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Semiconductor
For information on devices using semiconductors and
their history, see semiconductor device. For other uses,
see Semiconductor (disambiguation).
A semiconductor material has an electrical conductiv-
ity value between a conductor, such as copper, and an
insulator, such as glass. Semiconductors are the founda-
tion of modern electronics. The modern understanding
of the properties of a semiconductor relies on quantum
physics to explain the movement of electrons and holes
in a crystal lattice. An increased knowledge of semicon-
ductor materials and fabrication processes has made pos-
sible continuing increases in the complexity and speed of
microprocessors and memory devices.
The electrical conductivity of a semiconductor mate-
rial increases with increasing temperature, which is be-
haviour opposite to that of a metal. Semiconductor de-
vices can display a range of useful properties such as pass-
ing current more easily in one direction than the other,
showing variable resistance, and sensitivity to light or
heat. Because the electrical properties of a semiconduc-
tor material can be modiļ¬ed by controlled addition of im-
purities, or by the application of electrical ļ¬elds or light,
devices made from semiconductors can be used for am-
pliļ¬cation, switching, and energy conversion.
Current conduction in a semiconductor occurs through
the movement of free electrons and ā€œholesā€, collectively
known as charge carriers. Adding impurity atoms to a
semiconducting material, known as "doping", greatly in-
creases the number of charge carriers within it. When
a doped semiconductor contains mostly free holes it is
called ā€œp-typeā€, and when it contains mostly free elec-
trons it is known as ā€œn-typeā€. The semiconductor mate-
rials used in electronic devices are doped under precise
conditions to control the location and concentration of p-
and n-type dopants. A single semiconductor crystal can
have many p- and n-type regions; the pā€“n junctions be-
tween these regions are responsible for the useful elec-
tronic behaviour.
Some of the properties of semiconductor materials were
observed throughout the mid 19th and ļ¬rst decades of
the 20th century. Development of quantum physics in
turn allowed the development of the transistor in 1948.
Although some pure elements and many compounds dis-
play semiconductor properties, silicon, germanium, and
compounds of gallium are the most widely used in elec-
tronic devices.
1 Properties
Variable conductivity A pure semiconductor is a poor
electrical conductor as a consequence of having just
the right number of electrons to completely ļ¬ll its
valence bonds. Through various techniques (e.g.,
doping or gating), the semiconductor can be mod-
iļ¬ed to have an excess of electrons (becoming an
n-type semiconductor) or a deļ¬ciency of electrons
(becoming a p-type semiconductor). In both
cases, the semiconductor becomes much more con-
ductive (the conductivity can be increased by one
million fold or more). Semiconductor devices ex-
ploit this eļ¬€ect to shape electrical current.
Depletion When doped semiconductors are joined to
metals, to diļ¬€erent semiconductors, and to the same
semiconductor with diļ¬€erent doping, the resulting
junction often strips the electron excess or deļ¬-
ciency out from the semiconductor near the junc-
tion. This depletion region is rectifying (only allow-
ing current to ļ¬‚ow in one direction), and used to fur-
ther shape electrical currents in semiconductor de-
vices.
Energetic electrons travel far Electrons can be excited
across the energy band gap (see Physics below) of a
semiconductor by various means. These electrons
can carry their excess energy over distance scales
of micrometers before dissipating their energy into
heat ā€“ a signiļ¬cantly longer distance than is possible
in metals. This property is essential to the operation
of, e. g., bipolar junction transistors and solar cells.
Light emission In certain semiconductors, excited elec-
trons can relax by emitting light instead of produc-
ing heat. These semiconductors are used in the
construction of light emitting diodes and ļ¬‚uorescent
quantum dots.
Thermal energy conversion Semiconductors have
large thermoelectric power factors making them
useful in thermoelectric generators, as well as high
thermoelectric ļ¬gures of merit making them useful
in thermoelectric coolers.
2 Materials
Main article: List of semiconductor materials
A large number of elements and compounds have semi-
1
2 3 PHYSICS OF SEMICONDUCTORS
Silicon crystals are the most common semiconducting materials
used in microelectronics and photovoltaics.
conducting properties, including:[1]
ā€¢ Certain pure elements are found in Group XIV of
the periodic table; the most commercially important
of these elements are silicon and germanium. Sil-
icon and germanium are used here eļ¬€ectively be-
cause they have 4 valence electrons in their outer-
most shell which gives them the ability to gain or
lose electrons equally at the same time.
ā€¢ Binary compounds, particularly between elements in
Groups III and V, such as gallium arsenide, Groups
II and VI, groups IV and VI, and between diļ¬€erent
group IV elements, e.g. silicon carbide.
ā€¢ Certain ternary compounds, oxides and alloys.
ā€¢ Organic semiconductors, made of organic com-
pounds.
Most common semiconducting materials are crystalline
solids, but amorphous and liquid semiconductors are also
known. These include hydrogenated amorphous silicon
and mixtures of arsenic, selenium and tellurium in a va-
riety of proportions. These compounds share with bet-
ter known semiconductors the properties of intermedi-
ate conductivity and a rapid variation of conductivity
with temperature, as well as occasional negative resis-
tance. Such disordered materials lack the rigid crystalline
structure of conventional semiconductors such as silicon.
They are generally used in thin ļ¬lm structures, which do
not require material of higher electronic quality, being
relatively insensitive to impurities and radiation damage.
2.1 Preparation of semiconductor materi-
als
Semiconductors with predictable, reliable electronic
properties are necessary for mass production. The level
of chemical purity needed is extremely high because the
presence of impurities even in very small proportions
can have large eļ¬€ects on the properties of the material.
A high degree of crystalline perfection is also required,
since faults in crystal structure (such as dislocations,
twins, and stacking faults) interfere with the semicon-
ducting properties of the material. Crystalline faults are
a major cause of defective semiconductor devices. The
larger the crystal, the more diļ¬ƒcult it is to achieve the
necessary perfection. Current mass production processes
use crystal ingots between 100 and 300 mm (4 and 10 in)
in diameter which are grown as cylinders and sliced into
wafers.
Because of the required level of chemical purity and the
perfection of the crystal structure which are needed to
make semiconductor devices, special methods have been
developed to produce the initial semiconductor material.
A technique for achieving high purity includes growing
the crystal using the Czochralski process. An additional
step that can be used to further increase purity is known
as zone reļ¬ning. In zone reļ¬ning, part of a solid crystal is
melted. The impurities tend to concentrate in the melted
region, while the desired material recrystalizes leaving the
solid material more pure and with fewer crystalline faults.
