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VSEPR Valence Shell Electron Pair Repulsions
Covalent Bond: A Model ,[object Object],[object Object],[object Object],[object Object]
Example:  Methane ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Bonding Model ,[object Object],[object Object],[object Object]
Covalent Bonds ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Multiple covalent bonds around the same atom determine the shape ,[object Object],[object Object]
Single bonds ,[object Object],[object Object],[object Object],[object Object]
Double and Triple Bonds ,[object Object],[object Object],[object Object]
 
Lewis Structures ,[object Object],[object Object],[object Object]
Lewis Structure ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Rules for Drawing Lewis Structures ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Determine # Valence e-  from column #
 
 
 
 
Electron Clouds repel each other, thus structure around an atom is determined principally by minimizing repulsions
2 electron pairs (2 EP) around central atom ,[object Object],[object Object],[object Object]
3 electron pairs (3 EP)  around central atom ,[object Object],[object Object],[object Object],[object Object]
4 electron pairs (4 EP)  around central atom ,[object Object],[object Object],[object Object],[object Object],[object Object]
Orbital Hybridization #1 ,[object Object],[object Object],[object Object],[object Object],[object Object]
Orbital Hybridization #2 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Overlap of two s-orbitals NOT A GOOD LOCATION-  far from one nucleus Note:  shared in this overlap the e- pair would spend most of the time in an unfavorable location GOOD SPOT between both nuclei
Overlap of two p-orbitals One atom & its p-orbital The other atom & its p-orbital represents the nucleus BAD location far from other nucleus GOOD SPOT between  both nuclei
Hybrid Orbitals yield more favorable shape for overlap ,[object Object],[object Object],[object Object],[object Object]
Angles  and  Shape ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Orbital Hybridization #3 ,[object Object],[object Object],sp hybrids 2  EP 4  EP 3  EP sp 2  hybrids sp 3  hybrids
Electron-Pair Geometry vs Molecular Geometry ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Examples of 3 EP ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],O O O N O O O
Carbonate Ion (CO 3 2- )
Nitrate Ion (NO 3 - )
Nitrite Ion (NO 2 - )
Examples of 4 EP ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
4 BP + 0 NBP = 4 EP TETRAHEDRAL Cl Cl Cl Cl S
3 BP + 1 NBP = 4 EP TRIGONAL PYRAMIDAL N H H H ●● lone pair of e- NBP H H H N 107
2 BP + 2 NBP = 4 EP BENT O H H ●● lone pair of e- NBP H H O ●● lone pair of e- NBP 104.5 H
Hydronium Ion (H 3 O + )
Ammonia Molecule (NH 3 )
 
Summary of 4 EP
Exceptions to Octet Rule ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Lewis Structures in Which the Central Atom Exceeds an Octet
5 EP ,[object Object],[object Object],[object Object],[object Object],[object Object]
Trigonal planar shape
5 EP = trigonal pyramidal ,[object Object],[object Object]
5 EP = trigonal pyramidal ,[object Object],[object Object]
6 EP ,[object Object],[object Object],[object Object],[object Object],[object Object]
6 EP = octahedral 6 BP +0 NBP 6 EP
6 EP = octahedral 5 BP +1 NBP 6 EP
6 EP = octahedral 4 BP +2 NBP 6 EP
 
 
Summary: Molecular Geometry of Expanded Octets
Summary of EP Geometry ,[object Object]
Summary of EP Geometry
Predict the geometry, angles  and orbital hybridization Predict the geometry, angles  and orbital hybridization
 
 
Covalent Bond: A Model ,[object Object],[object Object],[object Object]
Example:  Methane ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Bonding Model ,[object Object],[object Object],[object Object]
 
Bond Energy and Enthalpy
 

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