The document discusses the differences between fats and oils, the saponification reaction of fats and oils with NaOH, and the structures of stearic acid, sodium stearate, and some syndets. It also describes observations made during soap preparation and comparisons between prepared soap and commercial syndets and liquid soaps. Key findings include that prepared soap is soluble in both water and oil, forming precipitates with hard water, and tests basic with litmus paper and phenolphthalein.
Based on the reactivity with Tollen’s, Benedict’s or Fehling’s reagent, carbohydrates are classified as;
Reducing sugars
Carbohydrates that can reduce Tollen’s, Benedict’s or Fehling’s reagents are called reducing sugars (sugar with free aldehyde or ketone group). All monosaccharides and most of the disaccharides are reducing sugars. Some examples are Maltose and Lactose.
Non-reducing sugars
Carbohydrates that cannot reduce Tollen’s, Benedict’s or Fehling’s reagents are called non-reducing sugars. Sucrose is a non-reducing sugar.
Introduction of fats, Reaction of fatty acids, Reaction of fats or oil- Hydrolysis, Hydrogenation, Halogenation, saponification, Drying of oil, Rancidity, Determination of acid value, saponification value, iodine value, acetyl value,
This was a presentation based on the Science of Soaps and Detergents....
I made it in 3 days as it was on a short-notice...!!
Hope you guyss like it :) :) :) :) :)
Based on the reactivity with Tollen’s, Benedict’s or Fehling’s reagent, carbohydrates are classified as;
Reducing sugars
Carbohydrates that can reduce Tollen’s, Benedict’s or Fehling’s reagents are called reducing sugars (sugar with free aldehyde or ketone group). All monosaccharides and most of the disaccharides are reducing sugars. Some examples are Maltose and Lactose.
Non-reducing sugars
Carbohydrates that cannot reduce Tollen’s, Benedict’s or Fehling’s reagents are called non-reducing sugars. Sucrose is a non-reducing sugar.
Introduction of fats, Reaction of fatty acids, Reaction of fats or oil- Hydrolysis, Hydrogenation, Halogenation, saponification, Drying of oil, Rancidity, Determination of acid value, saponification value, iodine value, acetyl value,
This was a presentation based on the Science of Soaps and Detergents....
I made it in 3 days as it was on a short-notice...!!
Hope you guyss like it :) :) :) :) :)
Name; Hasnain Nawaz
Surname : Shaikh
ROLL NO: 16 CH 42
B.E: Chemical Engineering (In Progress).
Mehran University of Engineering and Technology
Jamshore, ISO 9001 Certified.
Soap nut powder has been in use for almost 3,000 years. And still in many parts of India, soap nut powder is using as a natural soap to remove oil.Soap is a sodium salt or potassium salt of long chain fatty acids having cleansing action in water. They are using as cleansing agents to remove dirt, oil from the skin and clothes.Examples:Sodium stearate, sodium oliate and sodium palmitate formed using stearic acid oleic acid and palmitic acid.
Soap nut powder has been in use for almost 3,000 years. And still in many parts of India, soap nut powder is using as a natural soap to remove oil.Soap is a sodium salt or potassium salt of long chain fatty acids having cleansing action in water. They are using as cleansing agents to remove dirt, oil from the skin and clothes.Examples:Sodium stearate, sodium oliate and sodium palmitate formed using stearic acid oleic acid and palmitic acid.
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2. 1. Differentiate fats from oils.
2. Write an equation showing the
saponification of fats and oils with NaOH.
3. Draw the complete structures, showing all
bonds , for stearic acid and sodium stearate.
4. Draw structures of some syndets.
3. 1. Fats Oils
Tend to be solid or Tend to be liquid at
semi-solid at room room temperature
temperature
Usually come from Usually come from
animal sources plant sources
More saturated Less saturated
8. To observe the preparation of soap.
To compare syndets and prepared soap.
9.
10. Observation:
When we mixed the lard & the NaOH in 35ml of 1:1
ethanol-water. The lard was insoluble in the mixture.
When heated for 2 minutes the lard dissolved
When heated for 5 minutes the solution became
viscous
We stopped heating when we reached 18 minutes the
solution became very thick. (homogeneous mixture)
After mixing a salt solution with the soap mixture the
soap from a homogeneous mixture it became little
pieces.
