This document provides an overview of organic chemistry concepts including:
- The electronic structure of atoms and how this relates to bonding
- Different types of bonds (ionic, covalent, polar, nonpolar) and how they form
- Lewis structures and resonance forms
- Molecular shapes determined by hybridization of orbitals
- Isomerism including constitutional and geometric isomers
The document covers fundamental topics that provide context for understanding organic molecular structures and reactions.
Applied Chemistry, atomic and molecular structure, part 1, by Shiraz mahbob PhDMaqsoodAhmadKhan5
applied chemistry lecture and slide,
Applied Chemistry, atomic and molecular structure, part 1, by Shiraz mahbob PhD, lecturer in chemistry in pakistan institute of engineering and applied sciences
Applied Chemistry, atomic and molecular structure, part 1, by Shiraz mahbob PhDMaqsoodAhmadKhan5
applied chemistry lecture and slide,
Applied Chemistry, atomic and molecular structure, part 1, by Shiraz mahbob PhD, lecturer in chemistry in pakistan institute of engineering and applied sciences
A Strategic Approach: GenAI in EducationPeter Windle
Artificial Intelligence (AI) technologies such as Generative AI, Image Generators and Large Language Models have had a dramatic impact on teaching, learning and assessment over the past 18 months. The most immediate threat AI posed was to Academic Integrity with Higher Education Institutes (HEIs) focusing their efforts on combating the use of GenAI in assessment. Guidelines were developed for staff and students, policies put in place too. Innovative educators have forged paths in the use of Generative AI for teaching, learning and assessments leading to pockets of transformation springing up across HEIs, often with little or no top-down guidance, support or direction.
This Gasta posits a strategic approach to integrating AI into HEIs to prepare staff, students and the curriculum for an evolving world and workplace. We will highlight the advantages of working with these technologies beyond the realm of teaching, learning and assessment by considering prompt engineering skills, industry impact, curriculum changes, and the need for staff upskilling. In contrast, not engaging strategically with Generative AI poses risks, including falling behind peers, missed opportunities and failing to ensure our graduates remain employable. The rapid evolution of AI technologies necessitates a proactive and strategic approach if we are to remain relevant.
Embracing GenAI - A Strategic ImperativePeter Windle
Artificial Intelligence (AI) technologies such as Generative AI, Image Generators and Large Language Models have had a dramatic impact on teaching, learning and assessment over the past 18 months. The most immediate threat AI posed was to Academic Integrity with Higher Education Institutes (HEIs) focusing their efforts on combating the use of GenAI in assessment. Guidelines were developed for staff and students, policies put in place too. Innovative educators have forged paths in the use of Generative AI for teaching, learning and assessments leading to pockets of transformation springing up across HEIs, often with little or no top-down guidance, support or direction.
This Gasta posits a strategic approach to integrating AI into HEIs to prepare staff, students and the curriculum for an evolving world and workplace. We will highlight the advantages of working with these technologies beyond the realm of teaching, learning and assessment by considering prompt engineering skills, industry impact, curriculum changes, and the need for staff upskilling. In contrast, not engaging strategically with Generative AI poses risks, including falling behind peers, missed opportunities and failing to ensure our graduates remain employable. The rapid evolution of AI technologies necessitates a proactive and strategic approach if we are to remain relevant.
Welcome to TechSoup New Member Orientation and Q&A (May 2024).pdfTechSoup
In this webinar you will learn how your organization can access TechSoup's wide variety of product discount and donation programs. From hardware to software, we'll give you a tour of the tools available to help your nonprofit with productivity, collaboration, financial management, donor tracking, security, and more.
Model Attribute Check Company Auto PropertyCeline George
In Odoo, the multi-company feature allows you to manage multiple companies within a single Odoo database instance. Each company can have its own configurations while still sharing common resources such as products, customers, and suppliers.
Read| The latest issue of The Challenger is here! We are thrilled to announce that our school paper has qualified for the NATIONAL SCHOOLS PRESS CONFERENCE (NSPC) 2024. Thank you for your unwavering support and trust. Dive into the stories that made us stand out!
June 3, 2024 Anti-Semitism Letter Sent to MIT President Kornbluth and MIT Cor...Levi Shapiro
Letter from the Congress of the United States regarding Anti-Semitism sent June 3rd to MIT President Sally Kornbluth, MIT Corp Chair, Mark Gorenberg
Dear Dr. Kornbluth and Mr. Gorenberg,
The US House of Representatives is deeply concerned by ongoing and pervasive acts of antisemitic
harassment and intimidation at the Massachusetts Institute of Technology (MIT). Failing to act decisively to ensure a safe learning environment for all students would be a grave dereliction of your responsibilities as President of MIT and Chair of the MIT Corporation.
