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Esters
Esters
Esters are formed by the reaction of a carboxylic acid
with an alcohol e.g.
CH3COOH

+

Ethanoic acid

CH3OH
Methanol

=

CH3COOCH3 + H2O
Methyl ethanoate
Naming esters: methyl ethanoate
 The

first part of the ester name comes from
the parent alcohol with the - anol changed to
– yl and the second part of the name comes
from the parent acid with the - oic acid
changed to – oate.
Methyl methanoate

HCOOCH3
Ethyl methanoate HCOOC2H5
Methyl ethanoate

CH3COOCH3
Ethyl ethanoate

CH3COOC2H5
Physical properties
 Physical

state: Liquid
 Boiling points higher than the corresponding
alkanes, but lower than the corresponding
alcohols
Physical properties
 Soluble

in water and non-polar solvents
such as cyclohexane
 As the number of carbon atoms in a
molecule of the ester increases, solubility in
water decreases, while solubility in
cyclohexane increases
Occurrence and uses of esters
 Occur

naturally in fruits – are responsible for
their flavours  and flowers – are responsible for their
pleasant smells
 Fats and oils are naturally occurring esters of
long chain carboxylic acids
 Ethyl ethanoate is used as a solvent for
printing inks and paints

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