13. Oil
Prepared: Syndet: Liquid: Distilled
water:
Miscible Miscible Immiscible Immiscible
Oil is Oil is Oil is not Oil is not
emulsified emulsified emulsified emulsified
Tap Water:
Prepared: Syndet: Liquid: Distilled
water:
No No No No
precipitate precipitate precipitate precipitate
14.
15. Soaps are soluble both in water and oil.
The carboxylate end of the long-chain molecule is ionic
and therefore hydrophilic, or attracted to water.
The long hydrocarbon portion of the molecule, however
is non-polar and hydrophobic, or water avoiding, and
therefore more soluble in oils.
Since the liquid soap wasn’t soluble in oil. We can
conclude that it isn’t effective in removing oils from the
dishes.
There was no precipitate formed when we placed the
soap in the tap water. This indicates that the tap water
doesn’t contain soluble sodium carboxylates .
16.
17. CaCl2
Prepared: Syndet: Liquid:
No precipitate No precipitate No precipitate
formed formed formed
FeCl2
Prepared: Syndet: Liquid:
No precipitate Precipitate formed Precipitate formed
formed
MgCl3
Prepared: Syndet: Liquid:
precipitate formed No precipitate No precipitate
formed formed
18.
19. Soaps have some drawbacks
In hard water, w/c contains Ca2+, Mg2+, Fe3+,
SO42-, and HCO3-, soluble sodium
carboxylates are converted into insoluble
metal salts (precipitate), leaving the familiar
ring of scum around bathtubs and the gray
tinge on white clothes.
20. Litmus paper test:
Prepared: Syndet:
Blue Blue
Phenolphthalein solution:
Prepared: Syndet:
Colorless to Pink Colorless to Pink
21.
22. Litmus Paper Test:
Since the color of the paper is blue this means
that the soaps are basic.
Soap is made from sodium hydroxide and fats.
The presence of sodium hydroxide makes it basic
Phenolphthalein test:
Phenolphthalein turns pink when the solution is basic
With this it is proven that the prepared soap and the
syndet are both basic which is one of the qualities of
a soap.
23. 1. Explain why you poured the hydrolyzed fat
mixture into a concentrated solution to
precipitate the soap.
2. Why is the hydrolysis of a fat called
saponification.
3. Describe the cleansing action of soap.
4. Assuming a soap to be pure sodium stearate,
give an equation.
1. That shows why its solutions are alkaline
2. For its reactions with Mg+2 in hard water
3. For its reaction with hydrochloric acid
24. 1.Because in mixing the NaOH solution to the
lard both soap and glycerol is produced.
GLYCEROL- interferes with testing so we need
to take the glycerol out to take it out we add
the salt solution which has a salting out
effect thereby removing glycerol.
Additionally, we wash the soap with cold
water to remove the remaining glycerol and
salt.
25. 2. The hydrolysis of fat is called saponification
after the Latin word sapo, “soap”. This
reaction then results to the formation of
soap. Soap is a mixture of carboxylate salts
of fatty acids derived from the fatty acids of
the triacylglycerols contained in the fat or
oil.
26. 3. The cleansing action of both soaps and detergents
results from their ability to emulsify or disperse water-
insoluble materials (dirt, oil, grease, etc.) and hold
them in suspension in water. This ability comes from
the molecular structure of soaps and detergents.
When a soap or detergent is added to water that
contains oil or other water-insoluble materials, the
soap or detergent molecules surround the oil droplets.
The oil or grease is “dissolved” in the alkyl groups of
the soap molecules while the ionic end allows the
micelle to dissolve in water. As a result, the oil
droplets are dispersed throughout the water (this is
referred to as emulsification ) and can be rinsed away
28. Soaps are prepared through the process of
saponification. Soaps are basic, soluble in
both water and oil, but creates precipitate in
hard water (contains Ca2+, Mg2+, Fe3+, SO42-,
and HCO3-, soluble sodium carboxylates ).
Editor's Notes
hydrophilic-tending to dissolve in, mix with, or be wetted by waterHydrophobic-lacking affinity for water; tending to repel and not absorb water; tending not to dissolve in or mix with or be wetted by water
water hardness was defined as the measure of the capacity of the water to precipitate soap.
Sodium Hydroxide comes under the metal hydroxide category, so yes, it is a base.