Battery innovation: Incremental or Disruptive?

Andrew Gelston
Andrew GelstonAnalyst at NextEra Energy Resources
BATTERY INNOVATION: 
INCREMENTAL OR 
DISRUPTIVE? 
ALBERT CHEUNG 
/ / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /
LI-ION BATTERY PACK COST AND PRODUCTION, 2010- 
30 
Total pack cost ($/kWh) Annual production (MWh 
1,200 
1,000 
800 
600 
400 
200 
/ / / / / / 
180 
160 
140 
120 
100 
80 
60 
40 
20 
- 
Source: Bloomberg New Energy Finance 
0 
TODAY’S RANGE: 
$400-1500/KWH 
2010 2012 2014 2016 2018 2020 2022 2024 2026 2028 2030 
Annual battery production (GWh) Battery pack price (2010 $/kWh)
EV LITHIUM ION BATTERY SUPPLY & DEMAND (MWH) 
/ / / / / / 
Source: Bloomberg New Energy Finance 
12,200 
27,900 
33,300 
2,400 
8,800 
16,000 
2011 2012 2013 
Annualized supply capacity 
Declared annual demand
COST IS JUST ONE OBJECTIVE 
/ / / / / / 
COST 
CALENDAR 
LIFE 
ENERGY 
DENSITY 
POWER 
DENSITY 
CYCLE 
LIFE 
IDEAL 
BATTERY 
SAFETY
WHERE WILL GAINS BE MADE? 
Raw/processed 
materials 
Battery 
materials 
/ / / / / / 
Cells 
Packs 
Vehicle 
Integration 
Cost Performance 
Alternative electrodes / electrolytes 
Materials development 
Cell size and format 
Cell design features 
Pack design 
Thermal management 
Pack assembly 
Chassis integration 
LFP, NCM, 
electrolytes, etc. 
Process improvement & scale 
Integration with other vehicle systems
‘INCREMENTAL’ IMPROVEMENT IN CATHODE 
CHEMISTRY 
CATHODE COMPOSITION NCM PROPERTIES 
Current 
NCM 
LCO 
LMO 
Future 
NCM? 
/ / / / / / 
• NCM is one of several cathode types in use 
• Blend of three lithium oxides: 
nickel / cobalt / manganese 
• Major users include Sanyo (Panasonic) and 
GS Yuasa 
• Good energy density 
• Moderate safety (not as stable as LFP) 
Source: Bloomberg New Energy Finance. 
less less more 
Future 
NCM? 
Ni Co Mn
‘INCREMENTAL’ IMPROVEMENTS IN CATHODE 
CHEMISTRY 
CATHODE COMPOSITION LMO AND LCO PROPERTIES 
Current 
NCM 
LCO 
LMO 
Future 
NCM? 
/ / / / / / 
LCO: lithium cobalt oxide 
• Older technology (consumer batteries) 
• Good energy density 
• Poor safety / thermal properties 
LMO: lithium manganese oxide 
• Current technology (eg Nissan, GM, LG Chem) 
• Good safety / thermal properties 
• No expensive cobalt 
• Lower energy density 
Source: Bloomberg New Energy Finance. 
Future 
NCM? 
Ni Co Mn
‘INCREMENTAL’ IMPROVEMENTS IN CATHODE 
CHEMISTRY 
CATHODE COMPOSITION POSSIBLE FUTURE BLENDS OF NCM 
Current 
NCM 
LCO 
LMO 
Future 
NCM? 
/ / / / / / 
Less cobalt? 
• Lower cost 
• Better safety / thermal properties 
• Similar performance 
More nickel? 
• Increases energy density 
More manganese? 
• Potentially much higher energy density and lower 
cost 
• Needs better electrolytes and anode 
• Very early stage Source: Bloomberg New Energy Finance. 
Future 
NCM? 
Ni Co Mn
‘DISRUPTIVE’ CHANGE IN ANODE MATERIALS: SILICON 
• Silicon theoretically absorbs 10x as many Li ions as graphite - much higher E density 
• Historic problem: silicon structures suffer from fatigue/pulverisation after a few cycles 
• Solution: nanostructures / nanowires 
• Axeon claims energy density improvement of 35%, Panasonic claims 20% 
• Panasonic and LG Chem aim to launch Si-anode consumer batteries in 2012-13 
• Only small cell formats being commercialised 
/ / / / / / 
Source: Images from Nexeon.
