Durg).
3.1. Collection Of Water Sample:
Samples were collected through Grab sampling
process. Plastic collection bottles of 1000ml capacity
were used for collection of samples. The bottles were
rinsed with sampling point water and emptied
downstream of the sampling station after this they
were filled and sealed. The collected samples were
kept under normal room temperature during the testing
procedure [9].
4. RESULTS & DISCUSSIONS:
The tests results suggest that, due to addition of
discharges into the river water its pollution load has
been increased. Detailed description is listed below &
results of the analysis are also given in graphical
representations.
4.1. Temperature, Turbidity & pH:
The temperature of the water for upstream &
downstream was 24°C and 25.2°C respectively. pH of
the downstream was 9 which is greater than the BIS
limits [12] [4]. Turbidity values were also high for
both upstream & downstream.
International Journal of Research in Advent Technology, Vol.3, No.12, December 2015
E-ISSN: 2321-9637
Available online at www.ijrat.org
50
Figure 1: Upstream & Downstream Sample
comparison for pH, Turbidity & Temperature values.
Table 1: Analysis Results of Collected Samples.
Sr.
No.
Characteristics Unit of
Measurement
BIS WHO ICMR Upstream Downstream
Physical -
1 pH pH Scale 6.5-8.5 6.5 -8.5 7-8.5 7.6 9
2 Turbidity N.T.U. 1 5 4-5 5.5 6.7
3 Temperature (°C) °C - - - 24 25.2
4 Color 300Hazen units. 5 5 5 colorless colorless
5 Taste & Odour - - - - Unobjectionab
le
Unobjection
able
Chemical -
6 Calcium mg/l 75 75 75 48.2 77.8
7 Magnesium mg/l 30 50 50 9.27 10.82
8 Nitrates mg/l 45 45 45 16.2 43.2
9 Sulphates mg/l 200 200 200 9 19.9
10 Total Alkalinity mg/l 200 75 - 160 200
11 Total Hardness mg/l 200 500 500 140 197
12 TDS mg/l 500 197 211
13 DO mg/l 4-6 ppm 4-6 ppm 4-6 ppm 5.87 4.55
14 BOD mg/l 3 2 3 7 13
15 COD mg/l - - - 12 18
Bacteriological -
16 Faecal Coliforms CFU/ 100 ml Nil Nil Nil 68 84
International Journal of Research in Advent Technology, Vol.3, No.12, December 2015
E-ISSN: 2321-9637
Available online at www.ijrat.org
51
4.2. Hardness, Sulphates & Nitrates:
Tests results show that the Calcium hardness has
increased beyond the allowable limit i.e. more than 75
mg/l [12] [4]. Nitrates were also reaching near the
upper limit of specification. But magnesium hardness
and sulphates were within the allowable limits.
Figure 2: Upstream & Downstream Sample
comparison for Hardness, Sulphates & Nitrates values
(all in mg/l).
4.3. Total Alkalinity, Total Hardness & TDS:
The TDS values were found to be within the allowable
limits. Although Total alkalinity & total hardness
values were found to be within the limits ( i.e. ≤ 200
mg/l for both ) but they are found to be reaching near
the upper limits [12] [4].
Figure 3: Upstream & Downstream Sample
comparison for Total Alkalinity, Total Hardness &
TDS (all in mg/l).
4.4. BOD, COD, DO:
A significant increase in both BOD (7 and 13 mg/l for
upstream & downstream respectively) and COD (12
and 18 mg/l for upstream & downstream respectively)
values has been found more than the allowable limits.
[12] [4] DO was found to be within the limit but it was
decreased from 5.87mg/l (upstream) to 4.55 mg/l
(downstream).
Figure 4: Upstream & Downstream Sample
comparison for DO, COD & BOD values (all in mg/l).
4.5. Faecal Coliforms:
Faecal Coliforms were also increased in downstream
sample (i.e. from 68 CFU /100ml to 84 CFU /100ml)
which is not permissible.
Figure 5: Upstream & Downstream Sample
comparison for Faecal Coliforms values (in CFU/ 100
mg).
5. CONCLUSION
In above study it was found that maximum parameters
were not under allowable BIS limits. pH , Turbidity,
Calcium, Total Alkalinity, DO, BOD, COD and faecal
coliforms exceeded the BIS limits. The amount of
International Journal of Research in Advent Technology, Vol.3, No.12, December 2015
E-ISSN: 2321-9637
Available online at www.ijrat.org
52
faecal coliforms was very high which makes the water
unsuitable for use. This all shows that the quality of
the river water is below the prescribed standards and it
is unsuitable for drinking or household purposes
without any disinfection process.
REFERENCES
[1] APHA, Standard Methods for Examination of
Water and Wastewater, 16th Ed., American
Public Health Association, Washington, DC.
c1985, 197-1157.
