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TOP DOWN AND BOTTOM UP
APPROACH FOR NANOPARTICLE
SYNTHESIS
-for 0D,1D,2D,3D particle
A Presentation By
Md .Tariqul Islam-1111030
Muntaseer Bunian-1111001
Outlines of the lecture
• Approach to Nanoscale Structure
• Classification of Nanomaterials
• Classification Top-down approach
• TOP-DOWN fabrication of 1D devices
• Bottom-up approach
• Bottom Up Approach of 1D Devices
Classification of Nanomaterials
0D, 1D, 2D and 3D
nanostructured
materials
Zero dimensional (atomic
clusters, filaments and cluster
assemblies
one dimensional (multilayers)
two dimensional (ultrafine-
grained overlayers or buried
layers)
three dimensional nanostructures
(nanophase materials consisting
of equiaxed nanometer sized
grains)
Approaches
to
Nanoscale
Structures
Junior Research Seminar: Nanoscale Patterning and Systems
Teri W. Odom
Top-down approach
SUBSTRATE
CLEANING SPIN COAT
DEVELOP
PRE-BAKE
EXPOSE
INSPECTION
POST-BAKE
ETCH STRIP
TOP
DOWN
NANOPARTICLE
Process
Attributes(LITHOGRAPHY)
BULK
MATERIAL
Top-down approach
-Basic Mechanism
lithography
SPUN
COAT
EXPOSURE
DEVELOP
ETCH
STRIP
Coat, protect, expose, etch, repeat
Result:
Multiple patterned layers of different
materials.
SO
RESIST
BASE
RADIATION(UV)
MASK
Top-down
approach
TOP-DOWN fabrication of 1D devices
A top-down approach to making one-
dimensional quantum devices. Like resonant
tunneling via quantum dots. Method
pioneered by Randall and Reed at Texas
instruments in the late 1980s. However,
rather unsatisfactory device properties due
to fabrication induced damage and poor
lateral control.
Bottom-up approach
The opposite of the top-down approach.
• Instead of taking material away to make structures, the bottom-up
approach selectively adds atoms to create structures.
Bottom-up approach
BOTTOM
UP
NANOPARTICLE
BULK WAFER
PREPARATION
ALTERATION
AREA
ADDING SEED
CRYSTALS
GROW/ASSEMBLE
Process Attributes
BOTTOM-UP
Bottom -up approach
-Basic MechanismStart with bulk wafer
Alter area of wafer
where structure is to be
created by adding
polymer or seed
crystals or other
techniques.
Grow or assemble
the structure on the
area determined by
the seed crystals or
polymer. (self
assembly)
Process
Similar results can be
obtained through
bottom-up and top-
down processes
Bottom
Up
approach
Bottom-up fabrication of 1D devices
We have developed an alternative approach, to form
1D nanowires (NWs) by a bottom-up, or
selfassembling, method, allowing simple as well as
highly complex structures to be formed. In most cases
we combine a lithographic step such that the
fabrication can be described as guided self-assembly.
A special benefit of the seeded NW growth approach
is that III-V materials and devices can be grown on
silicon
Array if Zn blend InAs
nanowires with perfectly
periodic twin-plane super
lattice.
References
 Hench, L. L.; West, J. K. (1990). "The sol-gel process". Chemical Reviews 90: 33.
doi:10.1021/cr00099a003.
 Buzea, C.; Pacheco, I. I.; Robbie, K. (2007). "Nanomaterials and nanoparticles: Sources
and toxicity". Biointerphases 2 (4): MR17–MR71. doi:10.1116/1.2815690. PMID
20419892.
 Mnyusiwalla, Anisa; Daar, Abdallah S; Singer, Peter A (2003). "Mind the gap : science and
ethics in nanotechnology". Nanotechnology 14 (3): R9. Bibcode:2003Nanot..14R...9M.
doi:10.1088/0957-4484/14/3/201
 Alemán, J.; Chadwick, A. V.; He, J.; Hess, M.; Horie, K.; Jones, R. G.; Kratochvíl, P.; Meisel,
I.; Mita, I.; Moad, G.; Penczek, S.; Stepto, R. F. T. (2007). "Definitions of terms relating to
the structure and processing of sols, gels, networks, and inorganic-organic hybrid
materials (IUPAC Recommendations 2007)". Pure and Applied Chemistry 79 (10): 1801.
doi:10.1351/pac200779101801.

