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Green Plastics: An Emerging Alternative for
Petroleum Based Plastics
Presented By ANTU BHATTACHARJEE
• BARASAT GOVT.
COLLEGE
• WEST BENGAL STATE
UNIVERSITY
• MSC. 3rd SEM
• Reg no.-002559-2013 of
2013
• ROLL : BGC/ZOOL NO:
14105
• Year-2015
BACKGROUND
• ‘plastic’ is any organic
synthetic or processed
materials that are
mostly thermoplastic
or thermosetting
polymers of high
molecular mass.
• Littering or excessive
use, has harmed the
image of this useful
Product.
problems of conventional plastics
HISTORY OF GREEN PLASTICS
• In 1868 John W. Hyatt
invented Celluloid from
plant fibers (cellulose).
• After 1907,with the
invention of first
petroleum based
plastic sonly
conventional plastic
was steadily growing.
Fig: Henry Ford’s soy protein
plastic based composites
INTRODUCTION
• Green plastics can be made
from many different
sources like – (A)Plant Oil,
(F)Cellulose, (D)Corn,
(B)Starch,(C) Potato Starch,
(E)Sugarcane, Weeds etc.
• Examples: Polylactic acids
(PLA), Polyhydroxybutyrate
(PHB) etc.
PURPOSE OF GREEN PLASTICS
• Applications:Bottling,
resins, packaging, etc
• Advantages over
conventional plastics:
• 1.Reduces GHG in
production
• 2.Requires no
petrochemicals.
• 3.Biodegradable
• 4.Multiple end-of-life
options
• 5.Reduced carbon footprint
CHARACTERS OF GREEN PLASTICS
• Biodegradable and
compostable
• Renewability
• Environmentally
friendly nature
FIG: shows Bio-
Degradation of Green
Plastic.
THE DIFFERENCES AMONG
DEGRADABLE, BIODEGRADABLE,
AND COMPOSTABLE
• Degradable Plastic:
means that something
breaks down.
• Biodegradable Plastic: it
can be broken down by
the metabolism of micro-
organisms.
• Compostable Plastic:
means that it
biodegrades within a
certain amount of time,
under certain conditions.
• This Figure shows
typical data obtained
when the per cent
carbon released (as
CO2) from a green
plastic exposed in a
composting
environment is
plotted as a function
of time.
Green Plastics Classification
• Type I: Ex: polymers
derived from cellulose.
• Type II: Ex:PHA, PHBV.
• Type III: Ex : PLA
SYNTHESIS OF PLA
PRODUCTION OF PHB
CARBON CYCLE OF GREEN-PLASTICS
SOME FACTS ABOUT GREEN PLASTICS
• Processing Green Plastics Products
• Recycling Issues
• Synthetic Blending
Standards and Certifications for
COMPOSTABLE PLASTICS
• In the United States
ASTM D-6400
international (ISO-
14855).
• Certification from
other countries includes
EcoLogo (Canada) and
Vincotte (Belgium).
Cost Factor
• additional cost incurred
due to increased
processing steps.
• In India, the cost of
biodegradable plastics
is 2- 10 times more
than conventional
plastics.
DISCUSSIONS
• To promote green-
plastics:
• educating the society
• Standardizations and
certifications should be
publicized.
• Infrastructure for
collection and
composting needs to be
improved.
• Governmental
incentives.
CONCLUSION
• society’s current views
on environmental
responsibility make this
an ideal time for further
growth of green
plastics.
• If the trend continues
and the motivation for
innovation in this field
persists, the results
could be promising.
References
• Auras, R.A., Harte, B., Selke, S., & Hernandez, R. (2003). Mechanical, physical, and barrier properties
of poly(lactide) films. Journal of Plastic Film & Sheeting, 19(2),123-135.
• Blackburn, R. S. (2005). Biodegradable and sustainable fibers (Ed.). Cambridge,UK: Woodhead
Publishing Limited.
• Bregar, Bill (2010, October18). Greenwashing leads to consumer skepticism. Plastics News, pp. 12.
• Dartee, M. (2010). It's time to get to know your way around bioplastics. Plastics Technology, 56(3),
18-22. Proceedings of The 2011 IAJC-ASEE International Conferenc ISBN 978-1-60643-379-9
• Evans, J. (2010). Bioplastics get growing. Plastics Engineering, 66(2), 14-20 Municipal solid waste in
the United States:2007 Facts and figures(2008).
• Greer, D. (2006). Plastic from plants, not petroleum. BioCycle, 47(6), 33-35
• Hockensmith, D. (2010, October 4). P&G outlines broad sustainability plans. Plastics News, pp. 1,
20.
• Inomata, I. (2009). The current status of bioplastics development in Japan.Bioplastics, 4(1), 42-44.
• Khare, A., & Deshmukh, S. (2006). Studies toward producing eco-friendly plastics. Journal of Plastic
Film & Sheeting, 22(3), 193-211.
