Dielectrics 
Prof. V. Krishnakumar 
Professor and Head 
Department of Physics 
Periyar University 
Salem – 636 011
IInnttrroodduuccttiioonn 
• Dielectric materials: high electrical resistivities, but 
an efficient supporter of electrostatic fields. 
• Can store energy/charge. 
• Able to support an electrostatic field while 
dissipating minimal energy in the form of heat. 
• The lower the dielectric loss (proportion of energy 
lost as heat), the more effective is a dielectric 
material. 
• Another consideration is the dielectric constant, 
the extent to which a substance concentrates the 
electrostatic lines of flux.
Capacitance 
• Two electrodes separated by a gap 
define a capacitor. 
• When a bias is applied across the 
capacitor plates, one charges positively, 
the other negatively. 
• The amount of charge that the capacitor 
can store (Q) is proportional to the bias 
(V) times how good the capacitor is, the 
‘capacitance’ (C). 
• The capacitance is related to the area of 
the plates (A), their separation (d), and 
the Dielectric Constant (εεo) of the 
dielectric between the plates 
• Dielectric constant of vacuum; εo = 
8.85x10-12 F/m=55.2 Me/(V*m) 
C = ee oA 
d 
- 
Q A V m 
* 2 
ee * 
= = = - 
V e 
m 
m 
V 
d 
e 
o *
Why does charge built up? 
There is generally not a built-in electric field between the 
plates of an unbiased capacitor. 
When an electric field is applied, any charged carriers or 
species within the material will respond. 
For a conductor or semiconductor, e- will flow to the + 
plate, and possibly also holes will flow to the - plate. 
Current is carried=no charge buildup. 
For an insulator, there aren’t a significant number of free 
carriers. There are highly ionic species, however, but they 
aren’t very mobile at low temperatures. No appreciable 
current is carried=charge buildup.
Polarization in Insulators 
Positively charged species in insulators shift/rotate/align toward the 
negative electrode and negatively charged species shift/rotate/align 
towards the positive electrode; creating dipoles. The dipole moment 
density is termed the Polarization (P) and has the units of C/m2. 
Electron Cloud Electron Cloud 
+ 
+ 
- 
E 
Electronic polarization, occurs 
in all insulators 
- 
- - 
+ - + 
- 
+ + 
+ + 
E 
Ionic polarization occurs 
in all ionic solids: NaCl, 
MgO… 
- 
- 
- 
+ + 
- 
+ + 
E 
Molecular polarization, occurs 
in all insulating molecules; 
oils, polymers, H2O… 
Electric Dipole Moment 
p = q × x 
Polarization 
q 
A 
P = p º 
V
Dielectric Effects 
Metal plates 
Dielectric 
C = e A 
d 
What makes e different from e0? 
POLARIZATION 
e e e 
= + 
= 
1 
0 
e c 
r 
r 
In electrostatics, the CONSTITUITIVE RELATION is 
D E E P 
e e 
= 
= = + Polarization 
P E 
0 
0 
ce 
Susceptibility
Dielectric Effects 
POLARIZATION arises from charge shifts in the material— 
there is a macroscopic separation of positive charge (e.g., the 
ions) and negative charge (e.g., the BONDING ELECTRONS). 
Induced DIPOLE MOMENT 
POLARIZATION is then 
di = q × x0 
There are many sources of dipoles. 
Amount of charge shift 
P = Ndipolesdi
Definitions 
•Permittivity is a physical quantity 
that describes how an electric field 
affects and is affected by a dielectric 
medium and is determined by the 
ability of a material to polarize in 
response to an applied electric field, 
and thereby to cancel, partially, the 
field inside the material. Permittivity 
relates therefore to a material's ability 
to transmit (or "permit") an electric 
field…The permittivity of a material 
is usually given relative to that of 
vacuum, as a relative permittivity, 
(also called dielectric constant in 
some cases)….- Wikipedia 
Dk 
Df 
'r e 
" 
r e
Permittivity and Permeability Definitions 
Permittivity 
(Dielectric Constant) 
k = e = = - 
r r r e e je 
' " 
e 
0 
•interaction of a material in the 
presence of an external electric 
field.
Permittivity and Permeability Definitions 
Permittivity 
(Dielectric Constant) 
k = e = = - 
r r r e e je 
' " 
e 
0 
•interaction of a material in the 
presence of an external electric 
field. 
