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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 587
Geopolymer concrete-A solution for cementitious concrete pollution
A Review
Mohammad Amin1, Sandeep Nasier2
1ME Research Scholar, CED, Chandigarh University
2Assistant Professor, CED, Chandigarh University, Punjab, India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - From environmental aspect, the world is
concerning about the Global warming & increase in
environmental pollutions, which is caused in engineeringfield
mainly by cement production. While producing cementahuge
amount of carbon dioxide is emitted to atmosphere. To
overcome this phenomena, either we can partially replace
cement with fly ash, GGBS, Rice husk ash etc…orwecanusethe
Geopolymer technology. Geopolymer concrete which can also
be called zero cement concrete is an innovative construction
material that has alkaline solution i.e. (sodium hydroxide &
sodium silicate) and the fly ash as a binding material. Fly ash
is a rich source of silica and alumina which react with alkaline
solution and produces alumina silicate gel that acts instead of
cement in concrete.
Key Words: Global Warming, Fly ash, GGBS, Rice husk
ash, Geopolymer Concrete, Alumina silicate
1. INTRODUCTION
Urbanization increases need of concrete, where cement is
the main constituent of concrete as a binder material. And
production of 1Ton cement emits approximately 1Ton of
carbon dioxide to the air which actually causestemperature
rise and air pollution. Thus we need to concern about the
environment, and partially replacement of cement with
mineral admixtures can not solve the problem. So we are
supposed to have an alternative construction material,
where Geopolymer concrete is a best replacement for
conventional concrete.
Geopolymer technology was named and presented for the
first time by Davidovits in 1978 to represent a broad range
of materials characterized by networks of inorganic
molecules (Geopolymer Institute 2010) 1 Geopolymer
concrete can be called environment friendly or green
concrete by means of no cement in its composition and the
usage of industrial byproducts such as fly ash, GGBS , which
are harmful to the environment. Geopolymer concrete is
nothing but the combination of aggregates, fly ash, and
alkaline solution. It has two main limitations which need
more exploration such as late initial setting and the heat
necessity in curing time to gain strength 2.
2. PROPERTIES OF GEOPOLYMER CONCRETE
Its properties are as follow 1,3:
 Sets at room temperature
 Non-toxic, bleed free
 Durable and good thermal resistance
 High resistance to corrosion
 Impermeable
 High compressive strength
 Good for hot weather concreting.
3. ALKALINE SOLUTION
Sodium hydroxide and Sodium silicate are used to make
alkaline solution with different ratios. And varying molarity
of sodium hydroxide can be used such as 8 moles, 10 moles,
and 12 moles. The molecular weight of sodium hydroxide is
40. To make 10 molarity solution 400 gr of sodium
hydroxide flakes are weighed and they are dissolved in
water to form 1 liter of alkaline solution.
4. MIX PROPORTIONS
As there are no code provisions for the mix design of
Geopolymer concrete, the density of Geopolymer concreteis
assumed as 2400 kg/m3. The rest of the calculations are
done by considering the density of concrete.4
5. LITERATURE REVIEW
Ajay Kumar Singh studied strength and durability of Fly ash
and GGBS based Geopolymer concrete. The specimens were
taken to be tested after 28 days of curing in sun. Then the
specimens were immersed in 3% HCL, 3% H2SO4 and 3%
HNO3. Results showed greater resistance to acid
environment and high compressive strength compared to
conventional Portland cement concrete.5
K.Prasanna, Arun Kumar, M.Dinesh Kumaran J R and
Lakshminarayanan.B investigatedFlyashbasedGeopolymer
concrete with GGBS. Based on results gained from
experimental investigation.TheGeopolymerconcretegained
strength within 24 hours at ambient temperature without
water curing and also the strength of Geopolymer concrete
was increased with increase in percentage of GGBS in a mix.