• Knights, M. (2009). Injection molding biopolymers. Plastics Technology, 55(4), 39-48.
• Kuruppalil, Z. (2010, November). Plastics packaging: The challenge of going green. Accepted to
publish in The First International Conference on Green and Sustainable Technology conference
proceedings, University of North Carolina A & T.
• Patey, W. (2010). Thermoforming pla: how to do it right. Plastics Technology, 56(3),30-31.
References
• Phillips, A.L. (2008). Bioplastics boom. American Scientist, 96(2), 109-110.
• Pitzi, T. J. (2010). Injection molding PHA bioplastics: validating moldability for paper mate pens.
Plastics Technology, 56(8), 27-28.
• Queiroz, A.U.B., & Collares-Queiroz, F.P. (2009). Innovation and industrial trends in bioplastics.
Polymer Reviews, 49(2), 65-78.
• Rustin, D. (2009). Being green can turn into green. PD&F , 30(1), 8-11
• Schut, J. H. (2007). Foamed PLA Shows Promise In Biodegradable Meat Trays. Plastics
Technology,(53)12, 39-43.
• Schut, J.H. (2007). Extruding biopolymers. Plastics Technology, 53(2), 60-75.
• Schut, J.H. (2008). What's ahead for 'green' plastics. Plastics Technology 54(2), 64-89.
• Sherman, L. M. (2008). Additives are needed for toughness, heat resistance & processability.
Plastics Technology, 64(7), 58-63.
• Siracusa, V., Rocculi, P., Romani, S., & Rosa, M.D. (2008). Biodegradable polymers for food
packaging: a review. Trends in Food Science & Technology,19(12), 634-643.
• Stevens, E.S. (2002). Green Plastics: An introduction to the new science of biodegradable plastics.
Princeton, NY: Princeton University Press.
• Stevens, E.S. (2002). How green are green plastics?. BioCycle, 43(12), 42.
• Stevens, E.S. (2003). What makes green plastics green?. BioCycle, 44(3), 24,4.
• Tokiwa, Y., Calabia, B.P., Ugwu, C.U., & Aiba, S. (2009). Biodegradability of plastics. International
Journal of Molecular Sciences, 10(9), 3722-3742.
ACKNOWLEDGEMENT
• I am highly indebted to Dr. Tuhin Saha,
Associate Professor of PG Department of
Zoology, Barasat Govt. College for giving this
review work and his guidance and
encouragement throughout this study.
• Sincere thanks to all our respected sirs and
madams of the PG Department of Zoology,
Barasat Govt. College for giving me the
opportunity to present this seminer.
Green plastics :an emerging alternative of petroleum based plastics

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Green plastics :an emerging alternative of petroleum based plastics

  • 1. Green Plastics: An Emerging Alternative for Petroleum Based Plastics Presented By ANTU BHATTACHARJEE • BARASAT GOVT. COLLEGE • WEST BENGAL STATE UNIVERSITY • MSC. 3rd SEM • Reg no.-002559-2013 of 2013 • ROLL : BGC/ZOOL NO: 14105 • Year-2015
  • 2. BACKGROUND • ‘plastic’ is any organic synthetic or processed materials that are mostly thermoplastic or thermosetting polymers of high molecular mass. • Littering or excessive use, has harmed the image of this useful Product.
  • 4. HISTORY OF GREEN PLASTICS • In 1868 John W. Hyatt invented Celluloid from plant fibers (cellulose). • After 1907,with the invention of first petroleum based plastic sonly conventional plastic was steadily growing. Fig: Henry Ford’s soy protein plastic based composites
  • 5. INTRODUCTION • Green plastics can be made from many different sources like – (A)Plant Oil, (F)Cellulose, (D)Corn, (B)Starch,(C) Potato Starch, (E)Sugarcane, Weeds etc. • Examples: Polylactic acids (PLA), Polyhydroxybutyrate (PHB) etc.
  • 6. PURPOSE OF GREEN PLASTICS • Applications:Bottling, resins, packaging, etc • Advantages over conventional plastics: • 1.Reduces GHG in production • 2.Requires no petrochemicals. • 3.Biodegradable • 4.Multiple end-of-life options • 5.Reduced carbon footprint
  • 7. CHARACTERS OF GREEN PLASTICS • Biodegradable and compostable • Renewability • Environmentally friendly nature FIG: shows Bio- Degradation of Green Plastic.
  • 8. THE DIFFERENCES AMONG DEGRADABLE, BIODEGRADABLE, AND COMPOSTABLE • Degradable Plastic: means that something breaks down. • Biodegradable Plastic: it can be broken down by the metabolism of micro- organisms. • Compostable Plastic: means that it biodegrades within a certain amount of time, under certain conditions.
  • 9. • This Figure shows typical data obtained when the per cent carbon released (as CO2) from a green plastic exposed in a composting environment is plotted as a function of time.
