Batch adsorption experiments were carried out for
the adsorption of cationic dye from aqueous solution onto
composite activated carbon. The composite activated carbon was
prepared from brewer’s spent grain and sea bean shell at a ratio
of 1:1. The equilibrium studies were done at different
concentrations and temperatures. The equilibrium data were
fitted to Langmuir, Freundlich, Dubinin-Radushkevich, and
Temkin isotherm models. The results showed that both Lagmuir
and Freundlich isotherm model fitted the data reasonably well
but Freundlich isotherm fitted better in the temperature range
studied. This confirmed that the adsorption is heterogeneous,
non-specific and non-uniform in nature. Kinetic studies were also
undertaken in terms of first order, second order, pseudo first
order, pseudo second order, Elovich, Boyd, and intra-particle
diffusion models. The results indicated that the data followed
pseudo second order model with surface adsorption and intraparticle
diffusion concurrently operating during the adsorbateadsorbent
interaction. The values of the thermodynamic
parameters computed from Van’t Hoff plot confirmed the
process to be endothermic and spontaneous in nature.
A New Low Cost Biosorbent for a Cationic Dye TreatmentIJEAB
The aim of our study consists to investigate the adsorption of Methylene Blue from aqueous solution by a new biosorbent prepared from Papaya seed. Adsorption behavior of the cationic dye was analyzed by variation of solution pH, contact time, adsorbent dose, and temperature. Adsorption isotherms were studied according to the Langmuir and Freundlich Model, and adsorption kinetics according to pseudo first and second order. Results show that the maximum adsorption is obtained at ambient temperature with the yield of 98.82% and was reached in first 20min (pH = 10, adsorbent dose of 100 mg in 50 mL). The Langmuir isotherm shows a correlation coefficient of 99.4% higher than 95.4%obtained for Freundlich model and the adsorption kinetic model follow a pseudo-second order with a maximum adsorption capacity of 52.28 mg/g.
Laboratory investigation of insecticide O,O diethyl O-2 isopropyl 6- methyl pyrimidin-4-yl phosphorothioate insecticide adsorption using olive stones activated by phosphoric acid was carried out. The influence of several factors governing insecticide adsorption such as dosage, temperature, pH and time in addition to specific surface area of the prepared carbon was investigated. The obtained results showed that the adsorption was found to increase with increasing temperature and pH and the activated carbon prepared from olive stones has higher surface area (>700 m2g-1). Also, the removal of insecticide increased with the lapse of time; an olive stone activated by phosphoric acid has 75.6 % insecticide removal efficiency in comparison with that of activated carbon. The experimental results have been fitted with Langmuir and Freundlich isotherms. The Langmuir isotherm better fitted the experimental data since the average percent deviations were lower than with Freundlich isotherm. Moreover, activated carbon from olive stones is a suitable adsorbent and adsorption of 90% is possible in the high temperature, pH and adsorbent dosages.
Evaluation of Uptake of Methylene blue dye by Sulphonated biomass of Cicer ar...IOSR Journals
The uptake of methylene blue by sulphonated biomass of Cicer arientinum is conducted in batch mode. The effect of parameters like contact time, sorbent dose, pH and temperature has been studied. The value Kp is found to be 0.1928 and 0.8727 for initial and final concentrations respectively. The kinetics of biosorption results indicate that sorption process follows pseudo–second order model with determination coefficients greater than 0.988 for sorbent under all experimental conditions. Thermodynamic parameter via KD, and ΔG are calculated indicates, rise in KD, negative ΔG values determine the spontaneity of the process and significantly shows that sorption process is time, temperature and concentration dependant. The adsorption obeys the Langmuir isotherm, Hall separation factor values less than unity and low value of activation energy indicate that sorption is an activated and favorable physical process. The phenomenon of sorption includes liquid-film, mass transfer mechanism is well described by Weber and Morris intraparticle diffusion model. Thus sulphonated biomass of Cicer arientinum(S-III) is a low cost and easily available good sorbent for the removal of MB+ from wastewater.
International Refereed Journal of Engineering and Science (IRJES)irjes
International Refereed Journal of Engineering and Science (IRJES) is a leading international journal for publication of new ideas, the state of the art research results and fundamental advances in all aspects of Engineering and Science. IRJES is a open access, peer reviewed international journal with a primary objective to provide the academic community and industry for the submission of half of original research and applications
Optimal Process Parameters for the Adsorption of Methylene Blue on Thermally ...inventionjournals
In this work, the optimal parameters for the adsorption of MB by Enugu White clay as a local
adsorbent was investigated. The clay was obtained from Enugu, South-East province of Nigeria. In the research
work, the physicochemical properties, such as moisture content, volatile matter, specific surface area, and
oxides of metals, and also the effect of thermal activation on them were analyzed. Standard gravimetric methods
were used to characterized the clay. The pH value was determined with a pH meter, while the metal oxides and
Silicate, Alumina and oxide of Fe, were determined using EEL flame photometer and Pye-Unican
Spectrophotometer respectively. Adsorption kinetics and isotherms were also determined by carrying out
experiments using a batch reactor, and the results showed that Psuedo second order kinetic model fits the MB,
adsorption best, with rate constant of 0.2279g/mg.min and activation energy of 303.4J/mol.K. Equilibrium
results showed that MB adsorption by Enugu while clay can be correlated using both Freundlich and Langmuir
adsorption isotherms. Palm Oil was also used to test the bleaching performance of the activated clay, and the
results showed the clay to be effective. Response surface methodology (RSM), via Central Composite
Design,(CCD), was applied in the determination of the optimal adsorption conditions, as time – 100min,
adsorbent dosage – 0.2g, pH – 8 and MB concentration 80mg//lit. The predicted concentration value was
82.83% at 0.967 desirability. The result showed that Enugu white clay has a good adsorptive capacity and can
be used as a cheap and effective local adsorbent for the removal of pigments during refining of vegetable oils.
A New Low Cost Biosorbent for a Cationic Dye TreatmentIJEAB
The aim of our study consists to investigate the adsorption of Methylene Blue from aqueous solution by a new biosorbent prepared from Papaya seed. Adsorption behavior of the cationic dye was analyzed by variation of solution pH, contact time, adsorbent dose, and temperature. Adsorption isotherms were studied according to the Langmuir and Freundlich Model, and adsorption kinetics according to pseudo first and second order. Results show that the maximum adsorption is obtained at ambient temperature with the yield of 98.82% and was reached in first 20min (pH = 10, adsorbent dose of 100 mg in 50 mL). The Langmuir isotherm shows a correlation coefficient of 99.4% higher than 95.4%obtained for Freundlich model and the adsorption kinetic model follow a pseudo-second order with a maximum adsorption capacity of 52.28 mg/g.
Laboratory investigation of insecticide O,O diethyl O-2 isopropyl 6- methyl pyrimidin-4-yl phosphorothioate insecticide adsorption using olive stones activated by phosphoric acid was carried out. The influence of several factors governing insecticide adsorption such as dosage, temperature, pH and time in addition to specific surface area of the prepared carbon was investigated. The obtained results showed that the adsorption was found to increase with increasing temperature and pH and the activated carbon prepared from olive stones has higher surface area (>700 m2g-1). Also, the removal of insecticide increased with the lapse of time; an olive stone activated by phosphoric acid has 75.6 % insecticide removal efficiency in comparison with that of activated carbon. The experimental results have been fitted with Langmuir and Freundlich isotherms. The Langmuir isotherm better fitted the experimental data since the average percent deviations were lower than with Freundlich isotherm. Moreover, activated carbon from olive stones is a suitable adsorbent and adsorption of 90% is possible in the high temperature, pH and adsorbent dosages.
Evaluation of Uptake of Methylene blue dye by Sulphonated biomass of Cicer ar...IOSR Journals
The uptake of methylene blue by sulphonated biomass of Cicer arientinum is conducted in batch mode. The effect of parameters like contact time, sorbent dose, pH and temperature has been studied. The value Kp is found to be 0.1928 and 0.8727 for initial and final concentrations respectively. The kinetics of biosorption results indicate that sorption process follows pseudo–second order model with determination coefficients greater than 0.988 for sorbent under all experimental conditions. Thermodynamic parameter via KD, and ΔG are calculated indicates, rise in KD, negative ΔG values determine the spontaneity of the process and significantly shows that sorption process is time, temperature and concentration dependant. The adsorption obeys the Langmuir isotherm, Hall separation factor values less than unity and low value of activation energy indicate that sorption is an activated and favorable physical process. The phenomenon of sorption includes liquid-film, mass transfer mechanism is well described by Weber and Morris intraparticle diffusion model. Thus sulphonated biomass of Cicer arientinum(S-III) is a low cost and easily available good sorbent for the removal of MB+ from wastewater.
International Refereed Journal of Engineering and Science (IRJES)irjes
International Refereed Journal of Engineering and Science (IRJES) is a leading international journal for publication of new ideas, the state of the art research results and fundamental advances in all aspects of Engineering and Science. IRJES is a open access, peer reviewed international journal with a primary objective to provide the academic community and industry for the submission of half of original research and applications
Optimal Process Parameters for the Adsorption of Methylene Blue on Thermally ...inventionjournals
In this work, the optimal parameters for the adsorption of MB by Enugu White clay as a local
adsorbent was investigated. The clay was obtained from Enugu, South-East province of Nigeria. In the research
work, the physicochemical properties, such as moisture content, volatile matter, specific surface area, and
oxides of metals, and also the effect of thermal activation on them were analyzed. Standard gravimetric methods
were used to characterized the clay. The pH value was determined with a pH meter, while the metal oxides and
Silicate, Alumina and oxide of Fe, were determined using EEL flame photometer and Pye-Unican
Spectrophotometer respectively. Adsorption kinetics and isotherms were also determined by carrying out
experiments using a batch reactor, and the results showed that Psuedo second order kinetic model fits the MB,
adsorption best, with rate constant of 0.2279g/mg.min and activation energy of 303.4J/mol.K. Equilibrium
results showed that MB adsorption by Enugu while clay can be correlated using both Freundlich and Langmuir
adsorption isotherms. Palm Oil was also used to test the bleaching performance of the activated clay, and the
results showed the clay to be effective. Response surface methodology (RSM), via Central Composite
Design,(CCD), was applied in the determination of the optimal adsorption conditions, as time – 100min,
adsorbent dosage – 0.2g, pH – 8 and MB concentration 80mg//lit. The predicted concentration value was
82.83% at 0.967 desirability. The result showed that Enugu white clay has a good adsorptive capacity and can
be used as a cheap and effective local adsorbent for the removal of pigments during refining of vegetable oils.
Adsorption of Methylene blue and Malachite Green in Aqueous Solution using Ja...IJEAB
The adsorption of mixture of two basic dyes methylene blue and malachite green in aqueous solution onto jack fruit leaf ash in a batch system with respect to initial dye concentrations, pH, contact time, shaker speed and adsorbent doses was investigated.. The pseudo-first-order and pseudo-second- order kinetics model were used to describe the kinetic data. The rate constants at different pH values (3-9.1) were evaluated. The experimental data fitted well with the pseudo-second-order kinetic model. Equilibrium isotherms were analyzed by Langmuir, Freundlich and Temkin isotherm models. Maximum adsorption capacity was 20.41mg/g was achieved by Langmuir isotherm model. Error analysis was done to find the best model that described the experimental data well and it was the Langmuir model. The result indicated that jack fruit leaf ash could be fruitfully employed as low cost adsorbent for the removal of mixture of two basic dyes MB and MG from the wastewater.
— The biosorption of Malathion from aqueous solution by green algal biomass was investigated. The green algae used were of the species Spirogyra and was collected from Neugal river near Sujanpur, Himachal Pradesh. Batch biosorption experiments were performed to examine the effect of contact time, pH, biomass concentration and initial Malathion concentration. The concentration of residual Malathion concentration after biosorption was determined using UV-Vis Spectrophotometer at a wavelength of 309 nm. The maximum adsorption was found to be at pH 7 after a contact time of 5 hours with initial Malathion concentration of 100 mg/L and biomass of weight 75 mg. The equilibrium biosorption data were analyzed using Langmuir and Freundlich isotherm. Freundlich isotherm was found to be more favorable than Langmuir isotherm.
Removal of chromium (vi) by activated carbon derived from mangifera indicaeSAT Publishing House
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology
Adsorption Studies of an Acid Dye From Aqueous Solution Using Lagerstroemia ...IJMER
The effectiveness of adsorption for acid dye removal from wastewaters has made it an ideal alternative to other expensive treatment options. The removal of acid Violet 4BS onto seeds of Lagerstroemia indica (LIS) from aqueous solutions was investigated using parameters such as contact time, pH, temperature, adsorbent doses, and initial dye concentration. Adsorption isotherms of dyes onto LIS were determined and correlated with common isotherm equations such as the Langmuir and
Freundlich models. It was found that the Langmuir isotherm appears to fit the isotherm data better than
the Freundlich isotherm. Parameters of the Langmuir and Freundlich isotherms were determined using adsorption data. The maximum removal of Acid Violet 4BS by the adsorbent was obtained at pH 2. The maximum percentage of dye removal (86.67%) was obtained at an initial dye concentration of 10mg/L with adsorbent dosage of 50 mg per 50 ml of dye solution. The adsorption kinetics of acid violet 4BS could be described by the pseudo-second order reaction model. The data obtained from adsorption
isotherms at different temperatures were used to calculate several thermo-dynamic quantities such as the
Gibbs energy (ΔG0), enthalpy (ΔH0), and entropy (ΔS
0) of adsorption. The adsorption process was found
to be spontaneous, exothermic and physical in nature. Locally available adsorbent LIS was found to have
a low cost and was promising for the removal of acid violet 4BS from aqueous solutions
SYNTHESIS AND CHARACTERIZATION OF KAOLINITE COATED WITH CU-OXIDE AND ITS EFFE...Premier Publishers
In this paper, a novel copper oxide coated kaolinite was prepared as an adsorbent of Hg(II) ions from aqueous media. The materials used for this study were synthesized, characterised and the product tested for mercury ion removal using standard laboratory procedures. Reactivity and removal kinetic models derived from Freundlich isotherm were used to investigate contact time and pH effects on the coefficient of protonation and rate of mass transfer of Hg(II) ions to the reactive sites, Proton coefficient of 0.89 indicated a decrease in proton consumption function when compared with uncoated kaolinite. At the 12th h reaction time, a maximum adsorption capacity of 85% was achieved. Mass transfer rates of 0.9359h-1 and 0.0748h-1 for the first and second reaction phases indicated a reduction when compared with uncoated kaolinite. These changes may be ascribed to masking of reaction sites and exposed surface area of the Cu-Oxide coated kaolinite.
