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08/04/2016
5. Electricity & Chemistry
Syllabus statements
Statements from Cambridge IGCSE Chemistry syllabus 0620 (for exams in 2016 – 2018)
Electricity & Chemistry
• Define electrolysis as the breakdown of an ionic
compound, molten or in aqueous solution, by the
passage of electricity
• Describe the electrode products and the
observations made during the electrolysis of:
– molten lead(II) bromide
– concentrated hydrochloric acid
– concentrated aqueous sodium chloride
– dilute sulfuric acid
between inert electrodes (platinum or carbon)
Electricity & Chemistry
• State the general principle that metals or hydrogen
are formed at the negative electrode (cathode), and
that non-metals (other than hydrogen) are formed
at the positive electrode (anode)
• Relate the products of electrolysis to the electrolyte
and electrodes used, exemplified by the specific
examples above, together with aqueous copper(II)
sulfate using carbon electrodes and using copper
electrodes (as used in the refining of copper)
Electricity & Chemistry
• Describe electrolysis in terms of the ions present
and reactions at the electrodes in the examples
given
• Construct ionic half-equations for reactions at the
cathode
• Predict the products of the electrolysis of a
specified binary compound in the molten state
• Predict the products of electrolysis of a specified
halide in dilute or concentrated aqueous solution
Electricity & Chemistry
• Describe the electroplating of metals
• Outline the uses of electroplating
• Describe the reasons for the use of copper and
(steel-cored) aluminium in cables, and why
plastics and ceramics are used as insulators
Electricity & Chemistry
• Describe the transfer of charge during electrolysis
to include:
– the movement of electrons in the metallic
conductor
– the removal or addition of electrons from the
external circuit at the electrodes
– the movement of ions in the electrolyte
Electricity & Chemistry
• Describe the production of electrical energy from
simple cells, i.e. two electrodes in an electrolyte.
(This should be linked with the reactivity series in
section 10.2 and redox in section 7.4.)
Electricity & Chemistry
• Describe, in outline, the manufacture of:
– aluminium from pure aluminium oxide in
molten cryolite (refer to section 10.3)
– chlorine, hydrogen and sodium hydroxide from
concentrated aqueous sodium chloride
(Starting materials and essential conditions should
be given but not technical details or diagrams.)

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Topic 5 syllabus statements

  • 1. 08/04/2016 5. Electricity & Chemistry Syllabus statements Statements from Cambridge IGCSE Chemistry syllabus 0620 (for exams in 2016 – 2018)
  • 2. Electricity & Chemistry • Define electrolysis as the breakdown of an ionic compound, molten or in aqueous solution, by the passage of electricity • Describe the electrode products and the observations made during the electrolysis of: – molten lead(II) bromide – concentrated hydrochloric acid – concentrated aqueous sodium chloride – dilute sulfuric acid between inert electrodes (platinum or carbon)
  • 3. Electricity & Chemistry • State the general principle that metals or hydrogen are formed at the negative electrode (cathode), and that non-metals (other than hydrogen) are formed at the positive electrode (anode) • Relate the products of electrolysis to the electrolyte and electrodes used, exemplified by the specific examples above, together with aqueous copper(II) sulfate using carbon electrodes and using copper electrodes (as used in the refining of copper)
  • 4. Electricity & Chemistry • Describe electrolysis in terms of the ions present and reactions at the electrodes in the examples given • Construct ionic half-equations for reactions at the cathode • Predict the products of the electrolysis of a specified binary compound in the molten state • Predict the products of electrolysis of a specified halide in dilute or concentrated aqueous solution
  • 5. Electricity & Chemistry • Describe the electroplating of metals • Outline the uses of electroplating • Describe the reasons for the use of copper and (steel-cored) aluminium in cables, and why plastics and ceramics are used as insulators
  • 6. Electricity & Chemistry • Describe the transfer of charge during electrolysis to include: – the movement of electrons in the metallic conductor – the removal or addition of electrons from the external circuit at the electrodes – the movement of ions in the electrolyte
  • 7. Electricity & Chemistry • Describe the production of electrical energy from simple cells, i.e. two electrodes in an electrolyte. (This should be linked with the reactivity series in section 10.2 and redox in section 7.4.)
  • 8. Electricity & Chemistry • Describe, in outline, the manufacture of: – aluminium from pure aluminium oxide in molten cryolite (refer to section 10.3) – chlorine, hydrogen and sodium hydroxide from concentrated aqueous sodium chloride (Starting materials and essential conditions should be given but not technical details or diagrams.)