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TOPIC NAME: ESTER
NAME : GOSWAMI DHAVAL M.
BRANCH : CHEMICAL ENGG.
SEM : 3rd
What is Ester?
 Ester is produced when an alcohol reacts with an organic or
inorganic acid
 For ex:- Formation of ethyl acetate by reaction of ethanol and
acetic acid
 CH3COOH + C2H50H CH3COOC2H5 + H2O
 Esters are derived from carboxylic acids. A carboxylic acid
contains the -COOH group, and in an ester the hydrogen in
this group is replaced by a hydrocarbon group. The most
commonly discussed ester is ethyl ethanoate. In this case, the
hydrogen in the -COOH group has been replaced by an ethyl
group. The formula for ethyl ethanoate is:
 esters are derived from a carboxylic acid and
an alcohol
R and R' denote any alkyl or aryl group. R can also be
a hydrogen atom
Preperation Of Ester
(1)From Carboxylic Acid
 Esters are generally prepared by refluxing the acid with
alcohol in the presence of small amount of minerals acids as
catalysts.
 Example: 5-10% Concentrated sulphuric acid. The reaction is
reversible and its known as Esterification
(2)From Acid Anhydrides
 By the recation of an acid anhydrides with an alcohol.
Chemical Properties
(1)Hydrolysis
 Esters are Hydrolysed by acid or alkleis to from alcohols and acids
or there sodium salts
 E.X: ethyle acetate is hydrolysed as under
(2)Raction with Phospherous
Pentachloride
 Phospherous Pentachloride reacts with esters to produce acid
chloride and alkyl chlorides
Physical Properties of Ester
 Esters are covalent compounds(2 atoms sharing pair of more then one
electrone) which are only springly soluble in water.
 Esters are useally volatile, pleasant smelling liquid.
 Esters are neutral towards litmus
 Esters are colourless natural liquids.
What’s that Smell?
 Their bouquet is often floral or fruity.
 Esters have strong, sweet smells.
 This means they are used in food flavourings & perfumes.
 Also, very good at dissolving organic compounds so often used as
solvents
Esters Fragrance
Ethyl Methanoate Raspberries
3-methylbutyl ethanoate Pears
ethyl 2-methylbutanoate apples
phenylmethyl ethanoate jasmine
Uses
 As solvents for cellulose, oils, gums, resins, etc…
 In making artificial flavours and essences.
Ester

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Ester

  • 1. TOPIC NAME: ESTER NAME : GOSWAMI DHAVAL M. BRANCH : CHEMICAL ENGG. SEM : 3rd
  • 2. What is Ester?  Ester is produced when an alcohol reacts with an organic or inorganic acid  For ex:- Formation of ethyl acetate by reaction of ethanol and acetic acid  CH3COOH + C2H50H CH3COOC2H5 + H2O
  • 3.  Esters are derived from carboxylic acids. A carboxylic acid contains the -COOH group, and in an ester the hydrogen in this group is replaced by a hydrocarbon group. The most commonly discussed ester is ethyl ethanoate. In this case, the hydrogen in the -COOH group has been replaced by an ethyl group. The formula for ethyl ethanoate is:
  • 4.  esters are derived from a carboxylic acid and an alcohol R and R' denote any alkyl or aryl group. R can also be a hydrogen atom
  • 5. Preperation Of Ester (1)From Carboxylic Acid  Esters are generally prepared by refluxing the acid with alcohol in the presence of small amount of minerals acids as catalysts.  Example: 5-10% Concentrated sulphuric acid. The reaction is reversible and its known as Esterification
  • 6. (2)From Acid Anhydrides  By the recation of an acid anhydrides with an alcohol.
  • 7. Chemical Properties (1)Hydrolysis  Esters are Hydrolysed by acid or alkleis to from alcohols and acids or there sodium salts  E.X: ethyle acetate is hydrolysed as under
  • 8. (2)Raction with Phospherous Pentachloride  Phospherous Pentachloride reacts with esters to produce acid chloride and alkyl chlorides
  • 9. Physical Properties of Ester  Esters are covalent compounds(2 atoms sharing pair of more then one electrone) which are only springly soluble in water.  Esters are useally volatile, pleasant smelling liquid.  Esters are neutral towards litmus  Esters are colourless natural liquids.
  • 10. What’s that Smell?  Their bouquet is often floral or fruity.  Esters have strong, sweet smells.  This means they are used in food flavourings & perfumes.  Also, very good at dissolving organic compounds so often used as solvents Esters Fragrance Ethyl Methanoate Raspberries 3-methylbutyl ethanoate Pears ethyl 2-methylbutanoate apples phenylmethyl ethanoate jasmine
  • 11. Uses  As solvents for cellulose, oils, gums, resins, etc…  In making artificial flavours and essences.