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VSEPR
Valence Shell Electron Pair Repulsion Theory
VSEPR
        Linear

        Bent or Angular

        Trigonal Planar

        Trigonal Pyramidal

        Tetrahedral

        Trigonal Bipyramidal

        Seesaw

        T-shape

        Octahedral

        Square Pyramidal

        Square Planar

        Pentagonal Bipyramidal
VSEPR


Legend:                        A

A = Central atom

X = Bonding pair

E = Lone pair
                    H O H
                      X    E
VSEPR
Linear
3 types

1)



2)



3)
VSEPR
1) Linear

           180º




    3-D structure                    VSEPR diagram


  Examples:
                                 GENERAL FORMULA:
  HF, O2
  (all diatomic molecules)
                                      AX1En
VSEPR
2) Linear


            180º




    3-D structure           VSEPR diagram


Examples:
                        GENERAL FORMULA:
BeCl2, HgCl2, CO2            AX2E0
VSEPR
3) Linear


                 180º




    3-D structure                  VSEPR diagram


     Examples:                  GENERAL FORMULA:
     XeF2, l3                       AX2E3
VSEPR
Angular or Bent
2 types

1)




2)
                  Overall look
VSEPR
1) Angular/Bent




       <120º
   3-D structure             VSEPR diagram



  Examples:                GENERAL FORMULA:
  NO2-, SO2, O3                 AX2E1
VSEPR
2) Angular/Bent




       <<109.5º

   3-D structure             VSEPR diagram


    Examples:              GENERAL FORMULA:
    OF2, H2O                   AX2E2
VSEPR
         Why are the bond angles different?




                            vs.



            <120º                      <<109.5º



A lone pair is less confined in space and exerts greater
repulsions on nearby bonding pairs.

As a result, bonding pairs are pushed farther away from
the lone pairs.
VSEPR
Trigonal planar
1 type

1)
VSEPR
Trigonal planar




                120º



     3-D structure                VSEPR diagram


Examples:                      GENERAL FORMULA:
BF3, NO3-,SO3, CO32-               AX3E0
VSEPR
Trigonal pyramidal
1 type

1)
VSEPR
Trigonal pyramidal




             <109.5º

    3-D structure                VSEPR diagram


    Examples:                  GENERAL FORMULA:
    NH3, PCl3                      AX3E1
VSEPR
Tetrahedral
1 type

1)
VSEPR
Tetrahedral



                      109.5º




      3-D structure                  VSEPR diagram


Examples:                          GENERAL FORMULA:
CH4, PO43-, SO42-, ClO4-               AX4E0
VSEPR
Trigonal bipyramidal
1 type

1)
VSEPR
Trigonal bipyramidal


       90º

                     120º


     120º


     3-D structure             VSEPR diagram


Example:                     GENERAL FORMULA:
PCl5                             AX5E0
VSEPR
Seesaw
1 type

1)
VSEPR
Seesaw




   90º


           <120º
      3-D structure             VSEPR diagram


Example:                      GENERAL FORMULA:
SF4                               AX4E1
VSEPR
T-shape
1 type

1)
VSEPR
T-shape




     90º




     3-D structure             VSEPR diagram


Examples:                    GENERAL FORMULA:
ClF3, BrF3                       AX3E2
VSEPR
Octahedral
1 type

1)
VSEPR
Octahedral




                     90º
     90º



     3-D structure              VSEPR diagram


Examples:                     GENERAL FORMULA:
SF6, WCl6                         AX6E0
VSEPR
Square pyramidal
1 type

1)
VSEPR
Square pyramidal


                 <90º



                        90º




     3-D structure                VSEPR diagram


Examples:                       GENERAL FORMULA:
ClF5, BrF6, XeOF4                   AX5E1
VSEPR
Square planar
1 type

1)
VSEPR
Square planar




                     90º




     3-D structure             VSEPR diagram


Example:                     GENERAL FORMULA:
XeF4                             AX4E2
VSEPR
Pentagonal bipyramidal
1 type

1)
VSEPR
Pentagonal bipyramidal


 72º




                 90º



       3-D structure             VSEPR diagram


Example:                       GENERAL FORMULA:
IF7                                AX7E0

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Tang 06 vsepr

Editor's Notes

  1. http://www.youtube.com/watch?v=rMIPyOuQu08&amp;feature=related