Low calcium Fly ash (ASTM Class F) was used. Low calcium
Fly ash based Geopolymer concrete has excellent
compressive strength and is suitable for structural
applications.6
Satpute Manesh B., Wakchaure Madhukar R., Patankar
Subhash V. also had an experimental evaluation of Effects of
Duration and Temperature of curing on compressive
strength of Geopolymer Concrete. They have tested the
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 588
specimens in different curinghoursandvaryingtemperature
and got that by increasing the temperature in the same
curing time the compressive strength of Geopolymer
concrete increased in considerable amount. 7
Chennur Jithendra Reddy and Dr. S. Elavenil researchers
wrote GEOPOLYMER CONCRETE WITH SELFCOMPACTING:
A REVIEW, it is founded that, increasing the dosage of
sodium hydroxide molarity leads to decrease in fresh
properties, however it increased the compressive strength.
The contribution of GGBS helps the SCGC to attain high
compressive strength at ambientroomtemperature.GGBSat
ambient curing condition had more compressive strength
rather than Fly ash based SCGC.8
MR. PRATIK B. SHINDE.1, MR.SWAPNILA.SURYAWANSHI.2,
MR. AMIT D. CHOUGULE.3 investigated light weight
Geopolymer concrete and got results as follow: The light
weight Geopolymer concrete gain the strength within 24
hours without water curing. The strength of light weight
Geopolymer concrete was increased with decreased in
molarity of alkaline solution. It wasobserved that, witha1M
solution the sample gives good compressive strength with
achievable density to make it light weight.9
6. CONCLUSIONS
 All research papers and review papers show
Geopolymer concrete is a best alternative
construction material to replace the conventional
concrete for reducing the carbon dioxide emission.
 To gain sufficient strength 60 to 90-degree Celsius
curing temperature is good without water curing,
but still can gain strength in room temperature.
 Increase of molarity of sodiumhydroxide increases
strength of concrete.
 Low calcium fly ash and increasing GGBS showed
increase in strength of concrete.
ACKNOWLEDGEMENT
The author of present review paper work would like to
acknowledge Mr. Sandeep Nasier, Assistant Professor at
Chandigarh university for his technical assistance, valuable
guidance and spirited efforts.
REFERENCES
[1]. M.I Abdul Aleem, P.D. Arumairaj “GEOPOLYMER
CONCRETE- A REVIEW 2012 International Journal of
Engineering Sciences & Emerging Technologies.
[2]. D.B.Rajiwala,H.S.Patil(2011)”Geopolymer Concrete : A
concrete of Next Decade” Journal of Engineering Studiesand
Research Vol II Issue I.
[3]. Mr.Prashant M.Dhamanage Light- Weight Geopolymer
Concrete- AReview. International Journal of Research in
Advent Technology 19 March 2016
[4]. L.Krishnan, S.Karthikeyan “ GEOPOLYMER CONCRETE
AN ECO-FRIENDLY CONSTRUCTION MATERIAL”
International Journal of Research in Engineering and
Technology volume 03, June 2014.
[5]. Ajay Kumar Singh. Strength and Durability test of fly
ash and GGBS Based Geopolymer
concrete. Int. Journal of Engineering Research and
Application Vol.6, Issue 8, (Part-1) August 2016.
[6]. K.Prasanna, Arun Kumar.M, Lakshminarayanan.B, and
Dinesh Kumar.J.R. FLYASHBASEDGEOPOLYMERCONCRETE
WITH GGBS. International conference on Current Research
in Engineering Science and Technology (ICCREST-32016).
[7]. Satpute Manesh B., Wakchaure Madhukar R., Patankar
V. Effect of Duration and Temperature of Curing on
CompressiveStrength of Geopolymerconcrete.International
Journal of Engineering and InnovativeTechnologyVolume1,
Issue 5, May 2012.
[8]. Chennur Jithendra Reddy and Dr. S. Elavenil
GEOPOLYMER CONCRETE WITH SELF COMPACTING: A
REVIEW International Journal of Civil Engineering and
Technology (IJCIET) Volume 8, Issue 2, February 2017
[9]. MR. PRATIK B. SHINDE.1, MR. SWAPNIL A.
