1
CONTENTS
 Introduction
 Principle of Phosphorescence
 Mechanism
 Applications of Phosphorescence-
-Lightning -Phosphor Thermometry
-Glow in dark toys -Luminescence
-White LEDs -Electroluminescence
 Conclusion
 References
2
Introduction
 A phosphor, most generally is a substance that exhibits
the phenomenon of luminescence.
 Phosphors are commonly transition metal compounds
or rare earths.
 But the element Phosphorus named for its light
emitting behaviour due to chemiluminescence not due
to phosphorescence.
 Common pigments used in phosphorescent materials
include Zinc Sulphide and Strontium aluminate.
3
 Objects coated with phosphors that absorb UV light
resulting in the emission of visible light over an
extended period of time.
 Phosphors keep some of the energy and release some
of the lower energy as visible light.
 E.g. Glow in the dark
4
Principle of phosphorescence
 Any material absorbs light and enter in exited state,
then the emission of energy from triplet state to
ground singlet state is phosphorescence.
5
Applications
 Lightening
 Phosphor thermometry
 Glow in dark toys
 White LEDs
 Electroluminescence
6
.Lightening
 Phosphor layers provide most of the light produced by
fluorescent lamps.
 Various Neon signs use phosphor layers to produce
different colours of light.
7
Phosphor Thermometry
 It is a temperature measurement approach that uses
the temperature dependence of certain phosphors.
 A phosphor coating is applied to a surface of interest
and usually the decay time is the emission parameter
that indicates temperature.
 The method may be used for moving surfaces such as
high speed motor surfaces
8
Glow in dark toys
 Calcium sulphide with Strontium sulphide with
Bismuth as activator (Ca,Sr)S:Bi yields blue light (glow
times upto 12 hours).
 Red colour can be obtained from Strontium sulphide.
 Mix of Zinc sulphide and Cadmium sulphide emit
colour depending on their ratio.
9
White LEDs
 White Light Emitting Diodes are usually blue InGaN
LEDs with a coating of suitable material.
 This coated material absorbs the light from blue LED
and emits in a broad range from greenish to reddish.
 Mostly output is yellow.
 This yellow emission combined with the remaining
blue emission gives the “white” light.
 This white light can be adjusted to colour temperature
as warm(yellowish) or cold(bluish) white.
10
Electroluminescence
 Luminescence in light sources is known as
Electroluminescence.
 The excitation of the phosphor is usually achieved by
application of by application of electric field with
suitable frequency.
11
Conclusion
 A phosphor- the substance that exhibits the process of
luminescence.
 Phosphors are usually made from a suitable host
material with an added activator. The best known type
is Copper activated Zinc sulphide.
 These are widely used in LEDs.
12
References
 1. Cuba, V., Pavelkova, T., Barta, J., Jarý, V., Nikl, M.,
Jakubec, I. Photo- and radiation induced preparation of
Y2O3 and Y2O3:Ce(Eu) nanocrystals. J. Nanoparticle
Research, 2012, 14, 794-801.
 2. Yen W.M., Raukas M., Basun S. A., van Schaik W.,
Happek U., Optical and photoconductive properties of
cerium doped crystalline solids. J Lumin. 1996, 69, 287–294
 3. Cuba, V., Indrei, J., Mucka, Nikl, M., Beitlerova, A.,
Pospisil, M., Jakubec, I.. Radiation induced synthesis of
powder yttrium aluminium garnet. Radiation Physics and
Chemistry, 2011, 80, 957-62.
13

phosphroscene

  • 1.
  • 2.
    CONTENTS  Introduction  Principleof Phosphorescence  Mechanism  Applications of Phosphorescence- -Lightning -Phosphor Thermometry -Glow in dark toys -Luminescence -White LEDs -Electroluminescence  Conclusion  References 2
  • 3.
    Introduction  A phosphor,most generally is a substance that exhibits the phenomenon of luminescence.  Phosphors are commonly transition metal compounds or rare earths.  But the element Phosphorus named for its light emitting behaviour due to chemiluminescence not due to phosphorescence.  Common pigments used in phosphorescent materials include Zinc Sulphide and Strontium aluminate. 3
  • 4.
     Objects coatedwith phosphors that absorb UV light resulting in the emission of visible light over an extended period of time.  Phosphors keep some of the energy and release some of the lower energy as visible light.  E.g. Glow in the dark 4
  • 5.
    Principle of phosphorescence Any material absorbs light and enter in exited state, then the emission of energy from triplet state to ground singlet state is phosphorescence. 5
  • 6.
    Applications  Lightening  Phosphorthermometry  Glow in dark toys  White LEDs  Electroluminescence 6
  • 7.
    .Lightening  Phosphor layersprovide most of the light produced by fluorescent lamps.  Various Neon signs use phosphor layers to produce different colours of light. 7
  • 8.
    Phosphor Thermometry  Itis a temperature measurement approach that uses the temperature dependence of certain phosphors.  A phosphor coating is applied to a surface of interest and usually the decay time is the emission parameter that indicates temperature.  The method may be used for moving surfaces such as high speed motor surfaces 8
  • 9.
    Glow in darktoys  Calcium sulphide with Strontium sulphide with Bismuth as activator (Ca,Sr)S:Bi yields blue light (glow times upto 12 hours).  Red colour can be obtained from Strontium sulphide.  Mix of Zinc sulphide and Cadmium sulphide emit colour depending on their ratio. 9
  • 10.
    White LEDs  WhiteLight Emitting Diodes are usually blue InGaN LEDs with a coating of suitable material.  This coated material absorbs the light from blue LED and emits in a broad range from greenish to reddish.  Mostly output is yellow.  This yellow emission combined with the remaining blue emission gives the “white” light.  This white light can be adjusted to colour temperature as warm(yellowish) or cold(bluish) white. 10
  • 11.
    Electroluminescence  Luminescence inlight sources is known as Electroluminescence.  The excitation of the phosphor is usually achieved by application of by application of electric field with suitable frequency. 11
  • 12.
    Conclusion  A phosphor-the substance that exhibits the process of luminescence.  Phosphors are usually made from a suitable host material with an added activator. The best known type is Copper activated Zinc sulphide.  These are widely used in LEDs. 12
  • 13.
    References  1. Cuba,V., Pavelkova, T., Barta, J., Jarý, V., Nikl, M., Jakubec, I. Photo- and radiation induced preparation of Y2O3 and Y2O3:Ce(Eu) nanocrystals. J. Nanoparticle Research, 2012, 14, 794-801.  2. Yen W.M., Raukas M., Basun S. A., van Schaik W., Happek U., Optical and photoconductive properties of cerium doped crystalline solids. J Lumin. 1996, 69, 287–294  3. Cuba, V., Indrei, J., Mucka, Nikl, M., Beitlerova, A., Pospisil, M., Jakubec, I.. Radiation induced synthesis of powder yttrium aluminium garnet. Radiation Physics and Chemistry, 2011, 80, 957-62. 13