Dk
Permittivity and Permeability Definitions 
k = e = = - ' " 
r r r e e je 
' " 
e 
0 
•interaction of a material in the 
presence of an external electric 
field. 
m = m = - 
0 
mr jmr 
m 
interaction of a material in the 
presence of an external magnetic field. 
Permittivity 
(Dielectric Constant) 
Permeability 
Dk
Permittivity and Permeability Definitions 
k = e = = - ' " 
r r r e e je 
' " 
e 
0 
•interaction of a material in the 
presence of an external electric 
field. 
m = m = - 
0 
mr jmr 
m 
interaction of a material in the 
presence of an external magnetic field. 
Permittivity 
(Dielectric Constant) 
Permeability 
Dk
STORAGE 
Electric Magnetic 
Fields Fields 
Permittivity Permeability 
' " 
Electromagnetic Field Interaction 
MUT 
mr = mr - jmr ' " 
e r = e r - je r 
STORAGE
STORAGE 
Electric Magnetic 
Fields Fields 
LOSS 
Permittivity Permeability 
' " 
Electromagnetic Field Interaction 
MUT 
mr = mr - jmr ' " 
e r = e r - je r 
STORAGE 
LOSS
Loss Tangent 
d = e 
" 
re 
' 
tan 
r 
e r 
'r 
e 
''r 
e 
Energy Lost perCycle 
Energy Stored perCycle 
tand = D = 1 = 
Q 
D Dissipation Factor Q Quality Factor 
Df
Relaxation Constant t 
"t = Time required 
for 1/e of an aligned 
system to return to 
equilibrium or 
random state, in 
seconds. 
= 1 = 1 
wc pfc 
t 
2 
100 
1 
1 
10 
Water at 20o C 
10 100 
f, 
GHz 
most energy is lost at 1/t 
'r e 
" 
r e 
e w e e e 
= + - ¥ 
j 
wt 
s+ 
¥ 1 
Debye equation : ( )
Dielectric Effects 
e s =e static 
e ¥ =e optical 
e 0 ln(w) 
wLO wP 
30-50 meV 10-15 eV 
visible 
infrared 
Major source of POLARIZATION 
is distortion of the bonding 
electrons around atoms. This 
leads to the normal 
semiconductor dielectric 
constant. 
In POLAR materials, like 
GaAs and SiC, the different 
charge on the A and B atoms 
can be polarized as well, 
leading to a difference 
between the optical and the 
static dielectric constants. 
In Appendix C, the two values for GaAs are reversed!
Definition: 
A photonic crystal is a periodic arrangement 
of a dielectric material 
that exhibits strong interaction with light
Piezoelectric Effect 
In materials with NO REFLECTION SYMMETRY (like GaAs or 
many molecular species) the applied electric field produces a 
DISTORTION OF THE LATTICE (size change) and vice versa. 
FORCE 
ELECTRIC FIELD 
A common piezoelectric is Poly-Vinylidene Flouride, which is 
used in a variety of stereo headsets. The most common is 
crystalline quartz used as frequency control crystals—pressure 
applied to the quartz has a resonance which can be used in a 
feedback loop to create a highly-stable oscillator—the quartz 
crystal oscillator.
Phase sensitive multimeter interfaced 
with impendence analyzer for dielectric 
measurements

Dielectrics_1

  • 1.
    Dielectrics Prof. V.Krishnakumar Professor and Head Department of Physics Periyar University Salem – 636 011
  • 2.
    IInnttrroodduuccttiioonn • Dielectricmaterials: high electrical resistivities, but an efficient supporter of electrostatic fields. • Can store energy/charge. • Able to support an electrostatic field while dissipating minimal energy in the form of heat. • The lower the dielectric loss (proportion of energy lost as heat), the more effective is a dielectric material. • Another consideration is the dielectric constant, the extent to which a substance concentrates the electrostatic lines of flux.
  • 3.
    Capacitance • Twoelectrodes separated by a gap define a capacitor. • When a bias is applied across the capacitor plates, one charges positively, the other negatively. • The amount of charge that the capacitor can store (Q) is proportional to the bias (V) times how good the capacitor is, the ‘capacitance’ (C). • The capacitance is related to the area of the plates (A), their separation (d), and the Dielectric Constant (εεo) of the dielectric between the plates • Dielectric constant of vacuum; εo = 8.85x10-12 F/m=55.2 Me/(V*m) C = ee oA d - Q A V m * 2 ee * = = = - V e m m V d e o *
  • 4.