  • 10. Green Plastics Classification • Type I: Ex: polymers derived from cellulose. • Type II: Ex:PHA, PHBV. • Type III: Ex : PLA
  • 13. CARBON CYCLE OF GREEN-PLASTICS
  • 14. SOME FACTS ABOUT GREEN PLASTICS • Processing Green Plastics Products • Recycling Issues • Synthetic Blending
  • 15. Standards and Certifications for COMPOSTABLE PLASTICS • In the United States ASTM D-6400 international (ISO- 14855). • Certification from other countries includes EcoLogo (Canada) and Vincotte (Belgium).
  • 16. Cost Factor • additional cost incurred due to increased processing steps. • In India, the cost of biodegradable plastics is 2- 10 times more than conventional plastics.
  • 17. DISCUSSIONS • To promote green- plastics: • educating the society • Standardizations and certifications should be publicized. • Infrastructure for collection and composting needs to be improved. • Governmental incentives.
  • 18. CONCLUSION • society’s current views on environmental responsibility make this an ideal time for further growth of green plastics. • If the trend continues and the motivation for innovation in this field persists, the results could be promising.
  • 19.
  • 20. References • Auras, R.A., Harte, B., Selke, S., & Hernandez, R. (2003). Mechanical, physical, and barrier properties of poly(lactide) films. Journal of Plastic Film & Sheeting, 19(2),123-135. • Blackburn, R. S. (2005). Biodegradable and sustainable fibers (Ed.). Cambridge,UK: Woodhead Publishing Limited. • Bregar, Bill (2010, October18). Greenwashing leads to consumer skepticism. Plastics News, pp. 12. • Dartee, M. (2010). It's time to get to know your way around bioplastics. Plastics Technology, 56(3), 18-22. Proceedings of The 2011 IAJC-ASEE International Conferenc ISBN 978-1-60643-379-9 • Evans, J. (2010). Bioplastics get growing. Plastics Engineering, 66(2), 14-20 Municipal solid waste in the United States:2007 Facts and figures(2008). • Greer, D. (2006). Plastic from plants, not petroleum. BioCycle, 47(6), 33-35 • Hockensmith, D. (2010, October 4). P&G outlines broad sustainability plans. Plastics News, pp. 1, 20. • Inomata, I. (2009). The current status of bioplastics development in Japan.Bioplastics, 4(1), 42-44. • Khare, A., & Deshmukh, S. (2006). Studies toward producing eco-friendly plastics. Journal of Plastic Film & Sheeting, 22(3), 193-211. • Knights, M. (2009). Injection molding biopolymers. Plastics Technology, 55(4), 39-48. • Kuruppalil, Z. (2010, November). Plastics packaging: The challenge of going green. Accepted to publish in The First International Conference on Green and Sustainable Technology conference proceedings, University of North Carolina A & T. • Patey, W. (2010). Thermoforming pla: how to do it right. Plastics Technology, 56(3),30-31.
  • 21. References • Phillips, A.L. (2008). Bioplastics boom. American Scientist, 96(2), 109-110. • Pitzi, T. J. (2010). Injection molding PHA bioplastics: validating moldability for paper mate pens. Plastics Technology, 56(8), 27-28. • Queiroz, A.U.B., & Collares-Queiroz, F.P. (2009). Innovation and industrial trends in bioplastics. Polymer Reviews, 49(2), 65-78. • Rustin, D. (2009). Being green can turn into green. PD&F , 30(1), 8-11 • Schut, J. H. (2007). Foamed PLA Shows Promise In Biodegradable Meat Trays. Plastics Technology,(53)12, 39-43. • Schut, J.H. (2007). Extruding biopolymers. Plastics Technology, 53(2), 60-75. • Schut, J.H. (2008). What's ahead for 'green' plastics. Plastics Technology 54(2), 64-89. • Sherman, L. M. (2008). Additives are needed for toughness, heat resistance & processability. Plastics Technology, 64(7), 58-63. • Siracusa, V., Rocculi, P., Romani, S., & Rosa, M.D. (2008). Biodegradable polymers for food packaging: a review. Trends in Food Science & Technology,19(12), 634-643. • Stevens, E.S. (2002). Green Plastics: An introduction to the new science of biodegradable plastics. Princeton, NY: Princeton University Press. • Stevens, E.S. (2002). How green are green plastics?. BioCycle, 43(12), 42. • Stevens, E.S. (2003). What makes green plastics green?. BioCycle, 44(3), 24,4. • Tokiwa, Y., Calabia, B.P., Ugwu, C.U., & Aiba, S. (2009). Biodegradability of plastics. International Journal of Molecular Sciences, 10(9), 3722-3742.
  • 22. ACKNOWLEDGEMENT • I am highly indebted to Dr. Tuhin Saha, Associate Professor of PG Department of Zoology, Barasat Govt. College for giving this review work and his guidance and encouragement throughout this study. • Sincere thanks to all our respected sirs and madams of the PG Department of Zoology, Barasat Govt. College for giving me the opportunity to present this seminer.