In manufacturing semiconductor devices involving
heterojunctions between diļ¬€erent semiconductor ma-
terials, it is often important to align the crystal lattices
of the two materials by using epitaxial techniques.
The lattice constant, which is the length of the repeat-
ing element of the crystal structure, is important for
determining the compatibility of materials.
3 Physics of semiconductors
3.1 Energy bands and electrical conduc-
tion
Main articles: Electronic band structure and Electrical
conduction
Semiconductors are deļ¬ned by their unique electric con-
ductive behavior, somewhere between that of a metal and
an insulator. The diļ¬€erences between these materials can
be understood in terms of the quantum states for elec-
trons, each of which may contain zero or one electron (by
the Pauli exclusion principle). These states are associ-
ated with the electronic band structure of the material.
Electrical conductivity arises due to the presence of elec-
trons in states that are delocalized (extending through the
material), however in order to transport electrons a state
must be partially ļ¬lled, containing an electron only part
3.2 Charge carriers (electrons and holes) 3
Filling of the electronic Density of states in various types of ma-
terials at equilibrium. Here the vertical axis is energy while the
horizontal axis is the Density of states for a particular band in
the material listed. In metals and semimetals the Fermi level EF
lies inside at least one band. In insulators and semiconductors
the Fermi level is inside a band gap; however, in semiconduc-
tors the bands are near enough to the Fermi level to be thermally
populated with electrons or holes.
of the time.[2]
If the state is always occupied with an elec-
tron, then it is inert, blocking the passage of other elec-
trons via that state. The energies of these quantum states
are critical, since a state is partially ļ¬lled only if its energy
is near the Fermi level (see Fermiā€“Dirac statistics).
High conductivity in a material comes from it having
many partially ļ¬lled states and much state delocalization.
Metals are good electrical conductors and have many par-
tially ļ¬lled states with energies near their Fermi level.
Insulators, by contrast, have few partially ļ¬lled states,
their Fermi levels sit within band gaps with few energy
states to occupy. Importantly, an insulator can be made
to conduct by increasing its temperature: heating pro-
vides energy to promote some electrons across the band
gap, inducing partially ļ¬lled states in both the band of
states beneath the band gap (valence band) and the band
of states above the band gap (conduction band). An (in-
trinsic) semiconductor has a band gap that is smaller than
that of an insulator and at room temperature signiļ¬cant
numbers of electrons can be excited to cross the band
gap.[3]
A pure semiconductor, however, is not very useful, as it is
neither a very good insulator nor a very good conductor.
However, one important feature of semiconductors (and
some insulators, known as semi-insulators) is that their
conductivity can be increased and controlled by doping
with impurities and gating with electric ļ¬elds. Doping
and gating move either the conduction or valence band
much closer to the Fermi level, and greatly increase the
number of partially ļ¬lled states.
Some wider-band gap semiconductor materials are some-
times referred to as semi-insulators. When undoped,
these have electrical conductivity nearer to that of elec-
trical insulators, however they can be doped (making
them as useful as semiconductors). Semi-insulators ļ¬nd
niche applications in micro-electronics, such as substrates
for HEMT. An example of a common semi-insulator
is gallium arsenide.[4]
Some materials, such as titanium
dioxide, can even be used as insulating materials for some
applications, while being treated as wide-gap semicon-
ductors for other applications.
3.2 Charge carriers (electrons and holes)
Main article: Electron hole
The partial ļ¬lling of the states at the bottom of the con-
duction band can be understood as adding electrons to
that band. The electrons do not stay indeļ¬nitely (due
to the natural thermal recombination) but they can move
around for some time. The actual concentration of elec-
trons is typically very dilute, and so (unlike in metals)
it is possible to think of the electrons in the conduction
band of a semiconductor as a sort of classical ideal gas,
where the electrons ļ¬‚y around freely without being sub-
ject to the Pauli exclusion principle. In most semicon-
ductors the conduction bands have a parabolic dispersion
relation, and so these electrons respond to forces (elec-
tric ļ¬eld, magnetic ļ¬eld, etc.) much like they would in
a vacuum, though with a diļ¬€erent eļ¬€ective mass.[3]
Be-
cause the electrons behave like an ideal gas, one may also
think about conduction in very simplistic terms such as
the Drude model, and introduce concepts such as electron
mobility.
For partial ļ¬lling at the top of the valence band, it is
helpful to introduce the concept of an electron hole. Al-
though the electrons in the valence band are always mov-
ing around, a completely full valence band is inert, not
conducting any current. If an electron is taken out of the
valence band, then the trajectory that the electron would
normally have taken is now missing its charge. For the
purposes of electric current, this combination of the full
valence band, minus the electron, can be converted into
a picture of a completely empty band containing a posi-
tively charged particle that moves in the same way as the
electron. Combined with the negative eļ¬€ective mass of
the electrons at the top of the valence band, we arrive
at a picture of a positively charged particle that responds
to electric and magnetic ļ¬elds just as a normal positively
charged particle would do in vacuum, again with some
positive eļ¬€ective mass.[3]
This particle is called a hole,
and the collection of holes in the valence can again be un-
derstood in simple classical terms (as with the electrons
in the conduction band).
3.2.1 Carrier generation and recombination
Main article: Carrier generation and recombination
When ionizing radiation strikes a semiconductor, it may
excite an electron out of its energy level and consequently
leave a hole. This process is known as electronā€“hole pair
generation. Electron-hole pairs are constantly generated
4 4 EARLY HISTORY OF SEMICONDUCTORS
from thermal energy as well, in the absence of any exter-
nal energy source.
Electron-hole pairs are also apt to recombine.
Conservation of energy demands that these recom-
bination events, in which an electron loses an amount of
energy larger than the band gap, be accompanied by the
emission of thermal energy (in the form of phonons) or
radiation (in the form of photons).
In some states, the generation and recombination of
electronā€“hole pairs are in equipoise. The number of
electron-hole pairs in the steady state at a given tempera-
ture is determined by quantum statistical mechanics. The
precise quantum mechanical mechanisms of generation
and recombination are governed by conservation of en-
ergy and conservation of momentum.
As the probability that electrons and holes meet together
is proportional to the product of their amounts, the prod-
uct is in steady state nearly constant at a given temper-
ature, providing that there is no signiļ¬cant electric ļ¬eld
(which might ā€œļ¬‚ushā€ carriers of both types, or move them
from neighbour regions containing more of them to meet
together) or externally driven pair generation. The prod-
uct is a function of the temperature, as the probability of
getting enough thermal energy to produce a pair increases
with temperature, being approximately exp(āˆ’EG/kT),
where k is Boltzmannā€™s constant, T is absolute temper-
ature and EG is band gap.