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Nanoparticle Synthesis

  • 1. TOP DOWN AND BOTTOM UP APPROACH FOR NANOPARTICLE SYNTHESIS -for 0D,1D,2D,3D particle A Presentation By Md .Tariqul Islam-1111030 Muntaseer Bunian-1111001
  • 2. Outlines of the lecture • Approach to Nanoscale Structure • Classification of Nanomaterials • Classification Top-down approach • TOP-DOWN fabrication of 1D devices • Bottom-up approach • Bottom Up Approach of 1D Devices
  • 3. Classification of Nanomaterials 0D, 1D, 2D and 3D nanostructured materials Zero dimensional (atomic clusters, filaments and cluster assemblies one dimensional (multilayers) two dimensional (ultrafine- grained overlayers or buried layers) three dimensional nanostructures (nanophase materials consisting of equiaxed nanometer sized grains)
  • 4. Approaches to Nanoscale Structures Junior Research Seminar: Nanoscale Patterning and Systems Teri W. Odom
  • 5. Top-down approach SUBSTRATE CLEANING SPIN COAT DEVELOP PRE-BAKE EXPOSE INSPECTION POST-BAKE ETCH STRIP TOP DOWN NANOPARTICLE Process Attributes(LITHOGRAPHY) BULK MATERIAL
  • 6. Top-down approach -Basic Mechanism lithography SPUN COAT EXPOSURE DEVELOP ETCH STRIP Coat, protect, expose, etch, repeat Result: Multiple patterned layers of different materials. SO RESIST BASE RADIATION(UV) MASK
  • 8. TOP-DOWN fabrication of 1D devices A top-down approach to making one- dimensional quantum devices. Like resonant tunneling via quantum dots. Method pioneered by Randall and Reed at Texas instruments in the late 1980s. However, rather unsatisfactory device properties due to fabrication induced damage and poor lateral control.
  • 9. Bottom-up approach The opposite of the top-down approach. • Instead of taking material away to make structures, the bottom-up approach selectively adds atoms to create structures.
  • 10. Bottom-up approach BOTTOM UP NANOPARTICLE BULK WAFER PREPARATION ALTERATION AREA ADDING SEED CRYSTALS GROW/ASSEMBLE Process Attributes BOTTOM-UP
  • 11. Bottom -up approach -Basic MechanismStart with bulk wafer Alter area of wafer where structure is to be created by adding polymer or seed crystals or other techniques. Grow or assemble the structure on the area determined by the seed crystals or polymer. (self assembly) Process Similar results can be obtained through bottom-up and top- down processes
  • 13. Bottom-up fabrication of 1D devices We have developed an alternative approach, to form 1D nanowires (NWs) by a bottom-up, or selfassembling, method, allowing simple as well as highly complex structures to be formed. In most cases we combine a lithographic step such that the fabrication can be described as guided self-assembly. A special benefit of the seeded NW growth approach is that III-V materials and devices can be grown on silicon Array if Zn blend InAs nanowires with perfectly periodic twin-plane super lattice.
  • 14. References  Hench, L. L.; West, J. K. (1990). "The sol-gel process". Chemical Reviews 90: 33. doi:10.1021/cr00099a003.  Buzea, C.; Pacheco, I. I.; Robbie, K. (2007). "Nanomaterials and nanoparticles: Sources and toxicity". Biointerphases 2 (4): MR17–MR71. doi:10.1116/1.2815690. PMID 20419892.  Mnyusiwalla, Anisa; Daar, Abdallah S; Singer, Peter A (2003). "Mind the gap : science and ethics in nanotechnology". Nanotechnology 14 (3): R9. Bibcode:2003Nanot..14R...9M. doi:10.1088/0957-4484/14/3/201  Alemán, J.; Chadwick, A. V.; He, J.; Hess, M.; Horie, K.; Jones, R. G.; Kratochvíl, P.; Meisel, I.; Mita, I.; Moad, G.; Penczek, S.; Stepto, R. F. T. (2007). "Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)". Pure and Applied Chemistry 79 (10): 1801. doi:10.1351/pac200779101801.