‘DISRUPTIVE’ CHANGE IN ANODE MATERIALS: SILICON 
/ / / / / / 
Source: Images from Nexeon. 
Carbon anode: 
6C + Li+ + e- ↔ LiC6 
Silicon anode: 
4Si + 15Li+ + 15e- ↔ Li15Si4
MAX CAPACITY OF 18650-FORMAT LI-ION CELLS (AH) 
4.5 
4.0 
3.5 
3.0 
2.5 
2.0 
1.5 
1.0 
0.5 
0.0 
New Si-anode 
1990 1995 2000 2005 2010 2015 
/ / / / / / 
Source: Bloomberg New Energy Finance, Nikkei.
CELL AND PACK DESIGN CHOICES 
NUMBER OF CELLS IN MAIN EV MODELS CONSIDERATIONS 
315 
288 
192 
192 
Tesla Roadster 
BMW Mini-E 
Fisker Karma 
Chevrolet Volt 
Renault Fluence 
Nissan Leaf 
/ / / / / / 
18,650 format (consumer cells, 2-3Ah): 
• Leverages decades of experience 
• Sophisticated management system needed 
• Not as applicable for PHEV 
Larger cells (up to 50Ah): 
• Easier packaging and thermal mgmt 
• Greater potential for improvement with 
experience 
• Second life considerations? 
88 
5,088 
6,831 
Mitsubishi i-MiEV
OTHER AREAS OF INNOVATION 
/ / / / / / 
• Air vs. liquid cooling 
• Small vs. large cells 
• Intra/inter-cell thermal gradients 
• Use of CFD and advanced BMS 
Source: Images from Axeon. 
THERMAL 
MANAGEMENT 
VEHICLE 
INTEGRATION 
• Bespoke vehicle platforms 
• Battery placing and design can 
impact: 
• Handling 
• Safety 
• Cost
CONCLUSIONS 
• There will continue to be innovation at every step of the value chain 
• There are no clear lines between ‘incremental’, ‘step-change’ and ‘disruptive’ 
innovation 
• Innovation is non-linear and the experience curve hides many subtleties 
• There will be winners and losers 
• There are technologies that could ‘re-boot’ the experience curve: 
lithium-air, magnesium-ion, flow batteries, nanotube electrodes, etc... 
/ / / / / /
/ / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /
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Battery innovation: Incremental or Disruptive?

  • 1. BATTERY INNOVATION: INCREMENTAL OR DISRUPTIVE? ALBERT CHEUNG / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /
  • 2. LI-ION BATTERY PACK COST AND PRODUCTION, 2010- 30 Total pack cost ($/kWh) Annual production (MWh 1,200 1,000 800 600 400 200 / / / / / / 180 160 140 120 100 80 60 40 20 - Source: Bloomberg New Energy Finance 0 TODAY’S RANGE: $400-1500/KWH 2010 2012 2014 2016 2018 2020 2022 2024 2026 2028 2030 Annual battery production (GWh) Battery pack price (2010 $/kWh)
  • 3. EV LITHIUM ION BATTERY SUPPLY & DEMAND (MWH) / / / / / / Source: Bloomberg New Energy Finance 12,200 27,900 33,300 2,400 8,800 16,000 2011 2012 2013 Annualized supply capacity Declared annual demand
  • 4. COST IS JUST ONE OBJECTIVE / / / / / / COST CALENDAR LIFE ENERGY DENSITY POWER DENSITY CYCLE LIFE IDEAL BATTERY SAFETY
  • 5. WHERE WILL GAINS BE MADE? Raw/processed materials Battery materials / / / / / / Cells Packs Vehicle Integration Cost Performance Alternative electrodes / electrolytes Materials development Cell size and format Cell design features Pack design Thermal management Pack assembly Chassis integration LFP, NCM, electrolytes, etc. Process improvement & scale Integration with other vehicle systems
  • 6. ‘INCREMENTAL’ IMPROVEMENT IN CATHODE CHEMISTRY CATHODE COMPOSITION NCM PROPERTIES Current NCM LCO LMO Future NCM? / / / / / / • NCM is one of several cathode types in use • Blend of three lithium oxides: nickel / cobalt / manganese • Major users include Sanyo (Panasonic) and GS Yuasa • Good energy density • Moderate safety (not as stable as LFP) Source: Bloomberg New Energy Finance. less less more Future NCM? Ni Co Mn