Removal of Cu(II) Ions from Aqueous Solutions by Adsorption Onto Activated Ca...IJERA Editor
This paper studied the ability of using local activated carbon (LAC) derived from olive waste cakes as an
adsorbent for the removal of Cu(II) ions from aqueous solution by batch operation. Various operating parameters
such as solution pH, adsorbent dosage, initial metal ions concentration, and equilibrium contact time have been
studied. The results indicated that the adsorption of Cu(II) increased with the increasing pH, and the optimum
solution pH for the adsorption of Cu(II) was found to be 5. The adsorption process increases with increasing
dosage of LAC, also the amount of Cu(II) removed changes with Cu(II) initial concentration and contact time.
Adsorption was rapid and occurred within 25 min. for Cu(II) concentration range from 60 to 120 mg/l
isothermally at 30±1 oC. Maximum adsorption occurs at Cu(II) initial concentration lesser than 100 mg/l by
using adsorbent dosage (1.2 g/l). The equilibrium adsorption data for Cu(II) were fitted well with the Langmuir
and Freundlich adsorption isotherm models. The maximum adsorption capacity of LAC was found to be 106.383
mg/g. So, the results indicated the suitability use of the activated carbon derived from olive waste cakes (LAC)
as low cost and natural material for reliable removal of Cu(II) from water and wastewater effluents.
Treatment of Effluent from Granite Cutting Plant by Using Natural Adsorbents ...IJERD Editor
Granite cutting plant is one such industry that releases polluting and turbid effluent. The residue from all these processes is discharged with water as an effluent. The effluent mainly contains many solids that harm the environment. Hence it requires treatment techniques before disposal. Several conventional methods are available for removal of contaminants like coagulation, adsorption, polyelectrolyte methods and biological methods. Most of them are cost prohibitive. The reduction of solids concentration in the effluent before disposal by using the techniques, coagulation followed by adsorption using natural adsorbents, like rice husk carbon and saw dust carbon, in contrast to the usage of activated carbon as it is costly. From a local Granite cutting plant near Anantapur, the effluent is collected and its physico-chemical characteristics are estimated and found to be pH(7.5), TS(4240mg/l), TSS(21560mg/l), TDS(12373mg/l).Effluent obtained is subjected to coagulation by potash alum followed by adsorption using saw dust carbon and rice husk carbon.
adsorption of methylene blue onto xanthogenated modified chitosan microbeadsSiti Nadzifah Ghazali
Methylene Blue (MB) is thiazine dyes that widely use to color product in many industry such as textile, printing, leather, cosmetic and paper. Xanthogenated-Modified Chitosan Microbeads (XMCM) is use to observe the new alternative adsorbent in removing MB from water body through adsorption process. The interactions between MB and functional group in XMCM were confirmed by Fourier Transform Infrared (FT-IR) spectra. Several parameters that influence adsorption ability such as the effect of adsorbent dosage of XMCM and the effect of initial pH of MB aqueous solution were studied. This study were done at optimum condition which is at pH 4 of initial pH of MB solution, 0.01 g of initial XMCM dosage, 6 hours stirring time and temperature of (30 ± 2 ℃). The adsorption data fit well Langmuir model more than Freundlich model. Based on Langmuir model, the maximum monolayer adsorption capacity of MB was 21.62 mg g-1 which indicated that XMCM can be a new alternative adsorbent for removing MB.
The present study was conducted at Lucknow
District in Uttar Pradesh. The purpose of this study is to
document how being perform in extra-curricular activities can
influence development in academics, social skills, and high school
completion. In this paper we study the possible influence of
extracurricular activities on student’s performance of eighth-and
ninth graders. 120 students of age group between 13 to 16 years
comprised the sample of the study. Self-made questionnaire for
school students were administered. Data was analyzed in term of
percentage and t-test analysis. The statistical analysis revealed
that all the 6 types of extracurricular activities, viz. Yoga, Horse
riding, Sport activities, Dance, Music and Indoor and outdoor
activities together showed significant role in some extracurricular
activities and Student’s performance of Government and Private
School. Students who participate in extracurricular activities
generally benefit from the many opportunities afforded them.
Benefits of participating in extracurricular activities included
having better grades, having higher standardized test scores and
higher educational attainment, attending school more regularly,
and having higher a higher self-concept. Those who participate in
out-of-school activities often have higher grade point averages, a
decrease in absenteeism, and an increased connectedness to the
school. Finally, we discuss the possible influence of
extracurricular activities on student’s performance and whether
such participation is advisable
Background and objectives: Iron is one of the major component
of hemoglobin, is required for transport of oxygen, ferritin is a
protein for storage iron, and transferring is a protein for iron
transport, all these it may be change in breast cancer.
The aim of present study was to measure the serum ferritin, iron,
total iron binding capacity, transferring, and C-reactive protein
concentration in breast tumors.
Material and method: A prospective study was carried out from
April 2013 to August 2014 by clinical biochemistry department in
College of Pharmacy-University of Sulaimani on (45) healthy
female individuals, (group 1) and (50) females with breast tumor
(group 2).
Results: The mean value of serum iron, transferring, total iron
binding capacity were significantly lower in females with breast
tumors (group 2), than that of healthy female individuals, (group
1), while serum ferritin was significantly higher in females with
breast tumors (group2), than that of healthy individuals (group
1).
Conclusion: Based on findings of the present study it can be
concluded that breast tumors can cause deficient of all iron
profile except ferritin will be increase in female breast cancers.
Key words- Serum iron, S.Ferritin, S. Total iron binding, S.
Transferrin, S.C-Reactive protein, breast tumors.
Adsorption of Methylene blue and Malachite Green in Aqueous Solution using Ja...IJEAB
The adsorption of mixture of two basic dyes methylene blue and malachite green in aqueous solution onto jack fruit leaf ash in a batch system with respect to initial dye concentrations, pH, contact time, shaker speed and adsorbent doses was investigated.. The pseudo-first-order and pseudo-second- order kinetics model were used to describe the kinetic data. The rate constants at different pH values (3-9.1) were evaluated. The experimental data fitted well with the pseudo-second-order kinetic model. Equilibrium isotherms were analyzed by Langmuir, Freundlich and Temkin isotherm models. Maximum adsorption capacity was 20.41mg/g was achieved by Langmuir isotherm model. Error analysis was done to find the best model that described the experimental data well and it was the Langmuir model. The result indicated that jack fruit leaf ash could be fruitfully employed as low cost adsorbent for the removal of mixture of two basic dyes MB and MG from the wastewater.
— The biosorption of Malathion from aqueous solution by green algal biomass was investigated. The green algae used were of the species Spirogyra and was collected from Neugal river near Sujanpur, Himachal Pradesh. Batch biosorption experiments were performed to examine the effect of contact time, pH, biomass concentration and initial Malathion concentration. The concentration of residual Malathion concentration after biosorption was determined using UV-Vis Spectrophotometer at a wavelength of 309 nm. The maximum adsorption was found to be at pH 7 after a contact time of 5 hours with initial Malathion concentration of 100 mg/L and biomass of weight 75 mg. The equilibrium biosorption data were analyzed using Langmuir and Freundlich isotherm. Freundlich isotherm was found to be more favorable than Langmuir isotherm.
Removal of chromium (vi) by activated carbon derived from mangifera indicaeSAT Publishing House
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology
Adsorption Studies of an Acid Dye From Aqueous Solution Using Lagerstroemia ...IJMER
The effectiveness of adsorption for acid dye removal from wastewaters has made it an ideal alternative to other expensive treatment options. The removal of acid Violet 4BS onto seeds of Lagerstroemia indica (LIS) from aqueous solutions was investigated using parameters such as contact time, pH, temperature, adsorbent doses, and initial dye concentration. Adsorption isotherms of dyes onto LIS were determined and correlated with common isotherm equations such as the Langmuir and
Freundlich models. It was found that the Langmuir isotherm appears to fit the isotherm data better than
the Freundlich isotherm. Parameters of the Langmuir and Freundlich isotherms were determined using adsorption data. The maximum removal of Acid Violet 4BS by the adsorbent was obtained at pH 2. The maximum percentage of dye removal (86.67%) was obtained at an initial dye concentration of 10mg/L with adsorbent dosage of 50 mg per 50 ml of dye solution. The adsorption kinetics of acid violet 4BS could be described by the pseudo-second order reaction model. The data obtained from adsorption
isotherms at different temperatures were used to calculate several thermo-dynamic quantities such as the
Gibbs energy (ΔG0), enthalpy (ΔH0), and entropy (ΔS
0) of adsorption. The adsorption process was found
to be spontaneous, exothermic and physical in nature. Locally available adsorbent LIS was found to have
a low cost and was promising for the removal of acid violet 4BS from aqueous solutions
SYNTHESIS AND CHARACTERIZATION OF KAOLINITE COATED WITH CU-OXIDE AND ITS EFFE...Premier Publishers
In this paper, a novel copper oxide coated kaolinite was prepared as an adsorbent of Hg(II) ions from aqueous media. The materials used for this study were synthesized, characterised and the product tested for mercury ion removal using standard laboratory procedures. Reactivity and removal kinetic models derived from Freundlich isotherm were used to investigate contact time and pH effects on the coefficient of protonation and rate of mass transfer of Hg(II) ions to the reactive sites, Proton coefficient of 0.89 indicated a decrease in proton consumption function when compared with uncoated kaolinite. At the 12th h reaction time, a maximum adsorption capacity of 85% was achieved. Mass transfer rates of 0.9359h-1 and 0.0748h-1 for the first and second reaction phases indicated a reduction when compared with uncoated kaolinite. These changes may be ascribed to masking of reaction sites and exposed surface area of the Cu-Oxide coated kaolinite.
Removal of Cu(II) Ions from Aqueous Solutions by Adsorption Onto Activated Ca...IJERA Editor
This paper studied the ability of using local activated carbon (LAC) derived from olive waste cakes as an
adsorbent for the removal of Cu(II) ions from aqueous solution by batch operation. Various operating parameters
such as solution pH, adsorbent dosage, initial metal ions concentration, and equilibrium contact time have been
studied. The results indicated that the adsorption of Cu(II) increased with the increasing pH, and the optimum
solution pH for the adsorption of Cu(II) was found to be 5. The adsorption process increases with increasing
dosage of LAC, also the amount of Cu(II) removed changes with Cu(II) initial concentration and contact time.
Adsorption was rapid and occurred within 25 min. for Cu(II) concentration range from 60 to 120 mg/l
isothermally at 30±1 oC. Maximum adsorption occurs at Cu(II) initial concentration lesser than 100 mg/l by
using adsorbent dosage (1.2 g/l). The equilibrium adsorption data for Cu(II) were fitted well with the Langmuir
and Freundlich adsorption isotherm models. The maximum adsorption capacity of LAC was found to be 106.383
mg/g. So, the results indicated the suitability use of the activated carbon derived from olive waste cakes (LAC)
as low cost and natural material for reliable removal of Cu(II) from water and wastewater effluents.
Treatment of Effluent from Granite Cutting Plant by Using Natural Adsorbents ...IJERD Editor
Granite cutting plant is one such industry that releases polluting and turbid effluent. The residue from all these processes is discharged with water as an effluent. The effluent mainly contains many solids that harm the environment. Hence it requires treatment techniques before disposal. Several conventional methods are available for removal of contaminants like coagulation, adsorption, polyelectrolyte methods and biological methods. Most of them are cost prohibitive. The reduction of solids concentration in the effluent before disposal by using the techniques, coagulation followed by adsorption using natural adsorbents, like rice husk carbon and saw dust carbon, in contrast to the usage of activated carbon as it is costly. From a local Granite cutting plant near Anantapur, the effluent is collected and its physico-chemical characteristics are estimated and found to be pH(7.5), TS(4240mg/l), TSS(21560mg/l), TDS(12373mg/l).Effluent obtained is subjected to coagulation by potash alum followed by adsorption using saw dust carbon and rice husk carbon.
adsorption of methylene blue onto xanthogenated modified chitosan microbeadsSiti Nadzifah Ghazali
Methylene Blue (MB) is thiazine dyes that widely use to color product in many industry such as textile, printing, leather, cosmetic and paper. Xanthogenated-Modified Chitosan Microbeads (XMCM) is use to observe the new alternative adsorbent in removing MB from water body through adsorption process. The interactions between MB and functional group in XMCM were confirmed by Fourier Transform Infrared (FT-IR) spectra. Several parameters that influence adsorption ability such as the effect of adsorbent dosage of XMCM and the effect of initial pH of MB aqueous solution were studied. This study were done at optimum condition which is at pH 4 of initial pH of MB solution, 0.01 g of initial XMCM dosage, 6 hours stirring time and temperature of (30 ± 2 ℃). The adsorption data fit well Langmuir model more than Freundlich model. Based on Langmuir model, the maximum monolayer adsorption capacity of MB was 21.62 mg g-1 which indicated that XMCM can be a new alternative adsorbent for removing MB.