[2] Belorkar Seema A. “Assessment of the
Deterioration in Physiochemical and
Microbiological Quality of Shivnath River Water
in Durg District, India” E-Journal of Chemistry
ISSN: 0973-4945;
[3] Bhadja Poonam and Vaghela Ashokkumar,
“Assessment Of Physico-Chemical parameters
And Water Quality Index of Reservoir Water”
International Journal of Plant, Animal and
Environmental Sciences, Vol 3 july- sep 2013,
ISSN 2231-4490
[4] BIS (IS: 10500-2012) Drinking Water —
Specification.
[5] CPCB (2009), Central Pollution Control Board,
New Delhi.
[6] Garg S K , Water supply engineering, khanna
publishers oct 2010.
[7] Pandey Devendra “Surface Water Quality with
Painstaking Human Impacts-A Case Study of the
Wainganga River, Bhandara, Maharashtra, India”
International Journal of Bioassays (IJB) 272,
ISSN: 2278-778X.
[8] Pandey et. al. “Water Quality Assessment of
Bhandara and Gondia Districts of Maharashtra
State, INDIA” International Journal of Research
in Chemistry and Environment Vol. 1 Issue 1 July
2011(114-118) ISSN 2248-9649.
[9] Rennie Matthew J. “A Water Quality Survey of
the River Ouseburn”, MEng Civil Engineering ,
School of Civil Engineering & Geosciences,
Newcastle University 2012
[10]Singh Ajit Pratap and Shrivastava Parnika, “A
Comparative Study on Water Quality Assessment
of A River Using AHP and Promethee
Techniques”, Hydraulics, Water Resources,
Coastal and Environmental Engineering (HYDRO
2014)
[11]Upadhyay Manish and Mishra Anisha “Study o f
Physico-Chemical Properties of Surface Water
(Shivnath River & Ponds) In Durg and
Rajnandgaon Region” Acta Biomedica Scientia.
2014;1(1):14-17.
[12] WHO (1972). World Health Organization

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Paper id 312201519

  • 1. International Journal of Research in Advent Technology, Vol.3, No.12, December 2015 E-ISSN: 2321-9637 Available online at www.ijrat.org 48 Water Quality Assesment of Physiochemical Properties of Shivnath River in Durg District (Chhattisgarh) Sonam Shukla, D.K. Pandey D.K. Mishra Department of civil engineering, Manoharbhai Patel Institute of Engineering & Technology, Gondia, Maharashtra. Email: shukla.sonam22@yahoo.com Abstract- A study was undertaken to determine the quality of water of Shivnath river in Rasmara region of Durg district. The samples collected were analyzed for the physical properties like color, temperature, and odor, chemical properties like pH, Total dissolved solids (TDS), sulphates, nitrates etc. All the above stated properties were analyzed according to the guidelines provided by the Central Pollution Control Board, New Delhi, APHE, BIS and WHO for both upstream and downstream sampling points to determine the effect of industrial as well as domestic discharge on the quality of the river water. The results of different tests revels that, addition of discharges into the river water has increased its pollution load. The pH of water has increased downstream. Turbidity of the water is also quite high than the allowable limits. The DO, COD & BOD has also been found in excess than the limit. Amount of calcium is 77.4 mg/l which is more than the allowable limits & faecal coliforms were also found in larger amounts which are not permissible. Index Terms- Surface water, Investigation, TDS, Nitrate (NO3-), World Health Organization (WHO), BIS, Water Quality (WQ), Shivnath river . 1. INTRODUCTION Water is an essential natural resource and is vital for all forms of life. 70.9% of the Earth's surface is covered by the water. 96.5% of the planet's water is occupied in oceans, 1.7% in the form of groundwater, 1.7% in glaciers and the ice caps of Antarctica and Greenland 0.001% in the air as vapor, clouds and precipitation. Only 2.5% of the Earth's water is fresh water, and 98.8% of that water is in ice and groundwater [11]. Two-third of the human body is constituted of water. For the survival of humans, animals, plants & all other forms of life water is absolutely essential. Therefore, it is necessary that the water required for their needs must be free from any form of impurities and should be hygienic [6]. Overexploitation of the precious reserve is caused due to increasing population and urbanization. This has increases a major concern for water engineers and planners in recent years, to formulate effective strategies and model for sustainable water resource management. India was once bestowed with abundant freshwater reserves like various rivers & ground water reserves. Due to population explosion and economic development a serious problem of natural water