This Congress will not stand idly by and allow an environment hostile to Jewish students to persist. The House believes that your institution is in violation of Title VI of the Civil Rights Act, and the inability or
unwillingness to rectify this violation through action requires accountability.
Postsecondary education is a unique opportunity for students to learn and have their ideas and beliefs challenged. However, universities receiving hundreds of millions of federal funds annually have denied
students that opportunity and have been hijacked to become venues for the promotion of terrorism, antisemitic harassment and intimidation, unlawful encampments, and in some cases, assaults and riots.
The House of Representatives will not countenance the use of federal funds to indoctrinate students into hateful, antisemitic, anti-American supporters of terrorism. Investigations into campus antisemitism by the Committee on Education and the Workforce and the Committee on Ways and Means have been expanded into a Congress-wide probe across all relevant jurisdictions to address this national crisis. The undersigned Committees will conduct oversight into the use of federal funds at MIT and its learning environment under authorities granted to each Committee.
• The Committee on Education and the Workforce has been investigating your institution since December 7, 2023. The Committee has broad jurisdiction over postsecondary education, including its compliance with Title VI of the Civil Rights Act, campus safety concerns over disruptions to the learning environment, and the awarding of federal student aid under the Higher Education Act.
• The Committee on Oversight and Accountability is investigating the sources of funding and other support flowing to groups espousing pro-Hamas propaganda and engaged in antisemitic harassment and intimidation of students. The Committee on Oversight and Accountability is the principal oversight committee of the US House of Representatives and has broad authority to investigate “any matter” at “any time” under House Rule X.
• The Committee on Ways and Means has been investigating several universities since November 15, 2023, when the Committee held a hearing entitled From Ivory Towers to Dark Corners: Investigating the Nexus Between Antisemitism, Tax-Exempt Universities, and Terror Financing. The Committee followed the hearing with letters to those institutions on January 10, 202
Operation “Blue Star” is the only event in the history of Independent India where the state went into war with its own people. Even after about 40 years it is not clear if it was culmination of states anger over people of the region, a political game of power or start of dictatorial chapter in the democratic setup.
The people of Punjab felt alienated from main stream due to denial of their just demands during a long democratic struggle since independence. As it happen all over the word, it led to militant struggle with great loss of lives of military, police and civilian personnel. Killing of Indira Gandhi and massacre of innocent Sikhs in Delhi and other India cities was also associated with this movement.
3. Electronic Structure of the Atom
• An atom has a dense, positively
charged nucleus surrounded by a
cloud of electrons.
• The electron density is highest at
the nucleus and drops off
exponentially with increasing
distance from the nucleus in
any direction.
5. The 2p Orbitals
• There are three 2p orbitals
oriented at right angles to
each other.
• Each p orbital consists of two
lobes.
• Each is labeled according to its
orientation along the x, y, or z
axis.
6. Isotopes
• Isotopes are atoms with the same number of protons but a different
number of neutrons.
• Mass number is the sum of the protons and neutrons in an atom.
C
12
6 6C
14
8. Electronic Configurations
• The aufbau principle states we must fill the lowest energy orbitals first.
• Hund’s rule states that when there are two or more orbitals of the same energy
(degenerate), electrons will go into different orbitals rather than pairing up in the same
orbital.
9. Ionic Bonding
• To obtain a noble gas configuration (a full valence shell), atoms may transfer electrons
from one atom to another.
• The atoms, now bearing opposite charges, attract each other, forming an ionic bond.
10. Covalent Bonding
• Electrons are shared between the atoms to complete the octet.
• When the electrons are shared evenly, the bond is said to be nonpolar
covalent, or pure covalent.
• When electrons are not shared evenly between the atoms, the resulting
bond will be polar covalent.
11. Lewis Structures
CH
CH4
4 NH
NH3
3
H
H2
2O Cl
O Cl2
2
Carbon: 4 e
4 H@1 e ea: 4 e
8 e
Nitrogen: 5 e
3 H@1 e ea: 3 e
8 e
Oxygen: 6 e
2 H@1 e ea: 2 e
8 e 2 Cl@7 e ea: 14 e
13. Nonbonding Electrons
• Also called lone pairs
• Nonbonding electrons are valence-shell electrons that are not shared
between atoms.
14. Multiple Bonding
• Sharing two pairs of electrons is called a double bond.
• Sharing three pairs of electrons is called a triple bond.
15. Electronegativity and Bond Polarity
• A bond with the electrons shared equally between two atoms is called a nonpolar
covalent bond. An unequally shared pair of bonding electrons is called a polar
covalent bond.