The present study was conducted at Lucknow
District in Uttar Pradesh. The purpose of this study is to
document how being perform in extra-curricular activities can
influence development in academics, social skills, and high school
completion. In this paper we study the possible influence of
extracurricular activities on student’s performance of eighth-and
ninth graders. 120 students of age group between 13 to 16 years
comprised the sample of the study. Self-made questionnaire for
school students were administered. Data was analyzed in term of
percentage and t-test analysis. The statistical analysis revealed
that all the 6 types of extracurricular activities, viz. Yoga, Horse
riding, Sport activities, Dance, Music and Indoor and outdoor
activities together showed significant role in some extracurricular
activities and Student’s performance of Government and Private
School. Students who participate in extracurricular activities
generally benefit from the many opportunities afforded them.
Benefits of participating in extracurricular activities included
having better grades, having higher standardized test scores and
higher educational attainment, attending school more regularly,
and having higher a higher self-concept. Those who participate in
out-of-school activities often have higher grade point averages, a
decrease in absenteeism, and an increased connectedness to the
school. Finally, we discuss the possible influence of
extracurricular activities on student’s performance and whether
such participation is advisable
Background and objectives: Iron is one of the major component
of hemoglobin, is required for transport of oxygen, ferritin is a
protein for storage iron, and transferring is a protein for iron
transport, all these it may be change in breast cancer.
The aim of present study was to measure the serum ferritin, iron,
total iron binding capacity, transferring, and C-reactive protein
concentration in breast tumors.
Material and method: A prospective study was carried out from
April 2013 to August 2014 by clinical biochemistry department in
College of Pharmacy-University of Sulaimani on (45) healthy
female individuals, (group 1) and (50) females with breast tumor
(group 2).
Results: The mean value of serum iron, transferring, total iron
binding capacity were significantly lower in females with breast
tumors (group 2), than that of healthy female individuals, (group
1), while serum ferritin was significantly higher in females with
breast tumors (group2), than that of healthy individuals (group
1).
Conclusion: Based on findings of the present study it can be
concluded that breast tumors can cause deficient of all iron
profile except ferritin will be increase in female breast cancers.
Key words- Serum iron, S.Ferritin, S. Total iron binding, S.
Transferrin, S.C-Reactive protein, breast tumors.
This paper aims to identify Key determinants for
successful Project Implementation in the state of West Bengal
with special focus in the Durgapur Industrial area. The research
is motivated by the fact that of late there has been limited success
in Project Implementation in West Bengal which had earlier been
very successful in large scale project Implementation. Project
related Professionals of the region were deliberated and
interviewed. An objective realization instrument developed using
47 factors identified in the research as possible drivers in Project
implementation based on Likert’s seven point scale of ranking.
Weighted scores of respondents who have been involved in
project implementation in the area to the factors were analysed
using Factor Analysis, while the effects of the quantified weight of
the critical factors were analysed using regression tool. Result of
the analysis clearly identifies the Key determinant among all
factors which are essential for successful Project Implementation.
The 47 factors are further grouped into few segments like
Human, Resource, and Infrastructure etc. So through this
research segment priority is also determined for the area and
project manager based on priority can devote their time and
energy to ensure that the Project is successfully completed. The
customisation of Project planning and Project design has been
the key determinant for successful project implementation
The present study was attempted to examine the role of
paternal and maternal parenting styles as predictor of students’
academic achievement. Parental Authority Questionnaire (Buri,
1991) further translated in Urdu by (Babree, 1997) was used to
collect the information from participants. Student’s result of
previous final Exam was taken as Academic Achievement.
Sample of the present study was consist on the F.A/F.Sc students
(N= 350) of final year. Simple linear regression analysis was
applied to test the hypothesis. The result of the study showed that
maternal and paternal authoritative style was a positive predictor
of academic achievement of adolescent. While maternal and
paternal authoritarian styles of parents was found to be a
negative predictor of academic achievement. The results for
permissive parenting style of both mother and father were nonsignificant.
The present study provided an insight to the roles of
parenting to academic achievement
Background: Septoplasty is one of the commonest nasal surgeries
performed by otolaryngologist. Silicone is the most common
material used for nasal splints. Trans-septal suturing technique
has been described to approximate the mucosal flaps after septal
procedures to reduce the complication rate; however there are
few studies proving the efficacy.
Objective: This study is to elucidate the efficacy of trans-septal
suture method in preventing complications, discomfort and pain
in comparison with intranasal splinting using silicone plates after
septoplasty.
Patients and methods: This is a prospective study of 59 adult
patients underwent Septoplasty, between August 2013-January
2014 in Rizgary Teaching Hospital - Erbil city. Patients were
divided into 2 groups; trans-septal suture and silicone, 29 and 30
patients respectively. Visual analogue scale was used to evaluate
postoperative pain, bleeding, post-nasal drip, dysphagia and
sleep disturbance for three days. Epiphora and septal hematoma
are also evaluated. Septal perforation, crustation, and adhesion
were evaluated at 4th postoperative week.
Results: The severity of pain and post nasal drip were
significantly lower in trans-septal suture group than silicone
group (P< 0.05). The septal hematoma and septal perforation
were not seen in the study. No any significant difference found
concerning epiphora, crustation and adhesion.
Conclusion: we conclude that, suturing can be used safely in
septoplasty sp
Removal of noise is a determining track in
the image rebuilding process, but denoising of image remains a
claiming problem in upcoming analysis accomplice along
image processing. Denoising is utilized to expel the noise from
corrupted image, where as we need to maintain the edges and
other detailed characteristics almost accessible. This noise gets
imported during accretion, transmitting & receiving and
storage & retrieval techniques. In this paper, to discover out
denoised image the modified denoising technique and the local
adaptive wavelet image denoising technique can be obtained.
The input (noisy image) is denoised with the help of modified
denoising technique which is form on wavelet domain as well as
spatial domain along with the local adaptive wavelet image
denoising technique which is form on wavelet domain. In this
paper, I have appraised and analyzed achievements of
modified denoising technique and the local adaptive wavelet
image denoising technique. The above procedures are
contemplated with other based on PSNR between input image
and noisy image and SNR between input image and denoised
image. Simulation and experimental outgrowth for an image
reflects as the mean square error of the local adaptive wavelet
image denoising procedure is less efficient as compare to
modified denoising procedure including the signal to noise
ratio of the local adaptive wavelet image denoising technique is
effective than other approach. Therefore, the image after
denoising has a superior visual effect. In this paper, these two
techniques are materialized with the help of MATLAB for
denoising of image
Data mining , knowledge discovery is the process
of analyzing data from different perspectives and summarizing it
into useful information - information that can be used to increase
revenue, cuts costs, or both. Data mining software is one of a
number of analytical tools for analyzing data. It allows users to
analyze data from many different dimensions or angles, categorize
it, and summarize the relationships identified. Technically, data
mining is the process of finding correlations or patterns among
dozens of fields in large relational databases. The goal of
clustering is to determine the intrinsic grouping in a set of
unlabeled data. But how to decide what constitutes a good
clustering? It can be shown that there is no absolute “best”
criterion which would be independent of the final aim of the
clustering. Consequently, it is the user which must supply this
criterion, in such a way that the result of the clustering will suit
their needs.
For instance, we could be interested in finding
representatives for homogeneous groups (data reduction), in
finding “natural clusters” and describe their unknown properties
(“natural” data types), in finding useful and suitable groupings
(“useful” data classes) or in finding unusual data objects (outlier
detection).Of late, clustering techniques have been applied in the
areas which involve browsing the gathered data or in categorizing
the outcome provided by the search engines for the reply to the
query raised by the users. In this paper, we are providing a
comprehensive survey over the document clustering.
Kinetics and Thermodynamic Studies of Adsorption of Methylene Blue from Aqueo...IOSRJAC
:In the present study, Paliurus spina-christi Mill. Frutis and Seeds (PSCFS) was used as an adsorbent for the investigation of the adsorption kinetics and thermodynamic parameters of methyleneblue (MB) from aqueous solution at various temperatures and concentrations. Six kinetic models, the pseudo-first-order, pseudo-second-order, intra-particle diffusion, Elovich, Bangham and Avrami equations were used to predict the adsorption rate constants. It was found that the kinetics of the adsorption of MB onto PSCFS at different operating conditions was the best described by the pseudo-second-order model. The rate parameters of the other kinetic models for adsorption were also evaluated and compared to identify the adsorption mechanisms. The equilibrium constants were used to calculate thermodynamic parameters, such as the change of free energy, enthalpy and entropy. Thermodynamic analysis showed that adsorption was favourable and spontaneous, endothermic physical adsorption and increased disorder and randomness at the solid-solution interface of MB onto PSCFS
Adsorptive Removal of Methylene Blue Using Groundnut Shell Activated Carbon C...IOSRJAC
In this work, activated carbon prepared from groundnut shells (GSAC) by sulphuric acid treatment was coated with Fe3O4(GSAC- Fe3O4) and tested for its efficiency as an adsorbentfor the removal of methylene blue (MB) dye from aqueous solution. The structural morphology and functional groups present were investigated using scanning electron microscope (SEM) and Fourier transform infrared (FTIR) spectroscopy. Various sorption parameters such as effect of pH, contact time, initial dye concentration and adsorbent dosage were studied. The percentage removal of methylene blue increased with decrease in initial methylene blue concentration and increased with increase in contact time and dose of the adsorbent. Equilibrium data were analysed using Langmuir and Freundlich isotherm models. Kinetic data were studied using pseudo-first order and pseudo-second order kinetic models.
Removal of Methylene Blue from Aqueous Solutions by Nitrated biomass of Cicer...IOSR Journals
Investigation of removal of methylene blue by nitrated biomass of Cicer arientinum is conducted in batch conditions. The effect of different parameters such as contact time, sorbent dose, pH and temperature has been studied. Adsorption kinetic modeling data were found out. The kinetics of biosorption results shows that sorption process is well explained by pseudo–second order model with determination coefficients higher than 0.99 for sorbent under all experimental conditions. The value Kp is found to be 0.652 to 2.43 for initial and final concentrations. Thermodynamic parameter via KD, ΔG has also been calculated to determine the spontaneity of the process. The low value of activation energy indicates that sorption is an activated and physical process. The Weber and Morris intraparticle diffusion model show liquid-film, mass transfer is effective sorption mechanism. Thus nitrated biomass of Cicer areintinum is a low cost and easily available efficiently used as an excellent sorbent for the removal of MB+ from wastewater. It can be safely concluded that biomass of Cicer arientinum is much economical effectual, viable and can be an alternative to more costly adsorbents.
Adsorption of Methylene Blue From Aqueous Solution with Vermicompost Produced...IJMERJOURNAL
ABSTRACT: The removal of Methylene blue as a synthetic dye from aquatic system was investigated by using vermicompost. The dye concentration, contact time and pH of the solution carried out in the adsorption studies. Batch adsorption experimental data were suitable for the Langmuir isotherm and a very good fit to the second order kinetic model (pH=10). The maximum adsorption capacity calculated 256.66 mg g-1 . Vermicompost and the dye loaded vermicompost were characterized by SEM and FTIR. It was found that the vermicompost is stable without losing their activity.
Application of Langmuir-Hinshelwood Model to Bioregeneration of Activated Car...IOSR Journals
Environmental pollution, high cost and high energy consumption associated with thermal regeneration of activated carbon polluted with hydrocarbon necessitated the search for a better way of regenerating activated carbon, bioregeneration. Spent granular activated carbon was regenerated having been initially characterized using cultured Pseudomonas Putida. The rate of bioregeneration was studied by varying the volume of bacteria from 10ml, 20ml, 30ml and 40ml. The regeneration temperature was also varied from 25oC to ambient temperature of 27oC, 35oC and further at 40 and 45oC over a period of 21 days. The experimental results showed clear correlation when validated using the Langmuir-Hinshelwood kinetic model. The experiment at ambient temperature showed a negative correlation due to the fluctuation in the ambient temperature unlike all other experiment where temperature was controlled in an autoclave machine.
Isothermal, Kinetic and Thermodynamic Studies of the Adsorption of Erythrosin...IJAEMSJORNAL
Isothermal, kinetic and thermodynamic studies of the adsorption of erythrosine dye onto activated carbon from Periwinkle shell was carried out. The Periwinkle shell were washed, dried, carbonized at 400oC, crushed, sieved, chemically activated at 800oC, cooled, washed and dried at 110oC. Variable influencing factors, such as contact time, temperature and concentration were studied through single-factor experiment, while other factors are kept constant (at 30min, 30oC and 50mg/L) in each adsorption experiment. From the adsorption isotherms, the correlation coefficient for Redlich-Peterson is closer to unity than others used in the adsorption. The adsorption kinetic followed pseudo-second order reaction, while the thermodynamic parameters, (∆H) = 13.49KJ/mol, (∆S) = 43.48J/mol.K and (∆G) = 0.4, 0.06, -0.15, -0.27, -0.54, -7.30KJ/mol. These results obtained show that activated carbon from Periwinkle shell will be a good low-cost adsorbent for the removal of erythrosine from aqueous solution.