resource scarcity is being encountered in India. Biological, toxic, organic, and inorganic pollutants have contaminated 70% of India’s surface water resources and are contaminating growing percent age of its groundwater reserves also. In 1951 the average annual freshwater was 5177 cubic meter which is reduced to about 1869 cubic meters in 2001. It is estimated that this will further come down to 1341 cubic meters in 2025 and 1140 cubic meters in 2050 [10]. Main reason behind this is dumping of untreated municipal as well as industrial wastes directly into natural water bodies. Besides this excessive use of pesticides and fertilizers adds on the deterioration of fresh water bodies [3]. Hence, good water conservation techniques and water treatment methods are required to be formulated in an effective manner to maintain the water quality within standards. Many small and big rivers co-originate in Chhattisgarh state. Mahanadi River is the most important river of the state and is also known as the life line of Chhattisgarh. Shivnath River is the second important river of the state & is the main tributary of Mahanadi River [2]. Total length of flow of Shivnath river in Chhattisgarh State is 290 km. It emerges from Panbaras range situated at the height of 625 meters, at Ambagarh tehsil of Rajnandgaon district. After emerging from panabaras it flows about 40 km to the north direction & then turns its flow towards east direction at Ambagarh Chouky. Rajnandgaon, Durg and Janjgir, Champa district are some of the main areas situated at the bank of Shivnath River. Arpa, Lilagar, Maniyari, Kharoon, Aabar, Surahi, Tandula
  • 2. International Journal of Research in Advent Technology, Vol.3, No.12, December 2015 E-ISSN: 2321-9637 Available online at www.ijrat.org 49 etc are the main tributaries of shivnath River [2]. Due to dumping of variety of wastes (industrial as well as domestic) Shivnath is facing a huge problem of pollution. The present study focuses on assessment of impact of the discharges on the physicochemical and microbiological quality of the Shivnath river water in Durg district. . 2. METHODOLOGY • The analysis of water quality is carried out as per APHA norms to establish the existing water quality. • The existing water quality is then compared with the water quality standards presented by the Central Pollution Control Board, New Delhi, APHE, WHO & BIS (IS:10500-2012) [7] [2] [5]. The description analysis results of the physiochemical properties of the collected water samples are given in Table 2. The method used for studying physical, chemical & bacteriological properties are listed in the following table: (All the tests were carried out within 24 hours of sample collection.) [1] [4] [6]. Table 1: Methods Used for Testing the Water Characteristics. Characteristics Method of Testing pH pH Meter Turbidity Turbidity Meter Temperature (°C) Temperature sensitive probe Calcium Titrimetric Method Magnesium Hy. Calcution [TH-(CaH)] * 0.243 Nitrates PDA Method Sulphates Spectrophotometer Total Alkalinity Titrimetric Method Total Hardness Titrimetric Method TDS TDS Meter DO Winkler's iodometric method BOD Dilution Method COD Acidic Oxidation + Potassium dichromate Faecal Coliforms Membrane Filter Method 3. SELECTION OF SAMPLING POINTS: The sampling points were selected so as the water samples represent the entire river study area. Upstream Point: The Pulgaon Channel ( since it is one of the major sources of industrial and domestic area discharges ) joining into the river (Ganjpara, Durg), Downstream Point: Near the NH-6, bypass shivnath Railway bridge at Rasmara village (Rasmara Durg). 3.1. Collection Of Water Sample: Samples were collected through Grab sampling process. Plastic collection bottles of 1000ml capacity were used for collection of samples. The bottles were rinsed with sampling point water and emptied downstream of the sampling station after this they were filled and sealed. The collected samples were kept under normal room temperature during the testing procedure [9]. 4. RESULTS & DISCUSSIONS: The tests results suggest that, due to addition of discharges into the river water its pollution load has been increased. Detailed description is listed below & results of the analysis are also given in graphical representations. 4.1. Temperature, Turbidity & pH: The temperature of the water for upstream & downstream was 24°C and 25.2°C respectively. pH of the downstream was 9 which is greater than the BIS limits [12] [4]. Turbidity values were also high for both upstream & downstream.