The probability of meeting is increased by carrier trapsā€”
impurities or dislocations which can trap an electron or
hole and hold it until a pair is completed. Such carrier
traps are sometimes purposely added to reduce the time
needed to reach the steady state.
3.3 Doping
Main article: Doping (semiconductor)
The conductivity of semiconductors may easily be mod-
iļ¬ed by introducing impurities into their crystal lattice.
The process of adding controlled impurities to a semicon-
ductor is known as doping. The amount of impurity, or
dopant, added to an intrinsic (pure) semiconductor varies
its level of conductivity. Doped semiconductors are re-
ferred to as extrinsic. By adding impurity to the pure
semiconductors, the electrical conductivity may be var-
ied by factors of thousands or millions.
A 1 cm3
specimen of a metal or semiconductor has of the
order of 1022
atoms. In a metal, every atom donates at
least one free electron for conduction, thus 1 cm3
of metal
contains on the order of 1022
free electrons, whereas a 1
cm3
sample of pure germanium at 20 Ā°C contains about
4.2Ɨ1022
atoms, but only 2.5Ɨ1013
free electrons and
2.5Ɨ1013
holes. The addition of 0.001% of arsenic (an
impurity) donates an extra 1017
free electrons in the same
volume and the electrical conductivity is increased by a
factor of 10,000.
The materials chosen as suitable dopants depend on the
atomic properties of both the dopant and the material
to be doped. In general, dopants that produce the de-
sired controlled changes are classiļ¬ed as either electron
acceptors or donors. Semiconductors doped with donor
impurities are called n-type, while those doped with ac-
ceptor impurities are known as p-type. The n and p type
designations indicate which charge carrier acts as the ma-
terialā€™s majority carrier. The opposite carrier is called the
minority carrier, which exists due to thermal excitation
at a much lower concentration compared to the majority
carrier.
For example, the pure semiconductor silicon has four va-
lence electrons which bond each silicon atom to its neigh-
bors. In silicon, the most common dopants are group III
and group V elements. Group III elements all contain
three valence electrons, causing them to function as ac-
ceptors when used to dope silicon. When an acceptor
atom replaces a silicon atom in the crystal, a vacant state
( an electron ā€œholeā€) is created, which can move around
the lattice and functions as a charge carrier. Group V
elements have ļ¬ve valence electrons, which allows them
to act as a donor; substitution of these atoms for sili-
con creates an extra free electron. Therefore, a silicon
crystal doped with boron creates a p-type semiconductor
whereas one doped with phosphorus results in an n-type
material.
During manufacture, dopants can be diļ¬€used into the
semiconductor body by contact with gaseous compounds
of the desired element, or ion implantation can be used
to accurately position the doped regions.
4 Early history of semiconductors
Further information: Timeline of electrical and elec-
tronic engineering
The history of the understanding of semiconductors be-
gins with experiments on the electrical properties of ma-
terials. The properties of negative temperature coeļ¬ƒ-
cient of resistance, rectiļ¬cation, and light-sensitivity were
observed starting in the early 19th century.
In 1833, Michael Faraday reported that the resistance
of specimens of silver sulļ¬de decreases when they are
heated. This is contrary to the behavior of metallic sub-
stances such as copper. In 1839, A. E. Becquerel reported
observation of a voltage between a solid and a liquid elec-
trolyte when struck by light, the photovoltaic eļ¬€ect. In
1873 Willoughby Smith observed that selenium resistors
exhibit decreasing resistance when light falls on them.
In 1874 Karl Ferdinand Braun observed conduction and
rectiļ¬cation in metallic sulphides, and Arthur Schuster
found that a copper oxide layer on wires has rectiļ¬cation
properties that ceases when the wires are cleaned. Adams
5
and Day observed the photovoltaic eļ¬€ect in selenium in
1876.[5]
A uniļ¬ed explanation of these phenomena required a the-
ory of solid-state physics which developed greatly in the
ļ¬rst half of the 20th Century. In 1878 Edwin Herbert
Hall demonstrated the deļ¬‚ection of ļ¬‚owing charge carri-
ers by an applied magnetic ļ¬eld, the Hall eļ¬€ect. The dis-
covery of the electron by J.J. Thomson in 1897 prompted
theories of electron-based conduction in solids. Karl
Baedeker, by observing a Hall eļ¬€ect with the reverse
sign to that in metals, theorized that copper iodide had
positive charge carriers. Johan Koenigsberger classiļ¬ed
solid materials as metals, insulators and ā€œvariable con-
ductorsā€ in 1914. Felix Bloch published a theory of the
movement of electrons through atomic lattices in 1928.
In 1930, B. Gudden stated that conductivity in semicon-
ductors was due to minor concentrations of impurities.
By 1931, the band theory of conduction had been estab-
lished by Alan Herries Wilson and the concept of band
gaps had been developed. Walter H. Schottky and Nevill
Francis Mott developed models of the potential barrier
and of the characteristics of a metal-semiconductor junc-
tion. By 1938, Boris Davydov had developed a theory of
the copper-oxide rectifer, identifying the eļ¬€ect of the pā€“
n junction and the importance of minority carriers and
surface states.[6]
Agreement between theoretical predictions (based on de-
veloping quantum mechanics) and experimental results
was sometimes poor. This was later explained by John
Bardeen as due to the extreme ā€œstructure sensitiveā€ be-
havior of semiconductors, whose properties change dra-
matically based on tiny amounts of impurities.[6]
Com-
mercially pure materials of the 1920s containing varying
proportions of trace contaminants produced diļ¬€ering ex-
perimental results. This spurred the development of im-
proved material reļ¬ning techniques, culminating in mod-
ern semiconductor reļ¬neries producing materials with
parts-per-trillion purity.
Devices using semiconductors were at ļ¬rst constructed
based on empirical knowledge, before semiconductor
theory provided a guide to construction of more capable
and reliable devices.
Alexander Graham Bell used the light-sensitive property
of selenium to transmit sound over a beam of light in
1880. A working solar cell, of low eļ¬ƒciency, was con-
structed by Charles Fritts in 1883 using a metal plate
coated with selenium and a thin layer of gold; the device
became commercially useful in photographic light meters
in the 1930s.[6]
Point-contact microwave detector recti-
ļ¬ers made of lead sulļ¬de were used by Jagadish Chan-
dra Bose in 1904; the catā€™s-whisker detector using natu-
ral galena or other materials became a common device
in the development of radio. However, it was somewhat
unpredictable in operation and required manual adjust-
ment for best performance. In 1906 H.J. Round observed
light emission when electric current passed through sili-
con carbide crystals, the principle behind the light emit-
ting diode. Oleg Losev observed similar light emission
in 1922 but at the time the eļ¬€ect had no practical use.
Power rectiļ¬ers, using copper oxide and selenium, were
developed in the 1920s and became commercially impor-
tant as an alternative to vacuum tube rectiļ¬ers.[5][6]
In the years preceding World War II, infra-red detec-
tion and communications devices prompted research into
lead-sulļ¬de and lead-selenide materials. These devices
were used for detecting ships and aircraft, for infrared
rangeļ¬nders, and for voice communication systems. The
point-contact crystal detector became vital for microwave
radio systems, since available vacuum tube devices could
not serve as detectors above about 4000 MHz; advanced
radar systems relied on the fast response of crystal detec-
tors. Considerable research and development of silicon
materials occurred during the war to develop detectors
of consistent quality.[6]
Detector and power rectiļ¬ers could not amplify a signal.
Many eļ¬€orts were made to develop a solid-state ampli-
ļ¬er, but these were unsuccessful because of limited the-
oretical understanding of semiconductor materials.[6]
In
1922 Oleg Losev developed two-terminal, negative re-
sistance ampliļ¬ers for radio; however, he perished in
the Siege of Leningrad. In 1926 Julius Edgar Lilien-
feld patented a device resembling a modern ļ¬eld-eļ¬€ect
transistor, but it was not practical. R. Hilsch and R. W.
Pohl in 1938 demonstrated a solid-state ampliļ¬er using a
structure resembling the control grid of a vacuum tube;
although the device displayed power gain, it had a cut-
oļ¬€ frequency of one cycle per second, too low for any
practical applications, but an eļ¬€ective application of the
available theory.[6]
At Bell Labs, William Shockley and
A. Holden started investigating solid-state ampliļ¬ers in
1938. The ļ¬rst pā€“n junction in silicon was observed by
Russell Ohl about 1941, when a specimen was found to
be light-sensitive, with a sharp boundary between p-type
impurity at one end and n-type at the other. A slice cut
from the specimen at the pā€“n boundary developed a volt-
age when exposed to light.
In France, during the war, Herbert MatarƩ had observed
ampliļ¬cation between adjacent point contacts on a ger-
manium base. After the war, MatarƩ's group announced
their "Transistron" ampliļ¬er only shortly after Bell Labs
announced the "transistor".
5 See also
ā€¢ Semiconductor industry ā€” The 300 billion dollar
sector of the worldā€™s economy that designs and man-
ufactures semiconductor devices.
ā€¢ Semiconductor characterization techniques ā€” A
wide variety of techniques are used to analyze the
properties of semiconductors.
6 8 EXTERNAL LINKS
6 References
[1] B.G. Yacobi, Semiconductor Materials: An Introduction to
Basic Principles, Springer 2003 ISBN 0306473615, pp.
1ā€“3
[2] As in the Mott formula for conductivity, see Cut-
ler, M.; Mott, N. (1969). ā€œObservation of Ander-
son Localization in an Electron Gasā€. Physical Re-
view 181 (3): 1336. Bibcode:1969PhRv..181.1336C.
doi:10.1103/PhysRev.181.1336.
[3] Charles Kittel (1995) Introduction to Solid State Physics,
7th ed. Wiley, ISBN 0471111813.
[4] J. W. Allen (1960). ā€œGallium Arsenide as a
semi-insulatorā€. Nature 187 (4735): 403ā€“405.
Bibcode:1960Natur.187..403A. doi:10.1038/187403b0.
[5] Lidia Łukasiak and Andrzej Jakubowski (January 2010).
ā€œHistory of Semiconductorsā€. Journal of Telecommuni-
cation and Information Technology: 3.
[6] Peter Robin Morris (1990) A History of the World Semi-
conductor Industry, IET, ISBN 0863412270, pp. 11ā€“25
7 Further reading
ā€¢ A. A. Balandin and K. L. Wang (2006). Hand-
book of Semiconductor Nanostructures and Nanode-
vices (5-Volume Set). American Scientiļ¬c Publish-
ers. ISBN 1-58883-073-X.
ā€¢ Sze, Simon M. (1981). Physics of Semiconductor
Devices (2nd ed.). John Wiley and Sons (WIE).
ISBN 0-471-05661-8.
ā€¢ Turley, Jim (2002). The Essential Guide to Semicon-
ductors. Prentice Hall PTR. ISBN 0-13-046404-X.
ā€¢ Yu, Peter Y.; Cardona, Manuel (2004). Fundamen-
tals of Semiconductors : Physics and Materials Prop-
erties. Springer. ISBN 3-540-41323-5.
ā€¢ Sadao Adachi (2012). The Handbook on Optical
Constants of Semiconductors: In Tables and Fig-
ures. World Scientiļ¬c Publishing. ISBN 9-789-
81440597-3.
8 External links
ā€¢ Howstuļ¬€worksā€™ semiconductor page
ā€¢ Semiconductor Concepts at Hyperphysics
ā€¢ Calculator for the intrinsic carrier concentration in
silicon
ā€¢ Semiconductor OneSource Hall of Fame, Glossary
ā€¢ Principles of Semiconductor Devices by Bart Van
Zeghbroeck, University of Colorado. An online
textbook]
ā€¢ US Navy Electrical Engineering Training Series
ā€¢ NSM-Archive Physical Properties of Semiconduc-
tors]
ā€¢ Semiconductor Manufacturer List
ā€¢ ABACUS : Introduction to Semiconductor Devices
ā€“ by Gerhard Klimeck and Dragica Vasileska, online
learning resource with simulation tools on nanoHUB
ā€¢ Organic Semiconductor page
ā€¢ DoITPoMS Teaching and Learning Package- ā€œIn-
troduction to Semiconductorsā€
ā€¢ Semiconductor R&D Talent Locations report
7
9 Text and image sources, contributors, and licenses
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Semiconductor

  • 1. Semiconductor For information on devices using semiconductors and their history, see semiconductor device. For other uses, see Semiconductor (disambiguation). A semiconductor material has an electrical conductiv- ity value between a conductor, such as copper, and an insulator, such as glass. Semiconductors are the founda- tion of modern electronics. The modern understanding of the properties of a semiconductor relies on quantum physics to explain the movement of electrons and holes in a crystal lattice. An increased knowledge of semicon- ductor materials and fabrication processes has made pos- sible continuing increases in the complexity and speed of microprocessors and memory devices. The electrical conductivity of a semiconductor mate- rial increases with increasing temperature, which is be- haviour opposite to that of a metal. Semiconductor de- vices can display a range of useful properties such as pass- ing current more easily in one direction than the other, showing variable resistance, and sensitivity to light or heat. Because the electrical properties of a semiconduc- tor material can be modiļ¬ed by controlled addition of im- purities, or by the application of electrical ļ¬elds or light, devices made from semiconductors can be used for am- pliļ¬cation, switching, and energy conversion. Current conduction in a semiconductor occurs through the movement of free electrons and ā€œholesā€, collectively known as charge carriers. Adding impurity atoms to a semiconducting material, known as "doping", greatly in- creases the number of charge carriers within it. When a doped semiconductor contains mostly free holes it is called ā€œp-typeā€, and when it contains mostly free elec- trons it is known as ā€œn-typeā€. The semiconductor mate- rials used in electronic devices are doped under precise conditions to control the location and concentration of p- and n-type dopants. A single semiconductor crystal can have many p- and n-type regions; the pā€“n junctions be- tween these regions are responsible for the useful elec- tronic behaviour. Some of the properties of semiconductor materials were observed throughout the mid 19th and ļ¬rst decades of the 20th century. Development of quantum physics in turn allowed the development of the transistor in 1948. Although some pure elements and many compounds dis- play semiconductor properties, silicon, germanium, and compounds of gallium are the most widely used in elec- tronic devices. 1 Properties Variable conductivity A pure semiconductor is a poor electrical conductor as a consequence of having just the right number of electrons to completely ļ¬ll its valence bonds. Through various techniques (e.g., doping or gating), the semiconductor can be mod- iļ¬ed to have an excess of electrons (becoming an n-type semiconductor) or a deļ¬ciency of electrons (becoming a p-type semiconductor). In both cases, the semiconductor becomes much more con- ductive (the conductivity can be increased by one million fold or more). Semiconductor devices ex- ploit this eļ¬€ect to shape electrical current. Depletion When doped semiconductors are joined to metals, to diļ¬€erent semiconductors, and to the same semiconductor with diļ¬€erent doping, the resulting junction often strips the electron excess or deļ¬- ciency out from the semiconductor near the junc- tion. This depletion region is rectifying (only allow- ing current to ļ¬‚ow in one direction), and used to fur- ther shape electrical currents in semiconductor de- vices. Energetic electrons travel far Electrons can be excited across the energy band gap (see Physics below) of a semiconductor by various means. These electrons can carry their excess energy over distance scales of micrometers before dissipating their energy into heat ā€“ a signiļ¬cantly longer distance than is possible in metals. This property is essential to the operation of, e. g., bipolar junction transistors and solar cells. Light emission In certain semiconductors, excited elec- trons can relax by emitting light instead of produc- ing heat. These semiconductors are used in the construction of light emitting diodes and ļ¬‚uorescent quantum dots. Thermal energy conversion Semiconductors have large thermoelectric power factors making them useful in thermoelectric generators, as well as high thermoelectric ļ¬gures of merit making them useful in thermoelectric coolers. 2 Materials Main article: List of semiconductor materials A large number of elements and compounds have semi- 1
  • 2. 2 3 PHYSICS OF SEMICONDUCTORS Silicon crystals are the most common semiconducting materials used in microelectronics and photovoltaics. conducting properties, including:[1] ā€¢ Certain pure elements are found in Group XIV of the periodic table; the most commercially important of these elements are silicon and germanium. Sil- icon and germanium are used here eļ¬€ectively be- cause they have 4 valence electrons in their outer- most shell which gives them the ability to gain or lose electrons equally at the same time. ā€¢ Binary compounds, particularly between elements in Groups III and V, such as gallium arsenide, Groups II and VI, groups IV and VI, and between diļ¬€erent group IV elements, e.g. silicon carbide. ā€¢ Certain ternary compounds, oxides and alloys. ā€¢ Organic semiconductors, made of organic com- pounds. Most common semiconducting materials are crystalline solids, but amorphous and liquid semiconductors are also known. These include hydrogenated amorphous silicon and mixtures of arsenic, selenium and tellurium in a va- riety of proportions. These compounds share with bet- ter known semiconductors the properties of intermedi- ate conductivity and a rapid variation of conductivity with temperature, as well as occasional negative resis- tance. Such disordered materials lack the rigid crystalline structure of conventional semiconductors such as silicon. They are generally used in thin ļ¬lm structures, which do not require material of higher electronic quality, being relatively insensitive to impurities and radiation damage. 2.1 Preparation of semiconductor materi- als Semiconductors with predictable, reliable electronic properties are necessary for mass production. The level of chemical purity needed is extremely high because the presence of impurities even in very small proportions can have large eļ¬€ects on the properties of the material. A high degree of crystalline perfection is also required, since faults in crystal structure (such as dislocations, twins, and stacking faults) interfere with the semicon- ducting properties of the material. Crystalline faults are a major cause of defective semiconductor devices. The larger the crystal, the more diļ¬ƒcult it is to achieve the necessary perfection. Current mass production processes use crystal ingots between 100 and 300 mm (4 and 10 in) in diameter which are grown as cylinders and sliced into wafers. Because of the required level of chemical purity and the perfection of the crystal structure which are needed to make semiconductor devices, special methods have been developed to produce the initial semiconductor material. A technique for achieving high purity includes growing the crystal using the Czochralski process. An additional step that can be used to further increase purity is known as zone reļ¬ning. In zone reļ¬ning, part of a solid crystal is melted. The impurities tend to concentrate in the melted region, while the desired material recrystalizes leaving the solid material more pure and with fewer crystalline faults. In manufacturing semiconductor devices involving heterojunctions between diļ¬€erent semiconductor ma- terials, it is often important to align the crystal lattices of the two materials by using epitaxial techniques. The lattice constant, which is the length of the repeat- ing element of the crystal structure, is important for determining the compatibility of materials. 3 Physics of semiconductors 3.1 Energy bands and electrical conduc- tion Main articles: Electronic band structure and Electrical conduction Semiconductors are deļ¬ned by their unique electric con- ductive behavior, somewhere between that of a metal and an insulator. The diļ¬€erences between these materials can be understood in terms of the quantum states for elec- trons, each of which may contain zero or one electron (by the Pauli exclusion principle). These states are associ- ated with the electronic band structure of the material. Electrical conductivity arises due to the presence of elec- trons in states that are delocalized (extending through the material), however in order to transport electrons a state must be partially ļ¬lled, containing an electron only part
  • 3. 3.2 Charge carriers (electrons and holes) 3 Filling of the electronic Density of states in various types of ma- terials at equilibrium. Here the vertical axis is energy while the horizontal axis is the Density of states for a particular band in the material listed. In metals and semimetals the Fermi level EF lies inside at least one band. In insulators and semiconductors the Fermi level is inside a band gap; however, in semiconduc- tors the bands are near enough to the Fermi level to be thermally populated with electrons or holes. of the time.[2] If the state is always occupied with an elec- tron, then it is inert, blocking the passage of other elec- trons via that state. The energies of these quantum states are critical, since a state is partially ļ¬lled only if its energy is near the Fermi level (see Fermiā€“Dirac statistics). High conductivity in a material comes from it having many partially ļ¬lled states and much state delocalization. Metals are good electrical conductors and have many par- tially ļ¬lled states with energies near their Fermi level. Insulators, by contrast, have few partially ļ¬lled states, their Fermi levels sit within band gaps with few energy states to occupy. Importantly, an insulator can be made to conduct by increasing its temperature: heating pro- vides energy to promote some electrons across the band gap, inducing partially ļ¬lled states in both the band of states beneath the band gap (valence band) and the band of states above the band gap (conduction band). An (in- trinsic) semiconductor has a band gap that is smaller than that of an insulator and at room temperature signiļ¬cant numbers of electrons can be excited to cross the band gap.[3] A pure semiconductor, however, is not very useful, as it is neither a very good insulator nor a very good conductor. However, one important feature of semiconductors (and some insulators, known as semi-insulators) is that their conductivity can be increased and controlled by doping with impurities and gating with electric ļ¬elds. Doping and gating move either the conduction or valence band much closer to the Fermi level, and greatly increase the number of partially ļ¬lled states. Some wider-band gap semiconductor materials are some- times referred to as semi-insulators. When undoped, these have electrical conductivity nearer to that of elec- trical insulators, however they can be doped (making them as useful as semiconductors). Semi-insulators ļ¬nd niche applications in micro-electronics, such as substrates for HEMT. An example of a common semi-insulator is gallium arsenide.[4] Some materials, such as titanium dioxide, can even be used as insulating materials for some applications, while being treated as wide-gap semicon- ductors for other applications. 3.2 Charge carriers (electrons and holes) Main article: Electron hole The partial ļ¬lling of the states at the bottom of the con- duction band can be understood as adding electrons to that band. The electrons do not stay indeļ¬nitely (due to the natural thermal recombination) but they can move around for some time. The actual concentration of elec- trons is typically very dilute, and so (unlike in metals) it is possible to think of the electrons in the conduction band of a semiconductor as a sort of classical ideal gas, where the electrons ļ¬‚y around freely without being sub- ject to the Pauli exclusion principle. In most semicon- ductors the conduction bands have a parabolic dispersion relation, and so these electrons respond to forces (elec- tric ļ¬eld, magnetic ļ¬eld, etc.) much like they would in a vacuum, though with a diļ¬€erent eļ¬€ective mass.[3] Be- cause the electrons behave like an ideal gas, one may also think about conduction in very simplistic terms such as the Drude model, and introduce concepts such as electron mobility. For partial ļ¬lling at the top of the valence band, it is helpful to introduce the concept of an electron hole. Al- though the electrons in the valence band are always mov- ing around, a completely full valence band is inert, not conducting any current. If an electron is taken out of the valence band, then the trajectory that the electron would normally have taken is now missing its charge. For the purposes of electric current, this combination of the full valence band, minus the electron, can be converted into a picture of a completely empty band containing a posi- tively charged particle that moves in the same way as the electron. Combined with the negative eļ¬€ective mass of the electrons at the top of the valence band, we arrive at a picture of a positively charged particle that responds to electric and magnetic ļ¬elds just as a normal positively charged particle would do in vacuum, again with some positive eļ¬€ective mass.[3] This particle is called a hole, and the collection of holes in the valence can again be un- derstood in simple classical terms (as with the electrons in the conduction band). 3.2.1 Carrier generation and recombination Main article: Carrier generation and recombination When ionizing radiation strikes a semiconductor, it may excite an electron out of its energy level and consequently leave a hole. This process is known as electronā€“hole pair generation. Electron-hole pairs are constantly generated
  • 4. 4 4 EARLY HISTORY OF SEMICONDUCTORS from thermal energy as well, in the absence of any exter- nal energy source. Electron-hole pairs are also apt to recombine. Conservation of energy demands that these recom- bination events, in which an electron loses an amount of energy larger than the band gap, be accompanied by the emission of thermal energy (in the form of phonons) or radiation (in the form of photons). In some states, the generation and recombination of electronā€“hole pairs are in equipoise. The number of electron-hole pairs in the steady state at a given tempera- ture is determined by quantum statistical mechanics. The precise quantum mechanical mechanisms of generation and recombination are governed by conservation of en- ergy and conservation of momentum. As the probability that electrons and holes meet together is proportional to the product of their amounts, the prod- uct is in steady state nearly constant at a given temper- ature, providing that there is no signiļ¬cant electric ļ¬eld (which might ā€œļ¬‚ushā€ carriers of both types, or move them from neighbour regions containing more of them to meet together) or externally driven pair generation. The prod- uct is a function of the temperature, as the probability of getting enough thermal energy to produce a pair increases with temperature, being approximately exp(āˆ’EG/kT), where k is Boltzmannā€™s constant, T is absolute temper- ature and EG is band gap. The probability of meeting is increased by carrier trapsā€” impurities or dislocations which can trap an electron or hole and hold it until a pair is completed. Such carrier traps are sometimes purposely added to reduce the time needed to reach the steady state. 3.3 Doping Main article: Doping (semiconductor) The conductivity of semiconductors may easily be mod- iļ¬ed by introducing impurities into their crystal lattice. The process of adding controlled impurities to a semicon- ductor is known as doping. The amount of impurity, or dopant, added to an intrinsic (pure) semiconductor varies its level of conductivity. Doped semiconductors are re- ferred to as extrinsic. By adding impurity to the pure semiconductors, the electrical conductivity may be var- ied by factors of thousands or millions. A 1 cm3 specimen of a metal or semiconductor has of the order of 1022 atoms. In a metal, every atom donates at least one free electron for conduction, thus 1 cm3 of metal contains on the order of 1022 free electrons, whereas a 1 cm3 sample of pure germanium at 20 Ā°C contains about 4.2Ɨ1022 atoms, but only 2.5Ɨ1013 free electrons and 2.5Ɨ1013 holes. The addition of 0.001% of arsenic (an impurity) donates an extra 1017 free electrons in the same volume and the electrical conductivity is increased by a factor of 10,000. The materials chosen as suitable dopants depend on the atomic properties of both the dopant and the material to be doped. In general, dopants that produce the de- sired controlled changes are classiļ¬ed as either electron acceptors or donors. Semiconductors doped with donor impurities are called n-type, while those doped with ac- ceptor impurities are known as p-type. The n and p type designations indicate which charge carrier acts as the ma- terialā€™s majority carrier. The opposite carrier is called the minority carrier, which exists due to thermal excitation at a much lower concentration compared to the majority carrier. For example, the pure semiconductor silicon has four va- lence electrons which bond each silicon atom to its neigh- bors. In silicon, the most common dopants are group III and group V elements. Group III elements all contain three valence electrons, causing them to function as ac- ceptors when used to dope silicon. When an acceptor atom replaces a silicon atom in the crystal, a vacant state ( an electron ā€œholeā€) is created, which can move around the lattice and functions as a charge carrier. Group V elements have ļ¬ve valence electrons, which allows them to act as a donor; substitution of these atoms for sili- con creates an extra free electron. Therefore, a silicon crystal doped with boron creates a p-type semiconductor whereas one doped with phosphorus results in an n-type material. During manufacture, dopants can be diļ¬€used into the semiconductor body by contact with gaseous compounds of the desired element, or ion implantation can be used to accurately position the doped regions. 4 Early history of semiconductors Further information: Timeline of electrical and elec- tronic engineering The history of the understanding of semiconductors be- gins with experiments on the electrical properties of ma- terials. The properties of negative temperature coeļ¬ƒ- cient of resistance, rectiļ¬cation, and light-sensitivity were observed starting in the early 19th century. In 1833, Michael Faraday reported that the resistance of specimens of silver sulļ¬de decreases when they are heated. This is contrary to the behavior of metallic sub- stances such as copper. In 1839, A. E. Becquerel reported observation of a voltage between a solid and a liquid elec- trolyte when struck by light, the photovoltaic eļ¬€ect. In 1873 Willoughby Smith observed that selenium resistors exhibit decreasing resistance when light falls on them. In 1874 Karl Ferdinand Braun observed conduction and rectiļ¬cation in metallic sulphides, and Arthur Schuster found that a copper oxide layer on wires has rectiļ¬cation properties that ceases when the wires are cleaned. Adams
  • 5. 5 and Day observed the photovoltaic eļ¬€ect in selenium in 1876.[5] A uniļ¬ed explanation of these phenomena required a the- ory of solid-state physics which developed greatly in the ļ¬rst half of the 20th Century. In 1878 Edwin Herbert Hall demonstrated the deļ¬‚ection of ļ¬‚owing charge carri- ers by an applied magnetic ļ¬eld, the Hall eļ¬€ect. The dis- covery of the electron by J.J. Thomson in 1897 prompted theories of electron-based conduction in solids. Karl Baedeker, by observing a Hall eļ¬€ect with the reverse sign to that in metals, theorized that copper iodide had positive charge carriers. Johan Koenigsberger classiļ¬ed solid materials as metals, insulators and ā€œvariable con- ductorsā€ in 1914. Felix Bloch published a theory of the movement of electrons through atomic lattices in 1928. In 1930, B. Gudden stated that conductivity in semicon- ductors was due to minor concentrations of impurities. By 1931, the band theory of conduction had been estab- lished by Alan Herries Wilson and the concept of band gaps had been developed. Walter H. Schottky and Nevill Francis Mott developed models of the potential barrier and of the characteristics of a metal-semiconductor junc- tion. By 1938, Boris Davydov had developed a theory of the copper-oxide rectifer, identifying the eļ¬€ect of the pā€“ n junction and the importance of minority carriers and surface states.[6] Agreement between theoretical predictions (based on de- veloping quantum mechanics) and experimental results was sometimes poor. This was later explained by John Bardeen as due to the extreme ā€œstructure sensitiveā€ be- havior of semiconductors, whose properties change dra- matically based on tiny amounts of impurities.[6] Com- mercially pure materials of the 1920s containing varying proportions of trace contaminants produced diļ¬€ering ex- perimental results. This spurred the development of im- proved material reļ¬ning techniques, culminating in mod- ern semiconductor reļ¬neries producing materials with parts-per-trillion purity. Devices using semiconductors were at ļ¬rst constructed based on empirical knowledge, before semiconductor theory provided a guide to construction of more capable and reliable devices. Alexander Graham Bell used the light-sensitive property of selenium to transmit sound over a beam of light in 1880. A working solar cell, of low eļ¬ƒciency, was con- structed by Charles Fritts in 1883 using a metal plate coated with selenium and a thin layer of gold; the device became commercially useful in photographic light meters in the 1930s.[6] Point-contact microwave detector recti- ļ¬ers made of lead sulļ¬de were used by Jagadish Chan- dra Bose in 1904; the catā€™s-whisker detector using natu- ral galena or other materials became a common device in the development of radio. However, it was somewhat unpredictable in operation and required manual adjust- ment for best performance. In 1906 H.J. Round observed light emission when electric current passed through sili- con carbide crystals, the principle behind the light emit- ting diode. Oleg Losev observed similar light emission in 1922 but at the time the eļ¬€ect had no practical use. Power rectiļ¬ers, using copper oxide and selenium, were developed in the 1920s and became commercially impor- tant as an alternative to vacuum tube rectiļ¬ers.[5][6] In the years preceding World War II, infra-red detec- tion and communications devices prompted research into lead-sulļ¬de and lead-selenide materials. These devices were used for detecting ships and aircraft, for infrared rangeļ¬nders, and for voice communication systems. The point-contact crystal detector became vital for microwave radio systems, since available vacuum tube devices could not serve as detectors above about 4000 MHz; advanced radar systems relied on the fast response of crystal detec- tors. Considerable research and development of silicon materials occurred during the war to develop detectors of consistent quality.[6] Detector and power rectiļ¬ers could not amplify a signal. Many eļ¬€orts were made to develop a solid-state ampli- ļ¬er, but these were unsuccessful because of limited the- oretical understanding of semiconductor materials.[6] In 1922 Oleg Losev developed two-terminal, negative re- sistance ampliļ¬ers for radio; however, he perished in the Siege of Leningrad. In 1926 Julius Edgar Lilien- feld patented a device resembling a modern ļ¬eld-eļ¬€ect transistor, but it was not practical. R. Hilsch and R. W. Pohl in 1938 demonstrated a solid-state ampliļ¬er using a structure resembling the control grid of a vacuum tube; although the device displayed power gain, it had a cut- oļ¬€ frequency of one cycle per second, too low for any practical applications, but an eļ¬€ective application of the available theory.[6] At Bell Labs, William Shockley and A. Holden started investigating solid-state ampliļ¬ers in 1938. The ļ¬rst pā€“n junction in silicon was observed by Russell Ohl about 1941, when a specimen was found to be light-sensitive, with a sharp boundary between p-type impurity at one end and n-type at the other. A slice cut from the specimen at the pā€“n boundary developed a volt- age when exposed to light. In France, during the war, Herbert MatarĆ© had observed ampliļ¬cation between adjacent point contacts on a ger- manium base. After the war, MatarĆ©'s group announced their "Transistron" ampliļ¬er only shortly after Bell Labs announced the "transistor". 5 See also ā€¢ Semiconductor industry ā€” The 300 billion dollar sector of the worldā€™s economy that designs and man- ufactures semiconductor devices. ā€¢ Semiconductor characterization techniques ā€” A wide variety of techniques are used to analyze the properties of semiconductors.