The present work was carried out to evaluate the removal of p-nitrophenol by adsorption onto olive cake based activated carbon having a BET surface area of 672 m²/g. The batch adsorption experimental results indicated that the equilibrium time for nitrophenol adsorption by olive cake-based activated carbon was 120min. The adsorption data was modeled by equilibrium and kinetic models. The pseudo- first and second order as well as the Elovichkinetic models were applied to fit the experimental data and the intraparticle diffusion model was assessed for describing the mechanism of adsorption. The data were found to be best fitted to the pseudo-second order model with a correlation coefficient (R2=0.986). The intraparticle diffusion mechanism also showed a good fit to the experimental data, showing two distinct linear parts assuming that more than one step could be involved in the adsorption of nitrophenol by the activated carbon. The equilibrium study was performed using three models including Langmuir, Freundlich and Temkin. The results revealed that the Temkin equilibrium model is the best model fitting the experimental data (R2=0.944). The results of the present study proved the efficiency of using olive cake based activated carbon as a novel adsorbent for the removal of nitrophenol from aqueous solution.
Decolorization potential of immobilized pseudomonas putida mtcc 1194 with low...eSAT Journals
Abstract A simultaneous adsorption and biodegradation method for removal of reactive blue-4 is reported here. The mustard stalk activated carbon (MSAC) using Pseudomonas putida MTCC1194 was applied to decolorize reactive blue-4. Batch studies were performed to evaluate the influences of various parameters; initial pH, adsorbent dose, temperature and initial concentration, on removal of reactive blue-4. Optimum conditions for reactive blue -4 removals were found to be pH 7, adsorbent dose10g/l, temperature 32°C at equilibrium time 360 min for 150 mg/l of dye concentration. Experimental data were analyzed by pseudo-first order, pseudo-second order kinetics and intra-particle diffusion model. Equilibrium isotherms for the adsorption of reactive blue 4 onto MSAC were analyzed by Freundlich, Langmuir, Temkin and Dubinin–Radushkevich (D-R). The results show that experimental data follow pseudo-second order kinetics and intra-particle diffusion model. Out of four isotherms, Langmuir was found to be best fit with experimental data (R2 > 0.97), with 70.2% removal of reactive blue 4. Keywords: activated carbon mustard stalk, reactive blue 4, simultaneous adsorption and biodegradation (SAB), Pseudomonas putida
Adsorption Studies of an Acid Dye From Aqueous Solution Using Lagerstroemia I...IJMER
The effectiveness of adsorption for acid dye removal from wastewaters has made it an ideal
alternative to other expensive treatment options. The removal of acid Violet 4BS onto seeds of
Lagerstroemia indica (LIS) from aqueous solutions was investigated using parameters such as contact
time, pH, temperature, adsorbent doses, and initial dye concentration. Adsorption isotherms of dyes onto
LIS were determined and correlated with common isotherm equations such as the Langmuir and
Freundlich models. It was found that the Langmuir isotherm appears to fit the isotherm data better than
the Freundlich isotherm. Parameters of the Langmuir and Freundlich isotherms were determined using
adsorption data. The maximum removal of Acid Violet 4BS by the adsorbent was obtained at pH 2. The
maximum percentage of dye removal (86.67%) was obtained at an initial dye concentration of 10mg/L
with adsorbent dosage of 50 mg per 50 ml of dye solution. The adsorption kinetics of acid violet 4BS
could be described by the pseudo-second order reaction model. The data obtained from adsorption
isotherms at different temperatures were used to calculate several thermo-dynamic quantities such as the
Gibbs energy (ΔG
0
), enthalpy (ΔH
0
), and entropy (ΔS
0
) of adsorption. The adsorption process was found
to be spontaneous, exothermic and physical in nature. Locally available adsorbent LIS was found to have
a low cost and was promising for the removal of acid violet 4BS from aqueous solutions
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
IJERA (International journal of Engineering Research and Applications) is International online, ... peer reviewed journal. For more detail or submit your article, please visit www.ijera.com
nternational Journal of Engineering Research and Development is an international premier peer reviewed open access engineering and technology journal promoting the discovery, innovation, advancement and dissemination of basic and transitional knowledge in engineering, technology and related disciplines.
Thermodynamics and adsorption studies of rhodamine-b dye onto organoclayInnspub Net
Thermodynamics and adsorption studies were conducted with a dye of Rhoda mine-B (RB) on organoclay (OC). Adsorption of the dye was investigated with an initial dye concentration at pH 7±0.3, 298, 308 and 318 K. The adsorption experiments were carried out isothermally at three different temperatures. The Langmuir and Freundlich isotherm models were used to describe the equilibrium data and the results were discussed in details. The thermodynamic parameters such as standard free energy (∆G°), entropy change (∆S°) and enthalpy (∆H°) were calculated for OC. These values showed that adsorption of RB on OC was a spontaneous and endothermic process.
Similar to EQUILIBRIUM, KINETIC AND THERMODYNAMIC STUDIES ON BASIC DYE ADSORPTION USING COMPOSITE ACTIVATED CARBON (20)
Recent joint surgery studies reveal increased
revisions and resurfacing of the metal on metal hip joints. Metal
on metal hip implants were developed more than thirty years ago
and their application has been refined because of availability of
advanced manufacturing techniques and partly by advancements
in material science and engineering. Development of composite
materials may provide greater durability to metal-on-metal hip
implants .This review article is a study of the latest literature of
metal-on-metal hip implants and its various modeling techniques.
Numbers of methods are used for convergence and numerical
solution to investigate the performance of metal-on-metal hip
implant for accurate stable solution. This paper presents analysis
done by various researchers on metal-on-metal hip implants for
wear, lubrication, fatigue, bio-tribo-corrosion, design, toxicity
and resurfacing. After in vivo and in vitro studies, it is found that
all these methods have limitations. There is a need of more
insight for lubrication analysis, geometry of bearings, materials
and input parameters. The information provided in this work is
intended as an aid in the assessment of metal-on-metal hip joints.
Background Hospital contributes significantly tangible and intangible resources on a concurred plan by the scheduling of surgery on the OT list. Postponement decreases efficiency by declining throughput leads to wastage of resources hence burden to the nation. Patients and their family face economic and emotional implication due to the postponement. Postponement rate being a quality indicator controls check mechanism could be developed from the results. Postponement of elective scheduled operations results in inefficient use of the operating room (OR) time on the day of surgery. Inconvenience to patients and families are also caused by postponements. Moreover, the day of surgery (DOS) postponement creates logistic and financial burden associated with extended hospital stay and repetitions of pre-operative preparations to an extent of repetition of investigations in some cases causing escalated costs, wastage of time and reduced income. Methodology A cross-sectional study was done in the operation theaters of a tertiary care hospital in which total ten operation theaters of General Surgery Data of scheduled, performed and postponed surgeries was collected from all the operation theater with effect from March 1st to September 30th, 2018. A questionnaire was developed to find out the reasons for the postponement for all hospital’s stakeholders (surgeons, Anesthetist, Nursing Officer) and they were further evaluated time series analysis of scheduling of Operation Theater for moving average technique. Results Total 958 surgeries were scheduled and 772 surgeries performed were and 186 surgeries were postponed with a postponement rate of 19.42% in the cardiac surgery department during the study period. Month-wise postponement Rate exponential smoothing of time series data shows the dynamic of operating suits. To test throughput Postponement rate was plotted the postponed surgeries and on regression analysis is in a perfect linear relationship.
Introduction: Postponement of elective scheduled operations results in inefficient use of operating room (OR) time on the day of surgery. Inconvenience to patients and families also caused by postponements. Moreover, day of surgery (DOS) postponement creates logistic and financial burden associated with extended hospital stay and repetitions of pre-operative preparations to an extend of repetition of investigations in some cases causing escalated costs, wastage of time and reduced income. Methodology: A cross sectional study was done in the operation theaters of a tertiary care hospital in which total ten operation theaters of General Surgery Data of scheduled, performed and postponed surgeries was collected from all the operation theater with effect from march 1st to September 30th 2018. A questionnaire was developed to find out the reasons for the postponement for all hospital’s stakeholders (Surgeons, Anesthetist, Nursing officer) and they were further evaluated Time series analysis of scheduling of Operation Theater for Moving average Technique. Results: total 2,466 surgeries were scheduled and 1,980 surgeries were performed and 486 surgeries were postponed in the general surgery department during the study period. Month wise postponement forecast was in accordance with the performed surgeries and on regression analysis postponed surgeries were in perfect linear relationship with the postponement Rate.
In the present paper the experimental study of
Nanotechnology involves high cost for Lab set-up and the
experimentation processes were also slow. Attempt has also
been made to discuss the contributions towards the societal
change in the present convergence of Nano-systems and
information technologies. one cannot rely on experimental
nanotechnology alone. As such, the Computer- simulations and
modeling are one of the foundations of computational
nanotechnology. The computer modeling and simulations
were also referred as computational experimentations. The
accuracy of such Computational nano-technology based
experiment generally depends on the accuracy of the following
things: Intermolecular interaction, Numerical models and
Simulation schemes used. The essence of nanotechnology is
therefore size and control because of the diversity of
applications the plural term nanotechnology is preferred by
some nevertheless they all share the common feature of control
at the nanometer scale the latter focusing on the observation
and study of phenomena at the nanometer scale. In this paper,
a brief study of Computer-Simulation techniques as well as
some Experimental result
Solar cell absorber Kesterite- type Cu2ZnSnS4 (CZTS) thin films have been prepared by Chemical Bath Deposition (CBD). UV–vis absorption spectra measurement indicated that the band gap of as-synthesized CZTS was about1.68 eV, which was near the optimum value for photovoltaic solar conversion in a single-band-gap device. The polycrystalline CZTS thin films with kieserite crystal structure have been obtained by XRD. The average of crystalline size of CZTS is 27 nm
Multilevel inverters play a crucial part in the
areas of high and medium voltage applications. Among the three
main multilevel inverters used, the capacitor clamped multilevel
inverter(CCMLI) has advantage with respect to voltage
redundancies. This work proposes a switching pattern to improve
the performance of chosen H-bridge type CCMLI over
conventional CCMLI. The PWM technique used in this work is
Phase Opposition Disposition PWM(PODPWM). The
performance of proposed H-bridge type CCMLI is verified
through MATLAB-Simulink based simulation. It has been
observed that the THD is low in chosen CCMLI compared to
conventional CCMLI.
- In this paper, we introduce a practical mechanism of
compressing a binary phase code modulation (BPCM) signal
according to Barker code with 13 chips in presence of additive
white Gaussian noise (AWGN) by using a digital matched filter
(DMF) corresponding to time domain convolution algorithm of
input and reference signals using Cyclone II EP2C70F896C6
FPGA from ALTERA placed on education and development
board DE2-70 with the following parameters: frequency of
BPCM signal fIF=2 MHz, sampling frequency
f MHz SAM 50
,pulse period
T 200s
, pulse width
S 13sc
, chip width
CH 1sc
, compressing factor
KCOM 13
, SNRinp=1/1, 1/2, 1/3, 1/4, 1/5 and processing
gain factor SNRout/SNRinp=11.14 dB.
The results of filter operation are evaluated using a digital
oscilloscope GDS-1052U to display the input and output signals
for different SNRinp.
Flooding is one of the most devastating natural
disasters in Nigeria. The impact of flooding on human activities
cannot be overemphasized. It can threaten human lives, their
property, environment and the economy. Different techniques
exist to manage and analyze the impact of flooding. Some of these
techniques have not been effective in management of flood
disaster. Remote sensing technique presents itself as an effective
and efficient means of managing flood disaster. In this study,
SPOT-10 image was used to perform land cover/ land use
classification of the study area. Advanced Space borne Thermal
Emission and Reflection Radiometer (ASTER) image of 2010 was
used to generate the Digital Elevation Model (DEM). The image
focal statistics were generated using the Spatial Analyst/
Neighborhood/Focal Statistics Tool in ArcMap. The contour map
was produced using the Spatial Analyst/ Surface/ Contour Tools.
The DEM generated from the focal statistics was reclassified into
different risk levels based on variation of elevation values. The
depression in the DEM was filled and used to create the flow
direction map. The flow accumulation map was produced using
the flow direction data as input image. The stream network and
watershed were equally generated and the stream vectorized. The
reclassified DEM, stream network and vectorized land cover
classes were integrated and used to analyze the impact of flood on
the classes. The result shows that 27.86% of the area studied will
be affected at very high risk flood level, 35.63% at high risk,
17.90% at moderate risk, 10.72% at low risk, and 7.89% at no
risk flood level. Built up area class will be mostly affected at very
high risk flood level while farmland will be affected at high risk
flood level. Oshoro, Imhekpeme, and Weppa communities will be
affected at very high risk flood inundation while Ivighe, Uneme,
Igoide and Iviari communities will be at risk at high risk flood
inundation level. It is recommended among others that buildings
that fall within the “Very High Risk” area should be identified
and occupants possibly relocated to other areas such as the “No
Risk” area.
Without water, humans cannot live. Since time began,
we have lived by the water and vast tracts of waterless land have
been abandoned as it is too difficult to inhabit. At any given
moment, the earth’s atmosphere contains 4,000 cubic miles of
water, which is just 0.000012% of the 344 million cubic miles of
water on earth. Nature maintains this ratio via evaporation and
condensation, irrespective of the activities of man.
There is a certain need for an alternative to solve the water
scarcity. Obtaining water from the atmosphere is nothing new -
since the beginning of time, nature’s continuous hydrologic cycle
of evaporation and condensation in the form of rain or snow has
been the sole source and means of regenerating wholesome water
for all forms of life on earth.
An effective method to generate water is by the separation of
moisture present in air by condensation. In this study, the water
present in air is condensed on the surface of a container and then
collected in an external jacket provided on the container.
Insulations are provided to optimize the inner temperature of the
container.
The method is although uncommon but has certain advantages
which make it a success. The process is economical and does not
require a lot of utilities. It also helps in further reducing the
carbon footprint.