  • 3. International Journal of Research in Advent Technology, Vol.3, No.12, December 2015 E-ISSN: 2321-9637 Available online at www.ijrat.org 50 Figure 1: Upstream & Downstream Sample comparison for pH, Turbidity & Temperature values. Table 1: Analysis Results of Collected Samples. Sr. No. Characteristics Unit of Measurement BIS WHO ICMR Upstream Downstream Physical - 1 pH pH Scale 6.5-8.5 6.5 -8.5 7-8.5 7.6 9 2 Turbidity N.T.U. 1 5 4-5 5.5 6.7 3 Temperature (°C) °C - - - 24 25.2 4 Color 300Hazen units. 5 5 5 colorless colorless 5 Taste & Odour - - - - Unobjectionab le Unobjection able Chemical - 6 Calcium mg/l 75 75 75 48.2 77.8 7 Magnesium mg/l 30 50 50 9.27 10.82 8 Nitrates mg/l 45 45 45 16.2 43.2 9 Sulphates mg/l 200 200 200 9 19.9 10 Total Alkalinity mg/l 200 75 - 160 200 11 Total Hardness mg/l 200 500 500 140 197 12 TDS mg/l 500 197 211 13 DO mg/l 4-6 ppm 4-6 ppm 4-6 ppm 5.87 4.55 14 BOD mg/l 3 2 3 7 13 15 COD mg/l - - - 12 18 Bacteriological - 16 Faecal Coliforms CFU/ 100 ml Nil Nil Nil 68 84
  • 4. International Journal of Research in Advent Technology, Vol.3, No.12, December 2015 E-ISSN: 2321-9637 Available online at www.ijrat.org 51 4.2. Hardness, Sulphates & Nitrates: Tests results show that the Calcium hardness has increased beyond the allowable limit i.e. more than 75 mg/l [12] [4]. Nitrates were also reaching near the upper limit of specification. But magnesium hardness and sulphates were within the allowable limits. Figure 2: Upstream & Downstream Sample comparison for Hardness, Sulphates & Nitrates values (all in mg/l). 4.3. Total Alkalinity, Total Hardness & TDS: The TDS values were found to be within the allowable limits. Although Total alkalinity & total hardness values were found to be within the limits ( i.e. ≤ 200 mg/l for both ) but they are found to be reaching near the upper limits [12] [4]. Figure 3: Upstream & Downstream Sample comparison for Total Alkalinity, Total Hardness & TDS (all in mg/l). 4.4. BOD, COD, DO: A significant increase in both BOD (7 and 13 mg/l for upstream & downstream respectively) and COD (12 and 18 mg/l for upstream & downstream respectively) values has been found more than the allowable limits. [12] [4] DO was found to be within the limit but it was decreased from 5.87mg/l (upstream) to 4.55 mg/l (downstream). Figure 4: Upstream & Downstream Sample comparison for DO, COD & BOD values (all in mg/l). 4.5. Faecal Coliforms: Faecal Coliforms were also increased in downstream sample (i.e. from 68 CFU /100ml to 84 CFU /100ml) which is not permissible. Figure 5: Upstream & Downstream Sample comparison for Faecal Coliforms values (in CFU/ 100 mg). 5. CONCLUSION In above study it was found that maximum parameters were not under allowable BIS limits. pH , Turbidity, Calcium, Total Alkalinity, DO, BOD, COD and faecal coliforms exceeded the BIS limits. The amount of
  • 5. International Journal of Research in Advent Technology, Vol.3, No.12, December 2015 E-ISSN: 2321-9637 Available online at www.ijrat.org 52 faecal coliforms was very high which makes the water unsuitable for use. This all shows that the quality of the river water is below the prescribed standards and it is unsuitable for drinking or household purposes without any disinfection process. REFERENCES [1] APHA, Standard Methods for Examination of Water and Wastewater, 16th Ed., American Public Health Association, Washington, DC. c1985, 197-1157. [2] Belorkar Seema A. “Assessment of the Deterioration in Physiochemical and Microbiological Quality of Shivnath River Water in Durg District, India” E-Journal of Chemistry ISSN: 0973-4945; [3] Bhadja Poonam and Vaghela Ashokkumar, “Assessment Of Physico-Chemical parameters And Water Quality Index of Reservoir Water” International Journal of Plant, Animal and Environmental Sciences, Vol 3 july- sep 2013, ISSN 2231-4490 [4] BIS (IS: 10500-2012) Drinking Water — Specification. [5] CPCB (2009), Central Pollution Control Board, New Delhi. [6] Garg S K , Water supply engineering, khanna publishers oct 2010. [7] Pandey Devendra “Surface Water Quality with Painstaking Human Impacts-A Case Study of the Wainganga River, Bhandara, Maharashtra, India” International Journal of Bioassays (IJB) 272, ISSN: 2278-778X. [8] Pandey et. al. “Water Quality Assessment of Bhandara and Gondia Districts of Maharashtra State, INDIA” International Journal of Research in Chemistry and Environment Vol. 1 Issue 1 July 2011(114-118) ISSN 2248-9649. [9] Rennie Matthew J. “A Water Quality Survey of the River Ouseburn”, MEng Civil Engineering , School of Civil Engineering & Geosciences, Newcastle University 2012 [10]Singh Ajit Pratap and Shrivastava Parnika, “A Comparative Study on Water Quality Assessment of A River Using AHP and Promethee Techniques”, Hydraulics, Water Resources, Coastal and Environmental Engineering (HYDRO 2014) [11]Upadhyay Manish and Mishra Anisha “Study o f Physico-Chemical Properties of Surface Water (Shivnath River & Ponds) In Durg and Rajnandgaon Region” Acta Biomedica Scientia. 2014;1(1):14-17. [12] WHO (1972). World Health Organization