16. Dipole Moment
• Dipole moment is defined to be the amount of charge separation (d) multiplied by the
bond length (m).
• Charge separation is shown by an electrostatic potential map (EPM), where red
indicates a partially negative region and blue indicates a partially positive region.
17. Pauling Electronegativities
• Electronegativities can be used to predict whether a bond will be polar and also
predict the direction of its dipole moment.
• Since the electronegativities of carbon and hydrogen are similar, C—H bonds
are considered to be nonpolar.
18. Formal Charges
Formal charge = [group number ] – [nonbonding electrons ] – ½ [shared electrons]
H3O+ NO+
• Formal charges are a way of keeping track of electrons.
• They may or may not correspond to actual charges in the molecule.
21. Resonance Forms
• The structures of some compounds are not adequately represented by a single Lewis structure.
• Resonance forms are Lewis structures that can be interconverted by moving electrons only.
• The true structure will be a hybrid between the contributing resonance forms.
22. Resonance Forms
Resonance forms can be compared using the following criteria, beginning with
the most important:
1. Has as many octets as possible
2. Has as many bonds as possible
3. Has the negative charge on the most electronegative atom
4. Has as little charge separation as possible
23. Major and Minor Contributors
• The major contributor is the one in which all the atoms have a complete
octet of electrons.
24. Major and Minor Contributors (Continued)
• When both resonance forms obey the octet rule, the major contributor is
the one with the negative charge on the most electronegative atom.
The oxygen is more electronegative, so it
should have the negative charge.
25. Non-Equivalent Resonance
• Opposite charges should be on adjacent atoms.
The most stable one is the one with the smallest separation of oppositely charged atoms.
26. Solved Problem 2
Draw the important resonance forms for [CH3OCH2]+. Indicate which structure is the major and minor
contributor or whether they would have the same energy.
Solution
The first (minor) structure has a carbon atom with only six electrons around it. The second (major)
structure has octets on all atoms and an additional bond.
27. Solved Problem 3
Draw the resonance structures of the compound below. Indicate which structure is the major and minor
contributor or whether they would have the same energy.
Solution
Both of these structures have octets on oxygen and both carbon atoms, and they have the same number of
bonds. The first structure has the negative charge on carbon, the second on oxygen. Oxygen is the more
electronegative element, so the second structure is the major contributor.
28. Resonance Forms for the Acetate Ion
• When acetic acid loses a proton, the resulting acetate ion has a negative charge
delocalized over both oxygen atoms.
• Each oxygen atom bears half of the negative charge, and this delocalization stabilizes
the ion.
• Each of the carbon–oxygen bonds is halfway between a single bond and a double bond
and is said to have a bond order of 1½.
29. Condensed Structural Formulas
Lewis Condensed
• Condensed forms are written without showing all the individual bonds.
• Atoms bonded to the central atom are listed after the central atom (CH3CH3, not
H3CCH3).
• If there are two or more identical groups, parentheses and a subscript may be used to
represent them.
1 2
1 2
34. Line-Angle Drawings
• Sometimes called skeletal structure or stick figure.
• Bonds are represented by lines, and carbons are present where a line begins
or ends and where two lines meet.
• Hydrogens attached to carbon are not shown.
• Nitrogen, oxygen, and halides must be shown.
37. Effect of Resonance on pKa
• The molecular formula gives the number of atoms of each element in one molecule of a
compound
CH3CH2CH2CH2OH
butan-1-ol, molecular formula C4H10O
38. Calculating Empirical Formulas
The following are items that need to be considered when calculating
empirical formulas:
• Given % composition for each element, assume 100 g.
• Convert the grams of each element to moles.
• Divide by the smallest number of moles to get the ratio.
• The molecular formula may be a multiple of the empirical formula.
39. Wave Properties of Electrons
• Standing wave vibrates in a fixed location.
• Wave function, , is a mathematical description of size, shape, and orientation.
• Amplitude may be positive or negative.
• Node: Amplitude is zero.
40. Linear Combination of Atomic Orbitals
• Combining orbitals between two different atoms is bond formation.
• Combining orbitals on the same atom is hybridization.
• Conservation of orbitals
• Waves that are in phase add together.
Amplitude increases.
• Waves that are out of phase cancel out.
41. Sigma Bonding
• Electron density lies between the nuclei.
• A bond may be formed by s—s, p—p, s—p, or hybridized orbital overlaps.
• The bonding molecular orbital (MO) is lower in energy than the original
atomic orbitals.
• The antibonding MO is higher in energy than the atomic orbitals.
43. s-Bonding MO
Formation of a s-bonding MO: When the 1s orbitals of two hydrogen atoms overlap in
phase with each other, they interact constructively to form a bonding MO.