In every moment of functioning the Li-Ion
battery must provide the power required by the user, to have a
long operating life and to and to provide high reliability in
operation. The methods for analysis and testing batteries are
ensuring that all these conditions imposed to the batteries are
met by being tested depending on their intended use.
The success rate of real estate project is
decreasing as there is large scale of project and participation of
entities. It is necessary to study the risk factors involved in the
project. This paper focused on types of risks involved in the
project, risk factors, risk management tools & techniques.
Identification of risk of the project in terms of the total cost of the
project has been divided under Technical, Financial, Sociopolitical
and Statutory cost centers. Large real estate projects
have to tackle the following issues: land acquisition, skilledlabour
shortage, non-availability of skilled project managers, and
mechanization of the construction process to cater to the growing
demands. Non- availability of supporting infrastructure, political
issues like instability of the government leading to regulatory
issues, social issues, marketing forms an important part in these
projects as this is a onetime investment and the purchase cycle is
long , long development period makes the same project be at
different points in the real estate value cycle.
- In the present scenario carbon emission and sand
mining are major concern due to its hazardous effect to
environment and making serious imbalance to the ecosystem.
Various studies have been conducted to reduce severe effect on
environment, using byproducts like copper slag as partial
replacement of fine aggregate. Different researchers have also
revealed numerous uses of copper slag as a replacing agent in
determining the strength of concrete. A comprehensive review of
studies has been presented in this paper for scope of replacement
of fine aggregate from copper slag in concrete
- Security is a concept similar to being cautious
or alert against any danger. Network security is the condition of
being protected against any danger or loss. Thus safety plays a
important role in bank transactions where disclosure of any data
results in big loss. We can define networking as the combination
of two or more computers for the purpose of resource sharing.
Resources here include files, database, emails etc. It is the
protection of these resources from unauthorized users that
brought the development of network security. It is a measure
incorporated to protect data during their transmission and also
to ensure the transmitted is protected and authentic.
Security of online bank transactions here has been
improved by increasing the number of bits while establishing the
SSL connection as well as in RSA asymmetric key encryption
along with SHA1 used for digital signature to authenticate the
user
Background: Septoplasty is a common surgical
procedure performed by otolaryngologists for the correction of
deviated nasal septum. This surgery may be associated with
numerous complications. To minimize these complications,
otolaryngologists frequently pack both nasal cavities with
different types of nasal packing. Despite all its advantages,
nasal packing is also associated with some disadvantages. To
avoid these issues, many surgeons use suturing techniques to
obviate the need for packing after surgery.
Objective: To determine the efficacy and safety of trans-septal
suture technique in preventing complications and decreasing
morbidity after septoplasty in comparison with nasal packing.
Patients and methods: Prospective comparative study. This
study was conducted in the department of Otolaryngology -
Head and Neck Surgery, Rizgary Teaching Hospital - Erbil,
from the 6th of May 2014 to the 30th of November 2014.
A total of 60 patients aged 18-45 years, undergoing septoplasty,
were included in the study. Before surgery, patients were
randomly divided into two equal groups. Group (A) with transseptal
suture technique was compared with group (B) in which
nasal packing with Merocel was done. Postoperative morbidity
in terms of pain, bleeding, postnasal drip, sleep disturbance,
dysphagia, headache and epiphora along with postoperative
complications including septal hematoma, septal perforation,
crustation and synechiae formation were assessed over a follow
up period of four weeks.
Results: Out of 60 patients, 37 patients were males (61.7%)
and 23 patients were females (38.3%). Patients with nasal
packing had significantly more postoperative pain (P<0.05)><0.05). There was no significant difference between
the two groups with respect to nasal bleeding, septal
hematoma, septal perforation, crustation and synechiae
formation.
Conclusion: Septoplasty can be safely performed using transseptal
suturing technique without nasal packing.
The basic reason behind the need to
monitor water quality is to verify whether the examined
water quality is suitable for intended usage or not. This
study is conducted on Al -Shamiya al- sharqi drain in
Diwaniya city in Iraq to make valid assessment for the
level of parameters measured and to realize their effects
on irrigation. In order to assess the drainage water
quality for irrigation purposes with a high accuracy, the
Irrigation Water Quality Index (IWQI) will be examined
and upgraded (integrated with GIS) to make a
classification for drainage water. For this purpose, ten
samples of drainage water were taken from different ten
location of the stuay area. The collected samples were
analyzed chemically for different elements which affect
water quality for irrigation.These elements are :
Calcium(Ca+2), Sodium(Na+
), Magnesium(Mg+2),
Chloride( ), Potassium(K+
), Bicarbonate(HCO3),
Nitrate(NO3), Sulfate( , Phosphate( , Electrical
Conductivity(EC), Total Dissolved Solids (TDS), Total
Suspended Solids (TSS) and pH-values (PH). Sodium
Adsorption Ratio (SAR) and Sodium Content (Na%)
have been also calculated. Results suggest that, the use of
GIS and Water Quality Index (WQI) methods could
provide an extremely interesting as well as efficient tool
to water resource management. The results analysis of
(IWQI) maps confirms that: 52% of the drainage water
in study area falls within the "Low restriction" (LR) and
47%of study area has water with (Moderate
restriction)(MR),While 1% of drainage water in the
study area classified as (Sever restriction) (SR). So, the
drainage water should be used with the soil having high
permeability with some constraints imposed on types of
plant for specified tolerance of salts
The cable-hoisting method and rail cable-lifting
method are widely used in the construction of suspension bridge.
This paper takes a suspension bridge in Hunan as an example,
and expounds the two construction methods, and analyzes their
respective merits and disadvantages.
Baylis-Hillman reaction has been achieved on
different organic motifs but with completion times of three to
six days. Micellar medium of CTAB in water along with the
organic base DABCO has been used to effect the BaylisHillman
reaction on a steroidal nucleus of Withaferin-A for the
first time with different aromatic aldehydes within a day to
synthesize a library of BH adducts (W1a –W14a) and (W1bW14b)
as a mixture of two isomers and W15 as a single
compound. The isomers were separated on column and the
major components were chosen for bio-evaluation. Cytotoxic
activity of the synthesized compounds was screened against a
panel of four cancer cell lines Lung A-549, Breast MCF-7,
Colon HCT-116 and Leukemia THP-1 along with 5-florouracil
and Mitomycin-C as references. All the compounds exhibited
promising activity against screened cell lines and were found to
possess enhaunced activity than parent compound. BH adducts
with aromatic systems having methoxy and nitro groups were
found to be more active.
This paper presents the details on the
experimental investigation carried out to get the desired fresh
properties of the SCC. Tests were performed on various mixtures
to obtain the required SCC. In the present research work we
have replaced 15% of cement with class F fly ash. By varying the
quantity of water and sand the mortar mix was prepared. Later
varying percentage of coarse aggregate was added to the mortar
to obtain the desired SCC.
The batteries used in electric and hybrid vehicles
consists of several cells with voltages between 3.6V battery and
4.2 V in series or parallel combinations of configurations for
obtaining the necessary available voltages in the operation of a
hybrid electric vehicle. How malfunction of a single cell affects
the behavior of the entire battery pack, BMS main function is to
protect individual cells against over-discharge, overload or
overheating. This is done by correct balancing of the cells. In
addition BMS estimates the battery charge status
This project aims at using (PD-MCPWM) Phase
disposition multi carrier pulse width modulation technique to
reduce leakage current in a transformerless cascaded multilevel
inverter for PV systems. Advantages of transformerless PV
inverter topology is as follows, simple structure, low weight and
provides higher efficiency , but however this topology provides a
path for the leakage current to flow through the parasitic
capacitance formed between the PV module and the ground.
Modulation technique reduces leakage current with an added
advantage without adding any extra components.
More from International Journal of Technical Research & Application (20)
Courier management system project report.pdfKamal Acharya
It is now-a-days very important for the people to send or receive articles like imported furniture, electronic items, gifts, business goods and the like. People depend vastly on different transport systems which mostly use the manual way of receiving and delivering the articles. There is no way to track the articles till they are received and there is no way to let the customer know what happened in transit, once he booked some articles. In such a situation, we need a system which completely computerizes the cargo activities including time to time tracking of the articles sent. This need is fulfilled by Courier Management System software which is online software for the cargo management people that enables them to receive the goods from a source and send them to a required destination and track their status from time to time.
Vaccine management system project report documentation..pdfKamal Acharya
The Division of Vaccine and Immunization is facing increasing difficulty monitoring vaccines and other commodities distribution once they have been distributed from the national stores. With the introduction of new vaccines, more challenges have been anticipated with this additions posing serious threat to the already over strained vaccine supply chain system in Kenya.
Quality defects in TMT Bars, Possible causes and Potential Solutions.PrashantGoswami42
Maintaining high-quality standards in the production of TMT bars is crucial for ensuring structural integrity in construction. Addressing common defects through careful monitoring, standardized processes, and advanced technology can significantly improve the quality of TMT bars. Continuous training and adherence to quality control measures will also play a pivotal role in minimizing these defects.
Automobile Management System Project Report.pdfKamal Acharya
The proposed project is developed to manage the automobile in the automobile dealer company. The main module in this project is login, automobile management, customer management, sales, complaints and reports. The first module is the login. The automobile showroom owner should login to the project for usage. The username and password are verified and if it is correct, next form opens. If the username and password are not correct, it shows the error message.
When a customer search for a automobile, if the automobile is available, they will be taken to a page that shows the details of the automobile including automobile name, automobile ID, quantity, price etc. “Automobile Management System” is useful for maintaining automobiles, customers effectively and hence helps for establishing good relation between customer and automobile organization. It contains various customized modules for effectively maintaining automobiles and stock information accurately and safely.
When the automobile is sold to the customer, stock will be reduced automatically. When a new purchase is made, stock will be increased automatically. While selecting automobiles for sale, the proposed software will automatically check for total number of available stock of that particular item, if the total stock of that particular item is less than 5, software will notify the user to purchase the particular item.
Also when the user tries to sale items which are not in stock, the system will prompt the user that the stock is not enough. Customers of this system can search for a automobile; can purchase a automobile easily by selecting fast. On the other hand the stock of automobiles can be maintained perfectly by the automobile shop manager overcoming the drawbacks of existing system.
Final project report on grocery store management system..pdfKamal Acharya
In today’s fast-changing business environment, it’s extremely important to be able to respond to client needs in the most effective and timely manner. If your customers wish to see your business online and have instant access to your products or services.
Online Grocery Store is an e-commerce website, which retails various grocery products. This project allows viewing various products available enables registered users to purchase desired products instantly using Paytm, UPI payment processor (Instant Pay) and also can place order by using Cash on Delivery (Pay Later) option. This project provides an easy access to Administrators and Managers to view orders placed using Pay Later and Instant Pay options.
In order to develop an e-commerce website, a number of Technologies must be studied and understood. These include multi-tiered architecture, server and client-side scripting techniques, implementation technologies, programming language (such as PHP, HTML, CSS, JavaScript) and MySQL relational databases. This is a project with the objective to develop a basic website where a consumer is provided with a shopping cart website and also to know about the technologies used to develop such a website.
This document will discuss each of the underlying technologies to create and implement an e- commerce website.
Hybrid optimization of pumped hydro system and solar- Engr. Abdul-Azeez.pdffxintegritypublishin
Advancements in technology unveil a myriad of electrical and electronic breakthroughs geared towards efficiently harnessing limited resources to meet human energy demands. The optimization of hybrid solar PV panels and pumped hydro energy supply systems plays a pivotal role in utilizing natural resources effectively. This initiative not only benefits humanity but also fosters environmental sustainability. The study investigated the design optimization of these hybrid systems, focusing on understanding solar radiation patterns, identifying geographical influences on solar radiation, formulating a mathematical model for system optimization, and determining the optimal configuration of PV panels and pumped hydro storage. Through a comparative analysis approach and eight weeks of data collection, the study addressed key research questions related to solar radiation patterns and optimal system design. The findings highlighted regions with heightened solar radiation levels, showcasing substantial potential for power generation and emphasizing the system's efficiency. Optimizing system design significantly boosted power generation, promoted renewable energy utilization, and enhanced energy storage capacity. The study underscored the benefits of optimizing hybrid solar PV panels and pumped hydro energy supply systems for sustainable energy usage. Optimizing the design of solar PV panels and pumped hydro energy supply systems as examined across diverse climatic conditions in a developing country, not only enhances power generation but also improves the integration of renewable energy sources and boosts energy storage capacities, particularly beneficial for less economically prosperous regions. Additionally, the study provides valuable insights for advancing energy research in economically viable areas. Recommendations included conducting site-specific assessments, utilizing advanced modeling tools, implementing regular maintenance protocols, and enhancing communication among system components.
Event Management System Vb Net Project Report.pdfKamal Acharya
In present era, the scopes of information technology growing with a very fast .We do not see any are untouched from this industry. The scope of information technology has become wider includes: Business and industry. Household Business, Communication, Education, Entertainment, Science, Medicine, Engineering, Distance Learning, Weather Forecasting. Carrier Searching and so on.
My project named “Event Management System” is software that store and maintained all events coordinated in college. It also helpful to print related reports. My project will help to record the events coordinated by faculties with their Name, Event subject, date & details in an efficient & effective ways.
In my system we have to make a system by which a user can record all events coordinated by a particular faculty. In our proposed system some more featured are added which differs it from the existing system such as security.
Water scarcity is the lack of fresh water resources to meet the standard water demand. There are two type of water scarcity. One is physical. The other is economic water scarcity.
Saudi Arabia stands as a titan in the global energy landscape, renowned for its abundant oil and gas resources. It's the largest exporter of petroleum and holds some of the world's most significant reserves. Let's delve into the top 10 oil and gas projects shaping Saudi Arabia's energy future in 2024.
