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Dalton’s Law of Partial Pressure Dalton’s Law of partial pressure : The total pressure of a mixture of non-reacting gases in a system is the sum of their partial pressure. P Total  = P 1  + P 2  + P 3  +P 4  + …….+P n Partial pressure of a component : The pressure that would be exert if it were present alone and occupied the same volume as in the mixture. If a container with a volume of V, having three type of gases X, Y, Z will exert partial pressure of P x  , P y  , P z  on the wall.
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A mixture of gases at 800 torr contain 20% nitrogen, 10% hydrogen, 50% oxygen and 20% CO 2  by volume. What is partial pressure of each gas in torr ? (Assume that the total volume of  the mixture is 100 dm 3 .)  ,[object Object],Ouestion 1
The Molecular Behavior of Gases ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Relationship of the Gas laws to the Kinetic Molecular Theory of Gases ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
Maxwell-Boltzmann Distribution ,[object Object],[object Object]
[object Object],[object Object],Important features of Maxwell-Boltzmann distribution :
Real Gases – Deviation from Ideality ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Deviation from ideal Behavior ,[object Object],[object Object],PV/RT 1.0 P N 2 O 2 H 2 Ideal   gas NH 3 For ideal gas = PV/RT = n = 1 (dotted line).
[object Object],[object Object],[object Object]
Van der Waals equation ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Ouestion 2 ,[object Object],[object Object],[object Object],[object Object]

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Dalton’S Law Of Partial Pressure

  • 1. Dalton’s Law of Partial Pressure Dalton’s Law of partial pressure : The total pressure of a mixture of non-reacting gases in a system is the sum of their partial pressure. P Total = P 1 + P 2 + P 3 +P 4 + …….+P n Partial pressure of a component : The pressure that would be exert if it were present alone and occupied the same volume as in the mixture. If a container with a volume of V, having three type of gases X, Y, Z will exert partial pressure of P x , P y , P z on the wall.
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