    Why does chargebuilt up? There is generally not a built-in electric field between the plates of an unbiased capacitor. When an electric field is applied, any charged carriers or species within the material will respond. For a conductor or semiconductor, e- will flow to the + plate, and possibly also holes will flow to the - plate. Current is carried=no charge buildup. For an insulator, there aren’t a significant number of free carriers. There are highly ionic species, however, but they aren’t very mobile at low temperatures. No appreciable current is carried=charge buildup.
  • 5.
    Polarization in Insulators Positively charged species in insulators shift/rotate/align toward the negative electrode and negatively charged species shift/rotate/align towards the positive electrode; creating dipoles. The dipole moment density is termed the Polarization (P) and has the units of C/m2. Electron Cloud Electron Cloud + + - E Electronic polarization, occurs in all insulators - - - + - + - + + + + E Ionic polarization occurs in all ionic solids: NaCl, MgO… - - - + + - + + E Molecular polarization, occurs in all insulating molecules; oils, polymers, H2O… Electric Dipole Moment p = q × x Polarization q A P = p º V
  • 6.
    Dielectric Effects Metalplates Dielectric C = e A d What makes e different from e0? POLARIZATION e e e = + = 1 0 e c r r In electrostatics, the CONSTITUITIVE RELATION is D E E P e e = = = + Polarization P E 0 0 ce Susceptibility
  • 7.
    Dielectric Effects POLARIZATIONarises from charge shifts in the material— there is a macroscopic separation of positive charge (e.g., the ions) and negative charge (e.g., the BONDING ELECTRONS). Induced DIPOLE MOMENT POLARIZATION is then di = q × x0 There are many sources of dipoles. Amount of charge shift P = Ndipolesdi
  • 8.
    Definitions •Permittivity isa physical quantity that describes how an electric field affects and is affected by a dielectric medium and is determined by the ability of a material to polarize in response to an applied electric field, and thereby to cancel, partially, the field inside the material. Permittivity relates therefore to a material's ability to transmit (or "permit") an electric field…The permittivity of a material is usually given relative to that of vacuum, as a relative permittivity, (also called dielectric constant in some cases)….- Wikipedia Dk Df 'r e " r e
  • 9.
    Permittivity and PermeabilityDefinitions Permittivity (Dielectric Constant) k = e = = - r r r e e je ' " e 0 •interaction of a material in the presence of an external electric field.
  • 10.
    Permittivity and PermeabilityDefinitions Permittivity (Dielectric Constant) k = e = = - r r r e e je ' " e 0 •interaction of a material in the presence of an external electric field. Dk
  • 11.
    Permittivity and PermeabilityDefinitions k = e = = - ' " r r r e e je ' " e 0 •interaction of a material in the presence of an external electric field. m = m = - 0 mr jmr m interaction of a material in the presence of an external magnetic field. Permittivity (Dielectric Constant) Permeability Dk
  • 12.
    Permittivity and PermeabilityDefinitions k = e = = - ' " r r r e e je ' " e 0 •interaction of a material in the presence of an external electric field. m = m = - 0 mr jmr m interaction of a material in the presence of an external magnetic field. Permittivity (Dielectric Constant) Permeability Dk
  • 13.
    STORAGE Electric Magnetic Fields Fields Permittivity Permeability ' " Electromagnetic Field Interaction MUT mr = mr - jmr ' " e r = e r - je r STORAGE
  • 14.
    STORAGE Electric Magnetic Fields Fields LOSS Permittivity Permeability ' " Electromagnetic Field Interaction MUT mr = mr - jmr ' " e r = e r - je r STORAGE LOSS
  • 15.
    Loss Tangent d= e " re ' tan r e r 'r e ''r e Energy Lost perCycle Energy Stored perCycle tand = D = 1 = Q D Dissipation Factor Q Quality Factor Df
  • 16.
    Relaxation Constant t "t = Time required for 1/e of an aligned system to return to equilibrium or random state, in seconds. = 1 = 1 wc pfc t 2 100 1 1 10 Water at 20o C 10 100 f, GHz most energy is lost at 1/t 'r e " r e e w e e e = + - ¥ j wt s+ ¥ 1 Debye equation : ( )
  • 17.
    Dielectric Effects es =e static e ¥ =e optical e 0 ln(w) wLO wP 30-50 meV 10-15 eV visible infrared Major source of POLARIZATION is distortion of the bonding electrons around atoms. This leads to the normal semiconductor dielectric constant. In POLAR materials, like GaAs and SiC, the different charge on the A and B atoms can be polarized as well, leading to a difference between the optical and the static dielectric constants. In Appendix C, the two values for GaAs are reversed!