About
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
• Remote control: Parallel or serial interface.
• Compatible with MAFI CCR system.
• Compatible with IDM8000 CCR.
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
• Easy in configuration using DIP switches.
Technical Specifications
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
Key Features
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
• Remote control: Parallel or serial interface
• Compatible with MAFI CCR system
• Copatiable with IDM8000 CCR
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
Application
• Remote control: Parallel or serial interface.
• Compatible with MAFI CCR system.
• Compatible with IDM8000 CCR.
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
• Easy in configuration using DIP switches.
EQUILIBRIUM, KINETIC AND THERMODYNAMIC STUDIES ON BASIC DYE ADSORPTION USING COMPOSITE ACTIVATED CARBON
1. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
96 | P a g e
EQUILIBRIUM, KINETIC AND
THERMODYNAMIC STUDIES ON BASIC DYE
ADSORPTION USING COMPOSITE ACTIVATED
CARBON
Ejikeme, P.C.N., Ejikeme, Ebere M., Okonkwo, Gloria N.
Chemical Engineering Department,
Enugu State University of Science and Technology Enugu,
Enugu State Nigeria.
Abstract— Batch adsorption experiments were carried out for
the adsorption of cationic dye from aqueous solution onto
composite activated carbon. The composite activated carbon was
prepared from brewer’s spent grain and sea bean shell at a ratio
of 1:1. The equilibrium studies were done at different
concentrations and temperatures. The equilibrium data were
fitted to Langmuir, Freundlich, Dubinin-Radushkevich, and
Temkin isotherm models. The results showed that both Lagmuir
and Freundlich isotherm model fitted the data reasonably well
but Freundlich isotherm fitted better in the temperature range
studied. This confirmed that the adsorption is heterogeneous,
non-specific and non-uniform in nature. Kinetic studies were also
undertaken in terms of first order, second order, pseudo first
order, pseudo second order, Elovich, Boyd, and intra-particle
diffusion models. The results indicated that the data followed
pseudo second order model with surface adsorption and intra-
particle diffusion concurrently operating during the adsorbate-
adsorbent interaction. The values of the thermodynamic
parameters computed from Van’t Hoff plot confirmed the
process to be endothermic and spontaneous in nature.
Key words— Activated carbon, basic dye, brewer’s spent grain,
sea bean shell.
I. INTRODUCTION
Several Industries generate wastewaters such as textile,
chemical, refineries, plastics, and food processing plants. These
wastewaters include residual dyes which are not bio-
degradable. It is estimated that more than 100,000
commercially available dyes with over 7 x 105 tonnes of dye
stuff produced annually [1], [2], [3]. These residual dyes, when
discharged into the environment, will become a serious threat.
Generally, many dyes can be used in textile industry, like basic
dyes, acid dyes, direct dyes, azo dyes, mordent dyes, vat dyes,
disperse dyes, and sulphur dyes [4], [5]. Methylene blue (MB)
is a basic dye heavily used in the textile industry [5].
Some specific effluents from industrial production
processes may be difficult to purify by traditional wastewater
treatment technology, as a result of the complexity of some of
their components [6]. Many methods are used to remove dyes
from wastewaters such as coagulation, membrane separation
process, electrochemical, chemical oxidation, reverse osmosis,
aerobic and anaerobic microbial degradation. These methods
have restrictions, and therefore, are not successful for removing
the color completely from wastewater [5], [7]. Among all these
methods, adsorption is preferred due to its low cost and high
treatment efficiency [8]
Activated carbon is the main adsorbent used in adsorption
processes. The adsorption capacity of the activated carbon and
also the performance of the activated carbon adsorption system
are usually predicted from equilibrium sorption isotherm [9].
An adsorption isotherm is an invaluable curve describing the
phenomenon governing the retention (or release) or mobility of
a substance from the aqueous porous media or aquatic
environments to a solid phase at a constant temperature and pH
[10], [11], [12]. Experimental data were fitted into different
isotherm models like; Langmuir, Freundlich, Dubinin-
Raushkevich and Temkin isotherm models.
The study of sorption kinetics in wastewater treatment is
significant as it provides valuable insights into the reaction
pathways and mechanisms of sorption reaction. Kinetics
describe the solute uptake rate that controls the residence time
of the sorbate uptake at the solid-solution interface, and are
important because to design appropriate sorption treatment
plants, the rate at which any pollutant is removed from aqueous
solution must be predicted [13]. In this work, experimental
data were fitted to first order, second order, pseudo first order,
pseudo second order, Elovich Boyd and intra- particle diffusion
models.
II. MATERIALS AND METHODS
A. Preparation of Activated Carbon
The spent grain used as one of the precursors was brought
from Nigeria breweries Ninth Mile Enugu. It was collected
immediately after use as a fresh spent grain. It was dried for 7
days under the sunlight to reduce the moisture content of the
grain and after which it was packed until use. The hamburger
seed shell was collected as a waste from Abakpa market,
Enugu, Enugu state Nigeria.
B. Adsorbate
Methylene Blue (MB) (C1. 52015) with empirical formular
C16H18N3SC1 and formular weight of 319.9g/mol was
supplied by De Cliff Integrated Ltd Ogbete Enugu, Enugu State
Nigeria (97% purity). It has maximum absorbance at
wavelength 661nm.
C. Preparation of Activated Carbon
The dried hamburger seed shell and spent grain were
crushed to desired mesh size (1–2 mm) and then carbonized at
800oC for 2 hrs in a stainless steel vertical tabular reactor
placed in a tube furnace. The char produced was crushed and
sieved with 600μm sieve size. The char were soaked in 9M
KOH solution with (1.1.5) char to KOH ratio. The mixture
was then dehydrated in an oven at 105oC to remove moisture
and then was activated under the same condition as
carbonization, but to a different final temperature of 850oC for
1 hr. The activated products were then cooled to room
2. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
97 | P a g e
temperature and washed with hot deionized water and 0.1NHcl
until pH of the washing solutions reached 6-7.
D. Adsorption Kinetic Model
The kinetic experiments were performed using a procedure
similar to the equilibrium studies. 50mls of known
concentration of MB was mixed with 0.02g of the adsorbent in
a flask. Then, the flask was agitated in a shaker incubator for a
contact time varied in the range 0- 240mins at a speed of
200rpm under room temperature. The adsorbent was separated
from the solution by centrifugation and the filtrate was
analyzed by the same procedure as batch equilibrium studies.
The amount of MB adsorbed at each time interval per unit mass
of the adsorbent, qt (mg/g), was calculated by equation 1:
(1)
Where Co (mg/L) is initial MB solution, Ct (mg/L) is its
concentration at time t, V (L) is the volume of the solution and
W (g) is the mass of the adsorbent.
The kinetics of methylene blue adsorption was analysed
using pseudo-first order model, pseudo-second order model,
and intra particle diffusion model.
E. Adsorption Isotherm
Batch isotherm studies were carried out in 250ml conical
flask at different temperature of 303K, 313K, 323K, 343K on
an Isothermal shaker for 6 hours to ensure equilibrium. 0.02g
of the adsorbent was mixed with 50ml of 30mg/l, 50mg/l,
80mg/l and 110mg/l of the solution at different pH of 4, 8 and
10. The pH was adjusted using 0.1M Hcl or 0.1M NaOH before
addition of the adsorbent. At the end of equilibrium time of 6
hours, the reaction mixture was centrifuged and the residual
MB concentration analysed. The amount of MB adsorbent at
equilibrium qe(mg/g) was calculated from the following
equation (2).
(2)
F. Adsorption Kinetic Model
The adsorption kinetic produces valuable information about
the reaction pathways and mechanism of the reactions. The
kinetic of methyleene blue adsorption was analysed using first
order model, pseudo-first order model, second order model,
pseudo-second order model, intra particle diffusion model,
Elovich model and Boyd model.
1) First order Model
The adsorption kinetics can be described by a simple first
order equation below:
Linearization gives
Where Cat (mg/l) is the concentration of MB at time t, Cao
(mg/l) is the initial concentration of MB. Ki is the rate constant
of first order adsorption (h – 1) and t is the time gives in
minutes. A plot of log Cat versus t gives slope of and
intercept of LogCAo.
2) Pseudo First Order Model
The pseudo first order equation is generally expressed as:
Integrating and rearranging gives:
Where qe and qt are the amount of MB adsorbed (mg/g) at
equilibrium and at time t, respectively and Kpi is the rate
constant of pseudo-first order adsorption (min-1). A straight
lines will be obtained by plotting against t. the
values of the rate constant KI and qe were obtained from the
slopes and intercepts of the plot
3) Second order Model
The typical second order model equation is given as:
For the boundary condition of and
Integrating and rearranging gives
Where CAO and Cat are the initial concentration of MB
(Mg/l) and concentration at time t1 respectively. K2 is the rate
constant of the second order (min-1). A plot of
gives K2 and as slope and intercept respectively.
4) Pseudo Second order Equation
The pseudo second order adsorption kinetic rate equation is
expressed as:
Integrating for the boundary conditions
Which can be rearranged as follows:
and (10)
Where Kp2 is the rate constant of the pseudo second
equation (1/min) qe and qt are the sorption capacity at
equilibrium and time t (mg/l). h is the initial sorption rate. A
plot of t/qt versus (t) gives 1/qe and as slope and
intercept.
5) Intra Particle Diffusion Model
Weber-Morris found out that in many adsorption cases,
solute uptake varies almost proportionally with t½ rather than
with the contact time, t. the model is expressed as:
Where Kid is the intra particle diffusion rate constant
(mg/gh½). Plotting qt versus t ½ will give slope of kid and
intercept C (mg/g). Value of C gives the idea about the
thickness of boundary layer ie the larger the intercept, the
greater the contribution of the surface sorption in the rate
controlling step.
6) Elovich Model
The Elovich equation has been successfully applied to
represent chemisorptions processes and at low adsorption rate.
The equation is as follows:
(11)
Integrating with suitable boundary conditions gives:
Where x is the initial sorption rate constant (mg/gml), and
parameter β is related to the extent of the surface coverage and
3. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
98 | P a g e
to the activation energy of chemisorptions (g/mg). The constant
can be obtained from the plot of qt versus Lnt as the slope and
the intercept. The correlation coefficients were better but still
lower than that of pseudo second order model.
7) Boyd Model
In order to determine the actual rate controlling step
involved in sorption process, Boyd model is used which is as
follows:
Where F is the fractional attainment of equilibrium at time
t, and is obtained by the expression: where
qt(mg/g) is the amount of sorbate taken up at time t, and qe
(mg/g) is the maximum equilibrium uptake and
is time constant (min-1) of the sorbent particle (cm),
assumed to be spherical and m is an integer that defined the
finite solution hence, is given by the equation
Thus, the value of can be computed for each value of F1
and then plotted against time, t.
G. Adsorption isotherm Models
Adsorption isotherm equations are models describe
experimental sorption data. It helps to understand the nature of
the interaction between the adsorbate and adsorbent used for
the adsorption. An adsorption isotherm describes the
relationship between the amount of adsorbate uptaken by the
adsorbent and the adsorbate concentration remained in the
solution [14], [15]. The equation parameter and the underlying
thermodynamic assumptions of these equilibrium models often
provide some insight into the adsorption mechanism, the
surface properties of an adsorbent and affinity of the adsobate
for an adsorbate [16], [15], [17], [18]. In this study, the
experimental results were fitted to langmuir, freudlich, Temken
Dubinin – Radush Kevich Isotherms.
1) Langmuir Isotherm
The Langmuir adsorption isotherm describes quantitatively
the build-up of a layer of molecules on an adsorbent surface as
a function of the concentration of the adsorbed material in the
liquid in which it is in contact [19]. This isotherm is based on
the assumption that the adsorption process takes place at
specific homogenous sites within the adsorbent surface and that
once a dye molecule occupies a site, no further adsorption can
take place at that site which concluded that the adsorption
process is monolayer in nature [18]. The isotherm can be
written as:
The linear form of the isotherm is given as:
(16)
Where qe is the amount of adsorbate adsorbed per gram of
the adsorbent (mg/g), CAe is the concentration of adsorbate in
liquid equilibrium, (mg/l). the constant KL and qo relate to
energy of adsorption and maximum adsorption capacity
respectively. KL is a measure of heat of adsorption utilized to
calculate dimensionless separation parameter KL qo is in mg/g.
To determine if the adsorption process is favourable or
unfavourable, for the Langmuir type adsorption process, the
isotherm shape can be classified by a term “RL” a
dimensionless constant separation factor which is defined as
below [20].
(17)
Where KL(L/mg) is the Langmuir constant and Cao is the
lowest initial solute concentration (mg/l). a plot of Cao / qe
versus CAe from the linear relationship of the model will give
and 1/qo as intercept and slope respectively.
2) Freundlich Isotherm
The Freundlich Isotherm equation is based on the
assumption that the adsorbent has a heterogeneous surface
composed of different classes of adsorption site [21]. This
isotherm does not predict any saturation of the sorbent by the
sorbate, indicating multilayer sorption of the surfaces [22]. The
Freundlich isotherm is expressed by the following equation.
(18)
A linear form of the freundlich can be obtained by taking
the logarithm to the above equation.
(19)
Where KF = freundlich constant. Where KF (mg/g) is the
constant related to the adsorption capacity. The value of 1/n
ranging between 0 and 1 is a measure of adsorption intensity or
surface heterogeneity, becoming more heterogenous as its
value gets closer to zero [23]. A plot of Logqe versus CAe will
give intercept as LogKF and slope as 1/n.
3) Temkin Isotherm Model
The heat of the adsorption and the adsorbate – adsorbate
interactions in a adsorption process were studied by Temkin
and Pyzhev [24], and its equation is given as follows:
(20)
Where T is the absolute temperature in K and R is the
universal gas constant 8.3143J/molk. The constant b is related
to the heat of adsorption qe(mg/g) and Ce(mg/l) and the
equilibrium concentration respectively. A and B are constants
related to adsorption capacity and intensity of adsorption. A
plot of qe versus Ince yields a slope of B and intercept of BlnA.
4) Dubinin – Raduschkevich (D – R)
Dubinin – Radushkevich model is similar to the Langmuir
model but does not assume a homogenous surface or constant
energy potential [21]. The D – R equation can be written as:
) (21)
Where is the Polanyi potential (J/mol) given by:
Linearizing it gives
Where qe is the amount of sorbate adsorbed at equilibrium
(mg/g), qmax is the theoretical saturation capacity (mg/g), BD
is a constant related to the adsorption capacity (mg2/l2). A plot
of Lng versus (RTLn(1 + 1/Ce) yields a straight line with a
slope of -2BD and intercept of Lnqmax. The value of BD can
be used to calculate the sorption mean free energy E (KJ/Mol).
-1/2
Taking the logarithm of the D – R equation, it becomes
(22)
A plot of Lnqe against gives slope of -2BD and intercept
of Lnqmax.
4. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
99 | P a g e
III. RESULTS AND DISCUSSION
KINETIC EQUATION pH KINETIC PARAMETERS R2
First Order Kinetics 2
4
6
8
10
K1 = -0.0046 (min-1
)
K1 = -0.0046 (min-1
)
K1 = -0.0069 (min-1
)
K1 = -0.0069(min-1
)
K1 = -0.0046 (min-1
)
0.796
0.739
0.797
0.887
0.796
Second order Model 2
4
6
8
10
K2 = 0
K2 = 0.003
K2 = 0.017
K2 = 0.039
K2 = 0.020
0.852
0.852
0.871
0.904
0.876
Intra – Particle Diffusion Model 2
4
6
8
10
Kid = 1.9267 (min-1
), C = 38.917
Kid = 0.5807 (min-1
), C = 65.187
Kid = 0.3089 (min-1
), C = 70.297
Kid = 0.0986 (min-1
), C = 73.352
Kid = 0.0919 (min-1
), C = 73.362
0.8365
0.7186
0.8198
0.8959
0.822
Elovch Model 2
4
6
8
10
= 0.108g/mg, α = 16.145mg/g.min
= 0.351g/mg, α = 2.992mg/g.min
= 0.693g/mg, α = 1.474mg/g.min
= 2.288g/mg, α = 0.439mg/g.min
= 2.273g/mg, α = 0.442mg/g.min
0.941
0.861
0.887
0.874
0.936
KINETIC EQUATION INTERCEPT R2
Boyd Model 2
4
6
8
10
-0.165
1.372
1.813
2.837
3.208
0.972
0.961
0.929
0.873
0.976
TABLE 1. KINETICS PARAMETERS
Pseudo First order Pseudo – Second order
pH Quexp(mg/g) Qualc(mg/g) K1(min-2)
R2
IKP2(min-1
) H Qe(mg/g) R2
2
4
6
8
10
64.549
72.687
74.3575
74.7223
74.5688
20.09
3.313
1.5922
0.5688
0.3515
0.0161
0.0092
0.0046
0.0023
0
0.767
0.364
0.132
0.030
0.006
KP2= 0.001
KP2= 0.005
KP3= 0.009
KP3= 0.024
KP3= 0.034
5.102
29.586
53.28
42.012
201.183
71.429
76.923
76.923
76.923
76.923
0.998
1.0
1.0
1.0
1.0
TABLE 2. KINETICS PARAMETERS
A. Kinetics models
The study of sorption kinetics in wastewater treatment is
significant as it provides valuable insights into the reaction
pathways and mechanisms of sorption reaction
1) First order kinetics
In order to determine the controlling mechanism of
adsorption process such as transfer and chemical reaction, the
first order kinetic model was used to test the experimental data.
The values of rate constant were calculated from the slopes of
the graphs plotted and they are presented in table (1). The low
correlation coefficient (R2) obtained at different pH values
showed poor agreement of the first order model with the
experimental data.
2) Pseudo-first order
The pseudo-first order parameters at different pH along side
with their correlation coefficients (R2) are shown in table (2).
The R2 values obtained were small at all the pH studied, and
the experimental qe values did not agree with the calculated
values obtained from the linear plots (table 2).
3) Second order model
The values of the correlation coefficients, were relatively
small compared to the pseudo second order meaning that the
model did not fit the experimental values well.
4) Pseudo second order
The values of qe and K were obtained from the slope and
intercept. The values of the rate constants, correlation
coefficients, the experimental and calculated values are shown
in table 2.
It can be seen that the correlation coefficients for the linear
plot of the pseudo second order increased from 0.988 to 1 as
the pH increased, which is higher than the correlation
coefficients of all other models studied. Also, there is a good
agreement between the experimental qe values and the
calculated qe values. This indicates that the adsorption kinetic
is better represented by the pseudo-second order model. The
high initial sorption rate, h, obtained showed that the adsorption
was rapid. The uptake of adsorbate by adsorbent has been
observed to occur in two stages: the first rapid and
quantitatively predominant and the second slower and
quantitatively insignificant [25], [26]. The rapid adsorption of
MB by this adsorbent is probably due to the abundant
availability of active sites on the biomass, and the perceived
porous and mesh structure of the adsorbent which provides
ready access and large surface area for the adsorption of MB
dye on the binding sites [27], [28].
5. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
100 | P a g e
Fig. 1. Kinetics plots
5) Intra particle diffusion
The intra particle diffusion model was proposed to identify
the adsorption mechanism and to predict the rate controlling
step. The intra particle diffusion model usually includes three
steps. The first portion is the external surface adsorption or
boundary layer diffusion. The second portion is the gradual
stage of adsorption which is the intra particle diffusion. If the
plot of qt versus t1/2 is linear and passed through the origin,
then the intraparticle diffusion is the rate-controlling step [29].
The third portion is the final equilibrium stage in which the
intra particle diffusion starts to slow down due to the extremely
low dye concentration left in the solution [28].
The plot shows that the linear plot did not pass through the
origin whichindicated that the intra particle diffusion was not
only the rate controlling step and the boundary layer diffusion
controlled the adsorption to some extent [48]. This deviation
may be due to the difference in mass transfer rate in the initial
and final stage of adsorption [29], [30].
The values of C and Kid are given in Table 1. The values of
the intercept C increased with an increase in pH, which showed
that boundary layer effect increased as pH increases.
The correlation coefficients for intraparticle diffusion were
lower than that for the pseudo second order kinetics which
showed that the present system may be followed by
intraparticle diffusion, but is not the only rate controlling step.
6) Boyd model
A linear plot of Bt against t, passing through the origin
implies that pore-diffusion controls the rate of mass transfer.
However, if the plot is non linear or linear but does not pass
through the origin film-diffusion or chemical reaction dominate
the adsorption rate [31], [32], [33].
Boyd model was used to investigate the contribution of film
resistance to the kinetics of MB sorption. The model assumes
that the main resistance to diffusion is the boundary layer
surrounding the adsorbent particle.
The latter seems to be the case in MB adsorption on the
composite adsorbent as shown in figure. However, it seems the
pore diffusion becomes more important at lower pH, as the
intercept approaches O with decrease in pH as indicated on
table (1). The correlation coefficient is equally reasonable, but
still, they are lower than that of pseudo second order model.
B. Isotherm models
An adsorption isotherm is an invaluable curve describing
the phenomenon governing the retention (or release) or
mobility of a substance from the aqueous porous media or
aquatic environments to a solid phase at a constant temperature
and pH .
1) Langmuir
The value of the separation factor (RL) indicates the nature
of adsorption process. RL values indicates the type to be
irreversible (RL = 0), favourable (0< RL <1), linear (RL = 1) or
unfavourable (RL > 1). The linear plot of ce/qe vs ce indicated
the applicability of Langmuir adsorption isotherm.
Consequently, suggested the formation of mono layer coverage
of the adsorbate on the surface of the adsorbent [34]. Langmuir
constants, qo and KL were calculated from the slopes and
intercepts are given in table 3 along with the correlation
coefficient (R2) and separation factor (RL). From the table, it is
clear that the KL values were higher at higher temperature,
which showed endothermic nature of MB adsorption. The
average values of RL for each of the temperature and pH used
6. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
101 | P a g e
were between 0 and 1, which indicated the favourable
adsorption of MB. This was in agreement with the work done
by Dalia Khalid et al on the batch adsorption of basic dye using
acid treated kenaf fiber [29], work done by Emad N. ElQada et
al in adsorption of methylene blue into activated carbon form
[35], I.A.W Tan et al on equilibrium and kinetic studies on
basic dye adsorption by oil palm fibre activated carbon [36] etc.
2) Freundlich isotherm
The values of Freundlich constants and correlation
coefficients (R2) are given in table 3. The values of Kf and n
changed with the rise in temperature. The value of n showed an
indication of the favourability of adsorption. Values of n larger
than 1, showed the favourable nature of the adsorbent [34],
[37], [38]. The value of n suggested that MB was favourably
adsorbed by the activated carbon prepared from Hamburger
seed shells. The correlation coefficients greater than 0.980
showed that the data fitted well with Freudlich equation was
statistically confirmed by giving greater R2 values closer to
unity (0.85 – 0.999). This implies that Freudlich model may
better describes an adsorption isotherm for the adsorbent. This
adsorptive behaviour indicates that the adsorption takes place
on a heterogeneous surface, which may be attributed to the
various active sites on the adsorbent [39]. This was in line with
the work done by Hui Deng et al on adsorption of methylene
blue in adsorbent materials produced from cotton stalk [40].
Fig. 2. Isotherm plots
3) Temkin isotherm
The linear isotherm constants and coefficients of
determination are presented in table 4. It shows that the
equilibrium binding constant (A) (l/mg) which corresponds to
the maximum binding energy increased with increase in
temperature and was maximum at pH of 10. The constant b
which is related to the heat of adsorption, equally increased
with increase in temperature. The results implied that the
affinity of the binding sites for MB increased with increase in
temperature. Examination of the data shows that the Tempkin
Isotherm is applicable to the MB adsorption onto hamburger
activated carbon judged by high correlation coefficient (R2
ranged from 0.915 to 0.985).
TEMPERATURE LANGMUIR CONSTANT FREUNDLICH CONSTANT
TEMP(K) qo(mg/g) KL(L/mg) RL R2 1
/n n KF R2
303 pH4 0
pH10 500
0
1.0
1.0
0.032
0.997
0.923
0.859
0.517
1.164
1.934
78.7
185.35
0.999
0.989
313 pH4 1000
pH10 500
0.25
2.0
0.118
0.016
0.701
0.950
0.765
0.501
1.307
1.938
164.8
198.6
0.987
0.994
323 pH4 500
pH10 500
1.0
2.0
0.032
0.016
0.933
0.980
0.652
0.516
1.534
1.980
193.2
221.8
0.997
0.990
333 pH4 500
pH10 500
1.0
2.0
0.032
0.016
0.991
0.967
0.608
0.505
1.645
1.996
213.8
251.2
0.985
0.997
TABLE 3: ISOTHERM CONSTANTS FOR MB ADSORPTION ON COMPOSITE ADSORBENT
TEMKIN CONSTANT DUBININ–RADUSHKEVICH CONSTANT
B A b R2
Qm(mg/g) BD E(KJ/mol) R2
303 pH4 126.5
pH10 76.23
1.8
13.6
19.9
33.0
0.976
0.924
421.6
333.6
5 x10-4
15 x 10-4
3.1..6
5.7.7
0.986
0.951
313 pH4 112.1
pH10 74.55
5.1
16.6
23.2
34.9
0.915
0.946
435.3
343.8
2.5 x 10-4
1.5 x 10-4
4.472
05.77
0.958
0.972
323 pH4 97.16
pH10 77.85
8.3
18.4
27.6
34.9
0.954
0.967
411.6
376.2
2 x 10-4
1.5 x 10-4
5.0.0
5.777
0.979
0.984
333 pH4 92.87
pH10 75.83
10.9
25.3
29.8
36.5
0.985
0.951
428.8
389.2
1.5 x 10-4
1 x 10-4
5.77
7.0.7
0.994
0.926
TABLE 4: THERMODYNAMIC PARAMETER FOR MB ADSORPTION AT PH4
7. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
102 | P a g e
Concentrations (mg/ls) ΔG(KJ/mol) Po
H(KJ/mol) S(Jmol-1
K-1
)
30o
C 40o
C 50o
C 60o
C
30mg/l -11.556 -13.410 -15.264 -17.118 44.621 0.1854
50mg/l -11.221 -12.844 -14.468 -16.092 37.978 0.1624
80mg/l -11.009 -12.538 -14.067 -15.596 35.318 0.1529
110mg/l -11.104 -12.283 -13.461 -14.640 24.618 0.1170
AT pH10
Concentrations (mg/ls) ΔG(KJ/mol) H(KJ/mol) S(Jmol-1
K-1
)
30o
C 40o
C 50o
C 60o
C
30mg/l -15.424 -16.464 -17.504 -18.544 16.088 0.104
50mg/l -13.642 -14.652 -15.662 -16.672 16.961 0.101
80mg/l -12.827 -13.947 -15.067 -16.187 21.109 0.112
110mg/l -12.395 -13.225 -14.055 -14.885 12.754 0.083
4) Dubinin-radushkevich model
The Langmuir Isotherm constants do not give any
information concerning the chemical or physical properties of
the sorption. But the calculated sorption mean free energy E,
from the D-R isotherm gives information about the chemical or
physical properties of the sorption [19]. The values of the mean
adsorption energy that is less than 8kj/mol, revealed that the
adsorption of MB was predominantly a physical process rather
than a chemical one [37], [41]. The correlation coefficient of
the isotherm showed that D-R equation represents a good fit of
the experimental data (Table 4).
Moreover, the maximum adsorption capacity qm obtained
using D-R isotherm for adsorption of MB is 435.3mg/g, which
is close to half of that obtained (1000mg/g) from Langmuir
isotherm model (Table 4).
C. Adsorption thermodynamics
The thermodynamic parameters of the adsorption process
were determined from the Van’t Hoff equation by plotting
lnKD versus 1/T for different temperature at 303,313, 323 and
333K as follows:
ΔGo = ΔH – TΔS (23)
LnKc = -ΔH/RT + ΔS/R (24)
Where Kc is the equilibrium constant, which is the ratio of
the equilibrium concentration of the dye ion on the adsorbent to
the equilibrium concentration of the dye ions in solution. R is
the universal gas constant (8.314J/kmol), T (k) is the absolute
temperature. ΔH represents the difference in binding energies
between the adsorbent and the adsorbate (solute) and between
the solvent and the solute.
The values of ΔSo
and ΔHo
were obtained from intercept
and slope respectively of plot of LnKc against I/T.
The negative values of ΔGo
(table 5) indicated the
feasibility of the process and the spontaneous nature of the
adsorption. The value of ΔGo
became more negative with
increasing temperature. This showed that increase in
temperature was favourable for the removal process. The
results also showed that both enthalpy and entropy values were
positive at different concentration, signifying that the
adsorption process was endothermic and the degree of
dispersion increased with increase in temperature. The
endothermic behaviour observed from enthalpy value further
confirmed the trend of adsorption of MB on the adsorbents
which were found to increase as temperature was increased.
The nature of the adsorption process was confirmed by the
magnitude of the ΔHo
values. It is accepted that if magnitude of
enthalpy change is less than 84Kj/mol, adsorption is physical,
however, chemisorptions takes place from 84 to 420Kj/mol.
The range of values of ΔHo
from table 5 showed that the nature
of adsorption is physical.
IV. CONCLUSION
The composite activated carbon used for this study was
prepared from brewer’s spent grain and sea bean shell at a ratio
of 1:1. The result of this study can be summarized as follows;
The developed composite activated carbon is a
promising adsorbent for removal of cationic dye from
solution.
The experimental data showed perfect fit with the
Freundlich isotherm, which confirm that the
adsorption process is heterogeneous, non- specific and
non-uniform in nature. Therefore, the mechanism of
adsorbate-adsorbent interaction is complicated
involving a wide range of sites differing in a number
of aspects including energy considerations.
The kinetic study was investigated using first order,
pseudo first order, second order, pseudo second order,
Elovich, Boyd and intra-particle diffusion models.
The result indicates that adsorption kinetics followed
the pseudo second order with the intra- particle
diffusion model as one of the rate limiting step.
The sorption process was found to be endothermic in
nature with negative value of the entropy.
The negative value of the Gibbs free energy and
positive value of the enthalpy suggested the
adsorption to occur by physical process.
V. ACKNOWLEDGEMENTS
The authors wish to thank PYMOTECH RESEARCH
CENTRE AND LABORATORIES ENUGU, ENUGU STATE
NIGERIA for all their facilities used throughout the research
work.
REFERENCES
[1] J. W. Lee, S. P. Choi, R. Thiruvenkata Chari, W. G. Shim, H.
Moon, Evaluation of the performance of adsorption and
coagulation processes for the maximum removal of reactive
dyes, dyes pigments 69 (2006), 196-203.
[2] I. A. W. Tan, A. L. Ahmad, B. H. Hameed. Optimization of
preparation conditions for activated carbons from coconut husk
using response surface methodology, Chemical Engineering
Jornal, 137 (2008) 462-470.
8. International Journal of Technical Research and Applications e-ISSN: 2320-8163,
www.ijtra.com Volume 2, Issue 4 (July-Aug 2014), PP. 96-103
103 | P a g e
[3] Emad N. ElQada, Stehen J. Allen, Gavin M. Walker. Adsorption
of methylene blue onto activated carbon produced from steam
activated bituminous coal. A study of equilibrium adsorption
isotherm. Chemical Eng. Journal 124 (2006) 103-110.
[4] A. Damirbas, Agricultural based activated carbons for the
removal of dyes from aqueous solutions: a review, J. Hazard
Mater., 167 (2009) 1-9
[5] Dalia Khalid Mahmoud, Mohamed Amran Mohd Salleh, Wan
Azlina Wan Abdul Karim, Azni Idris, Zurina Zainal Abidin,
Batch adsorption of basic dye using acid treated kenaf fiber char:
Equilibrium, Kinetics and thermodynamic studies. Chemical
Engineering Journal 181-182 (2012) 449-457.
[6] Emmanuel, I. Unuabonah, Gilbert U. Adie, Lora O. Onah,
Olalere G. Adeyemi. Multistage optimization of the adsorption
of methylene blue dye defatted carica papaya seeds. Chemical
Engineering Journal 155 (2009) 567-579.
[7] M. T. Sulak, E. Demorbas, M. Kobya, removal of Astrazon
yellow 7GL from aqueous solutions by adsorption onto wheat
bran, Bioresour. Technol. 98 (2007) 2590-2598.
[8] R. Qadeer, Adsorption behavior of ruthenium ions on activated
charcoal fron nitric acid medium, Colloids surf, A 293 (2007)
217-223.
[9] K. Vasanth Kumar, S. Sivenesan. Isotherm parameters for basic
dye onto activated carbon. Comparison of linear and non-linear
methods. Journal of Hazardous materials B 13 (129), PP. 147-
150.
[10] K. Y. Foo, B. H. Hameed. Insight into the modeling of
adsorption isotherm systems. Chemical Engineering Journal 156
(2010) 2-10.
[11] G. Limousin, J.P Gaudet, L.Charlet, S. Szenknect, V. Barthens,
M. Krimissa, Sorption Isotherm: a review on physical bases,
modeling and measurements. Appl. Geochem. 22(2007) 249-
275.
[12] S. J. Allen, G. Mckay, J. F. Porter, Adsorption isotherm models
for basic dye adsorption by peat in single and binary components
systems. J. Colloid interface Sci. 280 (2004) 322-333.
[13] Yuh-Shan Ho, Chun –Chiao, Chiang and Yung –Cheien Hsu.
Sorption kinetics for dye removal from aqueous solution using
activated clay. Separation science and Technology. 36 (11),
2473-2488 (2001)
[14] M.S. Chiou, H.Y.Li. Equilibrium and Kinetic Modeling of
Adsorption of Reactive Dye on Cross Linked Chitosan Beads, J.
Hazard Mater. 93, 2002, pp.233 -248.
[15] I. Langmur. Adsorption of Gases on Plane Surface of Glass,
Mica and Platinum, J. AM. Chem. Soc. 40, 1981, pp. 1361-
1403.
[16] I. Langmur, The Constitution and Fundamental Properties of
Solids and Liquids. J. AM-Chem-Soc 38, 1916, pp.2221 - 2295.
[17] O. Abdel Washab. Evaluation of the Use of Loofa Activated
carbon as Potential Adsorbents for Aqueous Solutions
Containing Dye, Desalination 222, 2008, pp.357-367.
[18] M. Ghaedi, B. Sadeghian, A. Amiri Pebdan, R. Sahraei, A.
Daneshfar and C. Duran. Kinetics, Thermodynamics and
Equilibrium Evaluation of Direct Yellow 12 Removal by
Adsorption onto Silver Nanopartarticles Loaded Activated
Carbon. Chemical Engineering Journal 187, 2012, pp.133-141.
[19] Naseen rauf, S.S. Tahir, Jung-Ho Kang, Yoo-Seok Chan.
Equilibrium, Thermodynamics and Kinetics Studies for the
Removal of Alpha and Beta Endosulfan by Adsorption onto
Bentonite Clay. Chemical Engineering Journal. 2012
[20] E. Malkoc, Y. Nuhoglu. Determination of kinetic and Equilirium
Parameters of the Batch Adsoprtion of Cr (VI) onto Waste
Acorn of Quercus Ithaburensis, Chemical Eng. Process. 46,
2007, pp.1020-1029.
[21] Agustin Marsal, Fernado Maldonado, Sara Cuadros, M. Elena
Bautista, Albert, M. Manich. Adsorption Isotherm,
Thermodynamics and Kinetic Studies of Poly phenols onto
Tannery Shavings. Chemical Eng. Journal, 183, 2012, pp.21 –
29.
[22] R. Donat, A. Akdogan, E. Erdem, H. Cetisli. Thermodynamics
of Pb (+2) and Ni(+2) Adsorption onto Natural Bentonite from
Aqueous Solutions. J. Colloid Interf. Sci. 286, 2005, pp.43 – 52.
[23] E. Zeynep, N.A. Filiz. Equilibrium and kinetic Mechanism for
Reactive Black 5 Sorption onto high Lime Soda Fly Ash. J.
hazard mater. 143, 2007, pp.226 – 232.
[24] M.J. Temken, V. Pyzhev. Recent Modification to Langmuir
Isotherms. Acta Physiochim USSR 12, 1940, pp.217-222.
[25] M. Auta, B.H. Hameed. Odified Mesoporous Clay Adsorbent for
Adsorption isotherm and Kinetics of methylene Blue. 198-199,
2012, pp.219-227.
[26] Y.T. Sag, Kutsal. Fully Competitive Biosorption of Chromium
(VI) and Iron (II) Ions from Binary Metal Mixtures by R.
Arrhizus: Use of the Competitive Langmuir Model, process
Biochern. 31, 1996, pp. 561-579.
[27] W.H. Cheung, Y.S. Szeto, G. Mckay. Intraparticle Diffusion
Processes During Acid Dye Adsorption onto Chitosan,
Bioresour. Technol. 98, 2007, pp.2897 – 2904.
[28] Dalia Khalid Maamoud, Mohaamad Amran Mohasalleh, Wan
Azlina Wari Abdul Karima, Azni Idris and Zurina Zainal
Abidin. Batch Adsorption of Basic Dye using Acid treated
Kenaf Fibre Char: Equilibrium, Kinetic and Thermodynamic
Studies. Chemical Engineering Journal 181, 2012, pp.449 – 457.
[29] B.H. Hameed, H. Hakimi. Utilization of Clurian (Durio
Zibethinus Murray) Peel as Low Cost Sorbent for the Removal
of Acid Dye from Aqueous Solutions. Biochem. Engineering
Journal 39, 2008, pp.338 – 343.
[30] Mehmet Ulas Dural, Levent Cakas, Sergios K. Papagergiou and
Fotis K. Katsaros. Methylene Blue Adsorption on Activated
Carbon Prepared from Posidonia Oceanica (L) Dead Leaves:
Kinetics and Equilibrium Studies. Chemical Engineering Journal
168, 2011, pp.77 – 85.
[31] G.E. Boyd, A.W. Adamsum, L.S. Myers Jr. The Exchange
Adsorption of Ions from Aqueous Solutions by organic Zeolites
(II) Kintics. J. AM. Chem. Soc. 67, 1947, pp.2836 – 2848.
[32] D. Reichenberg. Properties of Ion Exchange Resins in Relations
to their Structure III. Kinetics of Exchange, J. AM. Chem. SOC.
75, 1953, pp.589 – 598.
[33] Z.A. Al-Othman, R. Ali and Mu. Navshat. Hexa Valent
Chroimium Removal from Aqeuous medium by Activated
carbon Prepared from peanut Shell: Adsorption Kinetics,
Equilibrium and Thermodynamic Studies. Chemical Engineering
Journal 184, 2012, pp.238 – 247.
[34] Emad N. El Qada, Stephen J. Allen, Gavin, M. Walker.
Adsorption of Methylene Blue unto Activated Carbon Produced
from Steam Activated Bituminous Coal: A Study of Equilirium
Adsorption Isotherm. Chemical Engineering Journal 124, 2006,
pp. 103 – 110.
[35] I.A.W. Tan, B.H. Hameed and A.L. Ahmed. Equilibrium and
Kinetic Studies on basic Dye Adsorption by Oil Palm Fibre
Activated carbon. Chemical Engineering Journal 127, 2007, pp.
111-119.
[36] N. Daneshur, D. Salari, S. Aber. Chromium Adsorption and
Cr(V) Reduction to Tribalent Chromium in Aqueous Solutions
by Soya Cake. J. Hazard Mater, 94, 2002, pp.49 – 61.
[37] P.K. Malik. Dye Removal from Wastewater Using Activated
Carbon Developed from Sawdust: Adsorption Equilibrium and
Kinetics. J. Hazard, mater, 113, 2004, pp.81 – 88.
[38] Vipasiri Vimonses, Shaomin Lei, Bo Jin, Chris W.K. Chow and
Chris Sant. Kinetic Study and Equilibrium Isotherm Analysis of
Congo Red Adsorption by Clay Materials. Chemical
Engineering Journal 148, 2009, pp. 354 – 364.
[39] Hui Deng, Jianjang, Lu, Guoxue LI, Genli Zhang and Xugen
Wang. Adsorption of Methylene Blue on Adsorbent Materials
produced from Cotton Stalk. Chemical Engineering Journal 172,
2011, pp. 326-334.
A.H. Chen, S.M. Chen. Biosorption of Azo Dyes from Aqueous
Solution by Glutaraldehyde Cross linked Chitosans, J. Hazard
Mater 172, 2009, pp.1111 – 1121.