45. s*-Antibonding MO
Formation of a
s*-antibonding MO: When two
1s orbitals overlap out of phase,
they interact destructively to
form an antibonding MO.
47. Cl2: p—p Overlap
• When two p orbitals overlap along the line between the nuclei, a bonding orbital and an
antibonding orbital result.
• Most of the electron density is centered along the line between the nuclei.
• This linear overlap is another type of sigma bonding MO.
48. s and p Orbital Overlap
• Overlap of an s orbital with a p orbital gives a s-bonding MO and a s*-antibonding MO.
49. Pi Bonding and Antibonding
The sideways overlap of two parallel p orbitals leads to a p-bonding MO and a p*-
antibonding MO. A pi (p) bond is not as strong as most sigma bonds.
50. Multiple Bonds
• A double bond (two pairs of shared electrons) consists of a sigma bond and a pi bond.
• A triple bond (three pairs of shared electrons) consists of a sigma bond and two pi
bonds.
51. Molecular Shapes
• Bond angles cannot be explained with simple s and p orbitals.
• Valence-shell electron-pair repulsion theory (VSEPR) is used to explain the molecular shape
of molecules.
• Hybridized orbitals are lower in energy because electron pairs are farther apart.
52. sp Hybrid Orbitals
• Hybrid orbitals result when orbitals
in the same atom combine.
• Two orbitals (s and p) combine to
form two
sp orbitals.
• Linear electron pair geometry
• 180° bond angle
53. The Bonding of BeH2
• The bond angle in BeH2 is 180° and the geometry is linear.
54. sp2 Hybrid Orbitals
• Three orbitals (one s and two p) combine to form three sp2 orbitals.
• Trigonal planar geometry
• 120° bond angle
55. Solved Problem 1
Borane (BH3) is not stable under normal conditions, but it has been detected at low pressure. (a) Draw the Lewis structure for borane.
(b) Draw a diagram of the bonding in this molecule, and label the hybridization of each orbital. (c) Predict the H–B–H bond angle.
Solution
There are only six valence electrons in borane. Boron has a single bond to each of the three hydrogen atoms.
The best bonding orbitals are those that provide the greatest
electron density in the bonding region while keeping the three pairs
of bonding electrons as far apart as possible. Hybridization of an
s orbital with two p orbitals gives three sp2 hybrid orbitals directed
120° apart. Overlap of these orbitals with the hydrogen 1s orbitals
gives a planar, trigonal molecule. (Note that the small back lobes of
the hybrid orbitals have been omitted.)
56. sp3 Hybrid Orbitals
• Four orbitals (one s and three p) combine to form four sp3 orbitals.
• The atom has tetrahedral electron-pair geometry.
• 109.5° bond angle.
59. Solved Problem 2
Predict the hybridization of the nitrogen atom in ammonia, NH3. Draw a picture of the three-dimensional structure of ammonia,
and predict the bond angles.
Solution
The hybridization depends on the number of sigma bonds plus lone pairs. A Lewis structure provides this information.
In this structure, there are three sigma bonds and one pair of
nonbonding electrons. Four hybrid orbitals are required, implying sp3
hybridization and tetrahedral geometry around the nitrogen atom, with
bond angles slightly smaller than 109.5°.
60. Bonding in Ethylene
• Ethylene has three sigma bonds formed by its sp2 hybrid orbitals in a trigonal planar geometry.
• The unhybridized p orbital of one carbon is perpendicular to its sp2 hybrid orbitals, and it is parallel
to the unhybridized p orbital of the second carbon.
• Overlap of these two p orbitals will produce a pi bond (double bond) that is located above and
below the sigma bond.
62. Rotation in Single Bonds
Single bonds are allowed to rotate giving a variety of conformations.
63. Rotation Around Double Bonds
• Double bonds cannot rotate.
• Compounds that differ in how their substituents are arranged around the double bond can be
isolated and separated.
64. Isomerism
• Molecules that have the same molecular formula but differ in the
arrangement of their atoms are called isomers.
• Constitutional (or structural) isomers differ in their bonding sequence.
• Stereoisomers differ only in the arrangement of the atoms in space.
65. Constitutional Isomers
• Constitutional isomers have the same chemical formula, but the atoms are
connected in a different order.
• Constitutional isomers have different properties.
• The number of isomers increases rapidly as the number of carbon atoms
increases.
66. Geometric Isomers: Cis and Trans
• Stereoisomers are compounds with the atoms bonded in the same order, but their atoms
have different orientations in space.
• Cis and trans are examples of geometric stereoisomers; they occur when there is a double
bond in the compound.
• Since there is no free rotation along the carbon–carbon double bond, the groups on these
carbons can point to different places in space.