The document discusses three types of isomers: structural isomers, geometric isomers, and enantiomers. Structural isomers have the same molecular formula but different connectivity of atoms. Geometric isomers have the same molecular formula and connectivity but different spatial arrangements, usually due to double bonds or rings. Enantiomers are non-superimposable mirror images that contain a chiral carbon with four different groups attached.
In 1891,Emil fischer devised a method of representing the 3D structures of
molecules in 2D Structures on a plane (Paper) by convention, horizontal line
represent bonds projecting from the plane of paper towards the observer and
vertical line represent away from the observer
In 1891,Emil fischer devised a method of representing the 3D structures of
molecules in 2D Structures on a plane (Paper) by convention, horizontal line
represent bonds projecting from the plane of paper towards the observer and
vertical line represent away from the observer
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ORGANIC CHEMISTRY
Isomers are molecules with the same molecular formula, but different structural or spatial arrangements of the atoms within the molecule. The reason there are such a colossal number of organic compounds which is more than 10 million is partly due to isomerism.
Here you will find about optical isomerism...
To know about more optical isomerism download it and then you will find a link... open this and go through..
more chemistry contents are available
1. pdf file on Termmate: https://www.termmate.com/rabia.aziz
2. YouTube: https://www.youtube.com/channel/UCKxWnNdskGHnZFS0h1QRTEA
3. Facebook: https://web.facebook.com/Chemist.Rabia.Aziz/
4. Blogger: https://chemistry-academy.blogspot.com/
ORGANIC CHEMISTRY
Isomers are molecules with the same molecular formula, but different structural or spatial arrangements of the atoms within the molecule. The reason there are such a colossal number of organic compounds which is more than 10 million is partly due to isomerism.
What is Isomerism and the Types of Isomerism?Tutoroot
Firstly, let us understand what Isomerism is. Chemical compounds are known to have similar chemical formulae, but they differ greatly in the arrangement of atoms for the compound as well as the arrangement of atoms. This phenomenon is called isomerism, and the compounds which express this property are called Isomers. Types of isomerism are Structural Isomerism, Stereoisomerism and Conformational Isomerism. Enroll now at Tutoroot for best one on one tuitions.
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Geometric isomerism of alkenes, cyclic compounds: cis-trans and (E)-(Z) system of
nomenclature
b) Conformational isomers: Open chain and cyclic system
c) Chirality of molecules: Enantiomers, diastereomers, racemic modification, Meso
compound, R & S configuration, sequence rule, Optical rotation
d) Asymmetric synthesis: Preparation of enantiomers by asymmetric synthesis & optical
resolution method
e) Stereo selective and stereo specific reaction
f) Pharmaceutical importance of studding stereochemistry
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2. Isomers
Compounds that have the same molecular
formula but difference structure and different
properties
3 types:
Structural isomers
Geometric isomers
Enantiomers
3.
4. Structural Isomer
same KIND and AMOUNT of atoms
(molecular formula) but the atoms have
different connectivity
Structural isomers usually have different
physical and chemical properties
10. Geometric Isomers
SAME molecular formula and the SAME
connectivity but different spatial
arrangements
Due to inflexibility of a bond, usually either:
double bonds (cis and trans formation)
bonds that can’t rotate (i.e. in a ring formation)
12. Geometric Isomer
Why is example 1 not a pair of geometric
isomers?
Hint: Look at example 2 & 3 and compare to example 1.
What is the minimum requirement for a pair of molecules to
be considered geometric isomers?
13. Geometric Isomer
Answer: Each carbon of the double bond
must have two different substituent groups
So if example 1 is not a pair of geometric
isomers, what are they classified as?
14. Geometric Isomer
Another type of geometric isomer is found in ring
structures and doesn’t involve double bonds
Due to the inflexible nature of the bonds that make
up the ring
Note: The ring lies on a flat plane (e.g. your paper)
and the OH groups are perpendicular to the plane
(e.g. up and down)
15. Enantiomer
Molecules that are
mirror images of each
other
Note: left and right
hands are a pair of
enantiomers (mirror
images not identical)
What other body parts
that are enantiomers?
18. Enantiomer
How are the lower
pairs of molecules
different from the
upper pairs?
What condition do
you think is
necessary for a pair
of molecules to be
enantiomers?
X
19. Enantiomer
Requirement: Enantiomers can only occur
when each of the four groups attached to the
central carbon atom are all different.
The central carbon is known as a chiral
carbon and the molecule is chiral.
20. Chiral Molecules
Asymmetric carbon: carbon with 4 different
groups bonded to it
No plane of symmetry
Mirror image is non-superimposable
23. Application: Amino acids
Amino acids are building
blocks of proteins
Some amino acids can
exist as enantiomers
because of their chiralty
Switching an enantiomer
in a biological system can
have detrimental effects
24. Application: Enzymes
Enzymes are always chiral.
Their binding sites are in a specific orientation that
fits only one form of an enantiomer.
Binding sites won’t fit if the wrong enantiomer is
present.
25. Racemic mixture
A mixture that contains equal quantities of
both enantiomers
Enantiomers can interconvert in vivo
26. Racemic mixture
Story of thalidomide (1960’s)
A racemic drug given to
pregnant women to combat
morning sickness
One of the enantiomers
caused birth defects
(teratogen) and death
http://www.thalidomide.ca/the-canadian-tragedy/
27. Racemic mixture
What’s in Advil (ibuprofen)?
Production results in a racemic mixture
One of the enantiomers is effective as an
anti-inflammatory
Takes about 30 minutes for the inactive
enantiomer to be converted
http://www.brookscole.com/chemistry_d/templates/student_resources/0534389996_mcmurry/CHEM_A_WORK/chapter9.htm
The World of Chemistry, 4 ed. 2007. Thomson Brooks/Cole. Joesten, Castellion, & Hogg.
28. Steps to identifying isomers
Do the molecules have the same
chemical formula?
If the formula is different, they are NOT
isomers but completely different molecules
Are the molecules identical?
If they are, they are NOT isomers.
Are all the atoms connected in the same
way to other atoms?
If not, they are STRUCTURAL isomers
Look for an inflexible bond (double bond
or ring) for geometric isomers
Look for mirror images for enantiomers
http://2.bp.blogspot.com/_K91FA3B4cpM/SJ_NUmBWWGI/AAAAAAAAACY/UzL8H8Q4oag/s400/ist2_1744503_frustration.jpg
29. Summary
Isomer Same Different Requirements
Structural
Geometric
Enantiomer
30. Summary
Isomer Same Different Requirements
Molecular
Structural Connectivity
formula
Geometric
Enantiomer
31. Summary
Isomer Same Different Requirements
Molecular
Structural Connectivity
formula
Molecular Double bond
Spatial
Geometric formula & Different substituent
arrangement
connectivity groups on each carbon
Enantiomer
32. Summary
Isomer Same Different Requirements
Molecular
Structural Connectivity
formula
Molecular Double bond
Spatial
Geometric formula & Different substituent
arrangement
connectivity groups on each carbon
Molecular
Spatial Chiral molecules
Enantiomer formula &
arrangement Mirror image
connectivity