  • 7. ‘INCREMENTAL’ IMPROVEMENTS IN CATHODE CHEMISTRY CATHODE COMPOSITION LMO AND LCO PROPERTIES Current NCM LCO LMO Future NCM? / / / / / / LCO: lithium cobalt oxide • Older technology (consumer batteries) • Good energy density • Poor safety / thermal properties LMO: lithium manganese oxide • Current technology (eg Nissan, GM, LG Chem) • Good safety / thermal properties • No expensive cobalt • Lower energy density Source: Bloomberg New Energy Finance. Future NCM? Ni Co Mn
  • 8. ‘INCREMENTAL’ IMPROVEMENTS IN CATHODE CHEMISTRY CATHODE COMPOSITION POSSIBLE FUTURE BLENDS OF NCM Current NCM LCO LMO Future NCM? / / / / / / Less cobalt? • Lower cost • Better safety / thermal properties • Similar performance More nickel? • Increases energy density More manganese? • Potentially much higher energy density and lower cost • Needs better electrolytes and anode • Very early stage Source: Bloomberg New Energy Finance. Future NCM? Ni Co Mn
  • 9. ‘DISRUPTIVE’ CHANGE IN ANODE MATERIALS: SILICON • Silicon theoretically absorbs 10x as many Li ions as graphite - much higher E density • Historic problem: silicon structures suffer from fatigue/pulverisation after a few cycles • Solution: nanostructures / nanowires • Axeon claims energy density improvement of 35%, Panasonic claims 20% • Panasonic and LG Chem aim to launch Si-anode consumer batteries in 2012-13 • Only small cell formats being commercialised / / / / / / Source: Images from Nexeon.
  • 10. ‘DISRUPTIVE’ CHANGE IN ANODE MATERIALS: SILICON / / / / / / Source: Images from Nexeon. Carbon anode: 6C + Li+ + e- ↔ LiC6 Silicon anode: 4Si + 15Li+ + 15e- ↔ Li15Si4
  • 11. MAX CAPACITY OF 18650-FORMAT LI-ION CELLS (AH) 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 New Si-anode 1990 1995 2000 2005 2010 2015 / / / / / / Source: Bloomberg New Energy Finance, Nikkei.
  • 12. CELL AND PACK DESIGN CHOICES NUMBER OF CELLS IN MAIN EV MODELS CONSIDERATIONS 315 288 192 192 Tesla Roadster BMW Mini-E Fisker Karma Chevrolet Volt Renault Fluence Nissan Leaf / / / / / / 18,650 format (consumer cells, 2-3Ah): • Leverages decades of experience • Sophisticated management system needed • Not as applicable for PHEV Larger cells (up to 50Ah): • Easier packaging and thermal mgmt • Greater potential for improvement with experience • Second life considerations? 88 5,088 6,831 Mitsubishi i-MiEV
  • 13. OTHER AREAS OF INNOVATION / / / / / / • Air vs. liquid cooling • Small vs. large cells • Intra/inter-cell thermal gradients • Use of CFD and advanced BMS Source: Images from Axeon. THERMAL MANAGEMENT VEHICLE INTEGRATION • Bespoke vehicle platforms • Battery placing and design can impact: • Handling • Safety • Cost
  • 14. CONCLUSIONS • There will continue to be innovation at every step of the value chain • There are no clear lines between ‘incremental’, ‘step-change’ and ‘disruptive’ innovation • Innovation is non-linear and the experience curve hides many subtleties • There will be winners and losers • There are technologies that could ‘re-boot’ the experience curve: lithium-air, magnesium-ion, flow batteries, nanotube electrodes, etc... / / / / / /
  • 15. / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /