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MODULE 4:
MATTER AND MATERIALS
 Earth:
 Water:
 Air:
 Fire:
 Aether:
 Wrote the first
chemistry textbook
 Contained a list of 33
elements
 Formulated the law of
triads
 1862
 Wrote the elements on a piece
of ribbon
 Ordered elements by atomic
weight
 Rolled ribbon into a cylinder with
16 units circumference
 Noticed that elements with
similar properties were aligned
vertically
 Called it the “telluric helix”
Modern day Telluric Helix: Alexandre Arrangement
 Formulated the Law of Octaves
 Law of octaves fail beyond Calcium
John Newlands was told that his arrangement was as
arbitrary as arranging the elements alphabetically
and his paper was rejected for publication
 Published the first version of
the periodic table
 Formulated the periodic law
“I saw in a dream a table where all the elements fell
into place as required. Awakening, I immediately
wrote it down on a piece of paper”
– Dimitri Mendeleev
Sb
51
121,76
Te
52
127,60
I
53
126,91
Ar
18
39,95
K
19
39,10
Ca
20
40,08
 “Corrected” the atomic
weights if it caused the
element to be placed in
the wrong group
Property Eka-aluminium Gallium
Atomic mass 68 69.72
Density (g/cm³) 6.0 5.904
Melting Point (°C) Low 29.78
Oxide's Formula
Ea2O3 (density:
5.5 g/cm³)
(soluble in both
alkalis and acids)
Ga2O3 (density:
5.88 g/cm³)
(soluble in both
alkalis and acids)
Chloride's
Formula
Ea2Cl6 (volatile) Ga2Cl6 (volatile)
 Recognised relationship
between x-ray wavelength and
nuclear charge
 Also predicted new elements
 Was sent to serve as foot
soldier in WWI before his
research was finished
 Was killed by a snipers
bullet
 Britain now assign non-
combat duties to their
scientists during war time
 Co-discovered 10 new
elements
 In 1944 he moved the
actanoids out of the main
body of the periodic table
to its current position
“This is the greatest
honour ever bestowed
upon me – greater even, I
think, than winning the
Nobel Prize.”
– Glenn T. Seaborg
I
I
I
II
I
II III
I
II III IV
I
II III IV V
I
II III IV V VI
I
II III IV V VIVII
I
II III IV V VIVII
VIII
I
II III IV V VIVII
VIII
I
II III IV V VIVII
VIII
I
II III IV V VIVII
VIII
I
II III IV V VIVII
VIII
I
II III IV V VIVII
VIII
 The chemical and physical properties of elements
 Periodicity:
Increase
 Decrease from left to right (increase from right to
left)
 Increase from top to bottom
The distance between the nucleus
and the outer most stable orbital
 Decrease from left to right
3p+
e-
5p+
e-
e-
e-4p+
e-
e-
 Increase from top to bottom
2p+
e- e-4p+
e-
e- e-e- 12p+
e-
e- e-
e-
e-
e-
e-e-
e-e-
e-e-
12p+
e-
e- e-
e-
e-
e-
e-e-
e-e-
e-e-
e-
e-
 Outer e- attracted
by nucleus
 Outer e- repelled
by inner e-
 Experience a
smaller net
attractive force
 Inner e- “shields”
outer e- from
nucleus
The energy required to remove an
electron from an atom
12p+
e- e- e-
e-e-
e-
e-e-
e-e-
e-
e-
MgMg+
 Increases from left to right
 Decreases from top to bottom
Increase
 Increase from left to right
 Decrease from top to bottom
 Borons ionization energy is less than that of
Beryllium
 Oxygen has a lower ionization energy than
Nitrogen
Periodic table e
Periodic table e

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