SURYAWANSHI.2, MR. AMIT D. CHOUGULE.3 “A
Characteristic Study of Light Weight Geopolymer Concrete”
International Research Journal of Engineering and
Technology (IRJET) e-ISSN: 2395 -0056Volume:03Issue:02
| Feb-2016

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IRJET-Geopolymer Concrete-A Solution for Cementitious Concrete Pollution A Review

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 587 Geopolymer concrete-A solution for cementitious concrete pollution A Review Mohammad Amin1, Sandeep Nasier2 1ME Research Scholar, CED, Chandigarh University 2Assistant Professor, CED, Chandigarh University, Punjab, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - From environmental aspect, the world is concerning about the Global warming & increase in environmental pollutions, which is caused in engineeringfield mainly by cement production. While producing cementahuge amount of carbon dioxide is emitted to atmosphere. To overcome this phenomena, either we can partially replace cement with fly ash, GGBS, Rice husk ash etc…orwecanusethe Geopolymer technology. Geopolymer concrete which can also be called zero cement concrete is an innovative construction material that has alkaline solution i.e. (sodium hydroxide & sodium silicate) and the fly ash as a binding material. Fly ash is a rich source of silica and alumina which react with alkaline solution and produces alumina silicate gel that acts instead of cement in concrete. Key Words: Global Warming, Fly ash, GGBS, Rice husk ash, Geopolymer Concrete, Alumina silicate 1. INTRODUCTION Urbanization increases need of concrete, where cement is the main constituent of concrete as a binder material. And production of 1Ton cement emits approximately 1Ton of carbon dioxide to the air which actually causestemperature rise and air pollution. Thus we need to concern about the environment, and partially replacement of cement with mineral admixtures can not solve the problem. So we are supposed to have an alternative construction material, where Geopolymer concrete is a best replacement for conventional concrete. Geopolymer technology was named and presented for the first time by Davidovits in 1978 to represent a broad range of materials characterized by networks of inorganic molecules (Geopolymer Institute 2010) 1 Geopolymer concrete can be called environment friendly or green concrete by means of no cement in its composition and the usage of industrial byproducts such as fly ash, GGBS , which are harmful to the environment. Geopolymer concrete is nothing but the combination of aggregates, fly ash, and alkaline solution. It has two main limitations which need more exploration such as late initial setting and the heat necessity in curing time to gain strength 2. 2. PROPERTIES OF GEOPOLYMER CONCRETE Its properties are as follow 1,3:  Sets at room temperature  Non-toxic, bleed free  Durable and good thermal resistance  High resistance to corrosion  Impermeable  High compressive strength  Good for hot weather concreting. 3. ALKALINE SOLUTION Sodium hydroxide and Sodium silicate are used to make alkaline solution with different ratios. And varying molarity of sodium hydroxide can be used such as 8 moles, 10 moles, and 12 moles. The molecular weight of sodium hydroxide is 40. To make 10 molarity solution 400 gr of sodium hydroxide flakes are weighed and they are dissolved in water to form 1 liter of alkaline solution. 4. MIX PROPORTIONS As there are no code provisions for the mix design of Geopolymer concrete, the density of Geopolymer concreteis assumed as 2400 kg/m3. The rest of the calculations are done by considering the density of concrete.4 5. LITERATURE REVIEW Ajay Kumar Singh studied strength and durability of Fly ash and GGBS based Geopolymer concrete. The specimens were taken to be tested after 28 days of curing in sun. Then the specimens were immersed in 3% HCL, 3% H2SO4 and 3% HNO3. Results showed greater resistance to acid environment and high compressive strength compared to conventional Portland cement concrete.5 K.Prasanna, Arun Kumar, M.Dinesh Kumaran J R and Lakshminarayanan.B investigatedFlyashbasedGeopolymer concrete with GGBS. Based on results gained from experimental investigation.TheGeopolymerconcretegained strength within 24 hours at ambient temperature without water curing and also the strength of Geopolymer concrete was increased with increase in percentage of GGBS in a mix. Low calcium Fly ash (ASTM Class F) was used. Low calcium Fly ash based Geopolymer concrete has excellent compressive strength and is suitable for structural applications.6 Satpute Manesh B., Wakchaure Madhukar R., Patankar Subhash V. also had an experimental evaluation of Effects of Duration and Temperature of curing on compressive strength of Geopolymer Concrete. They have tested the