  • 20.
    Definition: A photoniccrystal is a periodic arrangement of a dielectric material that exhibits strong interaction with light
  • 23.
    Piezoelectric Effect Inmaterials with NO REFLECTION SYMMETRY (like GaAs or many molecular species) the applied electric field produces a DISTORTION OF THE LATTICE (size change) and vice versa. FORCE ELECTRIC FIELD A common piezoelectric is Poly-Vinylidene Flouride, which is used in a variety of stereo headsets. The most common is crystalline quartz used as frequency control crystals—pressure applied to the quartz has a resonance which can be used in a feedback loop to create a highly-stable oscillator—the quartz crystal oscillator.
  • 26.
    Phase sensitive multimeterinterfaced with impendence analyzer for dielectric measurements

Editor's Notes

  • #9 There are lots of different terms in use today to describe electromagnetic properties of materials. And lots of confusion on what they all mean and how they relate to each other. So, in the next few slides, I’ll give a definitions of the terms I will be using and what they mean.
  • #10 Permittivity (e), also called dielectric constant, and sometimes designated by the greek letter Kappa, describes the interaction of a material with an external electric field. Kappa is equivalent to epsilon sub r, and is equal to the absolute permittivity, epsilon, relative to the permittivity of free space, epsilon sub zero. And it is a complex number: epsilon sub r prime minus jay epsilon sub r double prime. Which is quite mouthful! So I will drop the sub R. When I say epsilon or permittivity, you can assume I mean the permittivity relative to free space.
  • #11 To make matters more confusing, the real part of permittivity can also be called dielectric constant or Dk So in an effort to minimize the ambiguity, I will say “the real part of permittivity”.
  • #12 Permeability or mu describes the interaction of a material with an external magnetic field. And it is also a complex number.
  • #13 Both permittivity and permeability are complex but not constant (another reason why the term dielectric constant is ambiguous). Many materials exhibit considerable change over frequency and temperature. Some materials such as iron (ferrites), cobalt, nickel and their alloys have appreciable magnetic properties for which it is valuable to measure permeability; however, many materials are non-magnetic. All materials, on the other hand, have dielectric properties.
  • #14 When electric and magnetic fields pass through a material, each can interact with that material in two ways: First: Storage: Energy may be exchanged between the field and the material, in a bi-directional (lossless) manner This energy storage is represented by the real part of permittivity or permeability.
  • #15 Second Loss: Energy may be permanently lost from the field, and absorbed in the material (usually as heat). This energy loss is represented by the imaginary part of permittivity and permeability.
  • #16 Another term we will talk about, and you will often see on data sheets is loss tangent. This is also called tan delta. When complex permittivity is drawn as a simple vector diagram, the real and imaginary components are 90o out of phase. The vector sum forms an angle delta with the real axis. If we remember our trigonometry, we recall that the tangent of an angle is equal to the side opposite to the angle divided by the side adjacent to the angle. So, in this case, is the imaginary part of permittivity, divided by the real part of permittivity. This is why the term tan delta came about. Loss tangent is also equivalent to the dissipation factor and one over the quality factor. It is a measure of the energy lost relative to the energy stored. The term Df is also commonly used for Dissipation factor. It is no wonder people get confused, all these terms mean the same thing, Loss Tangent, tan delta, Dissipation factor, and Df.
  • #17 Also of interest to many applications involving liquid and polar materials, for example microwave heating, Specific Absorption Rate, chemical processing, etc.. is the relaxation constant or time,  For dipolar dielectrics (such as water),  describes the time required for dipoles to become oriented in an electric field. (Or the time needed for thermal agitation to disorient the dipoles after the electric field is removed.) At low frequencies, the dipole rotation can follow the field easily; ’ will be high and ” will be low. As the frequency increases, the loss factor, ” increases as the dipoles rotate faster and faster. The loss factor ” peaks at the frequency 1/. Here, the dipoles are rotating as fast as they can, and energy is transferred into the material and lost to the field at the fastest possible rate. As the frequency increases further, the dipoles can not follow the rapidly changing field and both ’ and ” fall off.  is one of the terms needed in the Debye equation that is often used to model the theoretical permittivity of polar liquids. This model works very well for water. The other terms are the predicted value of s, the DC or static value of permittivity, and  at infinity.