  • 6. 6 8 EXTERNAL LINKS 6 References [1] B.G. Yacobi, Semiconductor Materials: An Introduction to Basic Principles, Springer 2003 ISBN 0306473615, pp. 1ā€“3 [2] As in the Mott formula for conductivity, see Cut- ler, M.; Mott, N. (1969). ā€œObservation of Ander- son Localization in an Electron Gasā€. Physical Re- view 181 (3): 1336. Bibcode:1969PhRv..181.1336C. doi:10.1103/PhysRev.181.1336. [3] Charles Kittel (1995) Introduction to Solid State Physics, 7th ed. Wiley, ISBN 0471111813. [4] J. W. Allen (1960). ā€œGallium Arsenide as a semi-insulatorā€. Nature 187 (4735): 403ā€“405. Bibcode:1960Natur.187..403A. doi:10.1038/187403b0. [5] Lidia Łukasiak and Andrzej Jakubowski (January 2010). ā€œHistory of Semiconductorsā€. Journal of Telecommuni- cation and Information Technology: 3. [6] Peter Robin Morris (1990) A History of the World Semi- conductor Industry, IET, ISBN 0863412270, pp. 11ā€“25 7 Further reading ā€¢ A. A. Balandin and K. L. Wang (2006). Hand- book of Semiconductor Nanostructures and Nanode- vices (5-Volume Set). American Scientiļ¬c Publish- ers. ISBN 1-58883-073-X. ā€¢ Sze, Simon M. (1981). Physics of Semiconductor Devices (2nd ed.). John Wiley and Sons (WIE). ISBN 0-471-05661-8. ā€¢ Turley, Jim (2002). The Essential Guide to Semicon- ductors. Prentice Hall PTR. ISBN 0-13-046404-X. ā€¢ Yu, Peter Y.; Cardona, Manuel (2004). Fundamen- tals of Semiconductors : Physics and Materials Prop- erties. Springer. ISBN 3-540-41323-5. ā€¢ Sadao Adachi (2012). The Handbook on Optical Constants of Semiconductors: In Tables and Fig- ures. World Scientiļ¬c Publishing. ISBN 9-789- 81440597-3. 8 External links ā€¢ Howstuļ¬€worksā€™ semiconductor page ā€¢ Semiconductor Concepts at Hyperphysics ā€¢ Calculator for the intrinsic carrier concentration in silicon ā€¢ Semiconductor OneSource Hall of Fame, Glossary ā€¢ Principles of Semiconductor Devices by Bart Van Zeghbroeck, University of Colorado. An online textbook] ā€¢ US Navy Electrical Engineering Training Series ā€¢ NSM-Archive Physical Properties of Semiconduc- tors] ā€¢ Semiconductor Manufacturer List ā€¢ ABACUS : Introduction to Semiconductor Devices ā€“ by Gerhard Klimeck and Dragica Vasileska, online learning resource with simulation tools on nanoHUB ā€¢ Organic Semiconductor page ā€¢ DoITPoMS Teaching and Learning Package- ā€œIn- troduction to Semiconductorsā€ ā€¢ Semiconductor R&D Talent Locations report
  • 7. 7 9 Text and image sources, contributors, and licenses 9.1 Text ā€¢ Semiconductor Source: http://en.wikipedia.org/wiki/Semiconductor?oldid=638745923 Contributors: AxelBoldt, Sodium, Mav, Bryan Derksen, Zundark, Szopen, Sjc, Rjstott, Stokerm, Andre Engels, JeLuF, Fredbauder, Christian List, Gianfranco, Deb, Waveguy, Florian- Marquardt, Modemac, Stevertigo, RTC, Mike dill, Michael Hardy, Tim Starling, Mcarling, Card, Popas11, ŠŠ»ŠµŠŗсŠ°Š½Š“ър, Kimiko, Andres, Hashar, Tantalate, Zoicon5, Maximus Rex, LMB, Phoebe, Jerzy, ThereIsNoSteve, Rogper, Gentgeen, Robbot, Karolkalna, Katyemoe, Ro- manm, Chris Roy, Pelle, Stewartadcock, Roscoe x, Hadal, Fuelbottle, Wjbeaty, Centrx, Giftlite, Akadruid, Artakka, Tom harrison, Aver- age Earthman, Thierryc, Utcursch, Toytoy, Armandino, Mako098765, Ofey, Karl-Henner, Neutrality, Urhixidur, Edsanville, Deeceevoice, Qdr, DanielCD, Jkl, Rmalloy, Forbsey, El C, Laurascudder, Edward Z. 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  • 8. 8 9 TEXT AND IMAGE SOURCES, CONTRIBUTORS, AND LICENSES Tkgd2007 ā€¢ File:Silicon.jpg Source: http://upload.wikimedia.org/wikipedia/commons/2/2c/Silicon.jpg License: CC BY 3.0 Contributors: http:// images-of-elements.com/silicon.php Original artist: Jurii 9.3 Content license ā€¢ Creative Commons Attribution-Share Alike 3.0