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 588 specimens in different curinghoursandvaryingtemperature and got that by increasing the temperature in the same curing time the compressive strength of Geopolymer concrete increased in considerable amount. 7 Chennur Jithendra Reddy and Dr. S. Elavenil researchers wrote GEOPOLYMER CONCRETE WITH SELFCOMPACTING: A REVIEW, it is founded that, increasing the dosage of sodium hydroxide molarity leads to decrease in fresh properties, however it increased the compressive strength. The contribution of GGBS helps the SCGC to attain high compressive strength at ambientroomtemperature.GGBSat ambient curing condition had more compressive strength rather than Fly ash based SCGC.8 MR. PRATIK B. SHINDE.1, MR.SWAPNILA.SURYAWANSHI.2, MR. AMIT D. CHOUGULE.3 investigated light weight Geopolymer concrete and got results as follow: The light weight Geopolymer concrete gain the strength within 24 hours without water curing. The strength of light weight Geopolymer concrete was increased with decreased in molarity of alkaline solution. It wasobserved that, witha1M solution the sample gives good compressive strength with achievable density to make it light weight.9 6. CONCLUSIONS  All research papers and review papers show Geopolymer concrete is a best alternative construction material to replace the conventional concrete for reducing the carbon dioxide emission.  To gain sufficient strength 60 to 90-degree Celsius curing temperature is good without water curing, but still can gain strength in room temperature.  Increase of molarity of sodiumhydroxide increases strength of concrete.  Low calcium fly ash and increasing GGBS showed increase in strength of concrete. ACKNOWLEDGEMENT The author of present review paper work would like to acknowledge Mr. Sandeep Nasier, Assistant Professor at Chandigarh university for his technical assistance, valuable guidance and spirited efforts. REFERENCES [1]. M.I Abdul Aleem, P.D. Arumairaj “GEOPOLYMER CONCRETE- A REVIEW 2012 International Journal of Engineering Sciences & Emerging Technologies. [2]. D.B.Rajiwala,H.S.Patil(2011)”Geopolymer Concrete : A concrete of Next Decade” Journal of Engineering Studiesand Research Vol II Issue I. [3]. Mr.Prashant M.Dhamanage Light- Weight Geopolymer Concrete- AReview. International Journal of Research in Advent Technology 19 March 2016 [4]. L.Krishnan, S.Karthikeyan “ GEOPOLYMER CONCRETE AN ECO-FRIENDLY CONSTRUCTION MATERIAL” International Journal of Research in Engineering and Technology volume 03, June 2014. [5]. Ajay Kumar Singh. Strength and Durability test of fly ash and GGBS Based Geopolymer concrete. Int. Journal of Engineering Research and Application Vol.6, Issue 8, (Part-1) August 2016. [6]. K.Prasanna, Arun Kumar.M, Lakshminarayanan.B, and Dinesh Kumar.J.R. FLYASHBASEDGEOPOLYMERCONCRETE WITH GGBS. International conference on Current Research in Engineering Science and Technology (ICCREST-32016). [7]. Satpute Manesh B., Wakchaure Madhukar R., Patankar V. Effect of Duration and Temperature of Curing on CompressiveStrength of Geopolymerconcrete.International Journal of Engineering and InnovativeTechnologyVolume1, Issue 5, May 2012. [8]. Chennur Jithendra Reddy and Dr. S. Elavenil GEOPOLYMER CONCRETE WITH SELF COMPACTING: A REVIEW International Journal of Civil Engineering and Technology (IJCIET) Volume 8, Issue 2, February 2017 [9]. MR. PRATIK B. SHINDE.1, MR. SWAPNIL A. SURYAWANSHI.2, MR. AMIT D. CHOUGULE.3 “A Characteristic Study of Light Weight Geopolymer Concrete” International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056Volume:03Issue:02 | Feb-2016